• Volume 83,Issue 6,2009 Table of Contents
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    • Structure, Orientation and Finite Element Analysis of the Tail Club of Mamenchisaurus hochuanensis

      2009, 83(6):1031-1040.

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      Abstract:Abstract: The structure and orientation of the posterior extremity (tail club) of the caudal vertebrae of Mamenchisaurus hochuanensis Young and Chao, 1972 from the Upper Jurassic Shangshaximiao Formation has been analyzed to determine the tail club function using Finite Element Analysis. Of the four caudal vertebrae composing the tail club, the second largest (C"1") was probably the most proximal, and is fixed with the preceding sequence of the caudal vertebrae, whereas the smallest (C"4") is free and forms the termination of the tail club. Our analysis also suggests that the tail club is more efficient in lateral swinging rather than up-and-down motion, and that the best region for the tail club to impact is at the spine of the largest of the four caudals (C"2"), with a maximum load for impact at about 450 N. The tail club of Mamenchisaurus hochuanensis probably also had limitations as a defense weapon and was more possibly a sensory organ to improve nerve conduction velocity to enhance the capacity for sensory perception of its surroundings.

    • Comparative Analysis of Sequence Characteristics among Different Superimposed Stages of the Chelif Basin, Algeria

      2009, 83(6):1041-1051.

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      Abstract:Abstract: Superimposed basins were investigated with respect to tectonic evolution, sediment deposition and petroleum characteristics within a single superposition stage generally. The comparative study was seldom seen. Sequence characteristics were compared for two different superimposed stages – an expanding rifting stage and a depression-foreland transition stage – in the Chelif Basin during the Miocene in this paper. A model and mechanism for sequence evolution of superimposed basins in different dynamic situations are discussed with respect to sequence similarities and differences. The compared characters include sequence thickness, sequence boundaries and system tracts, as well as sediment deposition within sequences and sequence development patterns. Finally, some typical features of sequence development concomitant with changes of superimposed stages in the Chelif Basin are discussed.

    • Geology, Geochemistry and Minerogenesis of the Shijuligou Zinc–Copper Deposit in Gansu, China

      2009, 83(6):1052-1063.

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      Abstract:Abstract: The Shijuligou deposit was separated by an arcuate ductile shear zone cross the center of the deposit region, resulting in the difference between the southern and northern ore bodies. The lead (Pb) isotopic data of ores of the Shijuligou copper deposit have averages of 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb in 17.634, 15.444, and 37.312, respectively. It has been shown that ore-forming metals originated from intrusive and extrusive rocks in the upper part of ophiolites. The sulfur isotopic data of pyrite and chalcopyrite in the northern part change from +7.61‰ to +8.09‰ and +4.95‰ to +8.88‰ in the southern part. Isotopes of δ18O in the Shijuligou copper deposit are between +11.1‰ and +18.6‰, with the calculated δ18OH2O at +0.65‰. It is suggested that the mineralized fluid is a mixture of magma fluid, meteorological water, and seawater through circulating and leaching metals from the volcanic rocks. The zircon uranium-lead (U–Pb) dating of gabbro is 457.9±1.2 Ma, and the lower crossing age of the discordant and concordia curves of pyroxene spilite of zircon is 454±15 Ma. It is indicated that the Shijuligou deposit formed in a new ocean crust (ophiolite) of the back-arc basin in the late Ordovician. Mineralization should occur in the intermittence period after strong volcanic activity, and the age should be the late Ordovician. Moreover, the mineralization of ophiolite-hosted massive sulfide deposits in the ancient orogenic belt of the late Ordovician in the northern Qilian Mountains was controlled by the primary fault/fracture, with the forming of a metallogenic hydrothermal system by a mixture of volcanic magma fluid and seawater, which circularly leached the metallogenic metals from the volcanic rocks, resulting in their accumulation. The ore bodies were transformed with morphology and metallogenic elements. Jasperoid is an important sign for prospecting such deposits. There were many island arcs in the continent of China. This study provides evidence for understanding and exploration of ophiolite-hosted massive sulfide deposits in western China, especially in the area of northern Qilian Mountains.

