西藏结则茶卡超大型盐湖锂矿流域水化学特征及其盐类资源的形成研究
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1.中国地质科学院矿产资源研究所 2.自然资源部盐湖与环境重点实验室

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Study on hydrochemical characteristics and formation of salt resources in lithium basin of Jiezechaka super large salt Lake, Xizang
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Institute of Mineral Resources,China Academy of Geological Sciences,Key Laboratory of Saline Lake Resources and Environment,Ministry of Natural Resources

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    摘要:

    结则茶卡盐湖位于西藏阿里地区日土县东汝乡,LiCl资源量230万t,B2O3资源量160万t,KCl资源量979万t,是西藏少数正在开发的锂矿之一。研究盐湖水及补给水的物质来源具有重要的找矿意义和科学价值,本文通过水文地球化学方法,对结则茶卡盐湖及补给水进行系统分析。共采集湖水、河水及泉水样品65件,测试其TDS、pH值及主要离子成分,通过Chadha水化学图、Piper阴阳离子三角图、Gibbs图等方法研究湖水、补给水的主要离子特征、控制机制及来源。研究表明,盐湖水化学类型为Na-CO3型,河水化学类型为Ca-Mg-HCO3、Na-HCO3型,泉水化学类型为Na-HCO3型。水化学离子组成主要受到岩石风化作用和蒸发-结晶作用影响,河水、泉水的Na+和K+主要源于岩盐等蒸发岩溶解,Ca2+、Mg2+主要源于硅酸盐岩溶解。Li、Rb、Cs等成矿物质来源于岩石风化和深部水岩反应。河边泉、东如泉及清水河年补给水量分别为160.16万m3、644.09万m3和9361.65万m3,河水补给占92.09%,河水Li、Rb、Cs年补给量约为3501.26kg、176kg、156.34kg,泉水Li、Rb、Cs年补给量约为6824.18kg、288.87kg、691.59kg,主要为泉水补给,分别占66%、62%和82%。结则茶卡泥田、膜田面积约10.40km2,在经过提锂、钾后,卤水中铷铯浓度逐渐富集,达到扎布耶盐湖规范的铷铯单独开采品位要求。结则茶卡盐湖水位上涨及面积扩大,2023年4月份结则茶卡盐湖面积已达到118.07km2,比1977年增加12.69km2,对盐湖生产已经产生一定影响,建议持续对湖水进行动态变化监测。

    Abstract:

    Located in Dongru Township, Ritu County, Ngari Prefecture, Tibet, Jieze Chaka Salt Lake has 2.3 million tons of LiCl resources, 1.6 million tons of B2O3 resources, and 9.79 million tons of KCl resources. It is one of the few lithium mines under development in Tibet. It is of great significance and scientific value to study the material source of the salt lake water and its recharge water. This paper systematically analyzes the Gezechaka salt Lake and its recharge water by means of hydrogeochemical methods. A total of 65 samples of lake water, river water and spring water were collected to test their TDS, pH value and main ion composition. The main ion characteristics, control mechanism and source of lake water and recharge water were studied by Chadha hydrochemical diagram, Piper Cationonic triangle diagram and Gibbs diagram. The results show that the chemical type of salt lake water is Na-CO3, the chemical type of river water is Ca-Mg-HCO3, Na-HCO3, and the chemical type of spring water is Na-HCO3. The composition of hydrochemical ions is mainly affected by rock weathering and evaporation-crystallization. Na+ and K+ of river water and spring water are mainly derived from evaporative karst decomposition such as rock salt, and Ca2+ and Mg2+ are mainly derived from the dissolution of silicate rock. Metallogenic materials such as Li, Rb and Cs come from rock weathering and deep water-rock reaction. The annual replenishment of Hebian Spring, Dongru Spring and Qingshui River is 1,601,600 m3, 6,440,900 m3 and 93,616,500 m3, respectively. River water replenishment accounts for 92.09%, and the annual replenishment of Li, Rb and Cs in river water is about 3501.26kg, 176kg and 156.34kg. The annual replenishment of Li, Rb and Cs in spring water is about 6824.18kg, 288.87kg and 691.59kg, which are mainly spring water replenishment, accounting for 66%, 62% and 82% respectively. Chaka mud fields and membrane fields with an area of about 10.40km2. After extraction of lithium and potassium, the concentration of rubidium cesium in the brine gradually enriched, reaching the requirement of separate mining grade of rubidium cesium in Zabye Salt Lake. The water level of Geze Chaka Salt Lake has risen and its area has expanded. In April 2023, the area of Geze Chaka Salt Lake has reached 118.07km2, an increase of 12.69km2 over 1977, which has had a certain impact on the production of the salt lake. It is recommended to continuously monitor the dynamic change of the lake water.

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  • 收稿日期:2023-08-02
  • 最后修改日期:2024-07-23
  • 录用日期:2024-08-02
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