中国南方离子吸附型稀土矿床成矿类型及其母岩控矿因素探讨
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本文为国家自然科学基金重大研究计划培育项目(编号 91962107)、国家自然科学基金项目(编号 42173067)和青年基金项目(编号 42003066)、广西自然科学基金创新研究团队项目(编号 2020GXNSFGA297003)和广西自然科学基金项目(编号 2020GXNSFAA159029)联合资助的成果。


Mineralization diversity of ionadsorption type REE deposit in southern China and the critical influence of parent rocks
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    摘要:

    传统认为中国南方的离子吸附型稀土矿床可划分为以“足洞式”为代表的重稀土型和以“河岭式”(或“花山式”)为代表的轻稀土型两种矿化类型。然而,近年来发现的许多矿床(如清溪、寨背和馒头山等)的赋矿风化壳中出现了轻稀土矿与重稀土矿并存现象,表现出特殊的“上轻下重”双层矿体结构。这指示了除重稀土型和轻稀土型之外,还存在着轻重稀土共生型的过渡类型。本研究通过对三种不同成矿类型的若干典型矿床系统对比,指出成矿类型的多样性与母岩性质密切相关,尤其是母岩的稀土元素地球化学和稀土载体矿物属性是制约成矿类型变化的关键因素。统计数据表明,从重稀土型→轻重稀土共生型→轻稀土型,成矿母岩的全岩稀土总量变化不大(ΣREY: 200×10-6~450×10-6→200×10-6~500×10-6→200×10-6~800×10-6),但轻重稀土配分值出现较显著的区间性差异(ΣLREE/ΣHREY: 02~1→1~5→2~10)。与之同时,母岩中能为离子相稀土提供物源且具有重稀土配分属性的稀土副矿物类型和数量明显减少,这与全岩稀土元素地球化学特征中重稀土分量占比的降低趋势也互相匹配。该结果指示,以往认为重稀土配分母岩形成重稀土矿床、轻稀土配分母岩形成轻稀土矿床的传统观点需要外延,即一部分具有低度轻稀土配分属性(1<ΣLREE/ΣHREY<5)且含有丰富易风化稀土副矿物的母岩还可能形成轻重稀土共生型矿床,该认识可为今后离子吸附型稀土矿床勘查工作提供新的找矿依据。

    Abstract:

    It is traditionally known that the ionadsorption type REE deposits in South China can be divided into two mineralization types: HREEtype represented by the “Zudong pattern” and LREEtype represented by the “Heling pattern” (or “Huashan pattern”). However, in the orehosting weathering crust of many deposits discovered in recent years (such as Qingxi, Zhaibei and Mantoushan), the coexistence of HREE and LREE ore has appeared, within a special “upper LREE and lower HREE” structure. This indicates that in addition to the HREEtype and LREEtype, there is also a transitional type that could be defined as the HREE+LREEtype. Based on a comparative study of a large number of typical deposits from three different mineralization types, this study revealed that the diversity of mineralization types is closely related to the variation of oreforming parent rocks. In particular, REE geochemistry and REEbearing minerals of parent rocks are the key factors that regulate the variation of mineralization types. Statistics show that, from HREEtype→LREE+HREEtype→LREEtype, the total amount of REE in the parent rocks has changed little (∑REY: 200×10-6~450×10-6→200×10-6~500×10-6→200×10-6~800×10-6), but the partition value of LREE and HREY appear considerably different within the interval range (∑LREE/∑HREY: 02~1→1~5→2~10). Meanwhile, with the above sequence of oreforming parent rocks, the type and quantity of REE accessory minerals that can provide main source for ionexchangeable REY and of HREY partition property are obviously reduced. It is consistent with the decreasing trend of HREY ratio in the bulk REE geochemistry. The results indicate that the traditional view of “the HREE distributedpattern parent rocks form HREE deposits and the LREE distributedpattern rocks form LREE deposits” needs to be extended. That is, for some parent rocks with low degree (1<∑LREE/∑HREY<5) LREE distribution pattern and rich weatherable REE accessory minerals, there is potential to form a LREE+HREEtype deposit. The results are of indicative significance for future exploration of ionadsorption type REE deposits in southern China.

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付伟,赵芹,罗鹏,李佩强,陆济璞,周辉,易泽邦,许成.2022.中国南方离子吸附型稀土矿床成矿类型及其母岩控矿因素探讨[J].地质学报,96(11):3901-3923.
Fu Wei, Zhao Qin, Luo Peng, Li Peiqiang, Lu Jipu, Zhou Hui, Yi Zebang, Xu Cheng.2022. Mineralization diversity of ionadsorption type REE deposit in southern China and the critical influence of parent rocks[J]. Acta Geologica Sinica,96(11):3901-3923.

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  • 收稿日期:2021-11-11
  • 最后修改日期:2022-01-15
  • 录用日期:2022-01-27
  • 在线发布日期: 2022-12-21
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