青海东昆仑三通沟地区中—新元古界万宝沟群锰矿成因分析
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本文为省级财政资金地质勘查项目“青海省都兰县三通沟北地区锰多金属矿预查项目综合研究”(编号青自然资(2021)114号)资助成果。


Genesis analysis of manganese ore deposits from the Middle- Upper Proterozoic Wanbaogou Group in the Santonggou area, East Kunlun, Qinghai Province
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    摘要:

    在青海东昆仑三通沟地区中—新元古界万宝沟群发现的沉积型碳酸锰矿床,是近年来青海地区锰矿勘查的重要突破。矿区内自下而上发现5条锰矿体,其中Ⅰ~Ⅲ号锰矿体位于万宝沟群下部(称为下锰矿层),Ⅳ~Ⅴ号锰矿体位于上部(称为上锰矿层),平均品位为15%,矿体厚度大,延伸远,具有较大的勘查开发潜力。为了查明其成矿控制因素及成因机理,本文基于野外剖面实测、含锰岩系岩石学和地球化学的分析认为:万宝沟群锰矿层表现出Ce正异常、发育草莓状黄铁矿颗粒且粒度基本大于6 μm、Mn/Fe值小于6、碳同位素负偏,这些特征反映锰矿床的形成过程:锰质最初以氧化物或氢氧化物的形式在富氧水体中率先沉淀并富集,在早成岩阶段的富含有机质的还原条件下被还原成Mn2+,并与有机质分解产生的CO2- 3结合形成碳酸锰矿。下锰矿层表现出Eu和Y正异常,其Al/(Al+Fe+Mn)值<035、(Fe+Mn)/Ti值>20±5、Fe/Ti 值>20,显示出热水沉积特征,表明其锰质主要来源于热液;而上锰矿层SiO 2与Al 2O 3图解投点处于正常沉积与热液沉积的过渡区,可作为陆源输入代替指标的Al 2O 3与TiO 2含量很高,且同期火山活动强烈,分析认为其锰质由陆源和液热共同提供。依据SiO 2- K 2O/Na 2O和La/Ce- Al 2O 3/(Al 2O 3+Fe 2O 3)图解,结合沉积相及构造演化史分析,认为三通沟地区万宝沟群下锰矿层处于拉张背景下的初始洋盆环境,上锰矿层处于拉张背景下的局限深水陆棚环境。建立了局限深水陆棚相锰成矿和盆地相锰成矿两种模式。

    Abstract:

    The sedimentary manganese carbonate deposit discovered in the Meso- Neoproterozoic Wanbaogou Group in the Santonggou area, East Kunlun, Qinghai Province is an important breakthrough in manganese exploration in Qinghai Province in recent years. Five proven manganese ore bodies were documented in the mining area from bottom to top, among which No. Ⅰ- Ⅲ manganese ore bodies are located in the lower part of the Wanbaogou Group (called the lower manganese deposit), and No. Ⅳ- Ⅴ manganese ore bodies are located in the upper part (called the upper manganese deposit), with an average grade of about 15%, large thickness and wide extent, and have great exploration and development potential. Field measurements, petrology and geochemical analysis of manganese- bearing rock series were undertaken to discover the metallogenic controlling factors and genesis mechanism of mineralization. The results indicate that the manganese deposits in the Wanbaogou Group show positive Ce anomaly, developing strawberry pyrite particles with particle size greater than 6 μm, Mn/Fe value less than 6 and negative δ13C excursion. All these characteristics reflect the formation of manganese deposit: manganese was firstly precipitated and enriched as oxides or hydroxides in oxygen- rich water. In the early diagenesis stage, manganese was reduced to Mn2+ under reducing conditions with rich organic matter, and combined with CO2- 3 produced by decomposition of organic matter to form manganese carbonate. The lower manganese deposits show positive Eu and Y anomalies, with Al/(Al+Fe+Mn)<0. 35, (Fe+Mn)/Ti>20±5, and Fe/Ti>20, showing hydrothermal deposition characteristics, indicating that the manganese is mainly derived from hydrothermal solutions. The SiO 2 and Al 2O 3 diagram placement of the upper manganese deposit is in the transition zone between normal deposition and hydrothermal deposition. The contents of Al 2O 3 and TiO 2 used as proxies for terrigenous input are very high and the volcanic activity is strong in the same period. The analysis suggests that both terrigenous and hydrothermal sources provide the manganese in the upper manganese deposit. 〖JP2〗According to SiO 2- K 2O/Na 2O and La/Ce- Al 2O 3/(Al 2O 3+Fe 2O 3) diagrams, combined〖JP〗 with the analysis of sedimentary facies and tectonic evolution history, it is concluded that the lower manganese deposits of the Wanbaogou Group in the Santonggou area were formed in aninitial ocean basin environment under an extensional background and the upper manganese deposits in arestricted deep shelf environment. Restricted deep shelf and basin, two manganese metallogenic models have been established in the study area.

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李杰,李凤杰,李佐强.2023.青海东昆仑三通沟地区中—新元古界万宝沟群锰矿成因分析[J].地质学报,97(2):448-466.
Li Jie, Li Fengjie, Li Zuoqiang.2023. Genesis analysis of manganese ore deposits from the Middle- Upper Proterozoic Wanbaogou Group in the Santonggou area, East Kunlun, Qinghai Province[J]. Acta Geologica Sinica,97(2):448-466.

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  • 收稿日期:2021-08-12
  • 最后修改日期:2022-09-23
  • 录用日期:2022-12-09
  • 在线发布日期: 2023-03-01
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