This paper deals with reflection spectra and polarized reflection spectra of 20 sorts of rock in 2π space, and then creates a model of reflection spectra of rock surface in 2π space. We measured the change of reflection and polarized reflection spectra as altering the incidence angle, vertex angle, azimuth angle, band and polarization. The results show that influence of the incidence angle on spectral curves is very strong. And when the vertex angle is constant, the horizontal azimuth polarizes rock spectra, and distorts the circular spectrum to become elliptic. The polarization influences the reflection intensity of rock spectra, but has no evident influence on the characteristics of wave forms of rock in 2π space. Therefore, we can describe the whole reflection spectral characteristics, including polarization, of rock surface in 2π space by measuring and calculating the e and p values in several key directions.