中国伴生铟(镉镓锗)矿床的时空分布、成因类型及成矿机制:总结与展望
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本文为国家自然科学基金重大研究计划重点支持项目(编号92162210)、国家自然科学基金面上项目(编号42172096)和中国地质调查局二级项目(编号DD20221695,1212011220807,DD20190613)联合资助的成果


Temporal and spatial distribution, genetic type, and metallogenic mechanism of indium (gallium, germanium, cadmium) associated deposits in China: Overview and expectation
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    摘要:

    铟(In)是21世纪重要的紧缺战略性矿产,对国家稳定、发展和提升国际竞争力具有重要意义。中国拥有全球最丰富的铟资源,但尚未发现铟的独立矿床,目前已知的57个伴生铟矿床兼有镉(Cd)、镓(Ga)、锗(Ge)的资源潜力。本文在详细梳理所有伴生铟矿床的区域分布、成因类型、形成时代、赋存矿物、独立矿物和富集规律的基础上,总结了铟成矿作用的研究现状和发展方向。统计发现:我国伴生铟矿床高度集中于中亚造山带东段和华南地区;可划分为7种成因类型,包括矽卡岩型、岩浆- 热液型、海相火山岩型、陆相火山岩型、叠加(复合/改造)型、斑岩型和受变质型;7类矿床中,铟无一例外主要赋存于闪锌矿中,作为副产品被回收;85%的伴生铟矿床形成于中生代,古近纪和中生代之前的矿床数量较少。目前全球已发现了19种铟独立矿物,我国报道了其中的5种。硫铟铜矿(CuInS2)是我国最常见的铟独立矿物,其余的铟独立矿物如自然铟,羟铟矿等仅出现在特定的伴生铟矿床中。目前研究多关注扬子地台西南缘的矽卡岩型伴生铟矿床,而对散布于全国各地其他6类伴生铟矿床的研究尚处于起步阶段。这在很大程度上限制了对铟富集机制的认识,更不利于摸清国内铟资源家底。因此,加强对典型伴生铟矿床的详细研究,进而建立更加详细的数据库是亟需开展的重要工作。

    Abstract:

    Indium (In) is an important strategic mineral in short supply in the 21st century, which is of great significance to national stability, development and improvement of international competitiveness. China has the most abundant indium resources in the world, but no independent deposit of indium has been discovered. There are 57 associated indium deposits, which have the potential of cadmium (Cd), gallium (Ga) and germanium (Ge). Based on a detailed review of the regional distribution, genetic types, formation ages, indium- bearing minerals, independent indium minerals and enrichment regularity of 57 associated indium deposits, we summarized the research status and development direction of indium mineralization. The indium- bearing deposits are highly concentrated in the eastern part of the Central Asian Orogenic Belt and South China. There are seven genetic types, including skarn type, magma- hydrothermal type, marine volcanic- rock type, continental volcanic- rock type, superimposed (composite/modified) type, porphyry type, and metamorphosed type. Indium is mainly hosted in sphalerite without exception, and is recycled as by- product. 85% of the indium- bearing deposits were formed in the Mesozoic, with a small number of deposits in the Paleogene and pre- Mesozoic. At present, 19 indium independent minerals have been discovered, only 5 indium independent minerals were found in China. Roquesite (CuInS2) is the most common indium independent mineral that has been found in our country,other indium independent minerals such as natural indium and hydroxindium(InSb)are reported to occur only in specific associated indium deposits. At present, the skarn associated indium deposits, which are located in the southwestern margin of the Yangtze block, get more attention than other deposits. The research of the other six deposit types scattered throughout other areas were studied less. This is a limit not only to understand the indium enrichment mechanism, but also to find out new indium resources. Therefore, it is urgent to strengthen the detailed study of typical associated indium deposits and establish a more detailed database.

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引用本文

郑义,郭春丽,王登红,赵汀,王岩.2023.中国伴生铟(镉镓锗)矿床的时空分布、成因类型及成矿机制:总结与展望[J].地质学报,97(11):3569-3603.
ZHENG Yi, GUO Chunli, WANG Denghong, ZHAO Ting, WANG Yan.2023. Temporal and spatial distribution, genetic type, and metallogenic mechanism of indium (gallium, germanium, cadmium) associated deposits in China: Overview and expectation[J]. Acta Geologica Sinica,97(11):3569-3603.

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  • 收稿日期:2023-03-10
  • 最后修改日期:2023-07-12
  • 录用日期:2023-07-18
  • 在线发布日期: 2023-12-09
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