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YAN Zhen, HE Pingxian, FU Changlei, CHEN Hui, JIA Jianliang, XIANG Zhongjin, MA Xiaolin, MENG Xianglun, JIANG Sha
2026,100(2):363-386, DOI: 10.19762/j.cnki.dizhixuebao.2025268
Abstract:
The Guixi basin, one of the most important manganese ore concentration areas in China, is characterized by multiphase mineralization across multiple stratigraphic units, predominantly as marine sedimentary manganese deposits. The basin comprises a succession of terrigenous clastic rocks deposited in coastal tidal flat- lagoon environments during the earliest Devonian, shallow marine carbonates from the late Early Devonian to the Early Triassic, and Middle Triassic bathyal- abyssal sandy and argillaceous flysch, accompanied by episodic submarine volcanism. This sedimentary succession records the multi- stage tectonic and paleogeographic evolution. The deposition of manganese carbonate ore beds was controlled by sedimentary paleogeographic conditions, primarily localizing in subtidal settings of coastal to shallow marine environments characterized by high hydrodynamic energy, relatively oxic conditions, and connectivity with open marine waters. Manganese mineralization concentrated in specific sedimentary facies transitional zones where high- energy subtidal environments graded into low- energy settings, exhibiting distinct episodic periodicity. The three main metallogenic episodes, the late Late Devonian, late Early Carboniferous, and early Early Triassic, correspond to key geological periods of marine regression in the Guixi basin. Although all manganese mineralization occurred within the same marine basin, the centers of ore accumulation did not spatially coincide. Instead, they migrated systematically in response to evolving paleogeographic patterns and shifting sediment supply regimes. Lithofacies associations and the spatiotemporal evolution of sedimentary facies are key factors controlling the formation and distribution of manganese carbonate ores. A siliceous- argillaceous- carbonate assemblage constitutes the typical lithofacies signature of the Guixi manganese deposits, with manganese ore bodies hosted predominantly in the upper section, often near the top, of a bimodal facies sequence characterized by lower chert and upper argillaceous- to- siliceous limestone.
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XIANG Zhongjin, YAN Zhen, JIA Jianliang, FU Changlei, LI Rongzhi, YAN Quanren
2026,100(2):387-405, DOI: 10.19762/j.cnki.dizhixuebao.2025311
Abstract:
The Permian- Triassic igneous rocks exposed along the southern margin of the Nanpanjiang basin provide an important record of Late Paleozoic- Early Mesozoic regional tectonic evolution. As southwestern Guangxi is a key manganese and bauxite resource region in China, the genetic link between magmatism and mineralization has attracted increasing research attention. This study summarizes the rock assemblages, geochemical and isotopic signatures of these igneous rocks, and discusses their sources, petrogenesis, and relationship with manganese and bauxite metallogenesis. The magmatism occurred in three phases: Late Permian (~260 Ma), Early- Middle Triassic (250~241 Ma) and Late Triassic (~215 Ma). Among these, the Late Permian and Late Triassic are dominanted by the basic intrusive rocks and basalts, whereas the Early- Middle Triassic consists of intermediate- basic and acidic volcanic rocks with minor diorite. The Late Permian basic rocks are divided into high- Ti and low- Ti groups, with the high- Ti group (>2. 5%) being dominant. The high- Ti group belongs to the alkaline series, enriched in light rare earth elements (LREEs), large ion lithophile elements (LILEs) and high field strength elements (HFSEs). They have low (87Sr/86Sr)i values (0. 7053~0. 7054) and εNd(t) values close to 0 (1. 5~+1. 8), similar to OIB, and are derived from the partial melting of asthenospheric mantle. The low- Ti group belongs to the tholeiitic series, enriched in LILEs, with negative Nb- Ta anomalies and εHf(t) values less than 0, originating from the partial melting of ancient lithospheric mantle. The Early- Middle Triassic intermediate- basic volcanic rocks have SiO2 contents ranging from 53% to 60%, with high MgO (>5%), Cr and Ni, which are similar to the geochemical characteristics of high- Mg andesite/diorite. They are enriched in LILEs, with high Y, low Sr/Y and (La/Yb)N ratios, relatively large variations in (87Sr/86Sr)i values (0. 7065~0. 7119), and relatively uniform Nd- Hf isotopic compositions (εNd(t)=8. 8~6. 5 and εHf(t)=5. 3~2. 4). They are derived from the partial melting of lithospheric mantle metasomatized by subducted slab sediment melts (and fluids). The Early- Middle Triassic acidic volcanic rocks belong to peraluminous high- K calc- alkaline rocks, with high SiO2 content, low MgO and MnO contents, significant negative Nb- Ta anomalies, high (87Sr/86Sr)i ratios and low εNd(t) values (11. 5~9. 1), showing the characteristics of island arc volcanic rocks. The Late Triassic low- Ti basic intrusive rocks generally have low TiO2 content (<1. 5%), belonging to the tholeiitic basalt series. They are enriched in LILEs, with obvious negative Nb- Ta anomalies, and a large range of variations in (87Sr/86Sr)i values (0. 7068~0. 7090) and εNd(t) values (1. 7~8. 5). They are formed by the interaction between the partial melting of enriched lithospheric mantle and asthenospheric mantle melts. Overall, Late Permian and Early- Middle Triassic magmatism coincides with bauxite and manganese metallogenesis, respectively. The Late Permian low- Ti basic rocks and Early- Middle Triassic volcanic rocks likely supplied key material for metallogenesis.
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MENG Xianglun, XU Haipeng, LOU Debo, YIN Benchun, YAO Shuangqiu, QIN Feng, YING Xin, DONG Jianhui, FU Jizhuo, WANG Kailang, LI Jialong, AN Pengxin
2026,100(2):406-424, DOI: 10.19762/j.cnki.dizhixuebao.2025287
Abstract:
Western Guangxi constitutes an important bauxite metallogenic belt and resource base in China. Based on existing geological surveys and exploration research, this paper systematically summarizes the geological characteristics of typical paleokarst- type bauxite deposits in the area. This includes their spatiotemporal distribution, material sources, sedimentary environment, ore- controlling factors, metallogenic models, and indicative mineralization information. Furthermore, a prospecting prediction is conducted using the random forest algorithm to guide for future prospecting work. These paleokarst- type bauxite deposits formed during the late Permian Wuchiapingian and are hosted in the basal bauxite- bearing interval of the upper Permian Heshan Formation, which overlies a paleoweathering surface of the Maokou Formation. The typical stratigraphic sequence, from bottom to top, is “iron- bauxite- mud (coal).” Potential ore- forming materials are multi- sourced, including Permian volcanic island arc ash, weathered products of basement limestone, and terrigenous clastics from the Daxin Paleo- uplift. The mineralization process coincided with rapid transgression within an overall marine to marine- continental transitional environment. The platform back- reef tidal flat- lagoons surrounding the Daxin Paleo- uplift constituted the optimal setting for bauxite formation. Based on the random forest algorithm, this paper deeply explores the spatial distribution characteristics of ore- hosting strata, lithofacies paleogeography, geochemical and aeromagnetic anomalies, and remote sensing data, examining their spatial coupling with bauxite deposits and the correlations between different ore- controlling factors. A two- dimensional bauxite resource prediction and classification model is constructed, and combined with regional mineral inspection, 18 prospecting target areas for further exploration are delineated.
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CHEN Heqi, CHAO Wendi, ZHANG Zhenfu, NIU Sida, WANG Huaqing, QUAN Xiaoqin, YANG Yufan
2026,100(2):425-446, DOI: 10.19762/j.cnki.dizhixuebao.2025148
Abstract:
The western Tianshan, situated on the southwestern margin of the Central Asian Orogenic Belt, underwent a tectonic evolution associated with the South Tianshan Ocean—a branch of the Paleo- Asian Ocean. This region hosts a series of Devonian marine sedimentary manganese deposits. Based on field investigations, this paper examines the mineralogical and geochemical characteristics of four Devonian manganese deposits in the western Tianshan: the Bosuoguoshan manganese deposit, Guoergou Fe- Mn deposit, Kalanggou Mn deposit, and Xiawengxi Fe- Mn deposit, using petrographic observation, electron probe microanalysis (EPMA), and major and trace element geochemical analyses. The research results reveal that the manganese mineralization is mainly composed of oxides (manganosite, pyrolusite, romanèchite, hausmannite, birnessite, braunite, todorokite, cryptomelane, hollandite, and jacobsite), carbonates (rhodochrosite and manganese- bearing calcite), and silicates (rhodonite, spessartine, tephroite, bementite, caryopilite, alleghanyite, and manganoan phlogopite). MnO contents in the manganese oxide minerals range from 30. 9% to 83. 2%. Within the manganese carbonates, rhodochrosite exhibits average molar ratios of MnCO3/(MnCO3+MgCO3+CaCO3)=0. 92 and MgCO3/CaCO3=0. 17. The Bosuoguoshan manganese ores exhibit a depleted rare earth element (REE) pattern, consistent with passive continental margin signatures. In contrast, the Guoergou manganese ores display an enriched REE pattern with prominent Eu and Ce anomalies, characteristic of an active continental margin setting. The lgU- lgTh and Fe/Ti versus Al/(Al+Fe+Mn) diagrams collectively indicate a primary hydrothermal origin for the manganese mineralization. MnO- SiO2 scatter plots reveal that these deposits universally underwent high- energy reworking processes. Combined with the analysis of the regional tectonic evolution, we propose that the Devonian manganese deposits of the western Tianshan formed in a locally extensional environment on a continental margin related to the subduction of the South Tianshan Ocean. The mineralization was primarily sourced from endogenic processes, including submarine hydrothermal activity and volcanism. Small marginal oceanic basins such as Jigen, Kuokesaleling, Tieliemaiti, and Erbin exhibit significant potential for future manganese exploration.
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XU Hai, YIN Runsheng, GAO Junbo, YANG Ruidong, YANG Chenchen, ZHAI Mengdi, ZHAO Yinqiang
2026,100(2):447-468, DOI: 10.19762/j.cnki.dizhixuebao.2025144
Abstract:
Sedimentary manganese (Mn) carbonate ores are an important type of Mn deposit, and serve as a critical carrier for investigating the redox state of Earth' s surficial system. The precipitation mechanism, metallogenic process and paleoenvironment reconstruction of sedimentary Mn carbonate deposit are key issues of concern to geologists. In this study, we investigated petrographic, geochemical and C isotopic characteristics of Permian the Zunyi Mn carbonate deposit, to explores the material source, precipitation mechanism, metallogenic environment, and control factors. The Zunyi Mn deposit developed hydrothermal brecciated Mn ores crosscut by Mn- bearing calcite veins, and numerous hydrothermal origin minerals (e.g., chalcopyrite, siegenite, and molybdenite, etc.) were observed in Mn ores. Combined with the element ratio of the authigenic carbonate for Mn ores (e.g. , Fe/Ti, Ni/Co, and Cu/Zn ratios), REY differentiation characteristics, and genesis diagrams reveal that the ore- forming materials originated from the volcanism related hydrothermal activities during the late stage of Middle Permian. The preserved original Fe- Mn oxide residues within Mn carbonate minerals, coupled with Mn ores exhibit high REY concentration (mean 143. 6×10-6) and negative δ13Ccarb value (mean 6. 20‰), and δ13Ccarb value is negatively correlated with MnO content (R2=0. 51) and positively correlated with CaO+MgO content (R2=0. 52), suggesting that Mn carbonates were formed via the diagenetic reduction of Mn oxides. Lithofacies, sedimentary sequences, and redox indicators (e.g., MoEF, UEF, and Ce anomalies) indicate that the basin water column shifted from euxinic- anoxic to suboxic- oxic conditions during Mn precipitation. Integrating the global/regional paleotectonic, paleogeographic and paleoceanic evolution, the Zunyi Mn deposits are product of the combined effects of the coeval paleotectonic- magmatic- hydrothermal activities, paleogeographic, and paleoceanic environmental evolution. The ELIP uplift caused the formation of the Qianzhong rift basin and the rift systems and magmatic- hydrothermal activities within the basin, provided the essential material source, migration channel, and precipitation site for Mn mineralization. The formation of the redox stratified water column within the basin provides the necessary conditions for the initial enrichment of Mn (Ⅱ). The dual effects of the sustained ELIP uplift and large- scale regression driven the bottom water column shift from anoxic to suboxic- oxic conditions, triggering large- scale Mn (Ⅳ) oxides precipitation, and subsequently transformed into Mn carbonates via diagenetic reduction.
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LIANG Rongrong, ZHANG Tongyi, HU Zhaoguo, ZHANG Baotao, LIU Sen, LIU Xuefei
2026,100(2):469-483, DOI: 10.19762/j.cnki.dizhixuebao.2025382
Abstract:
Since the Paleozoic, different tectonic plates around the world have formed abundant karst bauxite deposits at varying times. Their complex genesis preserves not only paleoclimatic signatures but also records important geological events, including plate tectonic evolution. Detrital rutile, a refractory accessory mineral in karst bauxite, possesses high chemical stability and records key tectonic events throughout geological history. Based on trace element geochemistry and U- Pb geochronology of rutile from 23 karst bauxite deposits in the North China craton and South China block, this study systematically explores genetic types and their links to supercontinent evolution. Results show that rutile in Chinese karst bauxite of different ages is mainly metamorphic in origin, though their formation conditions differ. Rutile in the Late Carboniferous bauxite of the North China craton records relatively high metamorphic temperatures (granulite facies), while rutile from bauxite in the South China block records lower temperatures (amphibolite to granulite facies). The Late Carboniferous bauxite in the North China craton contains abundant metamorphic rutile associated with the assembly of the Nuna supercontinent, revealing that the North China craton was widely involved in Nuna assembly, and the resulting metamorphic suites served as the provenance for Carboniferous bauxite deposits. Rutile formed during the breakup of Rodinia and the assembly of Gondwana is generally recorded in bauxites of different periods from the South China block, indicating its deep involvement in these two stages of supercontinent evolution. The metamorphic rocks formed during these events provided key material for bauxite genesis in the South China block. This study reveals that detrital rutile in bauxite not only constrains the provenance of bauxite but also preserves a record of plate tectonic evolution, providing a new perspective for exploring global tectonic history.
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CHEN Xu, TIAN Yuming, GAO Baolong, WANG Zhe, WANG Huaqing, HUANG Fei, LIU Dongsheng, XIAO Dechang
2026,100(2):484-509, DOI: 10.19762/j.cnki.dizhixuebao.2025474
Abstract:
Manganese carbonate ore samples from Nanhua System deposits (Hunan- Guizhou region) were collected from mining tunnels and drill cores for analysis by SEM, TEM, and XPS. Analytical results indicate pervasive replacement of manganese oxide by manganese carbonate within the ore, with both minerals forming multilayered, micrometer- scale microfossils that make up the bulk of the ore layers. Based on microstructural observations, the discovery of microfossils within manganese layers and nodules, and previous experimental simulations of microbial metabolism, this study analyzes the mechanisms by which microbial physiology controlled manganese deposition. The findings confirm that biochemical processes were fundamental to large- scale manganese mineralization. The marine sedimentary manganese deposits of the Nanhua System occur within the lower member of the Datangpo Formation in the Hunan- Guizhou- Chongqing region. The manganese ore layers across all mining districts consist of crystalline aggregates of rhodochrosite hosted within microbial fossils. During the metallogenic period, cyanobacteria- dominated microbial mat ecosystems proliferated extensively in the bottom- water environments of the South China Ocean shelf. Within these mats, cyanobacteria interacted with aerobic heterotrophic bacteria (AHB) and sulfate- reducing bacteria (SRB) through mutualistic symbiosis, controlling manganese precipitation and the transformation of manganese oxides to carbonates. Suspended mineral particles were either adsorbed onto surface sites of living microorganisms or self- aggregated within the spaces of autolytic dead cells. Manganese fluxes in seawater influenced microbial mats to deposit industrial- grade rhodochrosite ore layers intercalated with black shales. This study reveals that the biological activities through which microbial mats promoted the precipitation and transformation of manganese minerals were essentially survival mechanisms: ① analogous to modern manganese nodules, heterotrophic bacteria actively precipitate manganese oxides through enzymatic reactions while passively reducing manganese oxides through the metabolic byproducts of organic matter degradation; ② cyanobacteria actively regulated EPS microenvironments to maintain weakly alkaline and weakly reducing conditions while enhancing Mn2+ concentrations through heterotroph regulation, thereby enabling continuous passive precipitation of manganese carbonate minerals; ③ manganese carbonates and oxides precipitate simultaneously outside microbial cells, meaning deposition capacity is not constrained by the rate or capacity of cellular manganese absorption, enabling the transformation of abundant manganese supplies into massive mineral deposits; ④ the microbial life cycle represents a “pulsed” deposition cycle of manganese carbonates and oxides, where generational growth causes manganese minerals to stack layer upon layer, forming characteristic micrometer- scale mineral structures. This work establishes a biochemical “exogenic mineralization model” for marine sedimentary manganese deposits of the Nanhua System, advancing the “Endogenous Origin and Exogenous Mineralization” metallogenic theory of manganese.
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QIN Feng, HUANG Shicai, WU Xiangke, XU Haipeng, MENG Xianglun
2026,100(2):510-523, DOI: 10.19762/j.cnki.dizhixuebao.2025157
Abstract:
Bauxite deposits are an important source of critical metals. This study focuses on the deposits within the Upper Permian Heshan Formation (P3h) in western Guangxi, a major bauxite- producing region in China. By analyzing the critical metals in this aluminum- bearing rock series, we aim to provide a framework for the comprehensive exploration, evaluation, and utilization of these resources. Based on the latest exploration results, this study: summarizes the planar distribution of associated critical metals across deposits; provides a detailed analysis of the aluminum- bearing rock series; investigates the vertical enrichment patterns of critical metals in the profile; and elucidates the sources of the metallogenic materials. The results demonstrate significant enrichment of critical metals (Ga, Li, Nb) and rare earth elements (REE) in the Heshan Formation. These critical metals are mainly enriched in two zones: the bauxite ore layers in the middle of the sequence and the ferruginous- aluminous rocks in the lower part. The aluminum- bearing rock series and the critical metals have a polygenetic origin. We propose a dual- source model where material was derived from both the underlying basement strata and from intermediate- to- felsic volcanic rocks derived from the Late Permian volcanic island arc.
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TANG Molan, FAN Bolun, YAO Shuangqiu, LU Guanghui
2026,100(2):524-536, DOI: 10.19762/j.cnki.dizhixuebao.2025298
Abstract:
Long- standing controversies regarding the provenance of ore- forming materials, the paleo- sedimentary environments, and the metallogenesis of sedimentary bauxite in western Guangxi have restricted a deeper understanding of their formation mechanisms and constrained targeted exploration efforts. In this study, we performed a systematic geochemical analysis of major and trace elements within the ore- bearing sequence from the Naduan mining area, Pinguo. The geochemical data reveal significant negative correlations of Al2O3 with Fe2O3 and SiO2, alongside a strong positive correlation with TiO2; these patterns indicate the depletion of iron and silica coupled with the residual enrichment of aluminum and titanium during the bauxitization process. Furthermore, low Si/Al ratios and high chemical index of alteration (CIA) values reflect a warm, humid paleoclimate characterized by intense chemical weathering and leaching. Trace element signatures suggest a freshwater depositional environment within a terrestrial to marine- terrestrial transitional facies, occurring under redox conditions ranging from oxic to suboxic. Building on this evidence, this paper proposes a three- stage metallogenic model for the Naduan sedimentary bauxite deposit: formation of the host basin, accumulation of precursor materials, and mineralization during marine transgression. In this model, the ore- forming materials were predominantly derived from island arc- related acidic volcanic ash. Within a transitional marine- terrestrial setting, these precursors underwent intense weathering, leaching, and hydrodynamic processes (e.g., tidal sorting) that ultimately led to the enrichment of bauxite. This study provides new geochemical evidence for understanding the metallogenic evolution of sedimentary bauxite in the Pinguo region and serves as a valuable reference for investigating the regional genesis of such deposits throughout western Guangxi.
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GUO Ningning, GAO Zhaofu, JIA Jianliang, YAN Zhen, XIANG Zhongjin, MA Qing, WANG Da, ZHU Xiangkun
2026,100(2):537-552, DOI: 10.19762/j.cnki.dizhixuebao.2025249
Abstract:
The Xialei manganese deposit in Guangxi is the most important super- large sedimentary manganese deposit of the Late Devonian in South China. There are two different views on the genetic mechanism of its typical manganese carbonate ores: one is oxidation precipitation- diagenetic transformation, and the other is direct precipitation in a reduced environment. Based on previous studies, this paper systematically analyzes the mineral paragenetic association, major and trace (rare earth) elements, and C- O isotope geochemical characteristics of typical rocks and ores in the Xialei manganese deposit, revealing the synergistic control of ore- forming material sources and redox conditions on manganese ores of different grades. In the low- grade manganese ores (MnO<25%) of the Xialei manganese deposit, rhodochrosite develops heteronuclear structures and is paragenetic with microcrystalline pyrite, indicating a direct precipitation process in a reduced (sulfidic) water environment. Meanwhile, their geochemical characteristics,including high Fe/Mn ratios, significant positive Eu anomalies (average δEu=1. 32), relatively concentrated and generally slightly positive δCe values (ranging from 0. 94 to 1. 30, with an average of 1. 12), and relatively negative δ13C values (average=5. 05‰), collectively indicate that the low- grade manganese ores are products of direct precipitation, where hydrothermal Mn2+ in deep water directly combines with dissolved CO2-3 in the sub- deep reduced water environment. In contrast, the high- grade manganese ores (MnO≥25%) exhibit systematic geochemical differences, such as insignificant positive Eu anomalies (average δEu=1. 11), significantly expanded variation range of δCe values (0. 81~1. 64), low Fe/Mn ratios, and more negative δ13C values (average=7. 72‰). Combined with evidence of residual manganese oxides reported in previous studies, it is indicated that the high- grade manganese ores underwent a phase transition process of “oxide precipitation→organic matter- driven reduction” after sufficient mixing of hydrothermal fluids and seawater. In conclusion, the formation of manganese carbonate ores with different grades in the super- large Xialei manganese deposit in Guangxi involves two distinct metallogenic mechanisms, which are jointly controlled by hydrothermal activities and the redox (sulfidic) stratified water environment. This may be genetically related to the contemporaneous intracontinental rifting- magmatic hydrothermal events and mass extinction events.
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HOU Siyuan, ZUO Pengfei, ZHANG Huiming, LIU Xuefei
2026,100(2):553-568, DOI: 10.19762/j.cnki.dizhixuebao.2025203
Abstract:
The North China Craton hosts extensive Late Carboniferous karst- type bauxite deposits; however, the mechanisms governing their spatial differentiation and the genetic relationships between bauxite and claystone remain controversial. This study investigates the Nangoucun deposit in the Gongyi area of western Henan Province, integrating multi- scale mineralogical analyses and paleoenvironmental reconstruction to elucidate the metallogenic evolution of these bauxite (clay) deposits. Field investigations reveal a characteristic karst- type bauxite sequence, which consists, from bottom to top, of a ferruginous weathering crust, ferruginous clay rock, and aluminous clay rock/bauxite. Results from X- ray diffraction (XRD) and electron probe microanalysis (EPMA) indicate that the bauxite (clay) deposits are predominantly composed of kaolinite, illite, goethite, hematite, anatase, rutile, and quartz. Stratigraphic variations in alkaline- environment indicators (e.g., illite, diaspore, chlorite) and acidic- environment indicators (e.g., kaolinite) across different layers collectively suggest a complex spatiotemporal evolution involving weathering, transportation, mineralization, and reworking. Notably, diaspore in oolitic bauxite is preserved only as micron- scale oolitic relics, with widespread kaolinization observed throughout mineral assemblages. This layer is also enriched in cubic hematite and weathering- resistant anatase. These features collectively indicate intense supergene weathering and acidic leaching, which drove the selective dissolution of primary aluminum hydroxides and the subsequent transformation of clay minerals. These findings therefore provide critical mineralogical insights into deciphering the multi- stage phase transformation mechanisms of aluminosilicates within paleokarst systems.
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SUN Kai, ZHANG Qizuan, SUN Hongwei, REN Junping, LU Yiguan, HE Shengfei, ZHANG Hang
2026,100(2):569-583, DOI: 10.19762/j.cnki.dizhixuebao.2025170
Abstract:
Manganese ore, a strategic mineral resource, exhibits a close genetic relationship with the co- evolution of Earth' s multi- sphere systems. This paper systematically reviews the genetic types, spatiotemporal distribution characteristics, and genesis mechanisms of global manganese deposits,focusing on elucidating the metallogeny of marine sedimentary deposits and their coupling with Earth' s redox history. Studies indicate that global manganese mineralization predominantly occurred during the Proterozoic and Phanerozoic eons. Paleoproterozoic manganese deposits correlate temporally with supercontinent cycles and atmospheric oxygenation events, while Phanerozoic manganese mineralization is associated with oceanic anoxic events and biological extinction episodes. Through detailed analysis of representative global deposits, such as the Longtou and Xilimiao deposits in China, the Bikkulovskoe deposits in Russia, and the Kalahari and Postmasburg fields in South Africa, this research reveals multi- sphere collaborative ore- controlling mechanisms, providing a theoretical foundation for manganese exploration and resource prediction.
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LU Yiguan, ZHANG Qizuan, ZENG Wei, LI Zhidan, CHEN Yin, ZHANG Feng, LIU Xijun, LU Guanghui, XU Haipeng, PANG Chongjin, LI Jianye, MENG Xianglun
2026,100(2):584-597, DOI: 10.19762/j.cnki.dizhixuebao.2025419
Abstract:
As the mostwidely produced metal after steel, aluminum is primarily sourced from bauxite. Based on bedrock types, bauxite deposits are classified into two main types: lateritic and karstic. The former represents the predominant bauxite mineralization type globally, accounting for 88% of total resources, while the latter is the primary bauxite mineralization type in China, constituting 95% of the national resource base. This paper summarizes research progress on bauxite in China, focusing on deposit distribution, metallogenic epochs, provenance, and genetic models. Since the implementation of recent prospecting breakthrough initiatives, continuous discoveries have been made in Shanxi, Guangxi, Guizhou, Henan, and other regions, cumulatively adding hundreds of millions of tons of bauxite resources. As the preferred target for expanding bauxite reserves in China, future efforts should address key issues such as the relationship between bauxite genesis and major geological events, the genetic mechanisms of diaspore, and the potential of associated critical metals. Additionally, research on aluminosilicate weathering and precipitation- related mineralization should be strengthened.
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WANG Huaqing, JIANG Sha, CHEN Jiahao, CHEN Heqi, XIONG Yunping, ZHOU Shangguo, LI Rongzhi
2026,100(2):598-613, DOI: 10.19762/j.cnki.dizhixuebao.2025491
Abstract:
As a key metal indispensable to modern industry, manganese plays a significant role in steel metallurgy, new energy batteries, the chemical industry, and other fields. As a major steel producer and a country experiencing rapid development in the new energy sector, China' s stable supply of manganese resources is of great significance to national economic security and industrial upgrading. Over the past decade, breakthrough progress has been made in manganese exploration in important metallogenic belts in China, such as the Nanhua System, Sinian System, Cambrian System, Ordovician System, Devonian System, Carboniferous System, Permian System and Triassic System. The newly added manganese resource reserves since 2021 have increased by 2.8% compared to the end of 2020. However, China' s current manganese resource reserves remain insufficient, and efforts to increase reserves and production still need to be continuously advanced. Based on a systematic analysis of the global manganese resource landscape, this paper summarizes the main progress in manganese exploration in China over the past decade, along with relevant exploration theories, methods, and technological achievements. Building on this, suggestions are proposed for future manganese exploration efforts.
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ZHAO Lihua, LIU Xuefei, WANG Qingfei, LIU Lei, SUN Xuefei, ZHAO Jun, YANG Shujuan, LIANG Rongrong, ZHANG Shangqing
2026,100(2):614-632, DOI: 10.19762/j.cnki.dizhixuebao.2025293
Abstract:
Karstic bauxite is formed from allochthonous materials that accumulated in paleokarst depressions and underwent intensive chemical weathering. The North China Craton (NCC) hosts over 5 billion tons of karstic bauxite deposits formed during the Late Carboniferous, making it the world' s largest karstic bauxite metallogenic belt. This paper systematically reviews the research progress, existing problems, and main future research directions of karstic bauxite in the NCC, aiming to contribute to a global theoretical framework for the genesis of analogous deposits. Key research progress includes: ① The scale and quality of bauxite are strictly controlled by the paleokarst landform and paleo- environmental conditions. Vast continental karst plains provide ideal sites for the formation of high- quality, large- scale bauxite. ② The provenance of parent rocks exhibits allochthonous and multi- source characteristics with significant spatial variability. The bauxite deposits in the northern part of the NCC are derived mainly from igneous and metamorphic rocks of the Bainaimiao Arc Terrane, the uplift on the northern margin of the NCC, and the Central Orogenic Belt. The bauxite in the southern part of the NCC originates primarily from igneous and metamorphic rocks of the North Qinling Orogenic Belt and Central Orogenic Belt. The bauxite in the central part of the NCC has the characteristics of a mixed source of both. ③ A mechanism for the surface crystallization of diaspore mediated by iron- aluminum solid solutions has been proposed, challenging the traditional understanding of surface weathering and subsequent diagenetic modification. ④ Large- scale Late Carboniferous volcanic activity along the northern margin of the NCC was a key factor driving the short- term and large- scale formation of these bauxite deposits. Existing problems and research directions include: ① The complexity of parent rocks for massive bauxite deposits. The provenance of karstic bauxite is temporally and spatially variable; thus, research on source rock composition and sediment supply dynamics in the NCC requires strengthening. ② The complex metallogenic environments and sedimentation mechanisms of bauxite. Formation environments of karstic bauxite vary greatly, extending from continental to marine and from sub- oxic to reducing conditions. Comparative studies on the surface precipitation mechanism of diaspore under these varying conditions are needed, and the newly mentioned Fe- Al solid solution- mediated mechanism still needs to be verified through experimental means. ③ The comprehensive utilization of associated resources in bauxite. Karst bauxite is accompanied by a large amount of mineral resources, such as REE, Li, Ga, and Sc. However, the research on their distribution and occurrence in bauxite remains limited, which restricts the efficient utilization of these ores.
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GUO Xinlian, CAI Weimin, LU Yiguan, REN Junping, SUN Kai, ZHANG Qizuan
2026,100(2):633-656, DOI: 10.19762/j.cnki.dizhixuebao.2025232
Abstract:
Manganeseis currently classified as a strategic metal by many countries; consequently, understanding its geochemical behavior, distribution patterns, and metallogenic mechanisms is crucial for resource exploration and industrial applications. This paper systematically summarizes the geochemical characteristics, deposit types, metallogenic models, and resource potential of manganese, and explores the spatial distribution patterns and typical geological features of global manganese deposits. The multivalent nature of manganese (Mn2+/Mn3+/Mn4+) is discussed in detail, highlighting that its mobility and precipitation are controlled by redox conditions, pH, and temperature. Global manganese deposits are classified into four main types: marine sedimentary (including BIF- type, black shale- hosted, and carbonate- hosted deposits), supergene, ferromanganese nodule, and ferromanganese crust. Focusing on typical global manganese deposits (such as the Kalahari Manganese Field in South Africa, the Peri- Tethyan manganese district in the Black Sea region, and the Gaodi manganese deposit in China), the geological setting, genesis, and geochemistry of each type are further summarized, and the relationship between tectonic background and sedimentary environment is preliminarily discussed. Based on previous research, the formation of these deposits was largely influenced by paleo- ocean redox fluctuations during the Paleoproterozoic (Great Oxidation Event), Neoproterozoic (Neoproterozoic Oxidation Event), and Phanerozoic (alternating ice- greenhouse climates). Finally, applications in steel metallurgy, new energy batteries, agricultural fertilizers, and environmental catalysis are reviewed. The expanding new energy industry continues to drive demand for manganese- based battery materials (e. g. , lithium manganate and Ni- Co- Mn ternary materials), reinforcing the strategic significance of manganese resource development.
