西藏结则茶卡超大型盐湖锂矿流域水化学特征及其盐类资源的形成研究
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本文为科技部第二次青藏高原综合科学考察研究专题“青藏高原盐湖铷、铯资源现状与远景评估”(编号2022QZKK0201)和西藏国能矿业发展有限公司委托项目“西藏结则茶卡和龙木错盐湖资源动态变化与资源潜力研究”(编号HE2202)、“西藏结则茶卡和龙木错地下卤水与湖相沉积物中锂资源潜力研究”(编号HE2236)联合资助的成果


Study on hydrochemical characteristics and formation of salt resources in lithium mines of Jiezechaka super large salt lake, Xizang
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    摘要:

    结则茶卡盐湖位于西藏阿里地区日土县东汝乡,锂(LiCl)、硼(B2O3)达到大型矿床规模,钾(KCl)达到中型矿床规模,是西藏少数正在开发的锂矿之一。研究盐湖水及补给水的物质来源具有重要的找矿意义和科学价值,本文通过水文地球化学方法,对结则茶卡盐湖及补给水进行系统分析。共采集湖水、河水及泉水样品65件,测试其TDS、pH值及主要离子成分,通过Chadha水化学图、Piper阴阳离子三角图、Gibbs图等方法研究湖水、补给水的主要离子特征、控制机制及来源。研究表明,盐湖水化学类型为Na- CO3型,河水化学类型为Ca- Mg- HCO3、Na- HCO3型,泉水化学类型为Na- HCO3型。水化学离子组成主要受到岩石风化作用和蒸发- 结晶作用影响,河水、泉水的Na+和K+主要源于岩盐等蒸发岩溶解,Ca2+、Mg2+主要源于硅酸盐岩溶解。Li、Rb、Cs等成矿物质来源于岩石风化和深部水岩反应。河边泉、东如泉及清水河年补给水量分别为160. 16万m3、644. 09万m3和9361. 65万m3,河水补给占92. 09%,河水Li、Rb、Cs年补给量约为3501. 26 kg、176 kg、156. 34 kg,泉水Li、Rb、Cs年补给量约为6824. 18 kg、288. 87 kg、691. 59 kg,主要为泉水补给,分别占66%、62%和82%。结则茶卡泥田、膜田面积约10. 40 km2,在经过提锂、钾后,卤水中铷铯浓度逐渐富集,达到扎布耶盐湖规范的铷铯单独开采品位要求。结则茶卡盐湖水位上涨及面积扩大,2023年4月份结则茶卡盐湖面积已达到118. 07 km2,比1977年增加12. 69 km2,对盐湖生产已经产生一定影响,建议持续对湖水进行动态变化监测。

    Abstract:

    Located in Dongru Township, Ritu County, Ngari Prefecture, Xizang, the Jiezechaka Salt Lake contains substantial mineral resources, including 2. 3 million tons of LiCl, 1. 6 million tons of B2O3, and 9. 79 million tons of KCl. As one of the few lithium mines under development in Xizang, studying the material sources of the salt lake water and its recharge water holds significant scientific and practical importance. This paper systematically analyzes the hydrogeochemical characteristics of Jiezechaka Salt Lake and its recharge water sources. A total of 65 samples, comprising lake water, river water, and spring water were collected and analyzed for TDS, pH, and main ion composition. Using Chadha hydrochemical diagrams, Piper cation- anion ternary plots, and Gibbs diagrams, we investigated the main ion characteristics, controlling mechanisms, and material sources of the lake and recharge water. The results show that the salt lake water exhibit an Na- CO3 hydrochemical type, while river water is classified as Ca- Mg- HCO3 and Na- HCO3, and the hydrochemical type of spring water is Na- HCO3. The hydrochemical composition is mainly affected by rock weathering and evaporation- crystallization processes. In river and spring water, Na+ and K+ are mainly derived from evaporative karst decomposition such as rock salt, whereas Ca2+and Mg2+are mainly derived from the dissolution of silicate rock. Metallogenic elements such as Li, Rb and Cs are sourced from rock weathering and deep water- rock reactions. The annual recharge volumes of Hebian spring, Dongru Spring, and Qingshui River are 1601600, 6440900 and 93616500 m3, respectively, with river water accounting for 92. 09% of the total recharge. The annual replenishment of Li, Rb, and Cs in river water is about 3501. 26 kg, 176 kg and 156. 34 kg, respectively. The annual replenishment of Li, Rb and Cs in spring water is about 6824. 18 kg, 288. 87 kg and 691. 59 kg, respectively, representing 66%, 62% and 82% of the total recharge for these elements, respectively. The Chaka mud fields and membrane fields, covering an area of about 10. 40 km2, exhibit progressive enrichment of Rb and Cs in the brine following lithium and potassium extraction. This enrichment has reached concentrations sufficient for separate Rb and Cs mining, comparable to the industrial grade observed in Zabye Salt Lake. The water level of Jiezechaka Salt Lake has risen, and its area has expanded. By April 2023, the lake covered 118. 07 km2, making an increase of 12. 69 km2 since 1977. This expansion has implications for salt lake production, underscoring the need for continuous monitoring of lake water dynamics to assess long- term impacts.

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马殿哲,张智彦,赵元艺,郑绵平,陈文西.2025.西藏结则茶卡超大型盐湖锂矿流域水化学特征及其盐类资源的形成研究[J].地质学报,99(8):2827-2840.
MA Dianzhe, ZHANG Zhiyan, ZHAO Yuanyi, ZHENG Mianping, CHEN Wenxi.2025. Study on hydrochemical characteristics and formation of salt resources in lithium mines of Jiezechaka super large salt lake, Xizang[J]. Acta Geologica Sinica,99(8):2827-2840.

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  • 收稿日期:2023-08-02
  • 最后修改日期:2024-07-23
  • 录用日期:2024-08-02
  • 在线发布日期: 2025-07-07
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