    • Geochronology and Geochemistry of Mafic Dikes from Hainan Island and Tectonic Implications

      2009, 83(6):1064-1073.

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      Abstract:Abstract: In the present study, the major and trace element compositions, as well as Sr, Nd isotopic compositions and K-Ar age data in mafic dikes from Hainan Island, China, have been analyzed. Whole-rock K-Ar dating yielded a magmatic duration of 61–98 Ma for mafic dikes. Mafic dikes have a very high concentration of incompatible elements, for example, Ba, Rb, Sr, K, rare earth elements, and especially light rare earth elements (LREE), and negative anomalies of Nb, Ta, and Ti in the normalized trace element patterns. The initial 87Sr/86Sr ratios and εSr(t) of the mafic dikes are 0.70634–0.71193 and +27.7 to +112.2, respectively. In the 87Sr/86Sr versus εNd(t) diagram, the Hainan Island mafic dikes plot between fields for depleted mantle and enriched mantle type 2. All these characteristics show that the mantle (source region) of mafic dikes in this area experienced metasomatism by fluids relatively enriched in LREE and large ion lithophile elements. The genesis of Hainan Island mafic dikes is explained as a result of the mixing of asthenospheric mantle with lithospheric mantle that experienced metasomatism by the subduction of the Pacific Plate. This is different from the Hainan Island Cenozoic basalts mainly derived from depleted asthenospheric mantle, and possibly, minor metasomatised lithospheric mantle. This study suggests that the Mesozoic and Cenozoic lithospheric revolutions in Hainan Island can be divided into three stages: (1) the compression orogenesis stage before 98 Ma. The dominant factor during this stage is the subduction of the ancient Pacific Plate beneath this area. The lithospheric mantle changed into enriched mantle type 2 by metasomatism; (2) the thinning and extension stage during 61–98 Ma. The dominant factor during this stage is that the asthenospheric mantle invaded and corroded the lithospheric mantle; and (3) the large-scale thinning and extension stage after 61 Ma. The large-scale asthenospheric upwelling results in the strong erupting of Cenozoic basalts, large-scale thinning of the lithosphere, the southward translating and counterclockwise rotating of Hainan Island, and the opening of the South China Sea.

    • Reclassification of the Meso- and Neoproterozoic Chronostratigraphy of North China by SHRIMP Zircon Ages

      2009, 83(6):1074-1084.

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      Abstract:Abstract: High-quality zircon U-Pb ages acquired from Meso- and Neoproterozoic strata in North China in recent years has provided a high-resolution chronostratigraphic framework for dating. A basis of this high-level chronostratigraphic system provides the foundation for a global Precambrian study and stratigraphic correlation and so recent geological studies have focused attention on systemic SHRIMP zircon dating. A chronology of Meso- and Neoproterozoic strata and the time of origin of the overlying Changcheng System is given on the basis of new SHRIMP zircon dating from the Qianxi Complex and diabase of the Chuanlinggou Formation. A new tectonostratigraphy for a Neoproterozoic chronostratigraphic framework in the southeastern margin of the North China continent is underpinned by the new SHRIMP zircon dating of a Neoproterozoic mafic magma diabase in the Jiao-Liao-Xu-Huai Sub-Province.

    • Geochemical Characteristics, Genesis of Concealed Cu-rich Ore Body in the Jinchuan Deposit, Northwestern China, and Its Prospecting

      2009, 83(6):1085-1100.