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WANG He, WANG Tongtong, XI Zhenzhu, ZENG Wei, ZHANG Shangqing, YANG Yongliang, XIONG Yunping
2026,100(2):657-669, DOI: 10.19762/j.cnki.dizhixuebao.2025158
Abstract:
To address the challenge of detecting the complex geoelectric structures of karstic bauxite deposits, this paper proposes a deep learning inversion method for the opposing coils transient electromagnetic method (OCTEM) integrated with geological model constraints, aiming to improve the inversion accuracy of subsurface resistivity structures. First, based on the karst metallogenic characteristics of these deposits, a geoelectric model with a low- high- low resistivity structure is constructed. A training dataset of resistivity models and their corresponding OCTEM responses is generated using variation coefficients of fixed horizon thicknesses. Second, the UResNet architecture is built by integrating a U- Net as the backbone network with a residual network (ResNet). This architecture enables multi- scale feature extraction through residual modules and establishes a nonlinear mapping relationship between the electromagnetic response data and subsurface electrical structures. Third, the proposed method is verified using synthetic data (both noise- free and noisy) and field- measured data from a karstic bauxite deposit in Yangcheng County, Shanxi Province. The research results show that the method exhibits minimal error in anomaly identification and high inversion accuracy, with the field- measured results showing a strong correlation with known geological data. This deep learning inversion method based on OCTEM can break through the dependence of traditional linear methods on initial models, providing an effective solution for detecting subsurface structures under complex geological conditions.
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LI Xing, HAN Runsheng, XI Zhenzhu, LONG Xia
2026,100(2):670-678, DOI: 10.19762/j.cnki.dizhixuebao.2025459
Abstract:
Opposing coils transient electromagnetic method (OCTEM) offers high resolution for shallow subsurface investigations, making it a potential tool for detecting bauxite layers. However, in laterite- covered terrains, the superparamagnetic response of the overburden masks the target response by superimposing a strong, long- decay signal onto the secondary transient field induced by eddy currents, significantly degrading detection resolution. To address the challenge of deep bauxite exploration in the Bailong Shujingcun ore block (Yunnan Fumin deposit, China), this study established a layered geological model based on local stratigraphy and statistical physical properties. This model integrates the resistivity characteristics of the bauxite layer, its host stratum, and the surrounding rocks. We conducted forward modeling to analyze the OCTEM response patterns with shallow superparamagnetic cover. Based on these patterns, a calibration and correction methodology was developed to suppress the superparamagnetic influence from the measured induced voltage. The corrected data were then inverted to recover the subsurface resistivity distribution. Comprehensive interpretation of 2D resistivity sections from two OCTEM profiles, integrated with an ore- prospecting model, successfully delineated the deep extension and distribution of the bauxite ore block. Drilling results subsequently confirmed these findings, verifying the accuracy of the approach. This study demonstrates that, with appropriate signal processing, OCTEM can be effectively applied for detecting bauxite layers in areas covered by superparamagnetic laterite.
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CHEN Jiahao, TIAN Yuming, JIANG Sha, WANG Huaqing, ZHOU Shangguo, XIA Liujing
2026,100(2):679-692, DOI: 10.19762/j.cnki.dizhixuebao.2025475
Abstract:
Given its status as a strategic metallic mineral resource, breakthroughs in metallogenic theory and exploration technology for manganese ore are of great significance for ensuring resource security. The Xialei manganese deposit, a major manganese resource base in China, serves as an ideal case study for evaluating the integrated application of manganese metallogenic theory and effective exploration methodologies. Using the Xialei manganese deposit as a framework, this paper systematically reviews the research progress in manganese metallogenic theory in China, focusing on elucidating the core concepts and scientific foundations of the latest theories. It is proposed that the “endogenous origin and exogenous mineralization” theory offers a robust genetic explanation for super- large manganese deposits. Simultaneously, the paper summarizes the current development status of main technical methods for manganese exploration and evaluation, analyzing their application effectiveness and the suitability of various methods in manganese prospecting. Research indicates that the guidance provided by geological methods combined with manganese metallogenic theory remains key to achieving breakthroughs in manganese prospecting. The findings of this paper can provide references for the study of metallogenic theory and exploration practices in similar manganese deposits.
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ZHONG Mingfeng, WANG Jinhai, XI Zhenzhu, WANG Liang, LIU Aju, HU Changhao, XIANG Yinhe
2026,100(2):693-707, DOI: 10.19762/j.cnki.dizhixuebao.2025094
Abstract:
The multi- polarization magnetotelluric method (MPMT) is a novel electromagnetic technique for detecting geological bodies characterized by contrasts in both resistivity and magnetic susceptibility. Based on the requirements for deep geological surveys in the Yueshanpu ore block of Ningxiang, Hunan, this study established an electromagnetic model of carbonate- hosted manganese deposits by integrating petrophysical statistics with existing borehole data. Forward modeling of MPMT was conducted to evaluate the method' s effectiveness. Using the Nonlinear Conjugate Gradient (NLCG) inversion technique, we first inverted data from known profiles to determine optimal MPMT inversion parameters. We then calculated 2D distributions of resistivity and magnetic susceptibility for three survey lines. By synthesizing the petrophysical characteristics of manganese ores and surrounding rocks, an exploration model was developed to delineate the 3D spatial distribution of ore layers in the Yueshanpu block. Verification drill holes confirmed that the dual- parameter information (resistivity and magnetic susceptibility) obtained from MPMT effectively constrains the spatial geometry of manganese orebodies. This approach reduces inherent ambiguities in geophysical interpretation and enhances prediction accuracy.
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LI Rongzhi, JIANG Sha, LONG Peng, LONG Tao, JIANG Xinhong, NONG Liangchun, ZHOU Shangguo, HUANG Qin, XIANG Yinhe
2026,100(2):708-722, DOI: 10.19762/j.cnki.dizhixuebao.2025155
Abstract:
The Debao Zurong- Tiandeng Dongping area in southwestern Guangxi is an important manganese metallogenic district in China, with the primary manganese- bearing strata hosted by the lower Triassic Shipao Formation. Although significant unexplored potential remains in this region, current exploration is focused on deep- seated targets and concealed orebody searching; however, the district currently lacks an effective metallogenic model to guide these efforts. Based on studies of two representative manganese deposits (Dongping and Fuwan), this paper identifies three distinct manganese- rich troughs within the Dongping manganese- forming basin: Dongping, Pingyao, and Fuwan. Within these troughs, the thickness of the manganese carbonate ore layer, Mn grade, ore texture, and the overall thickness of the manganese- bearing succession exhibit clear spatial distribution patterns. Based on the intensity of mineralization from strong to weak, the area is divided into central, transition, and marginal zones. On this basis, a new prospecting model was established and tested through exploration demonstrations. An integrated exploration suite is proposed, combining “stratigraphy- lithology- structure” geological surveys with Multi- Polarization Magnetotelluric Sounding (MPMT) and Time- Domain Multi- Pole Induced Polarization Sounding (TDMIP), followed by drilling verification. This integrated approach provides significant guidance for achieving breakthroughs in Triassic manganese exploration in southwestern Guangxi.
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XIE Qili, LOU Debo, SONG Guoxi, MENG Xianglun
2026,100(2):723-740, DOI: 10.19762/j.cnki.dizhixuebao.2025167
Abstract:
As a strategically critical resource, bauxite exploration requires urgent advancement. To address the limitations of traditional prospecting methods in efficiency and accuracy, this paper takes the karstic bauxite in the Pingguo area of western Guangxi as the research object and proposes a deep learning- based prospecting prediction method driven by multi- source data fusion. Based on the U- Net benchmark model, the study focuses on the impact of constructing multi- source geoscience data training sets using the sliding window technique and optimizing network architecture parameters on model performance. It also quantitatively evaluates model performance by introducing a composite score S (weighted by the intersection over union IoU, F1 score, and normalized training time Tn) and subsequently constructs a deep learning- based prospecting prediction model. The results show that: ① When constructing the dataset using sliding window technology, the S- value with a 75% overlap rate increased significantly by 71. 04% compared to that with a 0% overlap rate, indicating that this setting can effectively enhance the data and significantly improve model performance; ② In model architecture optimization, the optimal combination was determined through controlled experiments (64 base channels, replicate padding, SE+ module, ELU activation function, and Cross- Entropy+Dice composite loss function), which further increases the S- value by 8. 72%, significantly improving the recognition capability for complex geological features. Finally, prospecting prediction was conducted in the target area combined with multi- source data, successfully delineating five prospecting targets. The integration of multi- source data and deep learning technology enriches the prospecting prediction theory for karstic bauxite and provides scientific basis for exploration of this deposit type.
Volume 100,2026 Issue 2
Tectonic and Palaeogeographic Controls on Mineralization
Enrichment Mechanisms
Exploration and Research Progresses
Exploration Methods
Appendix
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U-Pb dating and trace element characteristics of monazite in granite porphyry from the Gaofeng mining area, Dachang, Guangxi: implications for petrogenesis, tectonic setting, and mineralization
Cheng Yongsheng, Wang Songpu, Wei Jun, Zhou Zhihui, Zhao Yuanyuan, Jiang Yaodan, Zhang Lichuan, Gan Wenzh, Li Yezheng, Liu Weijie, Ma Chao
Abstract:
The Gaofeng mining area in the Dachang ore field, Guangxi, is an important tin-polymetallic ore concentration area in China. However, the age, genesis, and mineralization potential of its deep magmatic activity remain unclear. This paper focuses on the concealed granite porphyry in the deep part of the Gaofeng mining area and conducts monazite U-Pb dating and trace element analysis. Combined with whole-rock geochemical data, it systematically discusses its petrogenesis and mineralization indicators. LA-ICP-MS monazite dating yields a weighted average age of 85.86-86.38 Ma, accurately defining for the first time a Late Cretaceous magmatic event later than the Tongkeng mining area granite porphyry (~91 Ma), revealing that the Dachang ore field has at least four periods of magmatic activity. Geochemical analysis indicates that this granite porphyry belongs to highly differentiated, peraluminous crustal A-type granite, formed in a post-collision extensional environment. The monazite in the rock mass exhibits a high Th/U ratio and strong Eu negative anomaly, consistent with the whole-rock geochemical characteristics, collectively indicating strong plagioclase fractional crystallization. Although this dike intrusion occurred later than the main mineralization period (~92 Ma) and is not a direct ore-forming parent rock, its significantly high Sn content (average 48 ×10-6) suggests that it originated from a deep parent magma chamber that underwent tin pre-enrichment. Therefore, this period of magmatic activity is a direct manifestation of deep tin enrichment events, implying the potential presence of related concealed tin ore bodies in the deep part of the Gaofeng mining area. This study further refines the regional metallogenic model and provides key evidence for guiding deep prospecting.
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Discovery of chromitite orebody in the Cubuzha ophiolite of the Western segment of the Yarlung-Zangbo ophiolitic belt, Tibet, China
LIAN Dongyang, CAI Pengjie, RUI Huichao, MA Haitao, CAO Shiji, SHI Rendeng, XU Xisheng, YANG Jingsui
Abstract:
Chromite is a strategically important mineral in short supply in China. Currently, the only chromite deposit under mining operation in China is the Luobusha deposit, located in the eastern segment of the Yarlung Zangbo Suture Zone (YZSZ); however, its production capacity is far from meeting the demands of national economic development. Therefore, exploring chromite deposits with industrial mining value in other domestic regions has become a crucial task that Chinese geologists urgently need to address. This paper reports a new discovery of high-grade massive chromitite in the Cuobuzha ophiolite of the western segment of the YZSZ in Tibet, China. The Cuobuzha ophiolite is situated in the northern subbelt of the western segment of the YZSZ, with the main body of the intrusion being mantle peridotite. This ophiolite is dominated by harzburgite, accompanied by a small amount of dunite. The massive chromitite orebody hosted within it can reach a thickness of 2~3 meters, and the Cr2O3 content of chromian spinel ranges from 56% to 60 wt%, which is typical of high-chromium chromite. Although the Cuobuzha ophiolite and other ophiolite bodies discontinuously exposed in the northern subbelt are all small in surface scale, previous interpretations of aeromagnetic data suggest that the scale of the mantle peridotite basement in the northern subbelt is much larger than that of the extensively exposed mantle peridotite in the southern subbelt. These pieces of evidence indicate that the ophiolite belt in the western segment of the YZSZ has excellent prospecting potential for chromite deposits.
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Applicability Eevaluation of Ccomprehensive Ggeophysical Pprospecting Mmethods for Ggold Eexploration in Huangtuliang
TAO Yin-Long, LIU He-fan, SONG Shu-jun, ZHAO Bao-qiang, ZHANG Yun-Peng, ZHANG Xing-kang
Abstract:
The Huangtuliang gold deposit is an important altered rock-type gold deposit in northwestern Hebei Province, China. The host rock is late Hercynian syenite, controlled by near-east-west trending structures, and the surrounding area has favorable metallogenic geological conditions. High-precision magnetic surveys, induced polarization (IP) sounding, and audio-frequency magnetotelluric (AMT) measurements were conducted in the surrounding area.The results show that the high-precision magnetic method has a significant effect on identifying structural zones, which often present spiky low magnetic anomalies; induced polarization sounding has a good effect on distinguishing amphibole plagioclase leptynite, porphyritic granite, altered rocks and syenite. Altered rocks show the characteristics of low resistivity, medium-high polarization and medium-low magnetism, which are easy to differentiate, and have important significance for prospecting gold ore bodies;Audio Magnetotellurics has a good performance in identifying fault zones, which are usually located near the apparent resistivity gradient zones. Based on these findings, a combination of geophysical prospecting methods for the Huangtuliang gold deposit was established, which included high-precision magnetic survey、induced polarization method and AMT (CSAMT). At the same time, a geophysical mineral exploration model for Huangtuliang-type gold deposit were established, providing a reference for the exploration of similar deposits in this region.
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Tectonic characteristics and evolution of the southern section of the western edge of Ordos Basin
Abstract:
The western margin of Ordos Basin is located at the junction of different blocks, and the structural deformation has the characteristics of multi-stage, multi-attribute and multi-scale. In recent years, although some achievements have been made in the exploration of oil and gas risks in the western margin of the basin, no major breakthrough has been made due to the complex geological structure. In this paper, based on the three high-precision two-dimensional grid lines newly processed in the southern section of the western margin of the Ordos Basin, combined with regional geological data, drilling data and field geological survey, the seismic geological profile is constructed, and the 2D-Move software is used to quantitatively analyze the profile after fine resolution. Inversion recovery and forward modeling. The research shows that: (1) The structural framework of the southern section of the western Ordos Basin was essentially finalized during the Yanshanian. Its structural characteristics transition from fold deformation controlled by a composite structural wedge in the south to basement-involved imbricate thrust structures controlled by several major thrust faults in the north. (2) The G202203 profile traversing the Shajingzi area in the northern part of the southern section of the western Ordos Basin has a current length of 74.86 km. After fault displacement removal and stratigraphic flattening, the profile length is restored to 91.19 km. Calculations indicate a cumulative stratigraphic shortening of 16.33 km, resulting in a tectonic shortening rate of approximately 18.0%. (3) The formation and evolution of the southern section of the western Ordos Basin are closely linked to tectonic events along the margins of the North China Craton. It underwent several key stages, including rift extension during the Changchengian, uplift and denudation from the Late Ordovician to Early Carboniferous, multiple phases of intense thrusting and nappe formation in the Mesozoic, and modification during the Cenozoic. The large-scale intracontinental thrust structures primarily developed in the late Mesozoic, controlled mainly by the multi-plate convergence system in East Asia resulting from the subduction and closure of the Paleo-Pacific, Mongol-Okhotsk, and Bangong-Nujiang oceanic basins. The research findings provide important references for understanding tectonic deformation, evolutionary history, and petroleum exploration in the western margin of the Ordos Basin.
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Multiphase rifting of the Mesoproterozoic Longdong Rift System in the Ordos Basin
Abstract:
Following the Lüliang Movement, the Ordos Basin entered a rifting evolution stage, forming multiple deep rift systems from south to north. Currently, the deep Mesoproterozoic strata hold significant hydrocarbon potential, exploration in the deep Ordos Basin remains at a relatively early stage, and the precision of seismic data is insufficient. This has resulted in numerous gaps in the understanding of the structure and evolutionary characteristics of the deep rift systems during this period. This study focuses on the Mesoproterozoic Longdong Rift System in the Ordos Basin. By integrating seismic data and drilling data, it systematically reveals the episodic characteristics, structural-evolutionary features, and genetic mechanisms of the Mesoproterozoic rift system in the Ordos Basin.?The key findings are as follows: ①The Mesoproterozoic of the Ordos Basin experienced multiple tectonic events, with eight unconformities identified and seven structural-stratigraphic sequences delineated. From bottom to top, these are sequences Pt?Ch_Ⅰ~Pt?Ch_Ⅳ (Early Synrift Stage), sequence Pt?Ch_Ⅴ (Late Synrift Stage), sequence Pt?Ch_Ⅵ (Postrift Stage), and sequence Pt?Jx (Epicontinental Sea Stage), reflecting the rift's evolution from a continental fault depression to a marine depression. ②The Longdong Rift System exhibits a half-graben structure, bounded by a master fault on its southern side. The internal strata wedge out northward and progressively deepen southward. ③The rift's tectonic-sedimentary evolution comprises four stages: Early Synrift, Late Synrift, Postrift, and Epicontinental Sea. The rift is characterized as an intracontinental rift driven by subduction along the southern margin of the North China Craton and mantle plume upwelling.?Initially, it functioned as an inland branch of the Xiong'er triple-junction rift system, with extension intensity decreasing northward. The rift activity progressed through initial faulting, volcanic eruptions, sustained extension, and eventual subsidence and demise.
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Early Permian tectonic setting of the southeastern Central Asian Orogenic Belt: Evidence and constraints from the metamorphic plutonic assemblage along the Xar Moron river
Liu Jianfeng, Li Jinyi, Zhao Shuo, Zhang Jin, Zhang Wenlong, Lv Qianlu, Wang Zixin
Abstract:
In response to the controversy over the early Permian tectonic setting in the southeastern Central Asian Orogenic Belt (CAOB),this study conducts systematic petrological,geochronological,geochemical,and zircon Hf isotopic studies on the metamorphic plutonic assemblage within the originally defined “Shuangjing paleocontinent” along the Xar Moron River. The plutonic assemblage is mainly composed of gabbro,diorite,granodiorite,and granite,with zircon U-Pb ages mostly ranging between 296 and 270 Ma. Based on regional geochronological data,it is determined that there are no Precambrian geological bodies within the “Shuangjing paleocontinent”,thereby ruling out its tectonic attribute as a Precambrian ancient block. Although the rock assemblage shows a bimodal feature in the TAS diagram,the Early Permian plutons generally have relatively low total alkali (Na2O + K2O) and K2O contents,belonging to calc-alkaline,high-K calc-alkaline and low-K tholeiitic series respectively,rather than the typical alkaline series in rift settings. In addition,the trace element distribution patterns of mafic magmatic rocks generally show depletion of the high field strength elements (HFSEs),such as Nb,Ta,and Ti,indicating the characteristics of subduction zone magmatic rocks. In the normative mineral classification diagram,the granitoids mainly fall within the tonalite-trondhjemite-granodiorite (TTG) field,which is commonly associated with active continental margins. Zircon Hf isotopic analyses further reveal that different gabbros originated from the asthenosphere and continental lithospheric mantle,respectively. And different granites were primarily derived from either juvenile crust or ancient crustal materials. Considering the close spatio-temporal relationship between the magmatic assemblage and the Xar Moron River ophiolite belt to the north,it is proposed that the observed bimodal magmatism and the variations in zircon Hf isotopic composition of different plutons resulted from the upwelling of the asthenosphere triggered by the delamination of the subducted Paleo-Asian Ocean slab. The asthenospheric upwelling further induced extension along the northern margin of the North China paleoplate and caused partial melting of different lithospheric layers.
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Short-wave infrared spectroscopy alteration zonation and Prospecting significance of the Tiegelongnan Copper-gold Deposit
Wangzengxiang, Lishe, Yijinjun, Dudongyang, Nimadunzhu, Zhanghong, Liangqiongwen, Niexin, Xuwenhao
Abstract:
The Duolong ore district in the Bangong Co–Nujiang metallogenic belt on the Tibetan Plateau is an important mineral resource base in China. Among them, the Tiegelongnan deposit, as a giant porphyry–epithermal Cu (Au) deposit, exhibits complex alteration mineral assemblages and mineralization systems. This study employs short-wave infrared spectroscopy (SWIR) to systematically scan and analyze drill core samples from 29 boreholes in the Tiegelongnan deposit. Key alteration minerals such as sericite, kaolinite, and dickite are identified, and their spatial distribution patterns are elucidated through statistical methods. The results reveal a significant shift in alteration mineral assemblages above and below the 4300?m elevation of the orebody: assemblages above this level are dominated by alunite, kaolinite, dickite, and pyrophyllite, while those below are primarily composed of sericite, with a marked reduction in kaolinite. The spatial overlap between low Pos2200 values of sericite and zones of high kaolinite crystallinity suggests that the southeastern deep part of the mining area is closer to a concealed porphyry intrusion. The advanced argillic alteration zone trends northwest, whereas the phyllic alteration zone is well-developed in the southeastern deep region, indicating potential for epithermal gold mineralization in the northwest and favorable prospects for porphyry Cu-Mo mineralization in the southeastern deep area. The alunite alteration zone is displaced by the Rongnagou fault, and combined with the vertical zonation of alteration, this implies further exploration potential in the southwestern deep part of the deposit. This research demonstrates a methodological approach for large-scale SWIR data analysis in delineating alteration zoning, offering scientific insights and technical support for deep and peripheral exploration of the Tiegelongnan deposit.
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Role of pre-existing structures in controlling the tectonic evolution of basin-mountain boundary: Insights from numerical simulation experiments of the southeastern Sichuan-western Hunan-Hubei fold thrust belt
mahuanpeng, huanghanyu, hedengfa, xiongjiabei, luoyufeng, gaoyaxiong, zhangweikang
Abstract:
The southeastern Sichuan-Western Hunan-Hubei fold thrust belt, located in the central-upper Yangtze region of South China, attracts significant scientific interest due to its substantial natural gas resources and intense structural deformation. Previous studies extensively examined the belt's tectonic origin, mechanisms, and structural styles, yet controversies persist regarding the impact of pre-existing structures on its tectonic evolution. Employing high-resolution seismic reflection interpretation profiles and discrete element numerical modeling, four comparative models were constructed incorporating the pre-existing Huayingshan fault, Qiyueshan basement lithological partitioning, and multiple detachment layers. These models investigated the formation of the Huayingshan and Qiyueshan faults, systematically revealing spatio-temporal control laws of pre-existing structures over regional deformation evolution. Simulation results indicate closest alignment with present-day structural configurations when integrating the Qiyueshan basement partitioning. During initial tectonic activity, rapid uplift east of the Qiyueshan basement differentiation boundary formed an incipient domal structure, contrasting with minimal deformation near the Qiyueshan basement differentiation boundary. Under prolonged tectonic stress, the domain east of this boundary experienced compressional thickening dominated by thick plastic basement, developing a synclinorium fold belt. Conversely, western domains governed by rigid basement and multilayered detachment systems formed an anticlinorium fold belt. At the terminal deformation phase, the synclinorium belt underwent gradual uplift with westward migration, while anticlinorium deformation terminated near the Huayingshan fault, establishing the extant tectonic framework. Integrated analysis with prior research suggests the Xuefeng Shan orogenic belt supplies the primary driving force for regional deformation. Modulated by Qiyueshan basement partitioning, deformation proceeded through stagewise evolution mediated collectively by multiple detachment layers. The Huayingshan fault is reinterpreted as non-pre-existing, whereas the Qiyueshan fault originates from basement partitioning mechanisms. Specifically, the western Hunan-Hubei fold thrust belt is primarily controlled by the basal detachment layer, while the southeastern Sichuan fold thrust belt is mainly governed by the Cambrian detachment layer. Secondary detachment layers such as the Silurian and Triassic play an adjusting role in both regions, influencing shallow structural patterns.
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Implications of detrital zircon U-Pb age in the sediments of the Songhua River Basin for provenance tracing
Liu Sining, Sun Lei, Liu Haijin, Wang Yanru, Xie Yuanyun, Wei Zhenyu, Wang Yehui, Qi haodong, Wu Peng, Zhang Yan
Abstract:
River sediments are widely regarded as essential archives for source-to-sink system analysis and paleogeographic reconstruction, yet their provenance signals may be substantially altered during downstream transport due to tributary dilution and heterogeneous zircon yield. Traditional provenance studies have frequently overlooked these factors, which may result in biased interpretations. In the Songhua River Basin, the mechanisms through which tributary inputs influence detrital zircon age variations in the mainstream, along with the quantitative evaluation of their sedimentary contributions, have yet to be fully clarified. In this study, detrital zircon U-Pb geochronology was conducted on sediments from the Songhua River mainstream and its major tributaries, including the Nenjiang, Jilin Songhua, and Lalin Rivers. By integrating a dilution index, zircon yield correction, and inverse Monte Carlo model, it explores the source-to-sink system of the Songhua River Basin. The detrital zircon age spectra are defined by four principal age populations: 202~110 Ma, 523~205 Ma, 2066~1564 Ma, and 2747~2341 Ma. Both tributary dilution and differences in zircon yield exert substantial control on zircon age distributions. The effects of tributary dilution gradually diminish with increasing transport distance, whereas zircon-yield correction effectively mitigates biases arising from variations in zircon fertility among source rocks. Two recommendations for provenance studies are proposed: (1) sampling sites should avoid river confluence zones and preferably be located at least 50~100 km downstream from confluences; and (2) zircon-yield correction ought to be prioritized to enhance the accuracy of provenance assessment. Zircon reproducibility tests demonstrate the absence of ~1800 Ma ages in detrital zircon records from the Jilin Songhua River, suggesting that reliance solely on age peaks is insufficient to fully capture regional magmatic-tectonic events. By integrating tributary dilution and zircon-yield controls and combining detrital and igneous zircon datasets, this study addresses the limitations of single-indicator provenance methods and establishes a more robust framework for sediment provenance tracing and paleogeographic reconstruction in the Songhua River Basin.
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Geological, geochemical characteristics and metallogenic mechanism of the Dongwan gold deposit in the Dabie, China
Xie Jinrui), Liu Xiaonian), Xiong Yuanhong), Liang Longfei), Liu Guangyong, Wang Guoping, Fu Lebing), Qiu Yongzhen
Abstract:
The Dongwan gold deposit, located in the eastern Tongbai-Dabie orogenic belt, is a newly discovered vein-type gold deposit whose metallogenic characteristics remain unclear, limiting the understanding of its gold enrichment mechanisms and processes. This study reveals that the ore bodies are controlled by a NE-trending fault system, and the mineralization can be divided into four stages: quartz–coarse-grained pyrite, gray quartz, quartz–polymetallic sulfides, and quartz–carbonate (S1-S4). The ore fluids belong to a NaCl-H?O±CO? system with moderate-to-low temperatures (114~336 °C) and salinities (1.4 %NaCleqv~16.1 %NaCleqv). The δDV-SMOW values range from -100.0‰ to -64.2‰, and δ1?OH?O values vary between -10.1‰ and 1.0‰. Electron probe microanalysis (EPMA) reveals that visible gold, primarily composed of native gold and electrum, occurs in fractures and intergranular spaces of the S3 pyrite, representing the main occurrence of gold in the deposit. Trace element analysis of pyrite from different stages indicates that invisible gold mainly exists as lattice-bound gold, with strong positive correlations between Au and Ag, as well as Ag and Pb. Except for Py1-1, the δ3?S values of pyrite range from 0.87‰ to 3.34‰, showing an initial increase followed by a decrease from the S1 to S3. Comprehensive analysis suggests that the ore-forming fluids were predominantly magmatic in origin. During the S3, gold-rich fluids superimposed on the system, leading to extensive precipitation of independent gold minerals through fluid immiscibility/boiling conditions. Therefore, although the Dongwan gold deposit is situated near a NW-trending fault zone, the NE-trending ore-controlling structures formed during the Early Cretaceous and the superposition of gold-rich fluids in the main stage are the most critical metallogenic conditions, which are essential for future gold deposit exploration in the region.
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Differential driving mechanisms of carbon cycling in continental subduction zones: A case study of the North Qaidam ultrahigh-pressure metamorphic belt
HE Xin, JIANG Xiaocong, LI Chuanzhi, LI Yunshuai, WANG Yue, LI Xiaofan, YU Shengyao
Abstract:
Subduction zone carbon cycling is a key process that regulates the carbon balance between Earth’s deep interior and shallow reservoirs. The pathways and timescales of this cycling directly influence the long-term evolution of the atmosphere. Previous studies have predominantly focused on identifying individual carbon pathways, leaving the coexistence and evolution of multiple pathways within a single tectonic system poorly understood. To address this, we conducted an integrated petrological, geochemical, and zircon U-Pb geochronological study on marbles from the Yuka terrane and carbonatites from the Lülangshan terrane in the North Qaidam ultrahigh-pressure (UHP) metamorphic belt. Our results show that the Yuka marbles recorded a UHP metamorphic age of ~443 Ma. Their low phosphorus contents and low rare earth element (REE) abundances suggest a sedimentary carbonate protolith. In contrast, the Lülangshan carbonatites display a dominant detrital zircon age peak of 430~410 Ma. Their geochemical features including enrichment in large-ion lithophile elements (LILEs), depletion in high-field-strength elements (HFSEs), and REE patterns consistent with global average crust-derived carbonatites collectively support a crust-derived igneous origin. Combined with the regional tectonic setting, we propose that the Yuka marbles represent a solid-state return pathway, where subducted carbonates were metamorphosed under UHP conditions and subsequently exhumed via a subduction channel. In contrast, the Lülangshan carbonatites likely represent a melt pathway, formed by the partial melting of carbonate rocks detached from the subducted slab during the post-collisional stage, facilitated by upwelling asthenosphere. These two distinct rock types reveal diverse mechanisms solid versus melt for the return of carbon from depth to the surface in an orogenic belt, providing new constraints for understanding the fate of carbon in subduction zones and orogenic carbon cycling.
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Reconstructing the evolution of the South Qinling Mountains: Insights from detrital zircon U-Pb and fission track double dating
LIN Xu ), GUAN Kaige ), WU Zhonghai ), WU Lin ), LIU Dongliang ), LI Siyi ), ZHOU Ziwen )
Abstract:
The Qinling Orogenic Belt presents a distinctive opportunity to investigate the intricate interplay of subduction, collision, and intracontinental deformation. The evolutionary process of the Qinling Mountains, however, remains characterized by considerable uncertainty. This study integrates zircon U-Pb (n = 690) and fission track (n = 450) dating of detrital sediments from the Hanjiang River catchment to reconstruct the magmatic and exhumation history of the South Qinling region from the Neoproterozoic to the Cenozoic. The U-Pb dating of zircons has unveiled magmatic events that occurred at 760, 452, and 210 Ma. These events correspond to the breakup of the Rodinia supercontinent at 760 Ma, the subduction of the Shangdan Ocean at 452 Ma, and the late Triassic subduction of the South China Block beneath the North China Craton at 210 Ma. Zircon fission track analysis reveals exhumation phases at 300, 165, 90, and 27 Ma. These ages reflect: (a) the South China Block and North China Craton collision spanning 300-165 Ma; (b) late Cretaceous (90 Ma) exhumation linked to Paleo-Pacific and Lhasa plate subduction; and (c) rapid exhumation during the early Oligocene (27 Ma) due to the Tibetan Plateau's eastward expansion. This study not only elucidates the tectonic evolution of the Qinling Orogenic Belt but also underscores the utility of combining high- and low-temperature thermochronometers to unravel complex thermal histories in orogenic systems.
