滇西保山地块金厂河Fe- Cu- Pb- Zn矽卡岩型多金属矿床黑柱石成因及地质意义
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本文为昆明理工大学“双一流”科技专项课题(编号202202AG050006- 2)、国家自然科学基金项目(编号42362010)、云南黄金集团校企合作项目(编号KKF02021212097)、云南省高层次科技人才及创新团队选拔专项(编号202305AT350004- 4)和云南省三江成矿系统与评价顶尖团队培育项目(编号202305AS350015)联合资助的成果


Genesis and geological significance of ilvaite in the Jinchanghe Fe- Cu- Pb- Zn skarn type polymetallic deposit, Baoshan block, western Yunnan
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    摘要:

    黑柱石是一种矽卡岩型铅锌及铁矿床中少见的矿物,与铅锌矿体、磁铁矿体关系密切。为查明黑柱石成矿过程中与铅锌铁铜多金属成矿作用的关系,本文对金厂河Fe- Cu- Pb- Zn多金属矿床中的黑柱石产状、矿物共生组合、化学成分、分带性等开展了研究。根据电子探针数据计算可得,金厂河矿区黑柱石的化学式为:Ca0. 95- 1. 08(Fe0. 87- 1. 97Mn0. 08- 0. 36Mg0. 01- 0. 06)2+(1. 89- 2. 03)(Fe0. 82- 1. 04Al0. 01- 0. 03)3+(0. 88- 1. 15)\[Si1. 94- 2. 08O7\]O(OH)。结合矿物组合类型、产状、分带特征等,推测矿床内矽卡岩由内带逐渐向外带交代的趋势。金厂河矿区主要有3种矿物共生组合:黑柱石+磁铁矿组合,黑柱石+磁铁矿+黄铁矿+黄铜矿组合,黑柱石+方铅矿+闪锌矿+黄铜矿组合,分别对应三个不同的蚀变阶段:晚期矽卡岩阶段(代表组合I),以石榴子石的分解为主,形成大量的黑柱石;退蚀变阶段(代表组合II),以阳起石、黄铜矿、黄铁矿发育为主;石英- 硫化物阶段(代表组合III),以发育大量的方铅矿、闪锌矿为主,同时这一阶段内黑柱石分解,形成阳起石、方解石、磁铁矿等。此外,黑柱石的稀土元素配分模式与石榴子石的类似,一定程度上保留了石榴子石的稀土元素特征。研究认为:黑柱石是早期石榴子石退化分解的产物,矿床自内向外逐渐交代,形成了铅锌铜矿体中以锰质黑柱石为主,而磁铁矿体、铜矿体中以含锰黑柱石为主的分带特性。锰质黑柱石有利于铅锌矿的形成,而对于磁铁矿有贫化的影响,同时也可为矿区揭露中酸性岩体和深部找矿提供重要科学意义。

    Abstract:

    Ilvaite is a common mineral in skarn- type Pb- Zn and Fe deposits, and is closely related to lead- zinc ore bodies and magnetite ore bodies. To identify the relationship with lead- zinc- iron- copper polymetallic mineralization during ilvaite mineralization, this paper investigated the production environment, mineral symbiotic assemblage, chemical composition and ilvaite zonation in the Jinchanghe Fe- Cu- Pb- Zn skarn type polymetallic deposit. The mineral chemical composition by EMPA showed that the molecular formula of ilvaite in the Jinchanghe mining area is Ca0. 95- 1. 08(Fe0. 87- 1. 97Mn0. 08- 0. 36Mg0. 01- 0. 06)2+(1. 89- 2. 03)(Fe0. 82- 1. 04Al0. 01- 0. 03)3+(0. 88- 1. 15)(Si1. 94- 2. 08O7)O(OH). Combined with the type of mineral assemblage, occurrence, zoning characteristics, etc., it was inferred that the skarn in the deposit will gradually metasomatize from the inner zone to the outer zone. Three mineral symbiotic combinations were identified in Jinchanghe mining area: ilvaite+magnetite combination, ilvaite+magnetite+pyrite+chalcopyrite combination, ilvaite+galena+sphalerite+chalcopyrite combination. These mineral assemblages correspond to three different alteration stages: the later skarn stage (representative assemblage Ⅰ), which is dominated by the decomposition of garnet, forming a large number of ilvaites; the retro- alteration stage (representative assemblage Ⅱ) where mainly actinolite, chalcopyrite, and pyrite developed; at the quartz- sulfide stage (representative assemblage Ⅲ), ilvaite was further decomposed to form quartz, calcite, magnetite, etc. In addition, the distribution pattern of rare earth elements in ilvaite is similar to that of garnet, which retains the characteristics of rare earth elements in garnet to some extent. It is believed that ilvaite is the product of the degradation and decomposition of early garnet, and the ore deposit is gradually metasomatized from the inside to the outside, forming a Mn- rich ilvaite in the lead- zinc- copper ore body and manganese ilvaite in the magnetite ore body banding feature. Mn- rich ilvaite is conducive to the formation of lead- zinc ore, and has an influence on the depletion of magnetite ore bodies and copper ore bodies. Meanwhile, it can also provide important scientific significance for the mining area to expose neutral acid rock and deep prospecting.

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陆波德,刘学龙,周云满,赵成峰,王基元,李方兰,李庆锐,王海,李守奎,曹振梁,周杰虎.2024.滇西保山地块金厂河Fe- Cu- Pb- Zn矽卡岩型多金属矿床黑柱石成因及地质意义[J].地质学报,98(4):1164-1182.
LU Bode, LIU Xuelong, ZHOU Yunman, ZHAO Chengfeng, WANG Jiyuan, LI Fanglan, LI Qingrui, WANG Hai, LI Shoukui, CAO Zhenliang, ZHOU Jiehu.2024. Genesis and geological significance of ilvaite in the Jinchanghe Fe- Cu- Pb- Zn skarn type polymetallic deposit, Baoshan block, western Yunnan[J]. Acta Geologica Sinica,98(4):1164-1182.

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  • 收稿日期:2022-08-06
  • 最后修改日期:2022-09-24
  • 录用日期:2022-10-27
  • 在线发布日期: 2024-04-22
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