喜马拉雅东段库曲锂辉石伟晶岩铌钽矿物特征及指示意义
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本文为第二次青藏高原综合科学考察研究项目(编号2019QZKK0802,2019QZKK0806)、国家重点研发计划青年科学家项目(编号2023YFC2908400)和国家自然科学基金项目(编号42272101)联合资助的成果


The feature of Nb- Ta- bearing minerals in the spodumene- bearing pegmatite dykes in Kuqu, eastern Himalaya, and its significance
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    摘要:

    铌钽矿物是花岗伟晶岩中重要的稀有金属矿物,记录了伟晶岩岩浆分异演化过程。喜马拉雅中段和东段新近取得伟晶岩型锂矿重要找矿发现。本文针对东段库曲岩体中三处含锂辉石伟晶岩脉和白云母花岗岩产出的铌钽矿物(铌铁矿族矿物和细晶石)进行内部结构和化学组成研究。含锂辉石伟晶岩脉中的铌铁矿族矿物(CGM)为铌锰矿- 钽锰矿,产出均一、核- 边、补丁、不规则分带、振荡环带和复合结构,分为三个形成世代(CGM- I、CGM- II、CGM- III),由CGM- I至CGM- II,铌铁矿族矿物向富Ta、Fe和略贫Y方向演化,体系经历了含Nb、Mn和Y矿物的结晶分异作用,形成了富Ta和Fe的富挥发分熔体或流体,由CGM- II至CGM- III,铌铁矿族矿物Ta/(Nb+Ta)和Mn/(Fe+Mn)值变化不一,反映了复杂的矿物- 流体相互作用。含锂辉石伟晶岩脉和白云母花岗岩中的细晶石产出均一、核- 边和不规则分带结构,分别揭示了富Ta和Ca流体作用、边界层效应或富Nb流体交代、以及动荡结晶环境下流体扰动。细晶石的TiO2、UO2、F含量以及Ta/(Nb+Ta)值可作为岩浆分异演化程度的潜在指示标志,但需考虑晚期热液流体对细晶石化学组成的影响。铌钽矿物研究揭示了库曲不同含锂辉石伟晶岩脉的岩浆特征与分异演化过程。1号含锂辉石伟晶岩脉岩浆相对富Fe,依次经历了含Fe矿物、含Nb和含Mn矿物、以及含Ta和含Mn矿物的结晶作用,局部伴随边界层效应或含Fe矿物结晶,晚期存在富Ta和Ca流体活动,并受边界层效应影响。2号含锂辉石伟晶岩脉岩浆就位后首先经历了含Nb和含Fe矿物结晶,之后经历了含Mn和含Y矿物结晶以及含Nb和含Ta矿物结晶耦合作用,晚期发育富Ta和Ca流体活动,随后发生富Nb流体作用。3号含锂辉石伟晶岩脉岩浆相对富挥发分,就位后经历了含Nb、Mn和Y矿物的结晶作用,以及复杂的矿物- 液相介质相互作用,体系晚期存在富Ta和Ca流体活动。库曲含锂辉石伟晶岩脉经历了熔体、富稀有金属和挥发分熔体至复杂流体(富Ta和Ca流体和富Nb流体等)的演化过程。铌钽矿物的内部结构分带和化学组成特征揭示了库曲岩体中淡色花岗岩和伟晶岩脉经历的岩浆分异演化过程以及晚期复杂的流体活动。

    Abstract:

    The Nb- Ta- bearing minerals are important rare- element minerals in granitic pegmatite and record the magma evolution process. Significant progress has been made in exploring lithium deposits in the middle and eastern regions of the Himalayas, China. This study focuses on examining the internal structures and chemical compositions of Nb- Ta- bearing minerals, namely columbite- group minerals (CGM) and microlite, from three spodumene- bearing pegmatite dykes and muscovite granite in the Kuqu pluton. The CGM samples obtained from the spodumene- bearing pegmatite dykes are columbite- (Mn) to tantalite- (Mn) with homogeneous, core- rim, patchy, irregular, oscillatory, and complex structures. These CGM samples can be categorized into three generations: CGM- Ⅰ, CGM- Ⅱ, and CGM- Ⅲ. The transition from CGM- Ⅰ to CGM- Ⅱ shows an enrichment of Ta and Fe in columbite- Mn, coupled with a depletion of Y. This evolution suggests that CGM- Ⅱ crystals were crystallized from a Ta- and Fe- rich fluxed melt or fluid, subsequent to the crystallization of Nb- , Mn- , and Y- bearing minerals. The evolution from CGM- Ⅱ to CGM- Ⅲ does not exhibit consistent trends in Ta/(Nb+Ta) and Mn/(Fe+Mn) values, reflecting complex interactions between minerals and fluids. Microlite samples from both spodumene- bearing pegmatite dykes and muscovite granite display a variety of internal structures, including homogeneous, core- rim, and irregular- zoned crystals. These variations suggest the influence of a Ta- Ca- rich fluid activity, a boundary effect or Nb- rich fluid activity, and fluid disturbances in an unstable crystallization environment. The chemical composition of microlite, specifically the TiO2, UO2, F contents, as well as Ta/(Nb+Ta) value, may serve as potential indicators for magma evolution. However, late fluid activity that could change the chemical composition of microlite should be considered. The study of Nb- Ta- bearing minerals provides valuable insights into the magma features and evolution processes of the three spodumene- bearing pegmatite dykes in the Kuqu intrusion. The first spodumene- bearing pegmatite magma (No.1) is relatively enriched in Fe and underwent successive crystallization of Fe- bearing minerals, followed by Nb- and Mn- bearing minerals, and finally Ta- and Mn- bearing minerals, with a late Ta- and Ca- rich fluid activity that is influenced by the boundary effect. The second spodumene- bearing pegmatite (No.2) experienced the crystallization of Nb- and Fe- bearing minerals, followed by Mn- and Y- bearing mineral crystallization, and a buffer of Nb- and Ta- bearing mineral crystallization. In the late stage of its evolution, there was evidence of Nb- rich hydrothermal metasomatism following a Ta- and Ca- rich fluid activity. The third spodumene- bearing pegmatite magma (No3) is relatively enriched in fluxes and underwent crystallization of Nb- , Mn- , and Y- bearing minerals, coupled with complex interactions between minerals and the liquid medium. Late- stage Ta- and Ca- rich fluid activity was also observed. The Kuqu spodumene- bearing pegmatites experienced an evolution from a melt to a rare- metal- rich and fluxed melt, and finally to complex fluids, including a Ta- Ca- rich fluid and a late- stage Nb- rich fluid. The occurrence, internal structure, and chemical composition of Nb- Ta- bearing minerals provide valuable insights into the evolution processes, particularly the late- stage fluid activities of the granites and pegmatite dykes in the Kuqu intrusion.

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周起凤,秦克章,何畅通,刘宇超,施睿哲,赵俊兴,陈彤,莫凌超.2024.喜马拉雅东段库曲锂辉石伟晶岩铌钽矿物特征及指示意义[J].地质学报,98(5):1473-1488.
ZHOU Qifeng, QIN Kezhang, HE Changtong, LIU Yuchao, SHI Ruizhe, ZHAO Junxing, CHEN Tong, MO Lingchao.2024. The feature of Nb- Ta- bearing minerals in the spodumene- bearing pegmatite dykes in Kuqu, eastern Himalaya, and its significance[J]. Acta Geologica Sinica,98(5):1473-1488.

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  • 收稿日期:2024-01-16
  • 最后修改日期:2024-03-24
  • 录用日期:2024-03-24
  • 在线发布日期: 2024-04-15