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Differential uplift process of the Qiangtang Basin in the Tibet Plateau during the Mesozoic–Cenozoic and its geological significance: Evidence from Low-Temperature Thermochronology
chenhongman, liuchiyang, pengheng, lurukui
Abstract:
The Qiangtang Basin, located in the central Tibetan Plateau, is a key area for unraveling the multi-block amalgamation, multi-stage uplift, and evolutionary history of the plateau. Based on an extensive set of low-temperature thermochronological data, this study focuses on the tectonic evolutionary setting of the Qiangtang Basin, the uplift and cooling histories of different tectonic units and within different parts of the same unit, as well as their underlying mechanisms. The results indicate that the Qiangtang Basin primarily underwent two episodes of differential uplift and cooling events: from the mid-Early Cretaceous to Late Cretaceous (135–70 Ma) and from the Eocene to Oligocene (55–30 Ma), followed by a phase of integral uplift and cooling since the Miocene (<23 Ma). The differential uplift of the basin exhibits the following distinctive characteristics: (1) The Western Uplift Zone experienced relatively early uplift starting during the Jurassic, which also induced earlier uplift and cooling in adjacent areas. Subsequently, the north-central Southern Qiangtang Depression and the central-southern Northern Qiangtang Depression responded sequentially, demonstrating an outward-expanding pattern of uplift; (2) The Central Qiangtang Low-Uplift Zone did not undergo accelerated cooling and uplift until 130–100 Ma. It was not until the Eocene–Oligocene (55–30 Ma) that the effects of uplift and cooling extended to the northern margin of the Northern Qiangtang Depression and the southern margin of the Southern Qiangtang Depression. This event is recorded widely in the Western Uplift Zone and throughout the Southern Qiangtang region, and was largely synchronous. Integrated with regional tectonic background analysis, this study proposes that the first two episodes of differential cooling in the Qiangtang Basin were primarily controlled by the Lhasa–Qiangtang collision and the “hard” collision between India and Eurasia along with subsequent continuous compression. The third episode represents integral uplift following the completion of amalgamation. The timing and characteristics of these three uplift events provide important constraints for understanding the dynamic mechanisms of the formation of the Tibetan Plateau.
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Chlorine isotopic characteristics and their implications for Resource and Environmental in Kunteyi Salt Lake, Qaidam Basin
lijun, Zhang Xiying, Gen Jun, Miao Weiliang, Li Wenxia, Yuan Xiaolong
Abstract:
The chlorine isotopic composition is of great significance for indicating the evaporation degree of salt lake brine, judging the potential of salt and potassium formation and environmental evolution. Due to the special provenance structure and salt-forming environment of the Kunteyi Salt Lake (KSL), a highly representative solid potassium-bearing sulfate mineral—polyhalite (Ca?MgK?(SO?)?·2H?O) was formed, which is associated with halite. However, research on the chlorine isotopic of halite under this special depositional background remains is weak, and whether chlorine isotope will be abnormal as a potassium prospecting index needs further study. In addition, investigations into the evolutionary environmental changes of the KSL, particularly its relationship with the great eastern lake, still require more geochemical evidence for support. Therefore, this study focuses on 25 primary halite samples from the ZK3608 core of the KSL, conducting an analysis of the fractionation characteristics and tracing significance of δ3?Cl. The results show that the δ3?Cl values range from -1.08‰ to 0.45‰, with an average of -0.22‰. The δ37Cl decreases from bottom to top, but it is positively correlated with the content of K+ in halite and polyhalite content. It indicates that KSL has experienced a gradual concentration evolution process since the middle Middle Pleistocene, yet no effective potassium accumulation has occurred. In other words, the special hydrogeological background did cause anomalies in chlorine isotopes of the KSL as an indicator for finding potassium, unlike the traditional negative correlation with indicators such as K?. Furthermore, the δ3?Cl values of halite reflect, to a certain extent, the glacial-scale climatic fluctuations of the KSL since Marine Isotope Stage 8 (MIS8). Specifically, they also response to environmental changes such as the freshening event around 170–180 ka, and the complete closure of the lake after the Late Pleistocene. Based on the phenomenon of “salt accumulation but no potassium accumulation” in the KSL since the middle Middle Pleistocene, as indicated by halite δ3?Cl, a preliminary assessment suggests that this phenomenon may be related to the potassium accumulation mechanism of the salt lake and K? supply, which requires further research to clarify.
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The Mineral Material Sources of Rutile-type Titanium Deposits in the Upper Carboniferous Benxi Formation, Southeastern North China Craton
ZHANG Baotao, HU Zhaoguo, MEI Zhenhua, LIU Sen, Hua Bei
Abstract:
Recently discovered paleo-weathering sedimentary rutile-type titanium deposits in the Benxi Formation of North China have raised critical scientific questions regarding their mineralizing material sources. Taking the Luxi area in the southeastern North China Craton as a case study, this research employs zircon in-situ microgeochemical analysis, integrates zircon geochemical big data, and conducts systematic comparisons with regional tectonic-sedimentary evolution to identify potential mineral sources. The findings provide insights for further scientific research and prospecting strategies. Key discoveries include: (1) Detrital zircons from mineralized geological bodies are predominantly Paleozoic magmatic in origin, exhibiting severe morphological damage indicative of long-distance transport; (2) In-situ microgeochemical analysis reveals that source rocks were primarily granitoids (granodiorite, tonalite, or syenite) formed in continental margin arc settings; (3) By integrating the Paleozoic source-to-sink evolution of the North China Craton, we propose that mineralizing materials likely derived from the North Qinling Orogenic Belt or analogous paleo-orogenic belts (now extinct), with the Qingshui-Taibai and Danfeng-Tongbai regions identified as potential source areas. Through three-dimensional analysis encompassing the craton"s Paleozoic continental evolution, source-to-sink tectonic history, and tectonic-sedimentary dynamics, we establish a comprehensive model for the craton"s geodynamic evolution and source-sink control effects. This framework elucidates the intrinsic causes of regional variations in rutile-type titanium mineralization potential across the North China Craton, providing theoretical foundations for further metallogenic studies and macro-scale prospecting strategies.
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Diagenetic and Metallogenic Chronology and Prospecting Significance in Sichuan Mianning Maoniuping Rare Earth Deposit
Jin Yanan, Wang Denghong, Wang Wei, He Bin, Zhao Zhi, Liu Shanbao, Zhao Ruiwei, Yu Yang, Yu Feng
Abstract:
The Maoniuping deposit in Mianning, Sichuan, is one of the most significant rare earth element (REE) deposits, situated within the Mianning-Dechang Himalayan REE metallogenic belt in southwestern China. Previous studies on Homo sapiens have indicated that REE mineralization is closely associated with alkaline-carbonatite complexes in the region, but there remains considerable debate regarding the genesis of these complexes and the timing of REE mineralization. This study obtained ages of 25.31±0.26 Ma (MSWD=4.3, n=12) for alkali-feldspar granite porphyry and 26.0±0.3 Ma (MSWD=2.0, n=15) for alkaline syenite, both of which fall within the error range of the magmatic age of the alkaline-carbonatite complexes in the area. This suggests a genetic link between the alkali-feldspar granite porphyry and the complexes, further supporting the formation of ore-bearing alkaline complexes during the transition from the Paleogene to the Neogene in the Cenozoic era. LA-ICP-MS U-Pb dating of bastn?site from different ore types ages of 32.68±0.66 Ma (n=21) for breccia-type ores, 30.2±0.89 Ma (n=16) and 30.19±0.77 Ma (n=19) for aegirine-augite-type ores, and 27.61±3.43 Ma (n=23) for calcite-type ores. The sequence from breccia-type ores → aegirine-augite-type ores → calcite-type ores → alkaline syenite → alkali granite porphyry shows progressively younger but continuous ages, indicating that mineralization occurred over a span of 6~7 Ma. This process was initiated by tectonic activities, which facilitated the upward migration of ore-bearing, fluid-rich magmas from deep crustal or possibly even mantle depths to shallow subsurface levels, forming subvolcanic rocks (porphyry). The simultaneous interaction of magma and magmatic hydrothermal fluids led to intense fracturing, alteration, and reverse crystallization of ores and rocks. This characteristic also suggests that the REE and F-rich metallogenic melts-fluids were not products of fractional crystallization of alkaline syenite and alkali-feldspar granite porphyry but rather resulted from direct crystallization of magmatic melt-fluids. Therefore, alkaline syenite and alkali-feldspar granite porphyry can serve as prospecting indicators for Maoniuping-type REE deposits. If alkaline syenite and alkali-feldspar granite porphyry were erupted into a marine environment, they might form trachyte or K-rich tuff similar to the H8 unit in the Bayan Obo deposit. In other words, while the Bayan Obo and Maoniuping REE deposits share common metallogenic mechanisms, their mineralization environments are fundamentally distinct.
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Genesis and significance of platinum-group element compositions and platinum-group mineral assemblages in magmatic processes and mineralization of mafic-ultramafic systems
Chen Chen, Wang Christina Yan, Wei Bo, Yao Zhuosen
Abstract:
The compositions of platinum-group elements (PGE) and the assemblages of platinum-group minerals (PGMs) in mafic-ultramafic rocks and related magmatic deposits are the results of diverse processes, such as mantle partial melting, fractional crystallization of mafic-ultramafic magmas, and the segregation and migration of sulfide melts. Therefore, PGE and PGM can be used to reveal the processes of magmatic differentiation and ore formation. Here, we introduce some case studies showing that PGE partitioning pattern and PGM assemblages can indicate the formation and evolution of ophiolitic peridotite, podiform chromitite and magmatic sulfide deposit. Firstly, in the harzburgites of K?z?lda? ophiolite from Türkiye, the total content of PGE ranges from 18.15 to 39.65 ×10-9, with narrow ranges of Os, Ir and Ru, variable ranges of Pd and Pd, and high Pd/Ir and Pt/Ir ratios. All harzburgite samples have consistent and relatively flat PGE patterns when normalized to the primitive mantle. Base on PGE and trace element compositions and quantitative models, we concluded that the harzburgites of K?z?lda? ophiolite are the products of 20% partial melting of primary mantle and melt-rock interaction. Secondly, the PGM assemblages in different types of chromitite from K?z?lda? ophiolite are different. In all chromitite samples, primary laurite and Os-Ir alloy are typically enclosed within chromite, suggesting the crystallization of chromite at temperature of 1100–1200℃ and log?S2 values of -2 to -1. However, in nodular ores, Os-Ru nanoparticle + OsRu3 nanoalloy + awaruite (FeNi3) + trevorite (Fe2NiO4) are located in the intergranular space of chromite, indicating that the nodular chromitite underwent weak serpentinization and had low water/rock ratios (<~1), fS2 and fO2. On the other hand, in banded and massive chromitite, Os-rich laurite + Os-Ir(Ru) alloy/oxide + pentlandite + millerite (NiS) are located in the intergranular space of chromite, suggesting high water/rock ratios and high fS2 and fO2 during serpentinization. Thirdly, in the J-M reef of the Stillwater Complex, Montana, USA, we discovered a new mineral, Wangyanite. Wangyanite is a Pd end-member mineral of the pentlandite group, which has 9.64-10.59% Pd. Based on the textural features and previous experimental Pd-Fe-Ni-S phase system, wangyanite could form by peritectic reaction between braggite, pentlandite and sulfide liquid, rather than exsolved from monosulfide solid solution (MSS) and intermediate solid solution (ISS). To sum up, the studies of PGE compositions and PGM assemblages can provide new information on the magmatic deposit formation process and mechanism.
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Characteristics of accessory minerals in diamond-bearing dolerite from Lan'gan, Anhui Province and their Implications for diamondgenesis
Zhu Renzhi, Ni Pei, Wan Fanglai
Abstract:
The discovery of nearly 3,000 diamonds in dolerite and other mafic rocks in Anhui's Lan'gan area, is the first such occurrence in China. Although the host rocks' characteristics and petrogenesis are well-constrained, diamond genesis remains unclear. This study conducted petrographic and compositional analyses of the characteristic accessory minerals, namely garnet and ilmenite, within the dolerite. The results show that the garnet appears pale red, elliptical to sub-angular in shape, with large grain sizes (450 ~ 600 μm), and exhibits low MgO (0.54% ~ 13.65%) and Cr?O? (0% ~ 0.26%) contents. The ilmenite is black, sub-angular in shape, with large grain sizes (500 ~ 600 μm), and has low MgO (0.42% ~ 2.35%) and Cr?O? (0% ~ 0.05%) contents. Both garnet and ilmenite are xenocrysts, and their mineralogical characteristics are significantly distinct from indicator minerals in typical diamond-bearing kimberlites (e.g., the Wafangdian 30th pipe in Liaoning, China, and the Big Hole pipe in South Africa). This indicates that the characteristic accessory minerals in the Lan'gan dolerite are not derived from kimberlites, and the diamonds contained therein show no genetic link to kimberlites. The composition of garnet further reveals that its material source is pyroxenite and eclogite, implying that the dolerite magma once incorporated breccias of these rock types. Consequently, the diamonds in the dolerite e may be inherited from partially assimilated diamonds within the breccia clasts.
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In-situ U-Pb and fission-track double dating of apatite by LA-ICP-MS microanalysis: Methodology and prospects
ZHANG Bin, YANG Jing, CHEN Wen, MA Licheng, WANG Sen, ZHANG Yan, ZHANG Shuanhong
Abstract:
Conducting simultaneous U-Pb and fission-track analysis on the same mineral crystal has emerged as an important and rapidly developing dating method in recent years. This technique effectively constrains the thermal history of geological bodies from high-temperature crystallization to low-temperature cooling, representing a significant frontier in thermochronology. Based on LA-ICP-MS technology, and building upon the established zircon U-Pb dating procedure, this study systematically established an in-situ microanalysis method for double U-Pb and fission-track dating of apatite, following three main steps: sample preparation, track counting, and U-Pb isotope analysis. The U-Pb ages obtained for the three zircon standards—Tanz, Ple?ovice and Qinghu—are 568.4 ± 1.9 Ma, 334.4 ± 1.4 Ma, and 158.85 ± 0.71 Ma, respectively. While analyses of three international apatite standards with varying common Pb contents—Durango, Mount Dromedary, and Fish Canyon Tuff—yielded U-Pb lower intercept ages of 31.7 ± 2.2 Ma, 101.1 ± 2.1 Ma, and 27.4 ± 4.2 Ma, and fission-track central ages of 31.15 ± 1.00 Ma, 98.4 ± 2.4 Ma, and 27.29 ± 1.34 Ma, respectively. These results are consistent with recommended reference values within error, fully validating the accuracy and reliability of the established experimental procedure. The method developed in this study provides robust technical support for fundamental applied research—such as reconstructing orogenic belt evolution, basin provenance analysis, landscape evolution, ore deposit preservation and modification, and geodynamics—as well as for basic principles of thermochronology. In the future, an important direction will be to combine this method with in-situ (U-Th)/He dating to develop a more efficient and precise triple-dating approach on single crystals.
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Multistage Hydrothermal Overprinting and Mineralization in the Large Cu-Co-Zn Deposit at De’erni, Qinghai, China: Evidence from Apatite U–Pb Dating and In-situ Pyrite Geochemistry
ZHENG Haozhu, WANG Hui, XU Deru, MAO Jingwen, Yu Fucheng, Wang Changjia, Wang Kaibin
Abstract:
The De’erni large-scale Cu-Co-Zn deposit is located within the Animaqing ophiolitic mélange belt on the southeastern margin of the East Kunlun orogenic belt. It represents a relatively uncommon type of ultramafic-hosted massive sulfide deposit (UM-VMS). The mineralization is dominated by dense massive sulfides, commonly accompanied by carbonate vein-type and stockwork mineralization, characterized by significant enrichment in Cu and Co. In this study, in-situ LA–ICP–MS U–Pb dating was performed on hydrothermal apatite from carbonate–chalcopyrite±cobaltite-siegenite veins that cut through massive pyrite ores. The obtained U–Pb age of 125.28 ± 0.87 Ma (n = 30) indicates that the overprinting hydrothermal mineralization occurred in the Early Cretaceous, likely associated with magmatic activity related to post-collisional intracontinental extension following the closure of the Paleo-Tethys Ocean. Apatite trace element geochemistry reveals a pronounced positive Eu anomaly (Eu/Eu* = 8.94–16.28) and a weak negative Ce anomaly (Ce/Ce* = 0.50–0.63), reflecting a relatively oxidizing fluid environment during this mineralization stage. LA–ICP–MS analysis of pyrite reveals significant differences in metal concentrations among different generations: pyrite formed during the serpentinization stage (Py1) is enriched in Ni, Co, and Cu with high variability; pyrite from the exhalative sedimentary stage (Py2) shows significantly decreased Ni contents but marked enrichment in Co and Cu; whereas pyrite formed during the hydrothermal superposition stage (Py3) is depleted in Co, Cu, and Ni. These results further confirm that extensive seafloor serpentinization released ore-forming elements from the ultramafic host rocks. Due to differences in geochemical behavior, Co and Cu preferentially entered circulating seawater and were subsequently enriched and precipitated during hydrothermal exhalative mineralization. Later, under an intracontinental extensional regime in the Early Cretaceous, deep-seated magmatism drove oxidized fluids along major faults, promoting the leaching, mobilization, and re-enrichment of Cu, Co, and Ni. This study enhances our understanding of the ore-forming processes in the De’erni deposit, a unique mineralization type, and provides important insights into the mechanisms of extreme cobalt enrichment in hydrothermal systems.
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Cenozoic Sedimentary Environment-Tectonic Evolution and Its Control on Saline Minerals in Qaidam Basin
PAN Tong), ZHANG Jinming), JIANG Chengwu), ZHU CHUANBAO, zhang shaodong, CHEN xiaoning
Abstract:
The Qaidam Basin, located on the northeastern margin of the Tibetan Plateau, is a typical inland petroliferous and evaporite basin. Its Cenozoic tectonic evolution and evaporite mineralization processes exhibit a significant spatiotemporal coupling relationship. Based on geological surveys, drilling data, isotopic geochemistry, and previous research results, this study systematically analyzes the control mechanisms of tectonic activities from the Paleogene to the Quaternary on the source, migration pathways, reservoir space, and subsequent alteration and preservation of saline minerals from the perspective of the "source–migration–reservation–alteration–preservation" mineralization system. The Cenozoic tectonic evolution of the Qaidam Basin is subdivided into three stages: the Paleogene fault–depression transition period (65–23 Ma), the Neogene compressional uplift period (23–2.6 Ma), and the Quaternary basin–mountain coupling period (2.6 Ma–present). The results indicate that the coupling of tectonics, sedimentation, and climate dominated the entire process of evaporite mineralization: the Paleogene basement faulting formed secondary depressions that provided sources and space for the initial accumulation of saline minerals; the Neogene compression formed anticlinal structural belts, which served as key pathways for the migration and enrichment of deep brines; and the eastward migration of the Quaternary depositional center, combined with an extremely arid climate, jointly facilitated the final formation of super-large potash and lithium salt deposits such as the Qarhan Salt Lake. Through comparison with typical global salt basins, this study enhances the understanding of evaporite mineralization patterns on the northern margin of the Tibetan Plateau and provides a theoretical basis and target recommendations for deep brine exploration.
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Research and Discussion on the Fundamental Concepts of Geomechanics: Commemorating the 70th Anniversary of the Publication of
LV Guxian, Deng Jun, LI Xiaobo
Abstract:
In 1953, Li Siguang published the paper "On the Triple Fundamental Concepts of Geological Structures," which discussed the definitions, categories, and geological implications of structural elements of tectonic traces, block morphology, and tectonic systems. He proposed the "triple fundamental concepts," which are independent yet overlapping and interrelated, leading the development of earth system science. This paper analyzes new data from the past 70 years, focusing on the fundamental concepts of geomechanics, including basic theory, application directions, and investigation methods, and explores the development of the geomechanics discipline.
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Geochemistry and zircon U-Pb isotopic ages of garnet amphibolites from the Hong'an block in the western Dabie orogenic belt and their tectonic implication
Zeng Xiaohua, Liu jia, Tan jun, Sun Siquan, Liu Xiaoyang, Du Wenyang, Liu Lei, Zhang Xiaobo, Xia Kun
Abstract:
The Hong'an block is an important component of the Dabie-Sulu orogenic belt. Studying its high-pressure/ultrahigh-pressure metamorphic rocks can provide valuable insights into the tectonic evolution of this orogenic belt. Three types of garnet amphibolite, exposed in northern Macheng of the Hong'an block, were selected for zircon U-Pb isotopic dating and geochemical compositions of zircon and whole-rock. In this study, ages of the metamorphism and protolith rocks and nature as well as the tectonic evolution context are discussed. Zircon U-Pb isotopic dating results reveal two age peaks (244-240 Ma for metamorphism and 817-772 Ma for formation of the protolith rocks). Rock sample LH1 exhibits low silicon content (SiO2 = 44.42 wt.%–49.29 wt.%) and high aluminum content (Al2O3 = 15.36 wt.%–16.31 wt.%), with a rare earth element (REE) distribution pattern similar to that of E-MORB. Rock sample LH2 shows relatively high SiO2 content (48.47 wt.%–52.49 wt.%), with a REE pattern being enriched in light REEs (LREEs). Rock sample LH3 displays geochemical characteristics of high silicon content (SiO2 = 56.60 wt.%–57.47 wt.%) and low aluminum content (Al2O3 = 13.51 wt.%–14.25 wt.%), enriched in large ion lithophile elements (LILEs) and depleted in high field strength elements (HFSEs), similar to that of continental arc andesite (CAA). Based on these resutls, the eclogites exposed in northern Macheng record middle Triassic metamorphism and preserve evidence of the Neoproterozoic thermal event in their protoliths. The protolith of sample LH1 is likely basalt forming in a back-arc basin and those of samples LH2 and LH3 are likely juvenile crustal rocks of the Yangtze block. The Hong'an block underwent detachment and exhumation of the subducted continental crust after the formation of a back-arc rift basin along the Yangtze block in the Neoproterozoic and Triassic continental thrusting during the Dabie orogeny.
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Does Qingbaikouan Exist or not in Yanliao Rift?——A ~1320Ma mafic sill of the Yanliao Lips imposes constraint on the depositional age of the Jingeryu Formation of Qingbaikouan
Tianhui, Sun li xin, Li Huaikun, Zhong Yan, Ren Yunwei, Zhang Jian, Change Qingsong, Yu Jianzhong, Chu Hang
Abstract:
For decades, the 810~900 Ma 40Ar-39Ar Age of the glauconite from Jingeryu Formation has been used to establish the temporal-spatial framework of the Qingbaikouan,which occupies the upper part of the Tianjin Jizhou Middle and Upper Proterozoic Standard Section in the Yan-Liao Rift. Recent isotopic studies of Proterozoic and Neoproterozoic strata in the Yan-Liao Rift have yielded substantial constraints on the these strata ages, except for the Qingbaikouan which remains ambiguous. Several mafic sills intrude into the Jingeryu Formation were found in this research around Jiashan Town, Chengde City. These mafic sills demonstrate clear contact relationships with the host rocks, and the sequences under and above the host rocks are well-defined. A zircon U-Pb age of 1327±23Ma was obtained from one of these mafic sills. The finding confirms that the original Qingbaikouan in the Yan-Liao Rift predates the Yan-Liao Lips(~1320Ma). Consequently, similar to the Xiamaling Formation, the original Qingbaikouan—including the Longshan and Jingeryu Formations should be classified as early members of the Daijianian. There is No significant sedimentary gap exists between the Xiamaling Formation and the overlying strata. The Longshan and Jingeryu Formation will be placed at the lower part of Ectasian in the International Chronological Chart. Neoproterozoic Qingbaikouan are proved to be excluded from the strata sequences in the Yan-Liao Rift, The sedimentary interval from the Changzhougou Formation to Jingeryu Formation is constrained to 1670-1320 Ma.
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Methodological Innovations in the Compilation of the New Generation “Five-in-One” Metallogenic Regularity Map
Abstract:
The compilation of the new generation of the “Five-in-One” metallogenic regularity map represents a core innovation in China’s Mineral Geological Records project. It aims to systematically and standardizedly express the five key attributes of ore deposits—mineral type, deposit type, scale, metallogenic epoch, and affiliated deposit-metallogenic series—through a well-structured symbolic system. The design follows a hierarchical and progressive principle: A foundational three-in-one legend is first established, using geometric shapes to represent deposit types, size to indicate deposit scale, and color or pattern to denote commodity type. This basic legend is applicable to mineral geological maps. A colored ring is then added to represent the metallogenic epoch. Finally, affiliation with a specific deposit-metallogenic series is indicated through marginal annotations and unique symbols, completing the “Five-in-One” legend tailored for metallogenic regularity maps. This legend system is supported by a unified classification scheme covering 182 mineral types, refining and standardizing the representation methods for metallic, non-metallic, energy, and hydro-gas resources, with particular attention to the symbolic notation of special minerals such as gemstones and jades. The design emphasizes the importance of host rocks in deposit classification and exploration applications, ensuring the legend is both scientifically rigorous and practically applicable. Deposit scale is strictly classified based on cumulative identified resource reserves and visually conveyed through legend size. Metallogenic epochs are represented by peripheral color rings, while affiliation with metallogenic series is linked via specific symbols and codes, clearly illustrating the spatio-temporal distribution patterns and genetic relationships of deposits within regional metallogenic systems. This innovative legend design effectively addresses the challenge of visualizing complex metallogenic information, providing a unified, standardized technical framework for the compilation of national and provincial Mineral Geological Records, as well as for mineral prediction, exploration, and prospecting. It serves as a crucial tool for advancing metallogenic regularity research toward standardization and quantification.
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Discovery of Neoproterozoic gabbro in Alxa block and its geological significance
chenlinjun, jiangsihong, chenlei, liuyifei, yanpengcheng, chenyanjing
Abstract:
A large number of Precambrian rocks are developed in the Alxa block. For a long time, the attribution of the Precambrian in the Alxa block has been controversial. The early Neoproterozoic gabbro was found in nuergong area of Alxa block for the first time, which provides new evidence for the attribution of Alxa block. Systematic petrology, zircon U-Pb geochronology and Lu-Hf isotopes of gabbros were studied. The zircon LA-IC-MS U-Pb ages of the two gabbro samples are 944 ± 7 Ma and 953 ± 6 Ma, respectively, belonging to the early Neoproterozoic. The results show that the SiO2 content of gabbro is 43.11% ~ 47.00%, MgO is 6.33% ~ 11.59%, TiO2 is 1.55% ~ 4.63%, which is a high aluminum subalkaline tholeiite series; Gabbro is rich in Rb, Ta, Zr, Ti and other elements, and depleted in Ba, Nb, Sr, Hf and other elements. It has a slightly right dipping REE distribution curve pattern, and the Eu anomaly is from weak negative to strong positive (δEu =0.84 ~ 1.65). The zircon Hf isotope ε Hf(t) is +2.2 ~ +6.6, and the single-stage model age (tDM1) is 1244 ~ 1426 Ma. The formation of gabbro is mainly controlled by the partial melting of asthenosphere mantle, and the parent magma is contaminated by crustal materials in the rising process. Through comparison, it is found that the gabbros developed in Alxa block are the product of a relatively common early Neoproterozoic extension event in the world, which may be related to the breakup of Rodinia supercontinent. The Precambrian evolution of Alashan block may be more related to the North China Craton.
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The response relationship between the sedimentary model and tectonic deformation of the Cambrian Gaotai Formation in eastern Sichuan and its significance in oil and gas geology
Abstract:
Previous studies have paid limited attention to both the intrinsic deformation mechanisms of the evaporite-bearing sequences within the Cambrian Gaotai Formation in eastern Sichuan and the relationship between sedimentary facies distribution and salt tectonic deformation. Consequently, the location of grain shoals along the margins of salt sags within the Gaotai Formation cannot be constrained, which has hindered petroleum exploration targeting this formation. To address these issues, this study integrates structural interpretation of seismic reflection profiles from the north-central part of eastern Sichuan, numerical simulation of structural deformation, fold uplift age data, drilling data, and thickness information of the overlying Xixiangchi Formation. This multi-faceted approach was used to investigate the development mechanisms of Gaotai Formation salt structures, the response relationship between salt tectonic deformation and original deposition, and to summarize the characteristics of favorable zones for grain shoal facies along the Gaotai Formation salt depression margins. The results indicate that: (1) The synclinal zone corresponds to the marginal zone of the saline depression during the depositional period of the Gaotai Formation, while the anticlinal area matches either the center of the saline depression or the facies transition zone between the saline depression and its margin. (2) The primary mechanisms for salt structure development in the salt depression areas are contraction and buoyancy forces. (3) The incongruous folds beneath the Gaotai Formation within the synclinal areas represent favorable zones for hydrocarbon accumulation.
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MATHEMATICAL RELATION BETWEEN THE EXCESS AREA WITH DEPTH TO DETACHMENT AND CRESTAL STRUCTURAL RELIEF OF DETACHMENT FOLDS
yanggeng, CHEN Zhuxing, Ren Rong, Su Nan
Abstract:
Detachment folds seem conceptually and geometrically the simplest of all fault-related folds, and researches on them mainly focuses on geometric analysis and genesis mechanisms. Detachment folds are defined by competent rocks units and are cored by incompetent units deformed internally above a detachment horizon.Many detachment folds may analyzed using a simple geometric model. Early mathematical triangle’s models of detachment fold were developed into various geometric models, and the theoretical calculation of the excess area of these fold models is only related to the length and dipping angle of the fold limbs. However, in practical applications, the area-depth-strain (ADS) methods is widely used to calculate the depth to detachment, shortening, and parallel strain of the formation, indicating a disconnect between theoretical models and practical applications. Based on this, this article establishes a theoretical relationship between the excess area of concentrated special types of detachment folds, such as box fold,lift-off fold,symmetric fold and asymmetric fold, and the depth to detachment. Based on the definition of excess area and depth to detachment in the deformation of detachment folds, assuming a constant thickness of the stratum and known height of the fold core structure (Crestal Structural Relief) and strata dip angles of the fold-limbs, this paper establishes the mathematical relationship between excess area and depth to detachment of different structural geometric styles of Swiss Jura detachment folds, such as box shaped detachment folds, lift-off detachment folds, symmetrical detachment folds with limbs dip angles, and asymmetrical detachment folds with limbs dip angles. A fast calculation method for the shortening of detachment fold deformation and depth to detachment is obtained. It should be noted that according to the principles of geometry, the geometric shape of box-shaped detachment folds remains basically unchanged, while the geometric shape of lift-off detachment folds transform upwards into chevron folds. Symmetric folds and asymmetric folds, due to the presence of a basal incompetent plastic layers, have different mathematical relationships between their excess area and the depth to detachment above and below specific fold deformation layer. It is referred to as a transition layer or Detachment Conversion Layer(DCL). In addition to differences in geometric styles, the deformation mechanisms of this transition layer also differs.