      Abstract (1761) HTML (0) PDF 11.13 M (47) Comment (0) Favorites

      Abstract:Abstract: The Jinchuan deposit is hosted by the olivine-rich ultramafic rock body, which is the third-largest magmatic sulfide Ni–Cu deposit in the world currently being exploited. Seeking new relaying resources in the deep and the border of the deposit becomes more and more important. The ore body, ore and geochemistry characteristics of the concealed Cu-rich ore body are researched. Through spatial analysis and comparison with the neighboring II1 main ore body, the mineralization rule of the concealed Cu-rich ore body is summed up. It is also implied that Cu-rich magma may exist between Ni-rich magma and ore pulp during liquation differentiation in deep-stage chambers, which derives from deep-mantle Hi–MgO basalt magma. It is concluded that the type of ore body has features of both magmatic liquation and late reconstruction action. It has experienced three stages: deep liquation and pulsatory injection of the Cu- and PPGE-rich magma, concentration of tectonic activation, and the later magma hydrothermal superimposition. In addition, the Pb and S isotopes indicate the magma of I6 concealed Cu-rich ore body originates predominantly from mantle; however, it is interfused by minute crust material. Finally, it is inferred that the genesis of the Cu–Ni sulfide deposit is complex and diverse, and the prospect of seeking new deep ore bodies within similar deposits is promising, especially Cu-rich ore bodies.

    • High-Resolution Records of the Holocene Paleoenvironmental Variation Reflected by Carbonate and Its Isotopic Compositions in Bosten Lake and Response to Glacial Activities

      2009, 83(6):1101-1115.

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      Abstract:Abstract: The Early Holocene paleoclimate in Bosten Lake on the northern margin of the Tarim Basin, southern Xinjiang, is reconstructed through an analysis of a 953 cm long core (BSTC2000) taken from Bosten Lake. Multiple proxies of this core, including the mineral components of carbonate, carbonate content, stable isotopic compositions of carbonate, Ca/Sr, TOC and C/N and C/S of organic matter, are used to reconstruct the climatic change since 8500 a B.P. The chronology model is made by nine AMS 14C ages of leaves, seeds and organic matter contained in two parallel cores. The climate was cold and wet during 8500 to 8100 a B.P. Temperature increased from 8100 to 6400 a B.P., the climate was warm and humid, and the lake expanded. The lake level was highest during this stage. Then from 6400 to 5100 a B.P., the climate became cold and the lake level decreased slightly. During the late mid-Holocene, the climate was hot and dry from 5100 to 3100 a B.P., but there was a short cold period during 4400 to 3800 a B.P. At this temporal interval, a mass of ice and snow melting water supplied the lake at the early time and made the lake level rise. The second highest lake level stage occurred during 5200 to 3800 a B.P. The climate was cool and wet during 3100 to 2200 a B.P., when the lake expanded with decreasing evaporation. The lake had the last short-term high level during 3100 to 2800 a B.P. After this short high lake level period, the lake shrank because of the long-term lower temperature and reduced water supply. From 2200 to 1200 a B.P., the climate was hot and dry, and the lake shrank greatly. Although the temperature decreased somewhat from 1200 a B.P. to the present, the climate was warm and dry. The lake level began to rise a little again, but it did not reach the river bed altitude of the Konqi River, an outflow river of the Bosten Lake.

    • Character of the Si and Al Phases in Coal Gangue and Its Ash

      2009, 83(6):1116-1121.

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      Abstract:Abstract: Analysis of the Si and Al phases in coal gangue fuel and its ash is important for use of coal gangue ashes. A comprehensive study by theoretical and experimental analyses with differential thermal analysis, X-ray diffraction and Infrared Spectroscopy has been made in the present article to explore the diagram of the Si and Al phases in coal gangue fuel and its ashes. It is found that kaolinite and quartz are the main phases in coal gangue fuel. The ratio of moles Al2O3 to SiO2 (i.e., Al2O3 (mole) /SiO2 (mole)) is usually no more than 0.5 in most coal gangue fuel and its ashes. The kaolinit at about 984°C releases a large quantity of SiO2, which makes calcine coal gangue more active than coal gangue itself. The relationship between the ratio Al2O3 (mole)/SiO2(mole) and the components of coal gangue ash is analyzed, resulting in a formula to calculate the quantity of each phase. Applying the formula to the testing samples from an electric plant in north China supports the above conclusions.

    • Glass and Mineral Chemistry of Northern Central Indian Ridge Basalts: Compositional Diversity and Petrogenetic Significance

      2009, 83(6):1122-1135.

