德兴铜矿区主要流域内环境介质中重金属含量特征与健康风险评价
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The Characteristics of Heavy metals Content and Health Risk Assessment in Different Environment Media from Dexing Copper mining area
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    摘要:

    德兴铜矿位于江西省东北部,是我国重要的有色金属生产基地,同时也导致发生了一些矿山环境问题。本文系统分析了矿区附近的大坞河、浮溪河和乐安河(德兴段)流域重金属在一级阶地(T1)和二级阶地(T2)环境介质(土壤-底泥-粮食-蔬菜)中的含量特征,并对土壤和农作物中重金属对成人和儿童的健康风险进行了评价,揭示矿业活动对周边环境和人体健康的影响。结果表明,三个流域土壤重金属平均含量均高于背景值,其中Cu累积最为明显,大坞河土壤样品中Cu超过国家Ⅱ级土壤标准的超标率达86.8%,此外Cu、As和Hg在大坞河T1上平均含量明显较T2上的高。与背景值相比,大坞河和浮溪河底泥重金属中Cu超过的倍数是最大的,土壤与底泥中Cu、As和Hg以及pH值呈现显著的正相关关系。稻米中重金属平均含量仅有Cu超过了国家粮食卫生标准,超标率最大为41.8%,稻米对Cd的富集明显高于其它重金属。小白菜重金属中Cd污染最为严重,超过国家蔬菜卫生标准的9~14倍,且富集系数在2~4。健康风险评价结果表明,土壤和农作物(稻米和小白菜)中重金属对人体非致癌风险总和在12.10 ~ 19.80,为不可接受风险,而致癌风险在10-3水平,大于USEPA推荐的最大接受水平10-4,因此研究区居民有极大的致癌风险。不同流域健康风险在一级和二级阶地上的分布特征存在差异,大坞河和浮溪河非致癌和致癌风险T1上比在T2上大,但乐安河(德兴段)相反,因此在不同河流阶地上种植农作物也应有差别。

    Abstract:

    Dexing copper mine is located in the northeast of Jiangxi province, which is important production base of nonferrous metal in China, also cause some mine environment question. This paper analysed characteristics of heavy metals content in environment medium (soil ,bottom mud, food ,vegetable) of the primary (T1) and the second terrace (T2),which is at Dawu river ,Fuxi river and Lean river (dexing section) of the mining area. Meanwhile, evaluating the heavy metals health risk in soils and crops for adults and children,to reveal the influence of mining activities on the surrounding environment and human health. Results show that the average content of heavy metals in soil are higher than background values, especially Cu . Copper content in soil of Dawu river reaches 86.8% than the national standard of the grade Ⅱ, average content of Cu, As and Hg is higher in T1 than T2.Contrasting to background value, Cu is the biggest multiples of all heavy metal in bottom mud of Dawu river and Fuxi river. Cu,As,Hg and pH has significantly positive correlation between soil and bottom mud. Only average content of Cu in rice exceeded the national food hygiene standards, which the maximum is 41.8%, the enrichment of Cd in rice was obviously higher than other heavy metals. Cd pollution in cabbage is the most serious, more than national vegetables hygienic standards for 9 ~ 14 times, and the enrichment coefficient at 2 ~ 4. Health risk assessment results show that the sum of cancer risk at 12.10 ~ 19.80 of heavy metals in soils and crops (rice and cabbage) on the human body, which is unacceptable risk. The risk of cancer at 10-3 levels is greater than the biggest accept level (10-4) that USEPA recommends. Thus, residents have great risk of cancer in the study area. The distribution of health risk of different valley has differences on the primary and secondary terrace. Not carcinogenic and cancer risk of Dawu river and Fuxi river is higer on T1than T2, but Lean river (Dexing section) on the contrary. Therefore, the cultivation of crops should also have the difference in different river terraces

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常玉虎,赵元艺,曹冲,单云,曹强.2015.德兴铜矿区主要流域内环境介质中重金属含量特征与健康风险评价[J].地质学报,89(5):889-908.
Changyuhu, zhaoyuanyi,曹冲,shanyun, caoqiang.2015. The Characteristics of Heavy metals Content and Health Risk Assessment in Different Environment Media from Dexing Copper mining area[J]. Acta Geologica Sinica,89(5):889-908.

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  • 收稿日期:2014-09-27
  • 最后修改日期:2015-01-31
  • 录用日期:2015-02-02
  • 在线发布日期: 2015-05-14