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Geometry and kinematics of strike-slip fault related structural patterns and their metallogenetic effects
CHEN Xuanhua, HAN Lele, ZHANG Yiping, WANG Ye, MA Feizhou, DING Weicui, SU He, XU Shenglin
Abstract:
Large-scale strike-slip faults developed at plate or terrane boundaries and intra-plate tectonic settings, serving as a prominent feature of tectonic deformation on the Earth""s surface. They can be categorized into convergent and divergent strike-slip faults. Based on previous studies on strike-slip fault-related structures, this study proposes a new classification system for them. The proposed framework divides strike-slip fault-related folds into three end-members, i.e., strike-slip fault-bend folds, strike-slip fault-propagation folds, and strike-slip detachment folds, along with composite styles of strike-slip interference folds, and establishes their geometric and kinematic models. The study introduces two new types of lotus-shaped superimposed folds related to strike-slip faulting, namely the Kulumudishan-type and Maidoushan-type superimposed folds, along with their formation mechanisms, and elucidates the developing process of strike-slip growth anticlines. It is concluded that strike-slip fault-related structures can serve as significant kinematic indicators for strike-slip faults. Using the West Junggar Orogenic Belt in Central Asia as an example, the study elucidates how the strike-slip fault activity controlled on the migration, concentration, and metallogenic effects of ore-forming elements through tectono-physicochemical processes.
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Multistage Mesozoic Exhumation–Erosion Processes and Tectono-Sedimentary Coupling in the Southern Margin of the Micang Mountain, South China
Zhang Mengfei, Qiu Nansheng, Chang Jian, Feng Qianqian, Li Chenxing, Liu Xin, Long Kangjie
Abstract:
The formation of the Micang Mountain Uplift is closely related to plate collision and the uplift of the Qinling Orogenic Belt. Previous research has predominantly focused on its uplift-erosion processes since the Middle-Late Mesozoic, though there remains controversy regarding its specific uplift process. This study selected Precambrian samples from the southern margin of the Micang Mountain Uplift to conduct low-temperature thermochronology experiments, combined with detrital zircon U-Pb age data from Mesozoic strata in the region, to systematically reconstruct the multi-stage uplift-erosion history since the Early Mesozoic. The research results show that the median age range of zircon fission tracks is 277±27Ma to399±39Ma, while the zircon (U-Th)/He age range is 136.4±6.8Ma to 290.0±14.5Ma. Through thermal history simulation, the tectonic evolution of the Micang Mountain Uplift since the Mesozoic can be divided into four stages: 1) from the Late Triassic to the Middle Jurassic, affected by the closure of the Mianlue Ocean and the subduction of the Yangtze Block under the Qinling Block, the Micang Mountain region began an initial slow uplift; 2) from the Late Jurassic to the Early Cretaceous, the continuous collision between the Qinling Block and the Yangtze Block triggered intense intracontinental orogeny, leading to rapid uplift of the Micang Mountain region; 3) from the Late Cretaceous to the Neogene Miocene, the region entered a brief tectonic quiescence period due to adjustments in regional plate movements; 4) since the Miocene, affected by the eastward propagation of the Tibetan Plateau’s uplift, the region has experienced another phase of rapid uplift and denudation. Detrital zircon U-Pb age spectra indicate a significant increase in Neoproterozoic zircons in the strata from the Upper Triassic to the Lower Jurassic, indicating that uplift had already initiated in the Late Triassic, which aligns well with the initial uplift timing indicated by low-temperature thermochronology data. This study reconstructs the tectono-thermal evolutionary history of the southern margin of the Micang Mountain Uplift since the Mesozoic, clarifies the temporal and spatial coupling relationship between the multi-stage uplift-erosion processes and multi-episodic plate tectonic movements, and provides new evidence for understanding plate collision dynamics and Qinling Orogen evolution
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Comparison of Geochronological Methods for Uranium-rich Granites: A Case Study from the Ziyunshan Uranium-rich Granite in Central Jiangxi Province*
Huang Chao, Li Guanglai, Yang Yongle, Meng Siyuan, Zhong Zhaoxuan, Zhou Maoqiang, Xu Kai, Liu Xiaodan
Abstract:
Zircon in uranium-rich granites frequently undergoes intense metamicization owing to elevated uranium content, resulting in unreliable U-Pb dating outcomes and complicating the accurate determination the U-Pb age of zircon from such granite. To tackle the challenges associated with precise dating of high-uranium granites, this study investigates the Ziyunshan pluton in central Jiangxi. Comprehensive petrographic and petrochemical analyses were performed, confirming its classification as a typical uranium-rich peraluminous granite. Using α-track etching technology, uranium-bearing minerals were identified and characterized through scanning electron microscopy and electron probe analysis. These analyses revealed primary magmatic minerals, including zircon, monazite, xenotime, and uraninite, alongside hydrothermal secondary minerals such as coffinite and thorite. Geochronological investigations of the principal uranium-bearing minerals indicated that zircon, affected by intense metamicization, produced scattered and anomalously young LA-ICP-MS U-Pb ages (142.8 ± 1.0 Ma), suggesting an open isotopic system. In contrast, monazite yielded a weighted average age of 150.5 ± 0.8 Ma, which is both consistent and reliable. Additionally, the electron probe U-Th-Pb chemical age of uraninite was determined as 151.4 ± 1.7 Ma, aligning with previously established rock formation ages. This study demonstrates that monazite, owing to its strong radiation resistance and robust isotopic system, can serve as an effective alternative to zircon for dating uranium-rich granites. Furthermore, electron probe chemical dating of uraninite proves to be a feasible and accurate method, offering valuable insights for geochronological studies of similar granite.
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Interpretable Machine learning-Based intelligent discrimination of Rhyolite Tectonic Settings
He Yuxing, He Haiyang, Xu Tangxing, Li JianXiong, Shen Qinqin, Zhang Huanbao, Liu Ke, Li Penggang, Li Xiangcheng
Abstract:
The discrimination of tectonic settings for rhyolites holds significant importance in geodynamic research. However, traditional graphical methods, constrained by low-dimensional parameter spaces and the influence of post-emplacement alteration, struggle to effectively resolve complex magmatic genetic mechanisms, leading to uncertainties in tectonic discrimination results. In recent years, machine learning (ML) techniques have been widely applied in Earth sciences, with intelligent identification of tectonic settings based on multi-dimensional geochemical feature analysis and pattern mining emerging as a critical research direction. This study utilizes the global rhyolite geochemical database (GEOROC) to establish a systematic dataset comprising 5,874 high-quality rhyolite samples, incorporating 46 parameters including major, trace, and rare earth element (REE) concentrations and ratios. Nine ML classifiers were developed, encompassing ensemble tree models (XGBoost, LightGBM, CatBoost), support vector machines (SVM), and deep learning architectures (MLP, TabPFN), with hyperparameters optimized via the Optuna algorithm to enhance model performance. Experimental results demonstrate that the Transformer-based TabPFN model achieved optimal performance without hyperparameter tuning, attaining a test-set accuracy of 88.37% and AUC value of 98.39%, highlighting its superiority in geochemical data learning. The optimized LightGBM model exhibited an improved average accuracy of 87.98%, confirming the efficacy of hyperparameter optimization. Interpretability analyses using SHAP (SHapley Additive exPlanations) and LIME (Local Interpretable Model-agnostic Explanations) identified critical discriminators including Cs, Hf, and Th/Ta ratios, whose contributions correlate closely with geodynamic processes such as subduction-related fluid activity, mantle partial melting, and crust-mantle interactions. Meanwhile, trace elements traditionally overlooked in conventional studies (e.g., Ga, Co) exhibited significant classification power, suggesting the potential value of multi-element synergy analysis in tectonic discrimination. This research demonstrates that integrating high-dimensional geochemical data with interpretable ML models substantially enhances tectonic setting identification accuracy, providing a novel methodology for determining the tectonic affinity of felsic magmatic rocks and advancing regional geodynamic evolution studies.
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Genesis of the Shaliuhe chromite body in the Northern Qaidam Orogen: Evidence from in-situ mineral and whole-rock elemental compositions
Zhuang Wu, Hongfu Zhang, Mingjie Zhang, Zheng Zhao, Changhai Luo, Haikui Tong
Abstract:
The Shaliuhe chromite body, situated in the Northern Margin of the Qaidam Basin (northeastern Qinghai-Tibet Plateau), is a newly discovered podiform chromitite hosted in an ophiolitic sequence, which provides an important basis for chromite exploration in the northeastern Tibetan Plateau. This study analyzed the mineral chemistry of chromite and the whole-rock major and trace element compositions of the ophiolite to investigate the genesis of the chromite, the composition of the parental magma, and the tectonic setting. The results are as follows: The chromite in the Shaliuhe ophiolite can be divided into primarily magmatic origin with some hydrothermal modification, and is generally of high-Cr type with a Cr# (chromium number) ranging from 61.74 to 99.74 (average 85.67). The chromite has a low TiO2 content (0.04–0.29 %), which is consistent with the typical geochemical characteristics of ophiolite-hosted chromitite. The chromite formed in a forearc tectonic setting of a subduction zone with a specific "magma-dominated + fluid-reworked" genetic mechanism: In the early stage, boninitic melts interacted with mantle peridotite through melt-rock reaction and melt mixing, promoting Cr saturation and crystallization to form primary chromite. In the late stage, serpentinization fluids dissolved and reworked the primary chromite, and the metasomatism by subduction-related slab fluids/melts influenced the final morphology and local re-enrichment of chromite. The parental magma exhibits a boninitic affinity and was derived from a highly depleted forearc mantle. The Shaliuhe ophiolite belongs to the SSZ (supra-subduction zone) type. The mantle source was dominated by forearc mantle peridotite, which underwent a high-degree partial melting process (exceeding 25%). This study provides a regional case for understanding the genesis of ophiolite-hosted podiform chromitite and offers a scientific basis for assessing the chromite resource potential in the North Qaidam Orogen.
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Polygenetic garnet records subduction, exhumation and anatexis of the Sulu orogenic belt
ZHANG Ruirui, LIU Zhong''ao, LI Yang, CAO Yuting, MENG Yuanku, LI Xuping, Wang Songjie
Abstract:
Garnet, owing to its exceptional physicochemical stability and strong capacity to incorporate trace elements, is widely employed to constrain metamorphic conditions and interpret geological processes. However, during continental deep subduction and exhumation, garnet often exhibits complex compositional zoning and multi-stage growth or modification, complicating its geological interpretation. This study investigates phengite-rich gneisses and leucogranites from the Yangkou area of the Sulu orogenic belt, integrating inclusion petrography with major- and trace-element analyses of garnet. Four types of garnet with distinct genetic origins are identified: Grt I (gneiss core) formed during prograde to peak high-pressure–ultrahigh-pressure metamorphism; Grt II (gneiss mantle–rim) represents dissolution–reprecipitation induced by external melt infiltration during exhumation; Grt III (leucogranite core) records diffusive modification of captured metamorphic garnet by anatectic melt; and Grt IV (leucogranite mantle–rim) crystallized directly from the evolved granitic melt at a late magmatic stage. This sequence of four garnet generations systematically documents the evolution of the continental crust from subduction through exhumation to anatexis, highlighting the significant influence of melt–rock interaction on garnet chemistry. Combined zircon geochronology and calculated rare earth element (REE) partition coefficients reveal that peak-stage Grt I is significantly enriched in HREE relative to coexisting zircon, indicating that garnet may serve as the principal HREE reservoir under “dry” metamorphic conditions. In contrast, Grt IV and associated zircon display near-equilibrium partitioning or slight HREE enrichment in zircon, consistent with experimental observations from melt-bearing systems. These results elucidate the multi-stage evolution of garnet in the Sulu UHP rocks and provide new insights into melt activity, mineral competition, and element redistribution during deep continental subduction.
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Indicator Study of Garnet for Diamond Provenance in the Chenggang–Xinyi Area, Northern Jiangsu
CAI Yitao, ZHANG Qi, XIAO Bingjian, WANG Guoqiang, ZHOU Qizhong, ZHANG Xuan, ZHAO Yu, ZHANG Yingjie
Abstract:
The Xinyi diamond placer is the only diamond-bearing placer deposit with proven resources in Jiangsu Province. However, the provenance of the diamonds and the exploration clues for potential primary deposits have long remained unresolved. In this study, systematic analyses of garnets from heavy mineral samples in the Chenggang–Xinyi area were conducted to trace the source region and to explore new indicators for primary diamond deposits. Bulk samples from the Xinyi placer (XK01, XK02, and XK03) and artificial heavy mineral concentrates from mafic–ultramafic rocks in the Chenggang Uplift were collected. Major-element compositions of the garnets were quantitatively analyzed using an electron microprobe, yielding 288 valid datasets. The results show that garnets from both the placer and the Chenggang Uplift are similar in composition, dominated by G3- and G4-type garnets, with occurrences of G3D-type garnets. The major-element compositions of garnets from the placer display a significant linear correlation with those from the Chenggang Uplift, indicating consistent elemental trends. This geochemical relationship suggests that the diamonds in the Xinyi placer were derived from metamorphosed pyroxenite within the Chenggang Uplift. Future exploration should therefore focus on identifying eclogite-type (E-type) indicator minerals. The garnets from the placer bulk samples mostly retain angular crystal shapes and resorption features, reflecting short-distance transport and implying that the diamonds were not transported over long distances but originated from local primary sources. These findings provide new mineralogical evidence for constraining the regional diamond metallogenic potential and guiding further exploration in northern Jiangsu.
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Three-dimensional shear wave velocity tomography of the upper crust in the Tongling ore concentration area
zhaorongtao, fengmei, anmeijian, yangyan, shidanian, liushasha, huangshi
Abstract:
Located in the Middle-Lower Yangtze River Metallogenic Belt, Tongling represents a unique ore concentration area. The velocity structure of its shallow crust plays a crucial role in deciphering the Mesozoic metallogenic processes of the entire ore district and holds considerable value for deep mineral exploration. During 2022–2023, we deployed 57 temporary broadband stations with a minimum inter-station distance of 2-5 km in eastern Tongling. We apply the continuous records to derive a high-resolution three-dimensional shear-wave velocity structure of the upper-crust in the study region by ambient noise surface tomography. The results show that the S-wave velocity in the shallow part of Xuannan Sag is significantly lower than that of Tongling Uplift, and the boundary of S-wave velocity anomalies delineates well the occurrence of the Dingqiao–Daihui Fault, which dips southeastward and extends to a depth of ~3 km. The S-wave velocity below 1 km depth of the Tongling Uplift is higher (~3 km/s) than that of the Xuannan Sag, implying possible intrusions of large-scale granities in the Tongling uplift. These intrusions display a dome-like laccolith beneath the Xinqiao and Shizishan, and a sill-like bedrock in the southern Fenghuangshan region. The results are of great significance for understanding the metallogenic dynamic process of the Tongling ore concentration area, and also provide new evidence for the magmatic underplating model of the Middle-Lower Yangtze River Metallogenic Belt.
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Structural characteristics and evolution of a multi-phase rifting sag within a wide rift basin: A case study of the Chagan Sag, Yin’e Basin
Shan Shuaiqiang, Wang Debo, Fu Mao, Wang Bin, Wan Jing, Yang Yabo, Zhang Chenyu, Shen Bingbei
Abstract:
The Yin"e Basin, located in the central-western part of Inner Mongolia Autonomous Region, consists of a series of Early Cretaceous rift depressions and forms part of the Late Mesozoic wide rift system in Northeast Asia. The Chagan Sag at the eastern margin of the basin is one of the few proven hydrocarbon-rich sags, whose Lower Cretaceous geological structure records the evolutionary process of multi-phase rifting. Conducting research on the geological structure and evolution of Chagan Sag is not only significant for revealing the evolution of Early Cretaceous intracontinental rift basins in northern China, but also provides valuable references for identifying hydrocarbon-rich sags and evaluating exploration targets in the region. Based on integrated datasets including 3D seismic surveys, drilling data, core samples, and field geological investigations, this study systematically investigates fault systems through structural analysis methods to characterize the grouping and evolutionary stages of major faults. The research identifies and delineates volcanic edifices to examine episodes of volcanic activity, reconstructs the Structural evolution since the Early Cretaceous using balanced cross-section techniques, and comprehensively analyzes the Early Cretaceous tectonic-sedimentary filling processes in the Chagan Depression. This study shows that the Chagan Sag exhibits well-developed volcanic-sedimentary interbeds, which can be vertically subdivided into three distinct structural layers: the rift structural layer, rift- depression transition structural layer, and depression structural layer. Within the rift sequence, three fault systems with NNW-, NNE-, and NE-trending orientations are identified, exhibiting an east-west zonation structural pattern. Three distinct episodes of volcanic activity are recognized in the Lower Cretaceous Suhongtu Formation, displaying a clear SE-to-NW migration trend throughout the sag. The results demonstrate that the Chagan Sag developed as a volcanically rift basin during the Early Cretaceous, having undergone a complete evolutionary sequence from rifting through rift-depression transition to depression since the Cretaceous. The rifting stage can be further subdivided into: (1) initial rifting phase, (2) intense rifting episode I, and (3) intense rifting episode II. Spatiotemporal variations in the activity of master faults were found to exert fundamental control on both the structural evolution of the sag and the migration patterns of volcanic activity.
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Physical simulation study on the development and evolution of fault systems under the coupled control of extension direction changes and basement fault activatio
Zhangyiyong, Huang lei, LiXin, LiWei, Wangshaohao, WangRuoWei, WangWei, Liuchiyang
Abstract:
The study of extensional fault systems is crucial for deciphering the tectonic evolution of rift basins and revealing regional geodynamic mechanisms. Although physical simulations have demonstrated that stress orientation and basement fault activity are key factors controlling extensional structures, the three-dimensional evolutionary processes of fault systems under the coupled influence of multi-phase extension direction changes and basement fault reactivation remain insufficiently explored. This study employs a physical modeling platform to simulate the evolution of extensional fault systems under two-phase extension with varying directions, based on pre-defined basement faults. During the first-phase orthogonal extension, a fault zone consisting of long straight boundary faults perpendicular to the extension direction and internal short faults was formed, with a transition from soft to hard linkage observed at fault stepovers. In the second-phase oblique extension, pre-existing faults generated during the earlier orthogonal extension continued propagating upward as inherited cover faults, exhibiting a staged evolution: In the initial stage, fault reactivation dominated within the fault zone, characterized by reactivated faults of varying lengths and unchanged strikes; During the intermediate stage, fault strikes within the zone began to shift, accompanied by newly formed faults with heterogeneous orientations, resulting in more complex structural patterns and cross-cutting relationships; In the late stage, an increasing number of peripheral new faults emerged, displaying en-echelon arrangements orthogonal to the extension direction and sensitive to stress field variations. Furthermore, PIV technology precisely captured the spatial reactivation positions of secondary faults and the timing of new fault formation during oblique extension, revealing differential fault development and linkage mechanisms within the fault zone. The experiments demonstrate that the evolution of late-stage fault systems is jointly controlled by basement faults, pre-existing cover faults, and extension direction. Basement faults play a fundamental role in shaping the overall fault zone architecture, while the extension direction significantly influences the morphology and structural characteristics of faults both within and outside the zone. The simulation results align with natural deformation examples, providing a model and guidance for tectonic analysis in similar geological settings.
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Geochemical characteristics of the Xujiahe Formation in the Muchuan area of southwestern Sichuan Basin and its indicative significance for the paleoenvironment and tectonic background of the source region
liu jianqing, zhao zhan, feng weiming, lu junze, feng xinglei
Abstract:
The material composition of clastic rocks is closely related to the tectonic background and paleoclimatic conditions of the source area. The study of sedimentary geochemistry can not only trace the tectonic environment of the source area during the sedimentary period, analyze paleoclimate and environmental conditions, but also enrich and improve the scientific system of sedimentary geochemistry. Research on this aspect of the Xujiahe Formation in the Muchuan area of southwestern Sichuan Basin has not yet been carried out. Based on profile measurement and microscopic research, geochemical studies of the Xujiahe Formation in Muchuan were carried out. Research shows that: (1) The Xujiahe Formation is mainly composed of debris sandstone, with a large amount of sub-volcanic debris, a small amount of metamorphic rocks (schist, calenite) and polycrystalline quartz. The chemical analysis of major elements shows that it is rich in quartz. The material sources come from passive continental margins, active continental margins and continental island arcs; (2) The sandstone and mudstone of the Xujiahe Formation is rich in light rare earths and has obvious negative Eu anomalies. The standardized curve shapes of the average mudstone are similar. The contents of Sr, Cu and Mo are lower than those of the average mudstone. The contents of Ga, V, U, Th, Cr, Co, Sc and Rb are close to those of the average mudstone. The contents of Ba, Ni and Zn are slightly higher than or close to those of the average mudstone. The elements Zr and Hf with terrestrial properties are significantly higher than those of the average mudstone. Geochemical characteristics show that it mainly comes from feldspar volcanic rocks, sedimentary rocks, granites and andesite; (3) The source area of the Xujiahe Formation suffered from moderate chemical weathering during sedimentation and was a warm and humid sedimentary environment. Evaporation and oxidation in the basin are relatively intense, and the water body has the characteristics of brackish water, with an ancient salinity ranging from 7.10‰ to 20.60‰. During the sedimentation process, the stratification of the water body was weak to moderate, and a reducing sedimentary environment occurred locally. The origin of the Xujiahe Formation is closely related to the convergence and rifting of the Kenorland, Columbia and Rodinia paleocontinents in southern China, as well as the early Paleozoic passive continental margin basin, the Caledonian collision orogeny, the Haixi-Indosic rifting cycle and the Late Triassic Paleo-Tethys Ocean closure collision orogeny. It is a sedimentary material for the re-cycle orogenic belt. And mainly they are long-distance sources in South China, with a small amount being close-range sources in the Kangding – Yunnan Paleocontinent. The source rock type is the silicon-aluminum layer of the upper crust and they are similar; The semi-arid and oxidizing paleoclimate environment within the basin is related to the surrounding closed paleoctopographic conditions, poor air circulation and strong evaporation.
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Early Paleozoic Post-Orogenic Extension in the Northern Altun Tagh: Constraints from Geochronology and Geochemistry of Diabase Dykes
FU Shunhao, YANG Mingcan, DAI Lingqi, YE Xiantao
Abstract:
The North Altun Orogenic Belt, a key part of the Qinling-Qilian-Kunlun orogenic system, preserves critical records of the evolution of the Proto-Tethys Ocean. However, the timing of its tectonic transition from post-collisional compression to extension remains poorly constrained. This study presents detailed field investigations, zircon SIMS U-Pb dating, and whole-rock geochemical and Sr-Nd isotopic analyses of newly identified diabase dikes in the Kaladawan and Aktash areas in the North Altun terrane. Zircon U-Pb dating reveals that the diabases emplaced at ca. 441 Ma. The rocks are classified as tholeiitic basalts, exhibiting low MgO (4.07%~4.47%) and total alkali (Na2O+K2O=4.84%~5.82%) contents with relatively high Fe2O3T (16.18%~16.75%). They are enriched in light rare earth elements (LREE) and large-ion lithophile elements (LILE) but depleted in high-field-strength elements(HFSE), displaying pronounced negative Nb-Ta-Zr-Hf-Ti anomalies on primitive mantle-normalized spider diagrams. Furthermore, their high initial 87Sr/86Sr ratios (0.7117~0.7125) and extremely low εNd(t) values (?20.0~?19.8) indicate derivation from an ancient lithospheric mantle which metasomatized by fluids released from subduction slab. These findings suggest that the diabases are direct products of post-orogenic extension, thus constraining the timing of the tectonic regime from compression to extension in the North Altun Orogenic Belt occurred at ca. 441 Ma.
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Geochemical Characteristics of Guidong Pluton in Eastern Guangdong and Their Constraints on the Formation of Ion-adsorption Rare Earth Deposits
guo min, tan juan juan, wang lei, tong Xirun, HUANG Huagu, XIAO Xilian, WANG Jietao, SHAO Xin, qiu xiao fei
Abstract:
The enrichment mechanism of rare earth elements in ion-adsorption rare earth deposits is a hot topic in ore deposit studies. Comprehensive zircon U-Pb geochronology and whole-rock major and trace element analyses were carried out on the fresh granites from 3 drill hole in the ion-adsorption rare earth deposit of the Guidong pluton in Shaoguan, northern Guangdong. The granites are mainly composed of quartz, potash feldspar, plagioclase and biotite, and are mainly of monzogranite and syenogranite in lithology. Zircon U-Pb dating of two monzogranites and one syenogranite show that their formation ages are 160±1 Ma, 162±1 Ma and 160±2 Ma, respectively, indicating that the western part of the Guidong pluton is formed concentrated at the Early Yanshanian (~160 Ma). These granites are peraluminous to strongly peraluminous, with high alkali content. The syenogranite is highly fractionated, featured by high SiO2 content, low Zr/Hf ratio, and enrichment of K and Rb. It is suggested that the Guidong Yanshanian granites are aluminous A-type granite, which may be derived from the biotite dehydration partial melting of late Paleoproterozoic tonalite under anhydrous conditions, and the syenogranites are the product of intense fractional crystallization of monzogranites. Compared with the adjacent Dadaonshan granites, it is proposed that the intense fractional crystallization of alkaline felsic melts may play an important role for the formation of HREE-enriched ion-adsorption rare earth deposits.
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Fractionation and Accumulation of Rare Earth Elements during in Zhaibei Rare Earth Deposits in Jiangxi,China
Yang Pengtao, Hong Hanlie, Zhao Chenlei, Yin Ke, Zhao Lulu, Liu Chen, Ji Kaipeng, Jia Fuwen
Abstract:
The weathering crust-type rare earth deposits occur widely in South China, but understanding of mechanisms of differentiation and enrichment of rare earth elements (REEs) during weathering process is still very limited. In this study, X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) methods were employed to better characterize the presence of REEs in the Zhaibbei rare earth deposit in southern Jiangxi Province. Our results showed that the Zhaibbei weathering profile of the rare earth deposit preserved the complete in-situ weathering soil layers, including saprolite layer, illuvial layer, eluvial layer, and topsoil layer from the bottom to the top. The saprolite layer contains mainly illite, smectite, and kaolinite. The illuvial layer and eluvial layer have similar clay mineral compositions of dominantly halloysite, kaolinite, and illite, with minor vermiculite, and the topsoil layer is consisted of mainly halloysite, with minor kaolinite and vermiculite. The heavy rare earth elements (HREEs) in the weathering profile are mainly associated with iron oxide minerals and are enriched in iron oxide minerals through substitution and co-precipitation, while the light rare earth elements (LREEs) are mainly associated with halloysite and kaolinite in ion adsorption. In addition, REEs in the upper profile can also form discrete secondary rare earth phosphate minerals. The enrichment and differentiation of REEs during the weathering process are mainly related to clay minerals and hematite. This study reveals occurrence of ore-forming REEs in the weathering crust-type rare earth deposit from the view of direct microscopic observation, which provides key evidence for the differentiation and enrichment process of REEs in rare earth deposits in the South China weathering crust.
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Metallogenic mechanism of ion-adsorbed rare earth deposit in Xiayao, Jiangxi Province
li ruodan, liu xinxing, zhang juan, chen binfeng, huang gang, zhang zhiwei
Abstract:
To restore the complete process of rare earth element enrichment during the formation of Ion-adsorption rare earth type deposits. In this study, the ore-forming parent rock and weathered crust samples in the Xiayao ion-adsorption rare earth type deposit were studied by inductively coupled plasma mass spectrometry (ICP-MS), inductively coupled plasma spectroscopy (ICP-OES), X-ray diffraction experiment (XRD), electron probe, zircon U-Pb dating and Hf isotope test. The Keshubei granite is identifiedas high-K calc-alkaline and slightly peraluminous. Zircon grains from the Keshubei granite exhibit U-Pb ages of 196.26±1.53 Ma, 194.72±1.1 Ma, and 197.18±1.77 Ma. The value of zircon εHf(t) inKeshubei graniterangefrom-3.35to1.79. Rare earth minerals include apatite, zircon, bastnaesite and Xenotime. The rare earth elements in the weathered crust are enriched in the middle and upper parts. It is indicated that the Keshubei granite is the product of Indosinian magmatic activity, which is produced in the ancient felsic crustal remelting environment induced by the extensional tectonic environment. The enrichment process of rare earth elements is mainly related to magmatic evolution, supplemented by hydrothermal action. The secondary enrichment of adsorbed elements in the weathered crust is restricted by clay minerals, pH value and weathering degree.
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Location prediction and exploration of VMS metallogenic system
WANG Jingbin, WANG Yuwang, XIE Hongjing, Li Qingzhe, GENG Jian
Abstract:
The VMS (volcanic massive sulfide) deposits associated with marine volcanic activities, constitute a metallogenic spectrum which range from Cu type, Cu-Zn type, Cu-Pb-Zn type to Pb-Zn type. The deposits are significant sources of minerals such as copper, zinc, lead, silver, gold, and sulfur. Due to the high ore grade, diverse useful components, and high economic value, VMS deposits are a globally important target for mineral exploration. This paper systematically summarizes the classification, ore-forming environment, characteristics of the metallogenic system, and positioning prediction indicators of VMS deposits, proposing that VMS deposits are products of submarine volcanic hydrothermal systems in extensional tectonic settings and are related to marine sodium-rich volcanic rocks.
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Mantle source lithology of ocean island basalts from Réunion Island in the Southwest Indian Ocean
NIU Chen, WANG Xiaojun, ZHAO Jian, LIU Jianqiang, ZHANG Chao, CHEN Lihui
Abstract:
Upwelling mantle plumes can transport deep mantle materials into the shallow mantle. Therefore, identifying the lithological composition of mantle plumes in the shallow mantle is helpful for understanding the Earth's deep mantle compositions and the related geodynamic processes. Seismic tomography reveals that the root of the Réunion mantle plume is connected to the African large low-shear-velocity province in the lower mantle. This suggests that the Réunion mantle plume originates from the lower mantle. However, the lithological composition of this plume remains unclear. Ocean island basalts (OIBs) from Réunion Island were generated by partial melting of the Réunion mantle plume over the past two million years, making them ideal samples for investigating the lithological composition of the mantle plume. To explore the lithological composition of the Réunion mantle plume, this study presents whole-rock major element compositions of the Réunion OIBs, along with the chemical compositions of olivine phenocrysts within these basalts. We first estimated the primary magma compositions of the studied samples, which were found to be rich in MgO and TiO2 but deficient in SiO2, CaO, and Al2O3. When comparing the primary magma compositions with experimental melts of different mantle rocks, we found that they predominantly fall within the range of melts produced by melting of silica-deficient pyroxenite. To further evaluate this proposal, we analyzed the chemical compositions of olivine phenocrysts in the Réunion OIB samples. The results indicate that the Fo value of olivine phenocrysts ranges from 80.1 to 90.1. Notably, high-Fo olivine phenocrysts exhibit elevated Ni contents, reduced Ca and Mn contents, and high Fe/Mn ratios. These olivine compositions resemble those found in Loihi (Hawaii) OIBs, whose source contains silica-deficient pyroxenite, but they are distinctly different from olivine phenocrysts in equilibrium with peridotite-derived melts. This suggests a significant contribution of pyroxenites to the mantle source of Réunion OIBs. Therefore, both the whole-rock major elements and the compositions of olivine phenocrysts suggest that the mantle source lithology of Réunion OIBs primarily consists of silica-deficient pyroxenite. This indicates that the Réunion mantle plume contains pyroxenite components rather than being composed exclusively of peridotite.