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      Abstract:Abstract: The glass and mineral chemistry of basalts examined from the northern central Indian ridge (NCIR) provides an insight into magma genesis around the vicinity of two transform faults: Vityaz (VT) and Vema (VM). The studied mid-ocean ridge basalts (MORBs) from the outer ridge flank (VT area) and a near-ridge seamount (VM area) reveal that they are moderately phyric plagioclase basalts composed of plagioclase (phenocryst [An60–90] and groundmass [An35–79]), olivine (Fo81–88), diopside (Wo45–51, En25–37, Fs14–24), and titanomagnetite (FeOt ~63.75 wt% and TiO2 ~22.69 wt%). The whole-rock composition of these basalts has similar Mg# [mole Mg/mole(Mg+Fe2+)] (VT basalt: ~0.56–0.58; VM basalt: ~0.57), but differ in their total alkali content (VT basalt: ~2.65; VM basalt: ~3.24). The bulk composition of the magma was gradually depleted in MgO and enriched in FeOt, TiO2, P2O5, and Na2O with progressive fractionation, the basalts were gradually enriched in Y and Zr and depleted in Ni and Cr. In addition, the SREE of magma also increased with fractionation, without any change in the (La/Yb)N value. Glass from the VM seamount shows more fractionated characters (Mg#: 0.56–0.57) compared to the outer ridge flank lava of the VT area (Mg#: 0.63–0.65). This study concludes that present basalts experienced low-pressure crystallization at a relatively shallow depth. The geochemical changes in the NCIR magmas resulted from fractional crystallization at a shallow depth. As a consequence, spinel was the first mineral to crystallize at a pressure >10 kbar, followed by Fe-rich olivine at <10 kbar pressure.

    • Tectonic Evolution of the Tianhuan Depression and the Western Margin of the Late Triassic Ordos

      2009, 83(6):1136-1147.

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      Abstract:Abstract: The Ordos Basin is one of the most important oil and gas basins in China. Based on surface outcrop, key exploratory wells and seismic reflection data and by using the technology of “prototype basin recovery”, seismic profile “layer flattening” and “restoration of balanced section”,and other methods, the sedimentary boundary, structure and the evolution history of the Tianhuan depression on the western margin of the Ordos Basin are reestablished. The following results have been obtained. (1) The west boundary of the Late Triassic Ordos Basin was far beyond the scope of the current basin. The basin is connected with the Late Triassic Hexi Corridor Basin, and its western margin did not have tectonic characteristics of a foreland basin. (2) The Tianhuan depression was first formed in the Late Jurassic. At the late stage it was impacted by the late Yanshanian and Himalayan tectonic movement and the depression axis gradually moved eastwards to the present location with a cumulative migration distance of ~30 km. (3) Eastward migration of the depression axis caused adjustment and even destruction of the originally formed oil and gas reservoirs, so that oil and gas remigrated and aggregated, resulting in secondary structural reservoirs formed at high positions on the western flank of the depression.

    • Mantle Branch Structure in the South-Central Segment of the Da Hinggan Mts., Inner Mongolia and Its Ore-controlling Role

      2009, 83(6):1148-1162.

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      Abstract:Abstract: Mantle branch structure is the third tectonic unit of multiple evolution of a mantle branch. It is not only the main mechanism of intercontinental orogeny, but also an important ore-forming and ore-control structure. Studies on geotectonic evolution, regional geological characteristics and ore-forming and ore-control structures have shown that since the Mesozoic the Da Hinggan Mts. region has entered a typical intercontinental orogenic stage, and it is closely related to mantle branch activities. The south-central segment of the Da Hinggan Mts. is a typical mantle branch structure and possesses obvious magmatic-metamorphic complexes in the core, detachment slip beds in the periphery and overlapped fault depression basins. Moreover, all of these are the principal factors leading to ore formation and ore control in the region. This paper also further explores the mechanism of mineralization in the south-central segment of the Da Hinggan, summaries the rules of mineralization, puts forward the models of mineralization and points out future ore-exploring orientation.