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Origins of ore?forming materials and enrichment mechanisms of the Guoluolongwa gold deposit, Eastern Kunlun Orogenic Belt, China
Zhang Xinming, Zhang Libin, Li Wenjun, Wei Junhao, Chen Jiajie
Abstract:
The Guoluolongwa gold deposit, located in the Gouli district of the Eastern Kunlun Orogenic Belt, exemplifies a Late Devonian-Early Carboniferous post?collisional extensional magmatic?hydrothermal vein?type gold system. We employed comprehensive field mapping, backscattered electron imaging (BSE), TESCAN mineral analysis (TIMA), in situ LA?ICP?MS trace element profiling, and LA?MC?ICP?MS sulfur isotope microanalysis to unravel its ore genesis. Four paragenetic stages were delineated—Stage I (quartz-pyrite), Stage II (quartz-arsenopyrite–pyrite), Stage III (quartz-polymetallic sulfides), and Stage IV (calcite-quartz)—and three pyrite generations (Py1-Py3) were identified. Progressive variations in trace element concentrations (Co, Ni, As, Au) and Co/Ni ratios among pyrite generations confirm a dominantly magmatic?hydrothermal fluid source. Pyrite δ34S values decline from 3.77‰ to 5.95‰ in Py1 to -2.60‰ to 0.06‰ in Py3, reflecting incremental oxidation and meteoric water infiltration that lowered H?S activity and drove sequential sulfide and gold precipitation. Integrating Re-Os ages (375~354 Ma) and Pb-H-O isotopic data, we propose a genetic model whereby magmatic?hydrothermal fluids migrated along EW?trending faults and precipitated in structural conduits during post?collisional extension.
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Sedimentary Environment and Material Source of the Hanjiashan Manganese Deposit in the Mianxian-Lueyang-Ningqiang Area, Shaanxi ProvinceGAO Feng1,2,CAI Wenchun1,2*,PAN Liang1,2,ZHANG Xiaoming1,2,KANG Qinqin2,3
GAO Feng, CAI Wenchun, Cai Wenchun, ZHANG Xiaoming, KANG Qinqin
Abstract:
The Mianxian-Lueyang-Ningqiang area is a significant polymetallic ore concentration region in the Southern Qinling Mountains and one of the main production areas for Sinian manganese deposits in Shaanxi Province, China. This study focuses on the Hanjiashan manganese deposit located in the central segment of the Mianxian-Lueyang suture zone. Through systematic field geological investigations, combined with petrographic, mineralogical, geochemical, and C-O isotopic analyses, the genesis, sedimentary environment, and material sources of the manganese deposit are discussed. The results indicate that the manganese-bearing series belongs to a carbonaceous fine-clastic rock - magnesium carbonate rock formation in the upper member of the Lower Sinian Doushantuo Formation, with the ore bodies occurring as stratiform and lenticular forms. Manganese deposits primarily during the sedimentary-diagenetic stage and are predominantly compsosed of rhodochrosite, manganoan dolomite and rhodochrosite, with observed framboidal pyrite. Geochemical characteristics show that the ores have low average ratios of Fe/Mn (0.10), Co/Ni (0.37), V/(V+Ni) (0.69), and Al/(Al+Fe+Mn) (0.11), but high average ratios of V/Cr (3.42), U/Th (1.17), and Y/Ho (34.47). The Post-Archean Australian Shale (PAAS)-normalized rare earth element (REE) patterns exhibit a left-leaning trend with a significant positive Y anomaly, and weak positive anomalies for both Eu (avg. 1.24) and Ce (avg. 1.33). The average δ13CPDB value is -5.46‰, which is close to values characteristic of modern seafloor hydrothermal vents and magmatic sources. Synthesizing these findings, it is concluded that the manganese deposit formed in a suboxic-to-anoxic outer shelf environment, with relatively high mineralization temperatures (avg. 106.07℃) and low salinity (avg. 1.88‰). The ore-forming materials were primarily derived from a submarine hydrothermal system, with additional contributions from seawater, classifying it as a hydrothermal sedimentary-type manganese deposit. This study confirms the dominant role of hydrothermal sedimentation in the mineralization process, deepens the understanding of manganese deposit genesis in the Mianxian-Lueyang-Ningqiang area, and provides a theoretical basis for research on regional metallogeny and prospecting exploration for manganese deposits.
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Lianyunshan - Hengyang fault zone in Hunan Province: structural attributes, formation background, and dynamic mechanisms
Bai Daoyuan, Zeng Guangqian, Hang chao, Li Bin, Chen Jianfeng, Xao Liquan
Abstract:
The Lianyunshan-Hengyang fault is a typical representative of regional NE-trending deep major faults, extending for 430 km within Hunan Province. Along this fault, numerous mineral deposits and large-scale fault basins have developed, rendering it highly significant in terms of resources and economic value. However, research on its overall vertical and lateral structural composition, the temporal context of its formation, and its dynamic mechanisms remains limited. In light of this, this paper conducts a comprehensive study of the fault"s structural composition, tectonic attributes, formation age, and dynamic mechanisms through field structural investigations and analysis of existing regional geological and geophysical data. The results indicate that the Lianyunshan-Hengyang fault is a composite structural zone composed of numerous faults of varying orders, scales, attitudes, ages, and properties and fault basins from deep to shallow levels. Geophysical exploration data, including regional gravity, aeromagnetic, seismic, and geothermal data, reveal the presence of a continuously extending large fault zone at depth along the Lianyunshan-Hengyang fault. At the surface, the Lianyunshan-Hengyang fault manifests as a large-scale fault zone, 10–25 km wide, consisting of a NE-trending main fault, Cretaceous-Paleogene fault basins on the northwestern side (hanging wall) of the main fault, and secondary basin-controlling faults with various strikes within and along the basin margins. The NE-trending main fault is composed of five NE-trending faults that are offset end-to-end from northeast to southwest, along with connecting faults oriented NEE and SN. The faults within the zone can be classified into six types based on strike: NE, NNE, SN, NW, EW, and NEE. These faults primarily formed as thrust and strike-slip faults under early Indosinian NW-compression, late Indosinian SN-compression, and early Yanshanian NWW-compression, and controlled the development of fault basins during the Cretaceous extensional activity. Under the NW–SE extensional environment of the Cretaceous, the various NE-trending main faults and connecting faults underwent inherited extensional activity, forming a continuous NE-trending large surface fault and an extended fault basin, thereby giving rise to the Lianyunshan-Hengyang deep major fault. The primary dynamic mechanism for regional extension is the circular mantle flow induced by the retreat of the ancient Pacific subducting slab. Mantle upwelling and horizontal flow of asthenospheric material associated with this mantle flow led to lithospheric extension and thinning.
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Developmental Characteristics of NW-Trending Blind Faults in the Pearl River Mouth Basin and Their Petroleum Geological Significance
Peng Guangrong, Li Hongbo, Wu Zhe, Cai Song, Zhu Dingwei, Zhang Huimin, Luo Junsheng, Hu Juncheng, Wan Zhifeng
Abstract:
The Pearl River Mouth Basin is a significant petroliferous basin formed on a pre-Cenozoic complex folded basement at the continental margin of South China. Although previous studies have extensively investigated the structural characteristics and hydrocarbon accumulation in the basin, considerable controversy remains regarding the structural attributes and basin-controlling mechanisms of the NW-trending blind basement faults. Based on integrated gravity-magnetic data, well-seismic data, and field geological surveys in South China, this study employs a land-sea collaborative research approach to systematically identify and define three major NW-trending blind fault zones in the Pearl River Mouth Basin (Guigang–Yangjiang–Yitong, Huaiji–Huizhou–Beiweitan, and Lianzhou–Lufeng–Dongsha fault zones) and establish their geometric developmental models. The research indicates that: (1) The NW-trending blind fault zones exhibit distinct spatial distribution patterns. Onshore, they are characterized by fault zones, stratigraphic dislocation, and large-scale drainage systems, while offshore, they show strong correlations with gravity-magnetic anomalies, basement lithology, sag structural features, and high CO2 concentration distributions. (2) The activity of the blind faults can be divided into three main stages: formation (Indosinian movement), transformation (Yanshanian movement), and reactivation (Himalayan movement). (3) Based on the degree of control exerted by the blind faults on sag evolution, three differential evolutionary models of sags are established: multi-fault joint control (transcurrent-composite transtension), single-fault strong control (restricted transtension), and weak-fault extension control (segmented transtension). (4) The control of NW-trending blind fault zones on sag evolution and source rock distribution significantly influences hydrocarbon migration, accumulation, and resource potential. The exploration discovery of the Huizhou 19-6 oilfield confirms the important controlling role of NW-trending fault zones in hydrocarbon enrichment. In summary, this study systematically reveals for the first time the developmental characteristics and evolutionary history of the NW-trending blind fault zones in the Pearl River Mouth Basin, further deepening the understanding of the basin’s tectonic evolution and providing important guidance and reference for petroleum exploration in the northern South China Sea.
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Geochemistry of the Mesozoic alkaline magmatic rocks in Luxi, western Yunnan: Implication for the rifting evolution of the Gaoligong Tectonic Belt
Abstract:
Luxi ophiolitic mélange zone, situated along the Lushui-Longling-Ruili Fault in the southeastern margin of the Gaoligong Tectonic Belt between the Tengchong and Baoshan terranes in western Yunnan, has been debated on its origin, with models suggesting subduction and accretion from the Meso-Tethys Ocean or rifting induced by continental lithospheric thinning. Identifying the characteristics of mafic magmatic rocks within the mélange zone is crucial to resolving this debate. Through large-scale mapping, we discovered a series of alkaline magmatic rocks including lamprophyres, amphibole-bearing basalts, and TiO2-rich basalts in the Late Triassic to Early Jurassic turbidites. This study employs mineralogical, petrogenetic, and geochemical methods to investigate their genesis and tectonic background. The lamprophyres are classified as sannaites, and have a porphyritic texture and amygdaloidal structure with the phenocrysts of kaersutite, Ti-augite, and Ti-biotite, and matrix of cryptocrystalline potassium feldspar and minor albite. Geochemically, they belong to potassic alkaline lamprophyres, with K2O/Na2O ratios of 1.6 to 3.3 and Mg# values of 50 to 56, and their trace and rare earth element characteristics are similar to those of OIB, but their K, Ba, Sr, Nb, Ta and light rare earth elements are more enriched than those of OIB. Compared to the primitive mantle, the lamprophyres show low Mg# values, depleted Co, Cr, and Ni, with a negative Pb anomaly and without Eu and Ce anomalies, which suggest their magmas underwent the fractional crystallization of olivine and pyroxene, but did not experience the fractional crystallization of plagioclase, and did not suffer crustal contamination and alteration subsequently. The lamprophyres characterized by low εNd(t) (+3.57~+3.73), high 87Sr/86Sri (0.706027~0.706161), high (La/Yb)N (27.8~28) and Dy/Yb (2.6~2.7) suggest they originated from weakly depleted mantle regions, bearing phlogopite and amphibole and within the garnet-bearing lithosphere-asthenosphere boundary. The Ti-rich basalts are alkaline, and resemble the lamprophyres in trace element characteristics and Nd(t) values, but they lack hydrous minerals of amphibole and biotite. The amphibole-bearing basalts lie between the lamprophyres and Ti-rich basalts in mineral assemblage, containing TiO2-rich amphibole and biotite as well as plagioclase phenocrysts. In comparison with the regional mafic magmatic rocks, we conclude that these alkaline mafic magmatic rocks are probably formed during the Jurassic period, and are attributed closely to the asthenospheric convection generated by the Paleo-Tethys Ocean subduction that caused thinning and rifting of the Luxi lithosphere. This study demonstrates that the Luxi ophiolitic mélange is a rifting complex. These findings provide significant constraints for understanding the tectonic evolution of the southeastern Qinghai-Tibet Plateau during the Mesozoic era.
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The major and trace elements of titanite indicate the magmatic-hydrothermal evolution of Suzhou A-type granite
pan wei, huqinghai, wuhui, wangwei, sunbinbin, liuxuemin, chenruo, wangxueqiu
Abstract:
The Suzhou granitic pluton is the first identified Nb–Ta-rich granite in China. Elucidating its magmatic-hydrothermal evolutionary process is critical for advancing our understanding of petrogenetic processes and Nb-Ta mineralization mechanisms in the region. This study for the first time systematically conducts petrographic, geochemical and chronological studies on titanite in the amphibole- and biotite-bearing granite within the Suzhou pluton. Based on the mineralogical and geochemical characteristics of titanite, the magmatic-hydrothermal evolution sequence and its constraints on Nb-Ta mineralization are clarified. The titanite in Suzhou granite records both magmatic and hydrothermal evolution: (a) Magmatic titanite exhibits relatively homogeneous compositional zoning, with high LREE (mean: 16,355 ppm) and HFSE contents (e.g., Nb averaging 5,550 ppm), elevated high TiO? content, Th/U ratios, crystallization temperatures (680 ± 30°C), as well as lower CaO content and Lu/Hf ratios. (b) Hydrothermal titanite is primarily divided into two stages. Early-stage hydrothermal titanite formed in a high-fO? hydrothermal environment, characterized by low LREE (mean: 661 ppm) and HFSE contents (e.g., Nb averaging 880 ppm). In contrast, late-stage secondary hydrothermal titanite crystallized in a relatively reduced hydrothermal fluids, with geochemical features showing significantly enriched Nb content, reaching up to 8,796 ppm. LA-ICP-MS dating yielded U–Pb ages of 125.2 ± 7.2 Ma for magmatic titanite and 125.4 ± 2.8 Ma for hydrothermal titanite, indicating their collective formation within the Early Cretaceous granitic magmatic-hydrothermal system. During hydrothermal fluid evolution, the interaction of F-rich fluids with titanite, amphibole, and biotite triggered non-equilibrium dissolution, releasing substantial HFSEs (e.g., Nb, Ta) and REEs into hydrothermal fluid. These elements were subsequently remobilized by F-enriched, relatively reduced hydrothermal fluids, either precipitated as secondary hydrothermal titanite (depleted in LREE with exceptionally high Nb concentrations up to 8,796 ppm) and ilmenite around primary minerals, or migrated over short distances to form Nb-Ta-enriched minerals such as fergusonite-(Y) and samarskite-(Y). In short, titanite exhibits progressive depletion in REE and HFSE (e.g., Nb, Ta) as the granitic system evolves from magmatic to hydrothermal regimes, and F-driven metasomatism (e.g., biotite alteration) promotes Nb enrichment. This indicates that the compositional evolution (major and trace elements) and microtextural features of titanite effectively archive both magmatic and subsequent hydrothermal processes. Consequently, titanite emerges as a new indicator for tracing Nb-Ta mineralization in granitic systems.
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Geochronology and geochemistry of Early Paleozoic metamorphic rocks in the North Wulan terrane of the North Qaidam Orogen, and its geological significance
ZHOU Kai, GAO Yijie, KONG Huilei, ZHANG Jiangwei, ZHAO Min, JIN Delong, HE Yongkang, XIE Chunlin
Abstract:
The North Wulan terrane representing the overriding plate of the Early Paleozoic subduction-collision system of North Qaidam Orogen, is key to understanding the composition of the lower part of the crust beneath arc?back-arc and the tectonic evolution of the subduction process of the South Qilian Proto-Tethyan oceanic crust. In this paper, we present detailed petrology, geochronology, geochemistry and metamorphic P?T condition of the representative mafic to felsic metamorphic rocks in the North Wulan Terrane. The results reveal that the protolith age and tectonic setting of the three types of metamorphic rock studied are significantly different. The amphibolites exhibit compositional characteristics similar to E-MORB, but it does not retain information about the protolith age and thus cannot be further discussed in terms of its significance. The biotite-amphibole gneisses display geochemical signatures of continental arc, with protoliths formed at 471 ± 3 Ma, representing magmatic records of the continental marginal arc during the subduction of the Proto-Tethyan oceanic crust. The granitic mylonites exhibit geochemical feature resembling arc granite and formed at 965 ± 6 Ma, which means that they represent arc magmatism in an active continental margin setting related to the assembly of the Neoproterozoic supercontinent Rodinia. Combined with previous studies, it is proposed that the composition of the lower part of the crust beneath arc?back-arc, represented by the North Wulan Terrane, are primarily composed of Precambrian basement (including various types and ages of metasedimentary and meta-igneous rocks) and Early Paleozoic continental arc magmatic rocks. These rocks were widely subjected to Middle-Late Ordovician HT/LP metamorphism, with the corresponding metamorphic ages concentrated around ca. 475–440 Ma. This period is notably confined to the late stage of oceanic subduction, as recorded by arc magmatism (ca. 510–450 Ma), and is nearly synchronous with the eclogite-facies metamorphic ages associated with subduction of oceanic crust documented in the Dulan UHP unit. Integrating previous studies on metamorphic P?T evolution, we suggest that the HT/LP metamorphism occurring under an extensional environment of the continental marginal arc during the late stage of plate convergence is caused by slab rollback. This highlights the critical role of studying metamorphism of the overriding plate of subduction zones for reconstructing the tectonic evolution of subduction of oceanic crust.
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Discovery of Diamonds in Mantle Peridotites from the Yushigou Ophiolite, North Qilian Orogenic Belt
ZHANG Manli, LIU Fei, FENG Guangying, ZHU Xinyang, FANG Zijian, wushaofeng, XU Jiahong, YANG Jingsui
Abstract:
Ophiolite-hosted diamonds have been discovered in several ophiolites within the Neo-Tethyan tectonic belt, however, the presence of diamonds in Paleo-Tethyan ophiolites remains unclear. This study focuses on the 550~495 Ma Yushigou ophiolite within the North Qilian orogenic belt. Heavy mineral separation and petrological studies of mantle peridotites were conducted. The results reveal the separation of 25 diamond-grains and other unusual minerals from approximately 510 kg of harzburgite. The diamonds mainly range in size from 50 to 150 μm, exhibiting colorless to pale yellow hues, and display crystal forms including octahedral, broken irregular, and rounded shapes. Raman spectroscopy shows a characteristic peak at 1330.37 cm?1. The host harzburgite consists mainly of olivine (75%~85%), orthopyroxene (14%~24%), and minor chromian spinel (<1%). Olivine has Fo values of 90.9~93.23, classifying it as forsterite, with the highest Fo value (93.23) observed in olivine inclusions within chromian spinel. Orthopyroxene occurs primarily in two types of porphyroclastic and intergranular. Porphyroclastic orthopyroxene has Mg# values of 91.07~92.59, Al?O? contents of 0.94~1.92%, and Cr?O? contents of 0.43~0.73%. Intergranular orthopyroxene has Mg# values of 91.40~92.31, Al?O? contents of 1.09%~1.80%, and Cr?O? contents of 0.46%~0.65%. The variation ranges of Mg#, Al?O?, and Cr?O? in porphyroclastic orthopyroxene are all slightly larger than those in intergranular orthopyroxene. Chromian spinel has Cr# values of 56.14~70.21, Mg# values of 43.89~58.33, and TiO? contents below 0.05%. The Mg#-Cr# diagram of spinel indicates that the harzburgite underwent a high degree of partial melting (25%~35%) and experienced metasomatism by melts/fluids in a forearc subduction zone. Ultrahigh-pressure minerals like diamonds suggest formation depths >150 km. This implies that oceanic crust/mantle materials were transported into the deep mantle during subduction. Diamonds and other minerals formed under high-pressure and highly reducing conditions, were encapsulated by mantle peridotite and chromitite, and then were subsequently carried to the surface during the exhumation process. This study confirms the globally significant distribution of ophiolite-hosted diamonds and provides new insights into deep subduction processes and deep mantle material recycling within the North Qilian orogenic belt.
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Analysis of secondary surface deformation characteristics and formation mechanisms on the eastern shore of Dingmu co triggered by the 2025 Tingri Mw7.1 earthquake
Wu Kungang, Li Haibing, Pan Jiawei, Yang Shaohua, Liu Fucai, Zhang Siqi, Su Qiang, Marie-Luce Chevalier, Lu Haijian
Abstract:
On January 7, 2025, at 09:05, an Mw 7.1 earthquake occurred in Tingri County, Xigaze, Tibet. The China Earthquake Networks Center (CENC) located the epicenter at 28.50°N, 87.45°E near Cogo Township, with a focal depth of 10 km. Field investigations identified the seismogenic structure as the Dingmuco Fault, the southern segment of the Xainza-Dinggye rift in the southern Tibetan Plateau. The earthquake produced a ~35km co-seismic surface rupture and caused secondary surface deformation along the eastern shore of Dingmuco, extending ~12km with a width varying between 0.2 and 0.5 km. A series of extensional (tension cracks, half-grabens, grabens) and compressional structures (sporadically distributed sand liquefaction features, pressure ridges, compressional bulges, and fold scarps), all parallel to the lakeshore and nearly N-S trending, develop progressively from east to west. These structures formed mainly within the poorly consolidated sandy sediments of the mid-to-lower sections of the alluvial fan. Detailed structural analysis reveals that the observed extensional features (e.g., tension cracks and grabens) and compressional features (e.g., compressional ridges and bulges) are not direct products of co-seismic rupture, but rather represent structures resulting from secondary shallow surface collapses induced by the earthquake. This phenomenon results from liquefaction, shear instability, and gravity-driven deformation of loose sediments under seismic loading. The dynamic formation process can be divided into four stages: liquefaction triggered by earthquake, initial instability, sliding deformation, and fluid migration facilitation. These stages collectively demonstrate a typical multi-stage coupling mechanism. During this seismic event, numerous buildings in villages such as Qiangga—located atop the slump mass—collapsed extensively. This destruction likely relates not only to seismic shaking effects in the hanging wall but is also closely associated with vibrations induced by the contemporaneous slumping deformation. Investigating such phenomena holds significant implications for both paleoseismic identification and geohazard assessment.
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Optimization Methodology for Calculating Carbon Sequestration Capacity in Core-Scale Basalt-CO2 Mineralization Storage Based on Laboratory Injection Experiments
Zhou Yuantao, Li Bo, Zhang Fengshou, Shi Zhenming, Kong Deheng
Abstract:
Basalt-CO2 mineralization sequestration is an emerging CCUS (Carbon Capture, Utilization, and Storage) technology for achieving China's ‘dual carbon’ strategy, among which the accurate evaluation of the sequestration potential of basalt formations is a key technical indicator for measuring the feasibility of mineralization sequestration projects. Currently, there are various methods for calculating the mineralization sequestration potential of basalt, such as the mineral replacement method and the unit mineralization method, but there is still a lack of consensus in the industry regarding the calculation principles, accuracy, and applicable conditions of different methods. Based on the independently developed CO2 steady-state seepage test system, this study conducted injectability mineralization tests to investigate the dynamic change processes of indicators such as solution ion concentration, permeability, and secondary mineral growth quality of basalt samples with different pore and fracture characteristics in the Wenchang area of Hainan during the long-term mineralization sequestration process, and by comparing the calculated values, the error ranges and principles of various calculation methods were clarified; on this basis, an optimized calculation method for carbon sequestration capacity was proposed and applied to calculate the carbon sequestration capacity of basalt formations in Heishanling (HSL), Penglai Town, Wenchang City, Hainan, and Bailonggang-Sanjia Port Area (SJG), Shanghai. The results show that: mineral dissolution mainly occurs in the early stage of the mineralization reaction, the concentrations of Ca2+ and Mg2+ ions are in a supersaturated state, and the permeability increases slightly followed by a continuous decrease; the growth of secondary minerals shows obvious regional characteristics, with dissolution reactions dominating in the inlet section and precipitation dominating in the outlet section, and simultaneously, affected by the pressure dissolution effect, the opening of fractured basalt decreased by 5.23 % and 2.97 % respectively during the mineralization process, the mass percentage of C element on the surface of intact basalt after the reaction was 2.6 %, and the reduction in fracture opening and pore 'blockage' are the main reasons for the decrease in permeability; differences in pore/fracture structures directly affect the carbon sequestration potential of basalt, and the carbon sequestration potential of basalt with large pores and fractures is 135.7 % higher than that of intact basalt with small pores; a comparison between the theoretical calculated values and experimental values of basalt carbon sequestration potential shows that the calculation error of the mineral replacement method is the lowest at 2.4 %, while the calculation results of the unit mineralization method and the pore filling method are significantly overestimated, and the optimized calculation method for carbon sequestration potential can improve calculation accuracy without introducing additional empirical parameters; using the optimized method, the potential carbon sequestration capacities of the proven basalt formations at the two sites (HSL and SJG) were calculated to be 7.01×104 tons and 9.50×104 tons under the condition of a 7500 m2 site, respectively. The above research results can provide a basis for the feasibility analysis of subsequent mineralization sequestration projects.
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The geochemical characteristics and genesis of Cryogenian Jiangkou banded iron formation, Hunan province
huangyuanhui, yangxiuqing, yehui, zhaochao, yangguowei, hezhiguo, zhangzimin, liushihan, Muhammad Ahmad
Abstract:
Banded iron formations (BIFs) are common chemical sedimentary rocks in Precambrian strata. Neoproterozoic BIFs were mainly deposited at Cryogenian period (~717–635 Ma). Many scholars argued that the emergence of Neoproterozoic BIF is closely linked to the "Snowball Earth" event, but the causal relationship between them remains poorly understood. The Jiangkou BIF in the South China Block is a typical Neoproterozoic BIF. The Jiangkou iron ores are dominated by quartz, hematite and magnetite, followed by minor chlorite and carbonate minerals, which is characterized by the features of chemical sedimentary rocks. The studied BIF show high TFe2O3 and SiO2 contents, followed by Al2O3, CaO and MgO. Other elements, such as TiO2, MnO, Na2O, K2O, P2O5, high field strength elements and total rare earth elements (REE) are relatively low. Moreover, the Jiangkou BIF show significant positive correlations between Al?O? and TiO?, Zr, while there are moderate positive correlations between K?O and Al?O?, TiO?. All samples show low Y/Ho ratios (average of 29.2). When normalized to Post Archean Australian Shale (PAAS), all BIF samples show enrichment of high REE patterns relative to low REE patterns (LaPAAS/YbPAAS = 0.22~0.59) and positive Eu anomalies (Eu/Eu*=1.02~1.40). Comprehensively, we argued that iron was sourced from hydrothermal fluids and seawater. Furthermore, significant terrigenous clastic materials have been incorporated into Jiangkou BIF. The positve iron isotope values in Jiangkou BIF and the absence of significant negative Ce anomalies suggest that Jiangkou BIF was deposited in a suboxic to anoxic conditions. Combining with previous studies, we suggest that widespread anoxic and ferruginous oceans prevailed during the Cryogenian period. The oxygen released from meltwaters of localized glaciers could have triggered iron precipitation and leading to the formation of BIF.
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Genetic mechanism of the Tongkeng Ag-Zn polymetallic deposit in Dachang, Guangxi: Constraints from fluid inclusions and C-H-O-S-Pb isotopes
CHENG Yongsheng, LI Xiangyang, WANG Lei, OU Enguo, LI Xiangrui, WEI Honglian, WANG Songpu, ZENG Dexing, ZHANG Zewen, LI Yezheng
Abstract:
The Dachang Tongkeng deposit in Guangxi is a world-class supergiant deposit, with long-standing research extensively elucidating its tin-polymetallic mineralization processes and enrichment mechanisms. In recent years, Ag-Zn polymetallic ore bodies have been discovered during mining development, yet studies on the genetic mechanism of this mineralization type remain extremely limited. This knowledge gap significantly constrains the comprehensive understanding of metallogenic processes in the Tongkeng deposit and hinders further exploration of polymetallic mineral resources. Focusing on the Ag-Zn mineralization, this study investigates the evolution of ore-forming fluids and material sources through fluid inclusion microthermometry, C-H-O-S-Pb isotope analyses, and field geological investigations, while exploring the genetic mechanism of Ag-Zn polymetallic mineralization and its intrinsic connections with other ore bodies.The homogenization temperatures of ore-forming fluids range from 102 to 321°C, with salinities of 1.2%–14.63% NaCleqv. Quartz H-O isotopes (δD=-59.8‰ to -57.9‰; δ18OH2O=4.85‰~11.06‰) and calcite C-O isotopes (δ13CV-PDB=-9.14‰~1.47‰; δ1?OH2O=3.01‰~6.80‰) indicate that magmatic hydrothermal fluids constitute the primary source of ore-forming fluids, with late-stage mixing of meteoric water accompanied by water-rock interactions, driving fluid evolution from medium-high temperature/salinity to medium-low temperature/salinity. Sulfur isotopes demonstrate dominant magmatic sulfur sources with localized sedimentary sulfur contamination, while lead isotopes reveal predominantly upper crust-derived metals with minor mantle contributions. Sulfur-rich hydrothermal fluids generated by magmatic differentiation migrated along fault systems. During decompression and cooling, mixing with meteoric water altered physicochemical conditions through water-rock interactions, triggering precipitation of Ag-Zn sulfides. The deposit represents a product of interactions between magmatic hydrothermal systems and wall rocks, characterized by magma-dominated metallogenesis coupled with multi-source fluid co-evolution.
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Provenance and tectonic implications of Eocene clastic rocks in NW Borneo: constraints from stratigraphy and detrital zircon U-Pb-Hf isotopes
WANG Yiwen, QIAN Xin, WANG Weitao), ZHANG Yipeng, Gan chengshi, WANG Cheng, BAI Tianxing, ZHANG Peizhen
Abstract:
Located on the southwestern margin of the South China Sea (SCS), Borneo provides a key geological window into the tectonic evolution of Paleo-Pacific Subduction and SCS.The Sintang-Semitau region, situated at the convergence of NW Borneo, SW Borneo, and Sibu-Miri tectonic zone, preserves a complete Paleozoic to Cenozoic multi-stage tectonic-magmatic-sedimentary record. This region is a key area for deciphering the tectonic evolution of West Borneo. However, previous studies predominantly focused on the Mesozoic magmatism and sedimentation, lacking the study on the Cenozoic sedimentary evolution and associated source-to-sink systems. To address this issue, we conducted systematic stratigraphic, petrographic, and in-situ detrital zircon U-Pb-Hf isotopic analyses on well-exposed clastic sandstones from the Eocene Melwai group (Payak Formation), Suwang group (Dangkan sandstone and Silat sandstone) and Teu Formation in the Sintang-Semitau region. The detrital zircons from the Payak Formation primarily exhibit age peaks at ~105 Ma and ~124 Ma, with corresponding εHf (t) values of +4.6 to +7.3 and +5.8 to +7.5, respectively. In the Dangkan sandstone, detrital zircon populations show dominant age peaks at ~86 Ma, ~115 Ma, and ~130 Ma, and yield εHf (t) values of +2.7 to +10.7, +6.3 to +9.5, and +4.2 to +15.6. The Silat sandstone displays major zircon age peaks at ~77 Ma and ~116 Ma. For the Teu Formation, characteristic age peaks occur at ~87 Ma, ~117 Ma, and ~263 Ma, with εHf (t) values of +4.3 to +11.3, -4.6 to +7.5, and -13.0 to -8.0. Regional correlation indicates that the Eocene detrital sediments were primarily sourced from the Mesozoic magmatic rocks related to the Paleo-Pacific subduction in NW and SW Borneo, with contributions from recycled proximal strata. Pre-Triassic sources are mainly derived from sedimentary and igneous rocks in the Indochina Block. Additionally, the Suwang and Melwai sandstones display features of proximal accumulation. The youngest single-grain zircon age (~46 Ma) in the Suwang Group indicates that the Eocene magmatism in NW Borneo might linke to the tectonic evolution of Proto-South China Sea.
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Characteristics and formation mechanism of pyroclasts from Dayishan Volcano in Longgang Volcanic Group, Jilin Province
Xue Chenli, Liu Yongshun, Nie Baofeng, Wang Yanan, Zhou Shuyuan, Sun Yujing, Feng Weixia, Jiang Shan
Abstract:
Tectonically, Longgang Volcanic Group is located on the northeastern margin of the Sino-Korean Craton and is controlled by the Kuandian–Longgang–Dunhua deep fracture. The Dayishan Volcano in Huinan County, Jilin Province, is a typical representative of the Quaternary volcanoes on the western part of the Longgang Volcanic Group. The eruption types of the Dayishan Volcano have the stage characteristics, that is, the eruptions in the first, second and fourth stages are magmatic eruptions, while the eruption in the third stage is a weak phreatomagmatic eruption. Its chair-shaped volcanic cone is composed of pyroclastic fall deposits from multi-stage magmatic eruptions and pyroclastic fall rhythmic layers of weak phreatomagmatic eruptions. Based on the strata and petrography of the pyroclastic deposits of Dayishan Volcano, the particle size distribution, particle shape and fractal characteristics of pyroclasts was quantitatively studied from the perspectives of particle size-shape analysis and fractal theory. The particle size distributions of the Dayishan pyroclasts are all unimodal, mainly showing a coarse-grain dominance. The peak value of the particle size distribution of the weak phreatomagmatic pyroclasts in the third stage is significantly smaller than those in other stages. In terms of particle shapes, as the eruptive intensity decreases, the pyroclast shapes tend to be more irregular. However, the particle shape values of the pyroclasts in the third stage of the Dayishan Volcano are all higher than those in the other stages, indicating that the eruption products in the third stage significantly approach a regular shape. The distribution characteristics of the Dayishan particles were fitted using the multi-segment power-law method. It was found that there are four significant fractal intervals in the particle size distribution of airfall pyroclasts of magmatic eruptions, while there are three fractal intervals in the one of weak phreatomagmatic eruption. This indicates that the formation of airfall pyroclasts of magmatic eruptions is mainly affected by the initial fragmentation of magma, high-energy secondary fragmentation and wind transportation. In addition to the effects of the above factors, the pyroclast of weak phreatomagmatic eruption is also related to the explosion caused by the steam forming from the contact between magma and water.
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Study on fault development characteristics and analysis of influencing factors of fault-controlled hydrocarbon accumulation in the Zambezi Delta Basin based on gravity and magnetic data
Li Wen, Wang Wanyin, Ding Liangbo, Li Zhongsheng
Abstract:
Fault structure as an important carrier of crustal deformation, its spatial distribution characteristics are of crucial significance for the study of regional tectonic evolution and the analysis of their influence on hydrocarbon accumulation control in petroliferous basins. Based on the gravity and magnetic anomaly data, this paper mainly uses the improved hyperbolic tangent function of total horizontal gradient (IHRHG) fault recognition technique to identify the distribution characteristics of the faults in the Zambezi Delta Basin, and the Euler deconvolution method is adopted to calculate the apparent depth of these faults. An improved fracture influence factor (IFIF) is proposed, and the petroleum exploration potential of each structural unit in the basin is predicted. This study reveals that there are 12 ultra-crustal faults and several crustal faults developed in the Zambezi Delta Basin, and an extensional-shear composite fault system dominated by extensional and strike-slip faults is constructed. The fault strikes show obvious directionality, the near SN trending faults are the most developed, followed by the NNE, NE, NNW, and NEE directions. Faults in the NW, NWW, and near EW directions are less developed. The apparent depths of the faults are concentrated between 2.5 and 10 km. Among them, the apparent depths of most ultra-crustal faults range from 2.5 to 10 km, and those of most crustal faults range from 2.5 to 7.5 km. The distribution of the IFIF values in the basin shows a zonal characteristic, which the western depression has an IFIF value of 0.35 to 1.0, the Beira High has an IFIF value of 0.0 to 0.35, and the IFIF value of the "eastern block" of the basin approaches zero. The study found that the coastal fault F3 extends from the southern margin of the Rovuma Basin southwestward to the Limpopo boundary fault zone, forming an important tectonic boundary in the basin - mountain transition zone. The ultra-crustal fault F4 extends westward from the Mozambique Channel and terminates on the west side of the Beira High, controlling the sedimentary differentiation between the Beira High and the western depression. The ocean-continent transition zone fault with a NEE-trending distribution in the central part of the "eastern block" of the basin have been identified, and The Prince Edward fault zone extends northward into the western depression and is truncated by the extensional fault F4. In addition, the hydrocarbon exploration potential of each structural unit in the basin was predicted based on the IFIF value, and the study suggests that the western depression and the Limpopo Plain have good hydrocarbon exploration potential. Further, using IFIF=0.35 as a marker, we delineated the favorable hydrocarbon exploration areas in the Zambezi Delta Basin. This study identifies the characteristics of the planar positions and apparent depths of the faults in the Zambezi Delta Basin, providing important geological constraints for the study of regional tectonic evolution. At the same time, they offer crucial tectonic evidence for deep-water oil and gas exploration.
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Three-dimensional characteristics of primary halo and implications for deep mineral exploration in the Guilaizhuang gold deposit, Pingyi, Shandong Province, China
Li Jian Lin, Zou Yan Hong, Chen Guo Dong, Mao Xian Cheng, Chen Jin, Zhang Ying Mei
Abstract:
The Guilaizhuang gold deposit in Pingyi County, Shandong Province, is the first discovered tellurium-gold type epithermal deposit in China. Its deep and peripheral areas still hold significant prospecting potential, and there is an urgent need to establish an effective exploration model. In this study, 672 primary halo samples collected from 58 exploration drill holes at the Guilaizhuang gold deposit were analyzed. A three-dimensional primary halo analysis method was adopted to overcomes the limitations of traditional two-dimensional approaches. Through multivariate statistical analysis, primary halo indicator elements were identified. A 3D geochemical anomaly model was constructed to reveal the characteristics of primary halos and their correlation with mineralization while evaluating the prospecting for concealed deep ore bodies. The results show that: (1) The Guilaizhuang gold deposit exhibits an axial zoning sequence of As-Sb-Se (frontal halo), Ag-Au-Te-Pb-Zn (proximal halo), and Mo-V (rear halo). Notably, rear halo elements (Mo, V) are enriched at the top of the orebody clusters, showing a distinctive "reverse zoning" phenomenon. (2) Gold-indicating element ratios (Ag/Au, As/Sb, Zn/Pb) display a NE-SW directional zoning, consistent with the strike of the structural-cryptoexplosive breccia zone controlled by the Guilaizhuang F1 fault. (3) The frontal-rear halo multiplicative ratio[w(As×Sb×Se)/w(Mo×V)] exhibits anomalous inflection points at elevations of -750 m and -1700 m, indicating the presence of concealed orebodies at depth. The findings suggest that the mineralization at Guilaizhuang involved multi-stage hydrothermal fluids superposition. Ore-forming fluids originating from the deep southwest part of the deposit migrate upward along the structural conduits formed by the Guilaizhuang F1 fault to the near-surface, forming structural-cryptoexplosive breccia type and quasi-layered carbonate-hosted type gold orebodies. It is inferred thar the deep prospecting potential of the deposit remains promising, with the deep southern region below -750 m elevation along exploration line 35 identified as a priority target zone for further exploration.
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Study on the classification characteristics of garnets based on TIMA in the Chenggang uplift zone, Northern Jiangsu Province
zhaoyu, caiyitao, zhangqi, zhouqizhong, wangguoqiang, zhangxuan
Abstract:
In this paper, the TESCAN Integrated Mineral Analyzer (TIMA) automated mineral analysis system was used for the first time to systematically classify garnets by species and analyze their genesis in the Chenggang uplift zone. The results show that the garnets in the zone are mainly spessartine (65.08%), followed by grossular-almandine-spessartine (11.96%), with spessartine mostly appearing in orange, maroon, and burgundy, and grossular-almandine-spessartine mainly in pink. The numbers of pyrope end-members in pink, orange, maroon, burgundy, and purplish-red garnets are 206, 93, 10, 1, and 1 grains, respectively. Combining the information of pyrope types in other areas and the results of Cr-K surface scanning, some of the pink and orange pyrope belong to eclogite-type pyrope, while the purplish-red pyrope is presumed to be chromium-bearing pyrope due to its moderate chromium content, suggesting that this area has geological potential for diamond mineralization. Through automated spectral scanning and database comparison, the TIMA technique has efficiently identified nearly 2000 garnet minerals and successfully recognized pyrope end-members related to diamond mineralization. This not only verifies the technique""s feasibility in mineral classification and mineralogical identification but also provides a new technological pathway for studying mineral genesis and predicting mineralization.
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Petrogenesis and geodynamic significance of late Neoarchean quartz dioritic gneisses in the Jiaobei terrane, North China Craton
YAO Jiachen, WANG Wei, YAO Xiaofeng, WANG Zongqi, YANG Weibo, HU Jincheng, LIANG Xueyin
Abstract:
The origin of early continental crust is a hot issue in early Precambrian research. Since the intermediate average composition of the continental crust, unraveling the petrogenesis of intermediate rocks and the processes of crust-mantle interaction is key to understand the formation of continental crust and related geodynamic regimes. In this study, the late Neoarchean quartz dioritic gneisses exposed in the Jiaobei terrane of North China Craton were selected as the research object, and the zircon U-Th-Pb-Lu-Hf isotopes and whole-rock major and trace elements were analyzed. Based on these data, comprehensive studies of the spatial and temporal distribution, geochemical characteristics, and crust-mantle interaction were conducted to decipher the origin mechanism of these intermediate magmas. The results show that the late Neoarchean quartz dioritic gneisses of Jiaobei terrane are mainly exposed in the northeastern part of Qixia, Majiayao, Huangyandi, Shilizhuang, and northern Dachai, with crystallization ages of 2563~2500 Ma. These quartz dioritic gneisses are further divided into >2.55 Ga and <2.55 Ga groups. The >2.55 Ga quartz dioritic gneisses show hornblende as the major mafic minerals, with depleted zircon εHf(t2) values. They have relatively low SiO2 (mostly of 54.59%~59.27%), Mg# (37.59~50.51), and Sr+Ba (357 ×10-6~1166 ×10-6), belonging to the low- to medium-K series. Meanwhile, they show moderately fractionated chondrite-normalized rare earth elements (REE) patterns with low (La/Yb)N (3.92~7.12). In comparison, the <2.55 Ga quartz dioritic gneisses contain less volume of mafic minerals that are dominated by biotite, with less depleted zircon εHf(t2) values. These samples exhibit relatively high SiO2 contents (55.48%~63.54%), Mg# (45.43~63.24), and Sr+Ba (866 ×10-6~3480 ×10-6), belonging to the medium- to high-K series. In addition, they have strongly fractionated chondrite-normalized REE patterns with high (La/Yb)N (10.84~65.67), which are chemically analogous to those of Archean sanukitoids. Detailed petrogenetic studies reveal that the >2.55 Ga quartz dioritic gneisses were derived from the partial melting of the depleted mantle weakly modified by the metasomatism of basaltic crustal melts. In contrast, the <2.55 Ga quartz dioritic gneisses were formed by the partial melting of a less depleted mantle that was strongly metasomatized by sediment melts. Taken together, the late Neoarchean quartz dioritic gneisses in the Jiaobei terrane record crust-mantle interactions involving the recycling of crust-derived materials and mantle metasomatism, which could mark an important episode of crustal growth that was likely evolved under a plate subduction setting during the late Neoarchean.
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Crustal structure analyze and three-dimensional modelling in front area of Sichuan-Yunnan rhombic block
Abstract:
We constructed the three-dimensional crustal model of the front area of Sichuan-Yunnan rhombic block using the iterative forward-inversion method. The gravity anomaly data, the multi-scale wavelet decomposition method and Parker interface inversion Parker interface inversion method are used during the crustal layer modelling. The magnetic anomaly data and the three-dimensional interpretation method are used in the fault modelling. The fault models we constructed in this area are the regional large fault including Lancangjiang fault, Wuliangshan fault, Honghe fault, Ailaoshan fault, Yuanmou fault, Xiaojiang fault and Shizong fault. The results show that the depth of the bottom of the upper crust in this area is between 9 and 18 km, and its relief is mainly controlled by the main faults. The depth of the bottom of the middle crust is between 25 and 34 km, and the fault control is weakened, showing the overall rise from north to south; The depth of Moho is between 31-41km, showing the crust thinning from north to south. The depth of the model constructed in this paper has similar range and significant correlation with the depth of Crust1.0 model-the correlation coefficient are greater than 0.5 and 0.8 of bottom of the middle crust and the Moho respectively.
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Low-Amplitude-Weak Inversion Anticline Structures in the Southern Part of Xihu sag: Genesis, Evolution, and Hydrocarbon Potential
Jiang Yi Ming, Tang Xian Jun, He Xin Jian, Zhu Hong Hao, Zhang Wu, Zhong Rong Quan
Abstract:
The central anticline belt in the Xihu sag: is a key area for hydrocarbon accumulation. However, previous studies have paid limited attention to low-amplitude-weak inversion anticline structures in this region. These structures differ significantly from the widely developed high-amplitude-strong inversion anticlines in terms of their genesis and evolution. Based on the latest 3D seismic data, this study conducts a detailed structural analysis of the H and Q anticlines in the low-amplitude-weak inversion anticline zone. It reveals their genesis, evolution, and impact on hydrocarbon accumulation. The research shows that low-amplitude-weak inversion anticline structures formed as cover anticlines during the rift phase under a paleo-uplift background and were finalized by compression-inversion during the Longjing Movement. These structures have a "early extension-late weak compression" composite genesis. During the extension phase, the early cover anticline morphology and flower-like fault systems formed simultaneously. Moreover, the intensity of tertiary fault activity in the wings of the anticline has always been greater than in the core of the anticline throughout the structural evolution process. Based on the new understanding of the evolution of low-amplitude-weak inversion anticline structures, this study identifies favorable conditions for hydrocarbon accumulation: "paleo-uplift background and cover anticline-controlled hydrocarbon migration and accumulation," "structure-lithologic traps controlled by extension-compression interaction," and "key hydrocarbon accumulation periods with source-fault-sand configurations in the wings of the anticline." These factors highlight the exploration potential for structure-lithologic gas reservoirs in the wings of the anticline. This research deepens the understanding of hydrocarbon enrichment patterns in inversion structures in the central anticline belt and has played a key role in breaking through natural gas exploration in the southern part of Xihu sag.
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Late Cenozoic vertical-axis rotation of the Tarim Basin- magnetic fabric evidence from the Mazatagh thrust belt
Li Bingshuai, Dou Jiahe, Yan Maodu, Peng Heng, Song xiangsuo, Zhang Peng
Abstract:
Surrounded by the West Kunlun Mountains and the Tian Shan fold-and-thrust belts, the Cenozoic vertical-axis rotations of the Tarim Basin are crucial for understanding the kinematic processes of the western Himalayan syntax and the Tian Shan orogeny. However, the Cenozoic rotation pattern and magnitude of the Tarim Basin remain disputed. This study conducted detailed magnetic fabric analyses on Late Cenozoic sediments along the Hongbaishan profile at the Mazatagh thrust belt in the central Tarim Basin. By examining the features of magnetic fabrics, paleocurrent directions and provenance, we concluded that the magnetic fabrics at Hongbaishan were embryonic tectonic fabrics, which can reflect paleostress directions. After rotation correction, the compressional direction during the Late Cenozoic at Hongbaishan was NNE, consistent with the upper-crust vectors revealed by GPS observations. This pattern is primarily related to the nearly N-S-directed India-Eurasia collision and the continuous indentation of the Indian plate into Eurasia since the Cenozoic. This indicates that compressional stress has propagated into the interior of the Tarim Basin since at least ~9.7 Ma from the collisional zone. The compressional stress directions at Hongbaishan, as revealed by magnetic fabrics, indicate that the Mazatagh region has undergone an absolute ~7.0° clockwise rotation since ~7.6 Ma (relative to the spin axis of the Earth). These rotation patterns and magnitudes are consistent with results from classical geological methods and GPS observations and may represent the true rotational features of the Tarim Basin since the Late Cenozoic. However, previous paleomagnetic results surrounding the Tarim Basin mostly reflect local rotation features within the peripheral orogeny. The Late Cenozoic clockwise rotations of the Tarim Basin may be related to the northward indentation of the Pamir salient or the heterogeneity of the Tian Shan, leading to the E-W inhomogeneity of the upper crust.
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Reconstruction of the sedimentary environment characteristics of the Subei Basin based on grain size end-member analysis
Abstract:
Grain size is a basic characteristic of sediments, which can reflect the dynamic conditions of sediment transport and sedimentary processes. Therefore, it has been widely used in palaeoenvironmental studies. However, due to the influence of various factors on the depositional environment in the basin, and the complexity of provenance and depositional dynamic conditions, it is difficult to understand the implications of each grain size component only based on grain size parameters. By extracting and analyzing the environmental-sensitive grain size components of sediments, it is possible to accurately reconstruct the hydrodynamic conditions and regional climate during geological period. In this study, the Miocene fluvial-lacustrine sedimentary deposits (~22.8-9.0 Ma) along the Tiejianggou section at the Subei Basin were analyzed by using a depositional grain-size end-member analysis model, and four end-members that could represent the depositional environments were obtained. Through comprehensive analyses of sediment grain size characteristics and end-member components, the sedimentary processes along the Tiejianggou section can be divided into four stages. (1) During ~22.8-21.4 Ma, the end-member component one (EM1) (representing lacustrine fine silt) and EM2 (representing lacustrine medium silt) wavelike decreased, while EM3 (representing river coarse silt) and EM4 (representing fan deltaic sandy) wavelike increased, the grain size coarsened upward and poorly sorted, indicating the depositional environment were dominated by low-energy fan deltaic facies with great fluctuations. (2) During ~21.4-17 Ma, EM1 and EM2 significantly increased, while EM3 and EM4 decreased, the grain size fined upward and was dominated by static deposition of fine sand with good sorting, indicating the strengthening influence of lakes and the depositional environment transited to a stable shallow lake or lacustrine face. (3) During ~17-14 Ma, EM1 decreased, EM2 and EM3 were relatively stable with EM3 accounting for the highest proportion, EM4 increased slightly, the grain size coarsened again and were dominated by coarse silt from river suspension input with poor sorting, indicating an unstable depositional environment with low-energy fluvial deposition. (4) During ~14-9 Ma, EM1 wavelike decreased, EM2 and EM3 were relatively stable, and EM4 continued increasing. The grain size significantly coarsened and was dominated by coarse sand from saltation and suspension input and the sorting was poor with enhanced hydrodynamic forces, indicating the most unstable depositional environment that was dominated by high-energy fan delta phases. The depositional environment of the Tiejianggou section transitioned from the early fan delta to the stable lacustrine and finally evolved into the high-energy fan delta phase, and the staged evolution of hydrodynamic conditions from weak to stable, and to enhanced ones. By comprehensive analyses of previous results, we concluded that the depositional environment and hydrodynamic changes during the middle to early Miocene (~22.8-14 Ma) in the Subei Basin were mainly dominated by the regional warm and humid climate, while the high-energy environment during the middle to late Miocene (since ~14 Ma) was jointly dominated by the uplift of the Tibetan Plateau and regional aridification.
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Enrichment of Li, Th, Mo, Pb, and U in Coals from the Taiyuan Formation, Jin-cheng Mining Area, Southern Qinshui Basin: Geological Controls and Implications
Guo Jun, Sun Beilei, liu Chao, Xie Xichao, Li jian
Abstract:
To investigate the distribution, occurrence modes, and enrichment cause of trace elements in coals from the southern Qinshui Basin through mineralogical and geochemical analyses of No. 9 and No. 15 coal seams in the Tai-yuan Formation from Tian'an Hongxiang Mine, Jincheng Mining area. The results demonstrate that: (1) The mineral composition in the coal is dominated by kaolinite, pyrite, calcite, and anatase. The No. 9 coal seam has a content of 37.1 μg/g (coal basis), 2.7 times than that world hard coal. The No. 15 coal seam exhibits significant Li enrichment (108 μg/g, coal basis), equivalent to 7.8 times higher than the average values world hard coal, along with moderate enrichment of Zn, Mo, Pb, Th, and U. Li primarily occurs in clay minerals, and Mo and Pb are mainly associated with pyrite (with minor Mo in organic matter and sulfates). Th is hosted in anatase and clay, the enrichment of U is primarily associated with semifusinite in the inertinite. (2) Li and Th are mainly controlled by the supply of the gra-nitic terrigenous material from the North Qinling orogenic belt. The weak hydrodynamic conditions and humid trop-ical climate promoted clay mineral formation which provided a host for Li and Th. (3) The peat formed in alkaline sedimentary environment with weak hydrodynamics. The enrichment of Mo, Pb, and U was significantly influenced by seawater, where Mo and Pb combined with S2? to form sulfides under reducing conditions (with minor Mo in sulfates and organic matter). Alkaline-reducing peat bogs favor the precipitation of UO22+ ions, and the occurrence of U in coal is primarily associated with inertinite.
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Fluid characteristics, telluride forming conditions and their constraints on the process of gold enrichment in Tantou deposit, western Henan Province
YaoDongdong, ChaoWeiwei, LengChengBiao, YeHuishou, Wang Dazhao, GaoMing, CaoYuan
Abstract:
The Tantou deposit is located in the Xiong’ershan district, the southern margin of the North China Craton. Various types of tellurides are developed and closely associated with native gold. However, the characteristics of fluids, the telluride forming conditions and their constraints on gold enrichment remain unlcear. Based on the detailed division of metallogenic stages, the fluid properties, tellurides and native gold geochemical compositions analyzed in detail by microthermometry, H-O isotopes, scanning electron microscopy and electron probe microanalysis. Tantou gold deposit can be divided into four metallogenic stages: (1) K-feldspar-quartz stage; (2) Quartz-pyrite stage; (3) Sulfide-telluride stage; (4) Quartz-carbonate stage. Gas-liquid inclusions are mainly developed in the quartz-pyrite stage. The homogenization temperatures for the quartz-pyrite stage and the sulfide-telluride stage are 275–363°C and 258–285°C, respectively, with salinities of 5.01%–9.32% NaClequiv and 5.62%–8.10% NaClequiv, densities of 0.68–0.84 g/cm3 and 0.71–0.86 g/cm3, pressures of 5.5–18.3 MPa and 4.1–6.5 MPa, and corresponding mineralization depths of 0.55–1.83 km and 0.41–0.65 km, respectively. Telluride are composed of petzite, sylvanite, stützite, empressite, hessite, altatite, lingbaoite, melonite, coloradoite and tellurium. Through the analysis of mineral assemblages and physical and chemical conditions, the formation conditions of quartz-pyrite stages are T = 300℃, log?O2 = -36.8~-32.1, pH = 3.7~5.7, log?Te2 = -18.0~-10.9, log?S2 = -11.6~-6.8, while that of sulfide-telluride stage are T = 250℃,log?O2 = -37.5~-31.8,pH = 3.9~5.9,log?Te2 = -12.9~-9.4,log?S2 =-14~-9.5. From the quartz-pyrite stage to the sulfide-telluride stage, as the ore-forming depth becomes shallower, the temperature and log?S? of the fluid decrease, while the log?Te? increases. The salinity, density, log?O?, and pH remain essentially unchanged. The early stage (quartz-pyrite stage) mainly precipitated Te-Au-rich pyrite through water-rock reaction, and the late stage (sulfide-telluride stage) mainly formed a large amount of sulfide, telluride and natural gold through fluid mixing. The tellurides start forming a metallic melt, which continuously extracts Au elements from the fluid, leading to the co-enrichment and precipitation of tellurides and gold.
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Quantitative Response of Turbidity Current Confluence Processes to Salt Diapirs in Submarine Canyons: A Case Study from the Northern Gulf of Mexico Continental Slope
Abstract:
Objectives: Quantitative analysis of submarine canyon confluence processes in salt diapir-affected regions is critical for understanding deep-water sedimentary systems, yet the three-dimensional hydrodynamic mechanisms and morphodynamic interactions under structural controls remain poorly understood. This study investigates the Dorsey-Sounder Canyon System in the northern Gulf of Mexico to systematically reveal the salt diapir-driven three-dimensional morpho-hydrodynamic evolution, sediment partitioning patterns, and associated depositional mechanisms. Methods: Integrated analyses of high-resolution 3D seismic data, automated canyon morphology identification, and hydrodynamic quantitative modeling were combined to reconstruct the spatiotemporal evolution of the canyon confluence zone. Multidisciplinary approaches focused on: (1) quantifying morphological parameters, (2) analyzing flow pathway dynamics through hydraulic modeling, and (3) deciphering erosional-depositional patterns under salt tectonic constraints. Results: The modern trunk canyon comprises an eastern tributary and a post-confluence segment, with the confluence point migrating ~1 km southeastward from the initial scour zone, forming a trumpet-shaped morphology characterized by pronounced widening and deepening. Salt diapirs dominantly controlled the confluence process through three-dimensional mechanisms: (1) Planar structural steering confined canyon pathways and defined the confluence zone; (2) Enhanced vertical confinement promoted incision and erosional amplification; and (3) Differential diapir growth rates governed confluence migration. These processes drove asymmetric sediment partitioning and distinct architectural stacking in the deep-water system. Conclusions: This work establishes the first integrated 3D model of salt diapir-controlled canyon confluence processes, elucidating how salt tectonics regulates sediment routing and reservoir heterogeneity in deep-water settings. The findings provide a predictive framework for analogous salt-affected basins, emphasizing the coupling between structural evolution and sedimentary responses in source-to-sink systems. This advances theoretical foundations for hydrocarbon reservoir prediction in complex deep-water environments.
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Research progress and prospect of the ophiolite peridotite in Turkey
CHEN Bohao), LIAN Dongyang), CAI Pengjie, BO Rongzhong)
Abstract:
Turkey ophiolites are distributed across several tectonic units, such as the Northern Anatolian Belt, the Tauride Ophiolite Belt, and the Southern Ophiolite Belt. These ophiolites represent remnants of the Tethyan oceanic lithosphere and reflect the complex tectonic evolution of the region. Studies show that the mantle peridotites within these ophiolites, including harzburgite, dunite, and lherzolite, are extensively serpentinized and exhibit mineralogical and geochemical affinities with peridotites formed in abyssal and forearc settings. The mineralogical characteristics of mantle peridotites, such as the chemical compositions of olivine, orthopyroxene, clinopyroxene, and the Cr# and Mg# values of chromite, provide crucial insights into their melting history and tectonic origin. Geochemical analyses further reveal that mantle peridotites in Turkish ophiolites exhibit significant variations in rare earth element (REE) and trace element distributions, indicating varying degrees of partial melting and subsequent melt-rock interactions. Lherzolites display a left-leaning REE pattern with light REE depletion, while harzburgites and dunites show “U”- or “V”-shaped REE patterns resulting from interaction with LREE-enriched melts/fluids in suprasubduction zone settings. Chromitite research is a key focus within Turkey ophiolites, especially the distribution and genesis of podiform chromitites, which provide valuable guidance for chromitite exploration. Studies indicate that chromitite formation is influenced by a combination of mantle partial melting, melt-rock interaction, and magmatic fractional crystallization, with contributions from deep mantle materials. The mantle-crust transition zone and the upper part of the mantle in supra-subduction zone settings are identified as critical areas for chromitite formation. Moderately depleted peridotites, especially harzburgites associated with dunites, are important exploration indicators, while large-scale dunites of boninitic affinities provide favorable spatial conditions for chromitite enrichment. Additionally, the preservation and exposure of ore-bearing bodies, closely tied to the degree of erosion, are crucial factors to consider during exploration. In conclusion, the study of Turkish ophiolites not only deepens the understanding of mantle dynamics and plate tectonics but also provides scientific guidance for chromitite exploration. By integrating the petrological and geochemical characteristics of mantle peridotites, focusing on favorable tectonic settings, large-scale dunite regions, and moderately eroded ore-bearing bodies, future chromitite exploration efforts are expected to achieve greater efficiency and yield more significant results.
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Study on topographic amplification effect of strong earthquake ground shaking in the Yarlung Tsangpo Grand Canyon - A case study of the 2017 Miling Ms6.9 earthquake
Li Haowen, He Kai, Li Bin, Wan Jiawei, Gao Yao, Wang Wenpei, Cui Fangpeng
Abstract:
The Ms6.9 magnitude earthquake occurred in the Yarlung Tsangpo Grand Canyon region of Minlin City, Tibet Autonomous Region, at 06:34 on November 18, 2017, which led to a number of large-scale landslide debris flows and river blockage in the uninhabited area of the Grand Canyon, resulting in serious hazards. In this paper, we use the 3D spectral element method SPECFEM3D numerical simulation program, combined with remote sensing image data, to simulate and study the ground vibration amplification effect of the complex terrain conditions of the Grand Canyon under the effect of the Ms6.9 magnitude earthquake in Minlin. The results show that: (1) when the seismic wave propagates along the Xixingla rupture, the velocity amplitude amplification occurs in front of the fault rupture, and the uneven energy of the seismic wave and the amplification of the velocity amplitude in many places occur when passing through the high and very high mountainous terrain of the Grand Canyon. (2) The simulated epicenter PGA of the Miling earthquake reached 4m/s2 (0.4g), and the high amplitude area was concentrated near the Xixingla rupture, which was mainly divided into the glacier aggregation area on the north side of the Gyala Peri Peak, the Jiala - Baimagouxiong section of the Yarlung Tsangpo River, the Xixingla - Naiqu section, and the Zhaqu - Duoka section. (3) The PGA of the Yarlung Tsangpo Grand Canyon in the area of rapid topographic change can be 1.97 m/s2, and the amplification rate can be up to 4 times from the bottom to the top of the mountain, and the maximum PGA of 4 m/s2 was detected above the concave and convex body of the seismic source model (4) Three major landslide-intensive zones appeared in the Yarlung Tsangpo Grand Canyon after the Milling earthquake, which were the Jiala-Baimagouxiong section, the Xixingla-Naiqu section, and the Zhaqu-Duoka section, and the PGA high amplitude area coincides with the distribution of landslide-intensive development area. The discussion can be concluded that the Milin earthquake has a non-negligible influence on the occurrence of high watershed-based geohazards in the Grand Canyon area after 2017.
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Rapid exhumation in Hainan Island and its implications for the formation of the South China Sea
Zhang Yulian, Zhang Wanfeng, Zheng Dewen, Li Chaopeng, Yu Jingxing, Li Pengfei
Abstract:
The paleographic pattern of the southern margin of the South China Block before the Cenozoic is essential for understanding the formation and evolution of the South China Sea. Hainan Island, located at the northern margin of the South China Sea and adjacent to the southern edge of the South China Block, serves as a key region for investigating the paleographic features of the passive continental margin of the South China Sea. In this study, we conducted biotite 40Ar/39Ar geochronological analysis on granites from the Triassic to Cretaceous on Hainan Island, to explore the exhumation characteristics and topographic evolution during the Mesozoic. The results show that the cooling ages obtained from biotite 40Ar/39Ar range from 107 to 92 Ma The consistent cooling ages of granitic plutons along the periphery of Hainan Island suggest that the Hainan Island underwent rapid cooling during this period. By synthesizing the available biotite 40Ar/39Ar age data, we observe a “younger on the periphery, older in the center” cooling age distribution, indicating that during this period, the peripheral regions of Hainan Island experienced more significant exhumation than the central areas during this time. It is inferred that during the Late Mesozoic, Hainan Island exhibited a “high in the periphery, low in the center” topographic pattern. Based on this observation, we evaluate and select samples suitable for paleoelevation reconstruction, using detrital zircon Eu/Eu* anomalies and whole-rock (La/Yb)N and Sr/Y ratios. The results of paleoelevation reconstruction of the peripheral regions of Hainan Island during the Cretaceous indicate that the paleoelevation in this period exceeded 3000 meters. Rapid exhumation of the peripheral granitic plutons provided a substantial detrital material to the low-lying Baisha Basin in the central region, further supporting the “higher in the periphery, lower in the center” topographic feature. A comprehensive analysis of the geochronological, geochemical, and provenance data from the South China Sea peripheral blocks reveals that the region experienced a widespread exhumation/cooling event during the Early-Late Cretaceous. This suggests that, at least during the Late Mesozoic, the southern and northern margins of the South China Sea still existed as a unified entity, implying that the initiation of the South China Sea rifting occurred after this period.