    • The Significance of Crust Structure and Continental Dynamics Inferred from Receiver Functions in West Yunnan

      2009, 83(6):1163-1172.

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      Abstract:Abstract: In our study we collected the teleseismic record of 31 broadband stations and 9 PASSCAL stations in West Yunnan, as well as extracted more than a million receiver functions. Using the waveform model and stacking techniques, we calculated the earth crust thicknesses and Vp/Vs ratios below the stations and obtained 35 valid data points. At the same time, we evenly stacked the receiver functions at the same station and superimposed the two profiles’ cross sections of the main tectonic units. The results show a clear difference between the crust thicknesses of different tectonic units. Because of the magma underplatting and delimanition of the lower crust in the role of deep process, the West Yunnan’s crust can be divided two kinds-mafic-ultramafic and feldspathic crusts. The research also shows that the mafic-ultramafic crust corresponds to a good background of mineralization. The delamination of the lower crust is one of the leading causes for moderate to strong earthquake prone in central Yunnan. The thinner crust and high velocity ratio as well as the multimodal structure of Ps in the Tengchong volcanic area confirms existence of a deep process of the strong magma underplating. Due to the basic crust structure and nature, it is believed that the Honghe fault is a main suture of the Gondwana and Eurasia continents.

    • Diagenesis and Restructuring Mechanism of Oil and Gas Reservoir in the Marine Carbonate Formation, Northeastern Sichuan: A Case Study of the Puguang Gas Reservoir

      2009, 83(6):1173-1181.

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      Abstract:Abstract: Based on the technology of balanced cross-section and physical simulation experiments associated with natural gas geochemical characteristic analyses, core and thin section observations, it has been proven that the Puguang gas reservoir has experienced two periods of diagenesis and restructuring since the Late Indo-Chinese epoch. One is the fluid transfer controlled by the tectonic movement and the other is geochemical reconstruction controlled by thermochemical sulfate reduction (TSR). The middle Yanshan epoch was the main period that the Puguang gas reservoir experienced the geochemical reaction of TSR. TSR can recreate the fluid in the gas reservoir, which makes the gas drying index higher and carbon isotope heavier because C2+ (ethane and heavy hydrocarbon) and 12C (carbon 12 isotope) is first consumed relative to CH4 and 13C? (carbon 13 isotope). However, the reciprocity between fluid regarding TSR (hydrocarbon, sulfureted hydrogen (H2S)?, and water) and reservoir rock results in reservoir rock erosion and anhydrite alteration, which increases porosity in reservoir, thereby improving the petrophysical properties. Superimposed by later tectonic movement, the fluid in Puguang reservoir has twice experienced adjustment, one in the late Yanshan epoch to the early Himalayan epoch and the other time in late Himalayan epoch, after which Puguang gas reservoir is finally developed.

    • Petroleum System of the Sufyan Depression at the Eastern Margin of a Huge Strike-slip Fault Zone in Central Africa

      2009, 83(6):1182-1187.

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      Abstract:Abstract: The present paper mainly studies the petroleum system of the Sufyan Depression in the Muglad Basin of central Africa and analyzes its control of hydrocarbon accumulation. On the basis of comprehensive analysis of effective source rock, reservoir bed types and source–reservoir–seal assemblages, petroleum system theory has been used to classify the petroleum system of the Sufyan Depression. Vertically, the Sufyan Depression consists of two subsystems. One is an Abu Gabra subsystem as a self generating, accumulating and sealing assemblage. The other subsystem is composed of an Abu Gabra source rock, Bentiu channel sandstone reservoir and Darfur group shale seal, which is a prolific assemblage in this area. Laterally, the Sufyan Depression is divided into eastern and western parts with separate hydrocarbon generation centers more than 10?000 m deep. The potential of the petroleum system is tremendous. Recently, there has been a great breakthrough in exploration. The Sufyan C-1 well drilled in the central structural belt obtained high-yielding oil flow exceeding 100 tons per day and controlled geologic reserves of tens of millions of tons. The total resource potential of the Sufyan Depression is considerable. The central structural belt is most favorable as an exploration and development prospect.