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Paleoclimate change and its driving mechanisms in the Gonghe Basin (NE Tibetan Plateau) in the Middle to Late Miocene
Luan Tianxinag, Zhang Bo, Zhang Jinjiang
Abstract:
The paleoclimate of the northeastern Tibetan Plateau during the Middle to Late Miocene may have been controlled by tectonic uplift in the northeastern plateau and global cooling. To investigate the impact of global climate change and tectonic activity on regional climate, as well as to enhance understanding of the interactions among Earth's spheres, this study focuses on the Miocene sediments from the Gonghe Basin in the northeastern Tibetan Plateau. By integrating existing stratigraphic paleomagnetic age data with comprehensive analyses of branched glycerol dialkyl glycerol tetraethers (brGDGTs), total organic carbon isotopes, total organic carbon content (TOC) and heavy mineral composition, we reconstructed the environmental evolution history of the Gonghe Basin during this period. The results show that from 14.5 to 8.7 Ma, the paleotemperature reconstructed by brGDGTs steadily decreased (by about 2.3 ℃), the total organic carbon isotopes increased from -25.23‰ to -24.88‰, pH value increased from 8.1 to 8.7, and TOC decreased by ~0.05%, indicating an intensification of aridification. From 8.7 to 6.8 Ma, the total organic carbon isotope decreased from -24.88‰ to -25.23‰, and the pH decreased from 8.7 to 8.2, indicating that the aridification was alleviated. Compared with the previous period, the cooling rate accelerated (increased from 0.4 ℃/Ma to 1.7 ℃/Ma), and the content of unstable heavy minerals increased. It is inferred that during this period, the significant uplift of the Elashan and Qinghai Nan Shan around the Gonghe Basin formed a topographic barrier to the southeast monsoon, leading to opposite trends in temperature and humidity within the basin. By integrating the tectonic and climatic records from the northern Tibetan Plateau, we believe that the alleviation of aridification in the study area and regions to its east during 9~7 Ma primarily responded to the orographic rainfall effect caused by tectonic uplift. In contrast, the continued aridification since the Middle Miocene in areas to the west of the study area, such as the Qaidam Basin and Tarim Basin, was controlled by both global cooling and tectonic uplift.
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Tectono-thermal evolution of the basin-range system in the north margin of Erlian Basin and its geological significance
ZhouGuiLin, LI Ke, TANG Jianzhou, ZHANG Zhicheng, ZHANG Huaihui, DING Cong
Abstract:
The Erlian Basin is a group of fault basins formed under the Mesozoic extension system in central Inner Mongolia. It is of great significance to study the characteristics of tectono-thermal history of the basins and identify the evolution law of tectono-geomorphologic exhumation in Inner Mongolia and its adjacent areas for understanding the dynamic mechanism of multi-tectonic domain superimposed transformation in NE China during the Mesozoic. Here, the apatite fission track (AFT) method is used to study the tectono-thermal evolution of the Bayindulan Sag and the Bayinbaolige Uplift in the northern margin of Erlian Basin. AFT dating results showed that the AFT ages in the Sag are 65.6±8.8~245.2±17.3 Ma, and the mean track lengths are 12.17±0.3~13.32±0.2μm. The ages of AFT in the Uplift region are 182±11~238.8±8.7 Ma, and the mean track length was 12.86±0.30~13.46±0.16 μm. The results of thermal history modeling show that the northern margin of Erlian Basin mainly experienced three stages of cooling, namely, late Paleozoic to Middle Jurassic (270-160 Ma), Late Jurassic to Early Cretaceous (160-100 Ma) and Late Cretaceous (100-70 Ma). Combined with the regional data, the tectono-thermal process in central Inner Mongolia presents three stages of evolution, and the late Paleozoic-Triassic uplift is related to the closure of the Paleo-Asian Ocean;During the Jurassic and Early Cretaceous, the central region of Inner Mongolia was affected by the extension collapse after the closure of the Mongol-Okhotsk Ocean and the subduction of the Paleo-Pacific plate. In the Late Cretaceous, the collision of East Asian continental margin blocks caused regional tectonic inversion in Erlian Basin. After the Late Cretaceous, the central part of Inner Mongolia did not experience significant cooling exhumation and the planation surface of Inner Mongolia Plateau was basically formed.
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Characteristics and Geochronology of Ductile Deformation in the Bayan Obo Ore District and Their Geological Significance
WANG Dongsheng, GAO Yupu, SHE Hongquan, ZHANG Li, LI Yike, GUO Bin, KE Changhui, YUAN Xingyu, MA Shouxian, ZHU Zeying, PENG Zidong
Abstract:
The Bayan Obo deposit is the largest comprehensive Fe-REE-Nb deposit in the world. The shape of ore bodies and the texture of ore are closely related to ductile structures. To understand the deformation characteristics and evolution of ore structures in the ore district, this study collected rocks for microscopic and Th-Pb geochronological analysis based on macroscopic structural analysis. Results show that rhombic, banded, and folded ore structures can be identified in the Bayan Obo deposit, which reflects gradually strengthening ductile deformation, involving minerals such as magnetite, monazite, fluorite, rare earth minerals, and dolomite. The most widely developed banded structures represent the products of ductile deformation of rocks during the compression stage. Selected syntectonic monazite gives a Th-Pb age of 432 ± 4 Ma, belonging to the Early Paleozoic. Referring to previous geochronological results in the Bayan Obo deposit, it is believed that this age represents the ductile deformation occurs at the Middle Silurian. In addition, the coarse-grained monazite shows an age range of 477 to 838 Ma and the geological significance represented by these ages is not yet clear. It may be related to the alteration of monazite during the mineralization by hydrothermal activity, resulting in a certain degree of lead loss. The U-Pb age of zircon in the undeformed diorite-porphyrite dyke is 274 ± 4 Ma, which constrains the upper limit of ductile deformation. Combining regional geological results, it is suggested that the Middle Silurian ductile deformation in the Bayan Obo deposit corresponds to the collage between the North China plate and the Bainaimiao arc. The intense collision has transformed the original ore-forming structure from both macro- and microscopic aspects, forming the existing pattern.
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Study on quality evaluation method of typical vein quartz deposits in Dabieshan area
Xiao Ying, Deng Yufeng, Ma Jinhai, Shen Huanxi, Zhan Jianhua, He Zhenzhong, Zhu Chuanhai, Hao Wenjun
Abstract:
The Dabieshan area in China is characterized by the widespread occurrences of Mesozoic metamorphism and magmatism, with abundant vein quartz resources, which may become one of the key regions for strategic mineral exploration of high-purity quartz (raw material) in China. This paper determines the quality grades of high-purity quartz vein quartz samples from the Hongjiawan mineral occurrence and Baishishan deposits in the Dabieshan area. A comparative analysis is conducted based on factors such as hand specimens, fluid inclusions, content and occurrence states of impurity element in the ores with different quality grades, to identify typical quality evaluation indicators for vein-quartz ores in the Dabieshan area. The content of SiO2 in the processed quartz sand from Hongjiawan and Baishishan vein-quartz ores can reach 99.9971% and 99.9968% respectively, which meets the quality requirements of middle and high-end products. The quality of the Hongjiawan ore is better than that of the Baishishan ore. The comparative study of different quality of high purity quartz raw materials shows that, if the vein quartz is snow-white in color, higher transparency, larger fluid inclusion sizes dominated by two-phase (liquid-vapor) primary fluid inclusions, and lower impurity elements content, the quartz has the greater probability of becoming high purity quartz raw materials. The contents of impurity elements in recrystallized quartz and core of quartz veins are generally low, thus we should pay more attention to this part of quartz. This conclusion has a significance for evaluating the potential resources of high purity quartz raw materials in this area and clarifying the geological characteristics of future prospecting targets.
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Apatite Fission Track Spatial Distribution Characteristics: Implications for the Evolution of Tectono-geomorphological Landscapes — A Case Study of Wugongshan
Gao Shangyan, Li Guangwei, Zhang Yuwei, Ye Zhanghuang
Abstract:
The evolution of landforms is controlled by the interaction between tectonic activities and surface processes, and exploring the contribution of both to the evolution of structural geomorphology has always been a hot and difficult point in the study of the evolution of orogenic geomorphology. In recent years, the rapidly developing low-temperature thermochronology has become a powerful method for studying the quantitative evolution of tectonic geomorphology. Therefore, this study uses low-temperature thermochronology method to investigate the exhumation processes and mechanisms of the typical granite gneiss dome in China - Jiangxi Wugong Mountain. We targeted the core of the Wugong Mountain range - the north and south sections of Mingyue Mountain for sampling and conducted apatite fission track analysis. The apatite fission track ages are mainly concentrated at ~65-42 Ma, and the ages on both sides of the mountain show a clear negative correlation with elevation. This may be due to the fact that the exhumation of the Wugong Mountain dome in the Late Cretaceous were mainly controlled by the detachment faults on both sides, while the denudation process in the Cenozoic was mainly affected by surface erosion. This indicates that for relatively old orogenic belts, the spatial distribution characteristics of low-temperature thermochronology ages can be used as an indicator to discern the main control mechanisms of tectonic geomorphological evolution. In addition, according to our thermal history simulation results, the Wugong Mountain area has experienced a rapid exhumation stage in the Late Cretaceous, a slow stage from the Paleocene to the early Miocene, and a relatively rapid exhumation stage since the early Miocene, mainly controlled by regional tectonic activities and climate change, respectively.
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Sedimentary geochemistry of Mesozoic cherts in Tongjiang area of Northeast China: Implication on the subduction of Paleo-Pacific subduction
ZHANGWenHao, ZHOU Jianbo, ZHOU Xingui, WANG Dandan, LIU Weibin, Meng Yuanlin, LIU Xufeng
Abstract:
The Sanjiang area in Northeast China hosts the sole exposed Mesozoic siliceous rock series in northern China, which holds significant geochemical characteristics for unraveling its genesis and tectonic setting, particularly to trace the temporal and spatial initiation of paleo-Pacific subduction. In the Tongjiang area north of Sanjiang, the "Heitongdi 1 Well" reveals a silicic rock system from the late Triassic to Early Jurassic Dajiashan Formation, spanning approximately 400 meters. Through field geological investigation, microscopic observation, and petrogeochemical analysis of core samples from this well, we have conducted a comprehensive study on the origin and tectonic environment of these siliceous rocks. Radiolarian fossils are observed in the siliceous rocks of the Tongjiang area. The mean Al/(Al+Fe+Mn) value in the siliceous rock samples was 0.74, with no discernible Ce anomaly and Ce/Ce* values ranging from 1.02 to 1.54, (La/Ce)SN≈1, no significant difference in Y/Ho values, a mean Y/Ho value of 30.02, and a mean Eu/Eu* value of 1.17, indicating that these siliceous rocks were formed in a continental margin island arc environment. The present study also provides compelling evidence for the initiation of subduction of the Paleo-Pacific plate beneath the Eurasian plate during the late Triassic period, leading to the establishment of an island arc environment along the eastern margin of Jiamusi Block. The inferred location of the subduction suture between these two plates is situated westward from Tongjiang drilling hole.
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Meso-Cenozoic tectonic evolution and geomorphologic restoration of the west section of Bonan low uplift, Bohai Bay Basin
Wu Zihan, Hu Zhiwei, Shi Panpan, Dai Liming, Li Sanzhong, Li Fakun, Wang Zhuo, Hu Zihao
Abstract:
The west section of Bonan low uplift in the Bohai Bay Basin has been found to have great characteristics of medium-deep buried-hill type oil and gas trap in recent exploration work, and internally discovered the Bozhong 26-6 large-scale oil and gas reservoir. Discussions on the formation and evolution of buried-hills, the development sedimentary systems, and the mechanisms of oil and gas generation, storage and migration often require tectonic analysis and tectonic geomorphological restoration work. Therefore, to reveal the complete tectonic deformation and geomorphic evolution of the west section of Bonan low uplift, and to provide theoretical support for oil and gas exploration, this paper, based on the reflection seismic and drilling data in the study area, detailed the strata distribution and tectonic deformation characteristics during Mesozoic-Cenozoic, and used Move software to conduct two and three dimensional tectonic restoration, accurately restoring the geomorphological features during the major periods of tectonic activity. Results reveal that: (1) During the early Mesozoic (from the Indosinian to the early Yanshanian), under the strong compressional orogeny transitioning from a near S-N to NE direction, the study area developed a numerous near E-W and NE directed thrusts, as well as several near S-N strike slip faults. The region experienced intensive uplift, with the overall lack of the Jurassic sedimentation and extensive erosion of the Paleozoic strata. The Precambrian basement was exposed and flattened, presenting a large-scale flattened mountain landform. (2) During the late Mesozoic (from middle to late Yanshanian), under a strong NW-SE directed extensional environment, the reverse faults in the Huanghekou Depression on the south side of the uplift experienced intense negative inversion activity. This allowed the depression to receive a large amount of Cretaceous volcaniclastic and muddy-sandy sediments. The west section of Bonan low uplift and part of the Bozhong Depression on the north side still exhibit uplifted landforms and serve as sediment source areas. (3) During the early Cenozoic (from early to middle Himalayan), under the strong NW-SE directed extensional and rift environment, the study area experienced near S-N directed bidirectional detachment activity. The Huanghekou Depression continued to experience southward faulting, forming a basket-shaped and half-graben shaped structure. The strata in the Bozhong Depression underwent northward faulting and detachment. The west section of Bonan low uplift was affected by transtensional detachment, presenting a geomorphic feature of “high and narrow in the west, low and wide in the east”, ultimately forming the current tectonic pattern of “two depressions with one uplift”, providing space for the deposition of Cenozoic Shahejie Formation source rocks and Dongying Formation cap rocks.
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Mineralogical and geochemical characteristics and enrichment mecha-nisms of critical elements in the No. 3 coal seam of the Shanxi Formation in the Hengcheng mining area, Ningdong coalfield
GUO Yajie, SHI Yutao, JI Xiaoyan, MA Shaodong, HUANG Pengcheng, YANG Dequan, CAO Yongbin, SUN Jia, ZHANG Qi, LI Baoqing
Abstract:
The study of coal-related critical elements deposits has become a frontier hotspot in coal geology research and an important source for increasing reserves of critical elements mineral resources. This study focuses on the No. 3 coal seam of the Early Permian Shanxi Formation at the Maliantai Coal Mine in the Hengcheng mining area of the Ningdong coalfield. It investigates the mineral composition and geochemistry to determine the distribution, occurrence, and en-richment characteristics of elements minerals in the coal, as well as to evaluate their compre-hensive utilization. The study results show that:(1)The No. 3 coal seam at Maliantai is characterized by medium ash yield, high volatile yield, ultra-low total moisture content, and low to medium total sulfur content, with minerals in the coal mainly composed of kaolinite;(2)The major elements in the coal are primarily composed of SiO2 and Al2O3, with minor amounts of Fe2O3, CaO, and MgO. Compared to the average coal worldwide, Li and Zr reach enrichment levels, while Ga, Nb, Hf, Ta, Pb, Th, and rare earth elements (REE+Y) are slightly enriched;(3)Li and Ga are mainly found in kaolinite, Zr (Hf) and Nb (Ta) are primarily found in zircon, and REY is primarily hosted in kaolinite and aluminum phosphate (goyazite) associated with kao-linite. The Yinshan ancient land in the northeast of Ningdong coal field provides important felsic clastic material for the Malitai No. 3 coal, in addition, the Alashan block also provides some volcanic clastic material. The enrichment of critical metals such as Li, Zr (Hf), and Nb (Ta) in the coal is mainly controlled by the input of alkaline-peralkaline felsic clastic materials, with chemical weathering and water-rock interactions being secondary controlling factors. The en-richment of Ga is primarily controlled by the intensity of chemical weathering. The enrichment of REY is mainly influenced by the input of clastic materials and water-rock interaction processes. In addition, the kaolinite content also plays a role in the enrichment of Li, Ga, and REY. Malian Tai No. 3 coal has potential as a source of Li-Ga-Zr-REY metals.
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Genetic relationship of the deposit in Qibaoshan ore-concentration area of Wulian County, Southern Margin of Jiaolai Basin: Constraints of in-situ sulfur isotope and trace element of sulfides
Tang Mingying, Ding Zhengjiang, Zhan Honglei, Zhu Wei, Wang Xin, Wei T, Li Fuhua, Chen Jian, Zou Zhanchun
Abstract:
The Au-Cu polymetallic deposits represented by the Qibaoshan ore-concentration area of Wulian county is developed in the Southern Margin of Jiaolai Basin, three typical deposits are developed, namely, Jinxiantou Au-Cu deposit, Diaoyutai pyrite deposit and Qibaoshan Pb-Zn polymetallic deposit. In order to further elucidate the genetic relationship between ore deposits, improve the study of ore-forming system in ore concentration area, and establish the ore-forming model of ore deposits, the main sulfides in the ore deposit were tested and analyzed in situ for sulfur isotopes and trace elements of pyrite.. The sulfides in the Qibaoshan ore concentration area has a relatively concentrated sulfur isotope peak distribution range (0‰ ~ 6‰), which comes from the same or similar deep magmatic system.. The Cu, Zn, As, Se, Ag, Sb, Pb and Bi in pyrite show relatively regular changes from Jinxiantou Au-Cu deposit to Diaoyutai pyrite and then to Qibaoshan Ag-Pb-Zn polymetallic deposit, The distribution characteristics of elements show that the ore-forming fluid as a whole presents an evolution process from magmatic hydrothermal to mixed hydrothermal. Comprehensive analysis shows that the deposits in Qibaoshan ore collection area are closely related in time and space. The deposits are the products of the same geological and tectonic environment and different parts of rock construction, which together constitute the porphyry-epithermal Au-Cu-Pb-Zn-Ag polymetallic metallogenic system in Qibaoshan area.
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Geochemical characteristics of apatite and hornblende in diorite of the Zhongguan iron deposit in Hebei Province and their records of petrogenesis and mineralization
caochong, caoqing, zhangyanbo, wangling, dongboxiao, Zhang Rongfang
Abstract:
The skarn-type iron deposit is an important guarantee of iron ore resources in China. It is necessary to study the source, genesis and evolution of physical-chemical conditions of ore-forming magma for understanding formation mechanism of skarn-type iron deposits. In this paper, the BSE images and corresponding major and trace element compositions of the hornblende and apatite in diorite from the Zhongguan iron deposit are conducted. The source of magma, magma mixing and crustal contamination process, as well as the changes of magmatic physical and chemical conditions caused by these processes are identified. Finally, the necessary magmatic conditions for the formation of the Zhongguan skarn iron deposits are proposed. The results show that the ore-forming magma experienced a double magma chamber system. In the deep magma chamber, the hornblende phenocrysts crystallized in the environment of temperature (average 943 °C), pressure (average 315MPa), oxygen fugacity (average ΔNNO + 0.34) and water content (average 5.97 %). In contrast, the hornblende matrix crystallized in the environment of temperature (average 773 °C), pressure (average 89MPa), higher oxygen fugacity (average ΔNNO + 1.5) and Cl content (average 0.15 %), and lower water content (average 4.87 %) in the shallow magma chamber. The changes of Al2O3 content of hornblende, as well as the 87Sr/86Sr(i)values (from 0.7053‰ to 0.7076‰) of apatite indicate that the ore-forming magma is mainly mantle-derived and mixed with a small amount of crust-derived materials. The obvious core-rim structures are shown in the BSE images of apatite, and the core is generally brighter than that of the rim. The cores are mainly enriched in SiO2, MnO, Ga, REEs et al. In contrast, the rims are more enriched in SO3, Na2O and Cl. Besides, the δEu values of the rims are higher than those of the cores. The chemical composition differences between phenocrysts and matrix of hornblende, as well as the core-to-rim compositional variations of apatite indicate that the ore-forming magma has undergone contamination of gypsum rock strata, crustal material mixing and fluid exsolution during the upward emplacement process, resulting in a significant increase in oxygen fugacity of magma, and promoting the enrichment of volatiles and Fe in magma. In summary, gypsum rock contamination or crust-derived magma mixing and hypabyssal emplacement are necessary conditions for the formation of the Zhongguan skarn high-grade iron deposits.
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Nickel and Cobalt metallogenic series andprospecting direction in Qinghai Province
Abstract:
Nickel ore is the main part of nickel and cobalt ore in Qinghai, and cobalt is usually produced as associated ores of magmatic nickel ores or contact metasomatic polymetallic ores, and independent cobalt ores are rare. Nickel deposits are relatively concentrated in the Qinling-Qilian-Kunlun metallogenic domain, South Qilian metallogenic belt and East Kunlun metallogenic belt nonferrous metal ore concentration area, the deposit type is magmatic, which is closely related to mafic-ultramafic rocks intruded by mantle-derived magma through deep liquation, and the abnormal enrichment and mineralization mostly occurred in the Early Paleozoic Ordovician (South Qilian metallogenic belt) and Devonian (East Kunlun metallogenic belt). The mineralization was formed in a post-collisional extensional environment during the late evolution of the Proto-Tethys. Cobalt deposits are mainly distributed in Qinling-Qilian-Kunlun metallogenic domain and Tethyan metallogenic domain, but independent cobalt deposits and associated cobalt deposits with economic value are exposed in East Kunlun metallogenic belt, South Qilian metallogenic belt and a"nyemaqen metallogenic belt. The main types of cobalt deposits are magmatic, marine volcanic and contact metasomatic; The metallogenic epoch of cobalt deposits is complex, which can be divided into four metallogenic stages, namely, Ordovician and Silurian of Early Paleozoic, Devonian and Carboniferous of Late Paleozoic and Triassic of Mesozoic. The metallogenic geological environments of different metallogenic stages are significantly different. The metallogenesis varies with the types of deposits, but it is basically consistent with the enrichment and formation process of the main ore species. The mineralization of Ordovician-Devonian is in the extensional environment after orogenesis. Forming magmatic deposits related to mafic-ultramafic rocks of non-ophiolite type; forming marine volcanic rock deposits in the Carboniferous period in the oceanic spreading environment; forming contact metasomatic deposits in the Triassic period related to the magmatic intrusion of continental margin arc. According to the spatial and temporal distribution characteristics, mineralization and metallogenic geological background of the deposits, the nickel and cobalt deposits in Qinghai are divided into 10 metallogenic series, 15 metallogenic subseries and 9 deposit types. Base on that regional metallogenic geological setting, regional metallogenic condition, the known mineralization information and the latest prospecting results, the regional element geochemical field, the metallogenic Serie of ore deposits and the research degree analysis, the prospecting potential of different types of nickel and cobalt deposits in the metallogenic belt is proposed. The South Qilian metallogenic belt, the northern Qaidam metallogenic belt and the East Kunlun metallogenic belt in the time-space domain of the former Tethys Ocean tectonic activity are still the first possible prospecting areas, and the field investigation should focus on the Ni-rich iron series basic-ultrabasic rocks unrelated to ophiolite, and then the magmatic nickel deposits related to ophiolite mafic-ultramafic rocks should be explored in the ophiolitic melange belt. For the less studied cobalt deposits, the first is to focus on the metallogenic geological environment and favorable metallogenic conditions of independent cobalt deposits of marine volcanic rock type, and the second is to focus on the occurrence state and abnormal enrichment mechanism of Co element in known deposits; The northern Kunlun magmatic arc in the Galinge-Yemaquan area in the western part of the East Kunlun metallogenic belt and the Qimantag-Xiariha magmatic arc in the Dulan area in the eastern part of the East Kunlun metallogenic belt are favorable for finding contact metasomatic polymetallic associated cobalt deposits. The East Kunlun metallogenic belt and a"nyemaqen metallogenic belt may become important prospecting areas for marine volcanic cobalt deposits related to the oceanic ridge magmatism during the spreading period of the Paleo-Tethys Ocean. In general, magmatic nickel deposits, marine volcanic type independent cobalt deposits and paragenetic cobalt deposits, magmatic type associated cobalt deposits and contact metasomatic type associated cobalt deposits can be regarded as the main direction of future exploration of nickel-cobalt deposits.
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2010,84(9):1300-1315, DOI:
Abstract:
Based on field observations and structural measurements, this paper describes basic features of the Dabashan foreland arc-shaped structural belt, its distribution pattern, zonation, segmentation, vertical stratification, deformation pattern, superimposed folding and paleostress field, then discusses main factors controlling the formation of this structural arc. It pointed out that the formation and development of the Dabashan foreland arc are different from classical model of collisional mountain built-up; it was shaped through three different stages: original boundary conditions formed during Paleozoic extension and rifting along the marginal zone of the Yangze; initiation during Middle-Late Triassic collisional orogen; and final formation during Middle-Late Jurassic intra-continental orogen. The arc-shaped Chengkou-Fangxian fault zone not only controls the Early Paleozoic deposition and magmatism, but also played key role in the foreland arc formation, and the basement uplifts at the two syntax acted as important boundary conditions. Sandbox modeling was carried out in the laboratory to model the formation and boundary condition of the Dabashan foreland arc. The model was set-up according to the real geologic data.
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maojingwen, CHEN Maohong, YUAN Shunda, GUO Chunli
2011,85(5):636-658, DOI:
Abstract:
The Qinhang belt is located along the Qinhang (Qinzhou Bay to Hangzhou Bay) or Shihang Shiwandashan Mt. to Hangzhou Bay) Neoproterozoic suture in South China, which separates the Yangtze craton and Cathaysian Block. The most ore deposits in the belt are Mesozoic age although they occurred along the Precambrian suture. Based on the previous researches we recognize these deposits in two episodes, i.e. Neoproterozoic marine exhalative Cu-Zn deposits, and Yanshanian granitoids – related W-Sn-Cu-Pb-Zn deposits. The latter can be subdivided in Mid-Late Juarassic porphyry-skarn-vein polymetallic copper deposits, Late Jurassic granite – related W-Sn deposits, and Cretaceous epithermal Au-Ag-Pb-Zn-Sn deposits. After descriptions of the basic characteristics, ore-forming mechanics, spatial-temporal distribution of these deposits it is proposed that the Neoproterozoic marine exhalative Cu-Zn deposits occurred in the foreland basins of the oceanic islands whereas the Mid-Late Juarassic porphyry-skarn-vein polymetallic copper deposits are related the high-K calc-alkaline granites derived locally from the remelt of the subducted Izanagi plate at 180-160 Ma along the ancient Precambrian suture. The large-scale Late Jurassic granite – related W-Sn deposits associated with the crust-source granites with input of the mantle substances at 160-150 Ma, which are inferred to be the result from subducted plate window in the central part in South China and bounded in west by the Qinhang suture, where a lot of large and supper large tin and tungsten deposits developed. After 135Ma the subducted oceanic plate changed its motion direction to be along northeast, paralleling the Eurasian continental margin, which induced the large-scale lithospheric extension. Therefore, the all Cretaceous epithermal Au-Ag-Pb-Zn-Sn deposits developed within the volcanic basins and faulting basins at 120-90 Ma along the Eurasian continental margin.
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2013,87(5):737-746, DOI:
Abstract:
Thaw lake is a common landscape in permafrost regions. The presence of a water body thus constitutes a heat source and releases the heat energy to the permafrost beneath and around lake, giving rise to the ground temperature increase. A talik, even penetrated talik maybe occur under the lake-bottom. The decline of permafrost table, elevation of permafrost base on the lakeshore accelerates the rapid permafrost degradation. This study predicted the temperature changes beneath and around lake and the process of permafrost degradation. The results showed that when the water depth is 2 m and 4℃ of mean annual lake-bottom temperature, the increase of ground temperature is about 4.7-3.2℃ beneath the lake-bottom, 2.2-1.1℃ beneath the lake-edge, and 0.3-0.1℃ beneath the lakeshore after 1000a. When the mean annual lake bottom temperature equals to or is less 0℃, a talik is impossible formation under the thaw lake; if the temperature increases to 1℃, a 25 m deep talik forms after 500a and the permafrost will be thawed completely after 900a. Therefore, the time of permafrost disappearance shortens with the increase of mean annual lake-bottom temperature.
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2013,87(6):759-772, DOI:
Abstract:
During the geological investigation of last several years, a group of A type granitic plutons has been found in the middle segment of the Bangonghu Nujiang suture. These granitic plutons occur as stocks with an exposed area of less than1 km2 and lithologically include two types of biotite granite and granodiorite porphyry, which intrude into Cretaceous sedimentary rocks. A systematic analysis of whole rock element geochemistry and Nd, Sr, Pb isotope for these A type granites indicates that they contain high SiO2 content varying from 68.62%~75.36%. Moreover they have relatively high K2O+Na2O(8.03%~9.37%)and Fe2O3T(0.86%~5.39%) and low Al2O3(12.76%~15.54%) content, appearing weak peraluminous and metaluminous features. Trace elements N MORB normalized spider diagram displays apparent enrichment in large ion lithophile element(LILE) Rb, Th, U, K, Pb with Ba and Sr of marked depletion. High field strenth element(HFSE) Nb, Ta and Ti are sharply depleted with Zr and Hf of relative enrichment. All of these are characteristic of A type granite and different from arc granite. These granites have high REE contents(∑REE=122.37×10-6~291.19×10-6,with an average of 201.31×10-6). Light REE are rich relative to heavy REE(LREE/HREE=4.89~9.58, with an average of 5.93)and negative Eu anormalies are sharp(〖QX(Y12#〗δ〖QX)〗Eu=0.14~0.54,with mean value of 0.34), making their chondrite normalized rare earth element patterns appear slightly right dipping V type. Nd, Sr and Pb isotope results indicate that the A type granites from the middle segment of the Bangonghu Nujiang suture are rich in radioactive isotope. Their 87Sr/86Sr and ISr ratio values vary from 0.719842~0.786395 and 0.706900~0.710378, respectively. 143Nd/144Nd ratio values are from 0.512123~0.512392, with large negativeεNd values(-3.37~-10.34), reflecting important involvement of crustal components. Pb isotope composition 206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb display ranges of 18.703~19.070, 15.680~15.732 and 39.121~39.576, respectively, which plot on the upper crustal line and above the orogenic evolution line in the plumtotectonic framework diagram of Zartman and Doe (1981) and show anormaly high enrichment components. The study points out that the A type granites were derived from partial melting of enriched lithospheric mantle (approximating EMⅡ), which were metasomalized by sediment melt from slab during the oceanic crust subduction and later heat by upwelling asthenospheric materials through slab windows formed as a result of slab break off during the postcollisional extension of the orogenic zone.
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2014,88(8):1353-1371, DOI:
Abstract:
Resources of dinosaur fossils in China are the most abundant in the world. So far, Zhucheng City of China has become a significant Late Cretaceous locality of dinosaur fossils, represented by the large hadrosaurs. Based on investigation and research of taphonomy characteristics of dinosaur fossils from Late Cretaceous, this article systematically demonstrates the taphonomy characteristics of dinosaurs fossil bones from Late Cretaceous and analyzes the taphonomy geological background, the taphonomic sedimentary facies and paleocurrent, the distribution, modification and gathering characteristics of fossil bones and taxonomy, the micro fabric and taphonomic model for the bone fossils, etc. Dinosaur fossil clusters of Late Cretaceous (the dating of feldsparArAr age is 76 2~73 5 Ma) in Zhucheng City, are mostly buried in the alluvial fan debris flow(DF) and flood plain(FP) and the braided river channel(BRC). Fossils are densely distributed in stratification, which are of assorted sizes, non equidensity, singular species, and different in sizes, shapes and standards of residue bones. The majority of fossil bones are damaged without leaving intact fossil bones, being of the columnar and tabular shapes. Larger bones are arranged in certain direction, reflecting the features of dinosaur fossil clusters’ taphonomy and sedimentation undergoing the shortrange transport allochthonously and fast burial. The sedimentary petrology and the thin section analysis reveal that the geologic climate of Zhucheng under which the dinosaurs lived and the fossil bones buried is featured with semiaridarid condition. The taphonomypreservation pattern of dinosaurs can be summarized as: poor living environmentdinosaurs’ massive deathbodies’ decaybones’ washed out and transported by flood or debris flowfast burialshallow burial diagenesisexposure by the Crust uplift. The research on Late Cretaceous Dinosaur taphonomy of Zhucheng provide a series of evidences to better understand and reconstructure the Cretaceous paleogeography, Paleoclimate and paleoenvironment
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Zhiqin Xu, Jingsui Yang, Haibing Li, Shaocheng Ji, Zeming Zhang, Yan Liu
2011,85(1):1-33, DOI:
Abstract:
The collision between India and Asia is the most spectacular tectonic event on Earth during the Cenozoic, resulting in the uplift of the Tibetan plateau and surrounding orogenic belts as well as a lot of material escaping toward the east and southeast. In this paper, the Tibetan plateau was divided into the following tectonic units: (1) the central Tibetan plateau including east Kunlun, Bayanhar-Songpanganzi, Qiangtang, and north Lhasa areas; (2) the Gangdese-Himalayan main subduction-collision belts consisting of Gangdese Andes-type subduction belt and the Himalayan-type collision belt; (3) surrounding transpressional orogenic belts characterized by thrusting and strike-slip faulting which include Western Kunlun-Altyn-Qilian transpressional belts in the north, Longmenshan-Jinpinshan belt in the east, Sino-Burma belt in the southeast, India-Pakistan-Afghanistan belt in the southwest; (4) lateral extrusion terrains including South Songpan, Lanping, Baoshan and Tenchong terrains bounded by large-scale strike-slip faults: Xianshuihe-Xiaojiang fault, Ailaoshan-Red river fault, Lancangjiang fault, Jiali-Gaoligong fault, Nabang fault and Sagaing fault around the eastern Himalayan Syntaxis, as well as Tianshuihai, Xindukushi, Kabuer and Afghanistan extrusion terrains around the western Himalayan Syntaxis. Various constraints for the India / Asia collision tectonics have been discussed, such as: collision between a small wedge of Indian plate and the larger Asian Plate, the roles of the Eastern and Western corners of the Indian plate, the impact of normal and oblique collisions, large strike-slip faulting related to lateral extrusion, transpressional mechanism with both strike-slip faulting and thrusting kinematic features related to uplift of surrounding orogenic belts, and mantle structures beneath the Tibetan Plateau.
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Yin-Zhang Zhou, Bao-Fu Han, Zhao Xu, Rong Ren, Li Su
2014,88(1):25-35, DOI:
Abstract:
In this paper, we focused on the structural and geochronological analyses for the Yingba area in western Inner Mongolia, China. At least three stages of Late Proterozoic to Mesozoic tectonomagmatism have been identified. New and previous zircon U-Pb ages have revealed Carboniferous (325~313 Ma) granodiorite and porphyritic granite, Early Permian (291~277 Ma) alkaline granite and purple red medium-fine grained granite and Early Cretaceous (~134~130 Ma) pegmatite and quartz monzonite. The first tectonic event is characterized by NW-SE compression after the Early Permian (290.9±1.8 Ma), which generated the low-angle NW-dipping gneissic foliations in the granodiorite and alkaline granite. The second event is indicative of NW-SE extension, during which a SE dipping low-angle ductile shear zone, which is characterized by the medium-high temperature (450~650 ºC) mylonite, crosscut the gneissic granodiorite and gneissic alkaline granite, and so it apparently postdated the first tectonic event (<290.9±1.8 Ma). The ductile shear zone is crosscut by the ~134 Ma pegmatite veins, indicating that the extension occurred before the Early Cretaceous pegmatite veins. The third tectonic event is represented by NW-dipping moderate-angle brittle normal faults, which resulted from NW-SE extension after the Early Cretaceous and crushed the ~134 Ma pegmatite into cataclasite. The Yingba area has recorded a typical process from the formation of an orogen to intracontinental extension during Late Proterozoic to Mesozoic.
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gaofeng, zheng changqing, yao wengui, lijuan, shilu, cuifanghua, gaoyuan, zhangxingxing
2013,87(9):1277-1292, DOI:
Abstract:
The granitic mylonitic gneiss is a set of metamorphic granitic rocks, located in Haduohe area, is mainly composed of fine grained biotite monzonitic granitic mylonitic gneiss, fine grained biotite granitic mylonitic gneiss and fine garnet mica granitic mylonitic gneiss. The results of geochemical study indicate that SiO2 values are in the range of 66.4%~74.52%, K2O+Na2O is between 7.36%~8.84%, Al2O3 values are in the range of 13.43%~15.74%, A/CNK=0.974~1.092, belonging to high-K calc-alkaline and quasi-aluminous to weakly peraluminous rocks; It’s higher in total rare-earth content (ΣREE= 94.15×10-6~164.30×10-6), the chondrite -normalized REE patterns demonstrate right-oblique linear REE patterns with weak negative Eu anomalies, and reveals LREE enrichment and HREE depletion; The trace element is characterized by a strong enrichment in large ion lithophile elements, such as Rb, Ba, U, K et al, depletion in Ta, Nb, P, Ti et al.. The zircon U-Pb dating results indicate that the magma formation can be divided into two periods, the first period is around 320Ma, the representative rock is fine grained biotite granitic mylonitic gneiss and fine garnet mica granitic mylonitic gneiss, the second period is around 304Ma, the representative rock is fine grained biotite monzonitic granitic mylonitic gneiss. Combining petrography, chronology and rock geochemical characteristics, the protolith of the granitic mylonitic gneiss is high-K calc-alkaline I type granite, formed in the post-collision environment of Xing'an block and Songnen block, during Late Carboniferous. And then suffered relatively strong ductile brittle metamorphism and deformation during Late Early Permian by the post-collision of Xing’an block and Songnen block.
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DONG Shuwen, LI Tingdong, GAO Rui, Lǖ Qingtian, WU Zhenhan, CHEN Xuanhua, ZHOU Qi, LIU Gang, LIU Zhiqiang, MEI Lin
2010,84(6):743-770, DOI:
Abstract:
To explore the interior structure and composition of the Earth, the habitat of our humankind, constitutes the ambition and pursuit of geologists and geophysicists for long. This article presents the research outlines and some results of major international deep probe programs worldwide since the 1970s, including the Consortium for Continental Reflection Profiling (COCORP) and EarthScope (USA), EUROPROBE (Europe), DEKORP (Germany), the British Institutions Reflection Profiling Syndicate (BIRPS), CROP (Italy), NRP20 (Switzerland), LITHOPROBE (Canada), AGCRC, Glass-Earth and AuScope (Australia), and so on. Based on the briefly retrospection of the historic deep exploration in China, the recently launched National Scientific Program of China titled as "Deep Exploration Technology and Experimentation" (ab. as SinoProbe) is introduced briefly, including its objectives and work plan of standard magnetotellurics observational and geochemical grid networks, integrated deep exploration experiments in North and South China regions, four corridor geophysical and geochemical explorations, and multiple integrated exploration sites. It is prospected that the deep exploration into the deep interior beneath the Chinese continent has its bright future.
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zhaowenguang, WU Ming'an, ZHANG Yiyong, WANG Keyou, FAN Yu, WANG Longyun, WEI Guohui, CHE Yingdan
2011,85(5):789-801, DOI:
Abstract:
The Nihe iron deposit, adjacect to the Tanlu fault, is located in the northwest margin of the Luzong Mesozoic volcanic basin, and is only three kilometers away from the Luohe iron deposit in the southwest. The Nihe iron deposit is a concealed deposit with multi-mineral resources, consisting of one large-scale magnetite ore deposit, one large-scale magnetite-pyrite ore deposit and one medium-scale anhydrite ore deposit. The magnetite ore bodies are situated in the south-west of the deposit, and are layer like or lenticular, occurring in the top of the intrusive dome that caused by the emplacement of pyroxene diorite-porphyrite in the Zhuanqiao formation during late Jurassic. The magnetite-pyrite ore bodies are situated in the north-east of the deposit, with two different occurrences, either in the pyroxene diorite-porphyrite body formed coevally with iron ore body, or in the volcanic rocks of the lower segment of the Zhuanqiao formation relating to strata. The anhydrite ore bodies are situated in the middle of the deposit, occurring as lens in the volcanic rocks of the lower segment of the Zhuanqiao formation. Ore types are so complex that the magnetite ore can be divided into eight natural types, while the magnetite-pyrite ore with five natural types. There are more than 40 minerals in the deposit, and the iron is rich in sulfur and phosphorus, but for the useful ore compositions of Fe, S and anhydrite, there are also other beneficial or harmful compositions in the ore, such as P, V, Ti, Cu, Zn, and so on. Within the Nihe iron deposit, there are intense alterations of the host rocks, and the alterations are widespread and variable, with obvious regularity such as transverse stratification and vertical zonality. In which, the anhydrite pyroxenitization is the most important alteration near the ore. The deposit type is similar to the Taocun-type in Nanjing-Wuhu district, and thus the genesis belongs to porphyrite-type.
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XU Zhiqin, YANG Jingsui, JI Shaocheng, ZHANG Zeming, LI Haibing, LIU Fulai, ZHANG Jianxin, WU Cailai, LI Zhonghai, LIANG Fenghua
2010,84(1):1-29, DOI:
Abstract:
The Chinese continent, which is strongly constrained by the Tethyan, Paleo Asian and Pacific tectonic systems, is characterized by a complex tectonic framework and a particular lithospheric structure. Based on the theory of continental tectonics and dynamics, here we provide a comprehensive overview of recent research results with a particular attention to four important scientific problems on the Chinese (East Asian) continent. ①Tectonics of the mantle beneath the Chinese continental lithospheric plate. Seismic tomographic profiling reveals that the western Pacific slab is subducted westward to depths of 400~600km beneath the East Asian continent, and the subducted slab becomes subhorizontal and listric shaped in the mantle transitional zone. The Indian slab is subducted northward to a depth of ~800km far north under the Banggonghu Nujiang sutute zong between the the Lhasa and Qiangtang terrains. Double subductions are asymmetrical beneath the western syntaxis of the Himalayan belt. In the eastern syntaxis, however, the Indian slab is subducted eastward to depths of 300~500km beneath the Burma Sanjiang terrain. ②Reactivation of the Chinese continent's metamorphic basements. Most blocks of the Chinese continent have not been reactived by significant tectonic, metamorphic or igneous events since the Phanerozoic. The north Indian and Arabian blocks (northern edge of Gondwana) were shaped by pan African orogenic belts at 530 470 Ma. This tectonic field occurred mainly in the higher Himalaya, Lhasa terrain and Sanjiang terrain. The Cenozoic metamorphic reactivation appeared ubiquitously and uniquely in the Himalaya, Namche Barwa, Lhasa terrain and Burma Sanjiang terrain with the youngest metamorphic ages of 2~1 Ma. ③The tectonic backgrounds and processes for the formation and exhumation of HP UHP metamorphic belts in China. The eclogite bearing HP UHP metamorphic belts in China formed in either oceanic or continental deep subduction zones. Most of the oceanic HP UHP belts in the Tibetan plateau are related to the collisions of multiple small oceanic basins among multiple micro continental blocks. Two mechanisms of the continental deep subduction are plausible: subduction drived by interblock shear collision and subduction of wedge shaped, teared lithospheric slabs. ④Three categories of mechanisms for the extrusion of deep materials within the Chinese continental orogenic belts: constrictional extrusion; lateral extrusion; and transcompressional extrusion.
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chenwen, WAN Yusheng, LI Huaqin, ZHANG Zongqin,DAI Tongmo, SHI Zeen, SUN Jingbo
2011,85(11):1917-1947, DOI:
Abstract:
Isotope geochronology is a newly developed science which combines geoscience, Physics, Chemistry and technical sciences, and it is a young and energetic branch of the earth system science. Based on the decay of radioactive isotopes, this science can determine the formation age of geological body and the age of geological events, aiming to study the formation history and evolution of earth and planetary materials. This paper presents brief introduction and summary of relative high-precise isotope dating methods in aspects of theory、experiment techniques、application scope、precautions for use, expecting to provide a useful reference to geologist. Involved isotope dating methods are U-Pb method、Ar-Ar method、 Rb-Sr method、Sm-Nd method、Re-Os method and(U-Th)/He method. (1)U-Pb method: It is one of the earliest radioactive methods for geological age determination as well as the most important isotope dating method in China so far. In the past 10 years, the introduction of insitu zircon U-Pb dating technique has played a significant role in promoting geological research in China, and its application is expanding. (2)Ar-Ar method: Ar-Ar dating has become one of the most important methods of isotope geochronology. The characteristics of this method are as follows: ① wide time-domain measurements, the oldest age is 3.8Ga (the age of lunar rocks), millennium age can be measured for the youngest age (eruption age of Mount Vesuvius, Italy); ② wide range of measurement object, in principle, all the k-bearing minerals and rocks can be used as Ar-Ar isotopic dating, even there are reports on successful determination of Ar-Ar ages from non-potassium minerals such as quartz、sphalerite which contain trace amounts of kainitite inclusion; ③Unique step heating technique and the management of Ar isotope correlation diagram of internal components can not only obtain high-precision age but unfold multi-stage geological evolution of the object; ④Joining with laser technique, it can be used to determine microzonation Ar-Ar age by search the minerals to be tested in polished section, so that we can obtain the priciest time information of the metamorphic rock P-T-t research; ⑤ wide application area, it is used in almost all the branches of geology; ⑥ the most important technique of deposit chronology; ⑦ the backbone technique of isotope thermochronology. Ar-Ar dating has its limitations: Firstly, the complex analysis leads to high cost and long cycle. Secondly, the accuracy of the determination of the neutron parameters directly affects the accuracy of dating samples. Nuclear recoil effect can result in high Ar-Ar age of very fine particles of clay minerals. As samples of Early Proterozoic and Archean metamorphic rocks, there may be natural K and Ar diffusion or later metamorphism, deformation and other disturbance, which will make it difficult for us to determine the age of early metamorphic events. (3)Rb-Sr method: It is a broadly applicated method. We can determine the isotope geological ages of intrusive rocks、volcanic rocks、metamorphic rocks and certain sedimentary rocks by using isochron technique. When determining the age of intermediate and acid intrusive rocks and volcanic rocks by using Rb-Sr isotopic system, if the rocks cooled rapidly, both the whole rock isochron and mineral isochron age may be the formation ages of the rocks. For metamorphic rocks, Rb-Sr isochron age generally represent the Sr isotope homogenization time when the latest strong thermal event happened. For sedimentary rocks, we can determine the authigenic mineral diagenesis age using Rb-Sr dating. The metal deposits, we can determine the formation ages of deposits using inclusion Rb-Sr isochron. Through Rb-Sr mineral dating to determine the formation of faults and ductile shear zone, we can limit the tectonic formation time. The biggest drawback of Rb-Sr dating is that, we may get wrong age due to the mobility of Rb which will result in an open system. In addition, we often face false isochrons problems. (4)Sm-Nd method: For Sm-Nd system is good at preservation and alteration and metamorphism resistance, ages from Sm-Nd dating can represent the original time when primary rocks formed and reflect the characteristics of diagenesis source material. For basic rocks、 ultrabasic rocks and for ancient rocks of Archean, Sm-Nd isochron dating method is a good method. Sm-Nd model age represent the time when the crustal rocks differentiated from CHUR mantle, using model ages of clastic sedimentary rocks, we can identify the source, the background of tectonic, the mean crustal residence age, and the formation and evolution history of crust. The disadvantage is the similarity of Sm, Nd geochemical properties, it will be difficult to separate from each other in the geologic process, and will result in narrow range of Sm, Nd ratio, which will make the Sm-Nd isochron dating problematic and even can not give reliable age. (5) Re-Os method: Re-Os isotope dating is the only mature method to determine mineralization ages of metal deposits directly. However, there are many problems in experiment techniques and applications: ① In recent years, some scientists find that the Re-Os ages of molybdenite in some metal deposits were higher than the ages of ore-bearing rocks, the reasons are unclear; ② the amount of Re in most sulfide mineral including pyrite is significantly low, and contains certain amount of common Os, this requires very low background in the process of chemical preparation of samples, which makes it difficult for general laboratory to achieve, and the common Os is difficult to deduct; ③ sometimes, post hydrothermal activities may reset Os isotope, therefore, the closure temperature and influencting factors of the metal sulfide Re-Os isotope system is a pressing problem to be solved. (6) (U-Th) / He method: The advantage of (U-Th) / He isotope system is that its closure temperature is the lowest among the existing isotopic systems, and it can record temperature information and the time when geologic body went through a lower temperature process. The method also has considerable application in the deposits chronology. The disadvantage is that as the closure temperature is very low, we should pay special attention to the cooling rate and effects of re-heating in geological dating.
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DONG Shuwen, ZHANG Yueqiao, LONG Changxiang, YANG Zhenyu, JI Qiang, WANG Tao, HU Jianmin, CHEN Xuanhua 1) Institute of Geomechanics , CAGS, Beijing , 100081 ; 2) Department of Earth Science, Nanjing University, Nanjing9 210093~ 3) Institute of Geology,
2007,81(11):1449-1461, DOI:
Abstract:
随着一系列新构造观察资料和高精度同位素测年数据的累积,加深了对发生在中国东部晚侏罗世—早白垩世时期构造变革事件的认识,对燕山运动的性质、时限和动力学内涵有了新的诠释。中—晚侏罗世初期(165±5Ma)东亚多板块拼贴运动学发生重大调整,构造体制发生重大转换,启动了以中朝地块为中心、来自北、东、南西不同板块向东亚大陆"多向汇聚"的构造新体制,形成以陆内俯冲和陆内造山为特征的东亚汇聚构造体系。同时大陆地壳岩石圈发生显著增厚,并紧随早白垩世以剧烈的大陆岩石圈伸展和火山—岩浆活动为特征的岩石圈巨量减薄和克拉通破坏,导致燕辽生物群灭绝和热河生物群兴盛的重大生物群更替,成为中国大陆和东亚重大构造变革事件,这是燕山运动的基本内涵。本文依据燕山运动构造变形型式、动力学背景以及产生的深部过程,将"燕山运动"定义为起始于165±5Ma的"东亚多向汇聚"构造体制及其形成的广泛陆内造山和构造变革,并将中国东部岩石圈巨量减薄视作燕山期陆内造山和陆内变形的后效。
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Ying Lijuan, Wang Denghong, Tang Juxing, Chang Zhesheng, Qu Wenjun
2010,84(8):1165-1174, DOI:
Abstract:
Molybdenite widely spreads in the different types of ores from the Jiama copper polymetallic deposit. Skarn is the major host rock, then hornfel is the secondary, and porphyry, marble and limestone contain few molybdenite. Molybdenite samples with different occurrences from skarn, hornfel and porphyry were collected and tested by Re-Os isotopic dating. Mode age of 27 samples changed between 14.2 and 17.5 Ma and the isochron age was 15.22±0.59 Ma. The isochron ages of porphyry and hornfel were 14.78±0.33 Ma and 14.67±0.19 Ma, which were consistent to metallogenic period of other porphyry copper deposits in the Gangdese metallogenic belt. The 187Re content in molybdenite was correspondingly higher in the range of 38.75~387.4 g/g. Molybdenite in the Jiama ore deposit was supposed to form in one period occurring in the different rocks. It was in the Langhian Stage of Miocene with the feature of postcollision. The metallogenic period of the Jiama ore deposit was close to that of molybdenite, therefore the previous overview of effusive sedimentary metallogeny was not scientific.
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2010,84(12):1727-1734, DOI:
Abstract:
Based upon the fine interpretations of 3D seismic in Tazhong low uplift, four series of fault systems are classified: (1)Cambrian-early Ordovician tensional fault systems whose distribution, configuration and development scales establish the foundation of the consequent structural activities; (2)late Ordovician thrust fault systems and northwestward slip fault systems whose structural characteristics vary in different zones and fragments: thrust fault system develops in the east, and northwestward slip fault system develops in the middle-west; (3)Silurian-Devonian northeastward slip fault systems formed in extrusion stress background and spread northeastward, which are made up of three parts: the main faults, the tailed en-echelon structures and the fault troughs; (4) the fault system related to Permian magmatic pierces, which distributes spottily or in bands, and are mostly developed along earlier faults and always superimpose or reform earlier faults. In plane, the Tazhong Paleozoic fault systems are a tensional-shear broom-like structure with sinistral internal rotation layers pointing to the divergent termination.
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2014,88(9):1623-1637, DOI:
Abstract:
The lower boundary age of Mesoproterozoic is positioned at 1600 Ma by International Commission on Stratigraphy (ICS), and the global platform covers are formed at Calymmian with time span of 1600 Ma to 1400 Ma. The North China Platform entered an epoch of extension-broken after its consolidated at 1800 Ma. Then the Luliang Mountains area in Shanxi Province, the Zhongtiao Mountains in South Shanxi Province and the Xiong’ershan area in Western Henan Province are split into a trigeminal Aulacogen. The SHRIMP and LA-ICP-MS zircon ages of the volcanic rocks from Luliang Xiaoliangling Formation are 1763±42 Ma and 1779±20 Ma respectively; and the SHRIMP zircon ages have been obtained from Xiong’er Group in Western Hennan Province are 1776±20 Ma (dated for the volcanic rocks) and 1779±29 Ma. It seems reasonable to take the 1800 Ma as the lower boundary age of the Xiaoliangling Formation and Xiong’er Group. The rocks of Hangaoshan Group of Luliang Mountains area are siliciclastic with volcanic rocks, deposited at the same time with Xiaoliangling Formation, which suggest the quick filling of the north part of Luliang-Shanxi-Henan trigeminal Aulacogen. The Hangaoshan Group and the Dagushi Formation (sedimentary rocks deposited at the bottom of Xiong’er Group) are the sediment covers after the rifting at 1800 Ma, the mafic dykes related to the volcanic rocks from Xiaoliangling Formation and the volcanic rocks from the Xiong’er Group are the products of magmatism in the stage of broken-up. The Miyun rapakivi granites from Beijing are emplaced at 1700 Ma, which indicate the start time of the broken up of the Yanshan-Taihangshan Aulacogen and the lower boundary age of Changzhougou Formation, Changcheng System. The weathering crust, overlap the Miyun rapakivi granites, is dated at 1650 Ma, represents the time began to accept the deposits after the rifting of Aulacogen. It is not the age of the lowest layer in Changzhougou Formation. The age 1700 Ma and 1650 Ma are the lower boundary ages of different areas in Changzhougou Formation. but it’s not equal to the lower boundary age of Changcheng System or Mesoproterozoic. The lower boundary age of the Gaoyuzhuang Formation is 1600 Ma, as the boundary age of Changcheng System and Jixian System. It is not only the close time of Yanshan-Taihangshan Aulacogen, but also the end of the extension-broken time of North China Platform from 1800 Ma. The new epicontinental basin began to develop at this time, and the North China Platform experienced tectonic transformation. Therefore, the significant tectonic events affected North China Platform at 1800 Ma and 1600 Ma, which reflect great regional tectonic implications. According to the determination principle of Pre-cambiran boundary age, both the two ages are used to be the lower boundary of Mesoproterozoic. But in this paper, we approve of 1800 Ma as the lower boundary age of Mesoproterozoic, because of it’s more in line with the Chinese tectonic: 1800 Ma is the lower boundary age of the platform covers from the North China Platform to intra-craton Aulacogen. There are different tectonic settings of the basins in the North China Craton at Mesoproterozoic at different times: it is Aulacogen at 1800~1600 Ma, then develop to epicontinental sea at 1600~1400 Ma, at last transfer to arc-back basin at 1400~1300 Ma; 1800 Ma、1600 Ma and 1400 Ma are three time points of regional tectonic transformation at Mesoproterozoic.
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SUN Jiming, MA Zhongping, TANG Zhuo, LI Xiangmin
2012,86(2):247-257, DOI:
Abstract:
Yumuquan granitoid complex, located in the south margin of Altyn Tagh, northwestern China, contain many of melanocratic magmatic enclaves (MME), and its petrology and geochemical characteristics indicating the mixing between acid magma and more mafic magma in liquid phase, which belong to the corresponding period. The LA-ICP-MS zircon U-Pb isotopic dating show that the age of Yumuquan granite is 496.9±1.9Ma (MSWD=0.68), corresponding with the ages of ultrahigh-pressure metamorphic rocks (509~487 Ma )exposed at south Altyn Tagh.and the geochemical characteristics of the granitoid show high Al2O3(ave.15.88%), K2O/Na2O ratios (avg. 1.26),Sr(ave.446×10-6),(La/Yb)N ratios(24.04)and Sr/Y ratios(avg. 40),and very lower Y(avg. 14.0 ×10-6)and Yb(avg. 1.5×10-6), similar to high Sr and lowerY(Yb) type potash granite derived from thickened lower crust , So, The southern Altyn orogen belong to continental collision orogeny during ~500Ma, this collision rifting made the crust thickened and overlay each other. We consider that, the crustal thickening at Later Cambrain (~500Ma) in the area of south Altyn Tagh caused the lower crust part melt and product acid magma, at the same time, there are under plating of mantle-derived mafic magmas, The reason may be related to the rise of the deep hot mantle, which caused by the same period of continental deep subduction.
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ZOU Caineng, YANG Zhi, ZHU Rukai, ZHANG Guosheng, HOU Lianhua, WU Songtao, TAO Shizhen, YUAN Xuanjun, DONG Dazhong, WANG Yuman, WANG Lan, HUANG Jinliang, WANG Shufang
2015,89(6):979-1007, DOI:
Abstract:
The new century has witnessed a strategic breakthrough in unconventional oil & gas. Hydrocarbon accumulated in micro /nano scale pore throat shale systems has become an important domain that could replace current oil & gas resources. Unconventional oil & gas plays an increasingly important role in our energy mix. Tight gas, CBM, heavy oil and asphaltic sand have served as a key domain of exploration & development, with tight oil becoming a 'bright spot' domain and shale gas becoming a 'hotspot' domain. China has made great breakthroughs in unconventional oil & gas resources, such as tight gas, shale gas, tight oil and CBM, and great progress in oil shale, gas hydrate, heavy oil and oil sand. China has an estimated (223~263)×108 t of unconventional oil resources and (890~1260)×1012 m3 of gas resources. China has made a breakthrough for progress in unconventional oil & gas study. New progress achieved in fine grained sedimentary studies related to continental open lacustrine basin large scale shallow water delta sand bodies, lacustrine basin central sandy clastic flow sediments and marine continental fine grained sediments provide a theoretical basis for the formation and distribution of basin central reservoir bodies. Great breakthroughs have been made in unconventional reservoir geology in respect of research methodology & technology, multi scale data merging and physical simulation of formation conditions. Overall characterization of unconventional reservoirs via multi method and multi scale becomes increasingly popular and facilitates the rapid development of unconventional oil & gas geological theory, method and technology. The formation of innovative, continuous hydrocarbon accumulation theory, the establishment of the framework of the unconventional oil & gas geological theory system, and the determination of the implications, geological feature, formation mechanism, distribution rule and core technology of unconventional oil & gas geological study lays a theoretical foundation for extensive unconventional oil & gas exploration and development. Theories and technologies of unconventional oil & gas exploration and development developed rapidly, including some key evaluation techniques such as 'sweet spot zone' integrated evaluation and a six property evaluation technique that uses hydrocarbon source, lithology, physical property, brittleness, hydrocarbon potential and stress anisotropy, and some key development & engineering technologies including micro seismic monitoring, horizontal drilling & completion and "factory like" operation pattern, "man made reservoir" development, which have facilitated the innovative development of unconventional oil & gas. These breakthroughs define a new understanding in four aspects: ①theoretical innovation; ② key technologies; ③ complete market mechanism and national policy support; and ④ well developed ground infrastructure, which are significant for prolonging the life cycle of petroleum industry, accelerating the upgrade and development of theories and technologies and altering the global traditional energy structure.
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2010,84(2):171-182, DOI:
Abstract:
Through the east and west orogenic geological cross-section observation sides of Junggar Basin, the system fission track dating and thermal analysis of the evolution of simulation results, combined with previous research findings, the Junggar Basin in the peripheral orogenic belt, mainly through the late Mesozoic tectono-thermal event. Through fission-track analysis and comparison,Orogenic belts on both sides of the Junggar Basin has a different Uplift history.The northwestern margin of the Junggar basin as early as in the eastern part of the uplift, the uplift rate is greater than the eastern part of. Northwestern margin of Junggar Basin has experienced since the Cretaceous period from the edge of the Junggar Basin to the Zaire mountain uplift events followed one after another, indicating that the northwestern margin of the Junggar thrust fault system thrust to the internal basin by overstep propagation. Junggar Basin, east-west belt of rocks on both sides of fission track data are a reflection of the cooling since the Cretaceous uplift events, and fully confirmed by the late Yanshan tectonic movement prevalent in the Junggar region, which provide vital evidence for a detailed study Yanshanian intracontinental tectonic activities in northern Xinjiang.
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Tong Hengmao, Zhao Baoyin, Cao Zhe, Liu Guoxi, Dun Xiaomei, Zhao Dan
2013,87(11):1647-1661, DOI:
Abstract:
On the basis of structural analysis of 3D seismic data in Nanpu sag, applying faulting model with pre-existing weaknesses, combining with sand modeling results, the fault system and structural styles in Nanpu sag were systematically analyzed. The results show that, the structural style is typical oblique extension. The complicated “Y” shaped style , which is jointly controlled by listric (or ramp-flat) boundary normal faults and pre-existing faults, is the basic structural style in Nanpu sag, followed by complicated “X” shaped, “domino”, “Ladder” and “imbricate faulted blocks” structural styles. 4 fault systems are divided in the plane, that are Beipu-Laoyemiao fault system, Gaoliu fault system, Baigezhuang fault system and Nanpu fault system. Among them, Gaoliu fault system and Nanpu fault system can be further divided into 2 and 3 sub-fault systems respectively. While, it can be divided into two fault systems vertically: lower fault system (E2s3 tectonic layer) and upper fault system (E2s1-Q layers). There are four kinds of fault assemblages: “parallel-like”, “parallel intertwined” “comb-like” and “broom-like”. Cenozoic structural deformation of Nanpu sag can be reasonably explained with two-phases extension model: structural deformation of E2s3 era is caused by NW-SE direction extension with Mesozoic pre-existing weaknesses, while structural deformation since E2s1 is caused by north-south direction extension with pre-existing faults formed in E2s3 era, and E2s2 era is stress transition phase. There are significant segmentations in the sag boundary faults (Xinanzhuang Fault, Baigezhuang Fault and Gaoliu Fault), the strike, properties, activation of different segments showed a significant difference, and significant changes occurred in the different stages of the tectonic evolution. The tectonic framework by the sag boundary faults, Nanpu Fault and Gatou Fault in sag played an important controlling role on the fault formation and evolution of Nanpu sag. The complicated pre-existing faults were the root causes of lateral variation of fault system.