    • Origin and Distribution of Hydrogen Sulfide in Oil-Bearing Basins, China

      2009, 83(6):1188-1201.

      Abstract (2131) HTML (0) PDF 11.79 M (41) Comment (0) Favorites

      Abstract:Abstract: The concentration of hydrogen sulfide gas (H2S) varies greatly in the oil-bearing basins of China, from zero to 90%. At present, oil and gas reservoirs with high H2S concentration have been discovered in three basins, viz. the Bohai Bay Basin, Sichuan Basin and the Tarim Basin, whereas natural gas with low H2S concentration has been found in the Ordos Basin, the Songliao Basin and the Junggar Basin. Studies suggest that in China H2S origin types are very complex. In the carbonate reservoir of the Sichuan Basin, the Ordos Basin and the Tarim Basin, as well as the carbonate-dominated reservoir in the Luojia area of the Jiyang depression in the Bohai Bay Basin, Wumaying areas of the Huanghua depression, and Zhaolanzhuang areas of the Jizhong depression, the H2S is of Thermochemical Sulfate Reduction (TSR) origin. The H2S is of Bacterial Sulphate Reduction (BSR) origin deduced from the waterflooding operation in the Changheng Oilfield (placanticline oil fields) in the Songliao Basin. H2S originates from thermal decomposition of sulfur-bearing crude oil in the heavy oil area in the Junggar Basin and in the Liaohe heavy oil steam pilot area in the western depression of the Bohai Bay Basin. The origin types are most complex, including TSR and thermal decomposition of sulfcompounds among other combinations of causes. Various methods have been tried to identify the origin mechanism and to predict the distribution of H2S. The origin identification methods for H2S mainly comprise sulfur and carbon isotopes, reservoir petrology, particular biomarkers, and petroleum geology integrated technologies; using a combination of these applications can allow the accurate identification of the origins of H2S. The prediction technologies for primary and secondary origin of H2S have been set up separately.

    • Diagenesis and Their Succession of Gas-bearing and Non-gas-bearing Reservoirs in the Sulige Gas Field of Ordos Basin, China

      2009, 83(6):1202-1213.

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      Abstract:Abstract: Comparisons have been made among lithology, diagenesis, and reservoir characteristics of gas-bearing and non-gas-bearing ones in the Sulige gas field of the Ordos Basin based on the laboratory analysis of thin sections, scanning electron microscope, and liquid inclusion of the reservoirs. The reservoirs of the Sulige gas field are now in the middle stage of diagenesis and have undergone compaction, cementation and dissolution. The secondary pore of the reservoir originated from the dissolution of the feldspar and tuff because of the organic acid action from the source rocks during the diagenetic middle stage. Gas-bearing reservoirs are common in soluble pore diagenetic facies of coarse detritus quartzose sandstone, whereas non-gas-bearing ones are common in tense compaction diagenetic facies of mud-bearing medium-fine detritus quartzose sandstone and residual intergranular pore diagenetic facies of mud-bearing medium-coarse detritus quartzose sandstone. The secondary pore is developed in gas-bearing reservoirs of the Sulige gas-field as the medium-coarse grain reservoirs formed in a powerful sedimentary environment and experienced strong dissolution. However, the sediments of fine grain size form the non-gas-bearing reservoirs because of less residual primary pore and secondary pore.

    • Tectonic and Hydrocarbon Accumulation Elements Characteristics of the Tethyan Realm in South China

      2009, 83(6):1214-1223.

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      Abstract:Abstract: The evolution of the global Tethys Sea can be classified into three stages, Proto-Tethys, Paleo-Tethys and Neo-Tethys. The Tethyan realm has distinctive features of zonations and segmentations along north-south and east-west, respectively, and has variable richness in oil and gas. The petroleum geological conditions of Tethys are complicated, partly represented by multi-layer of source and seal rocks, and reservoirs. The hydrocarbon accumulation elements and periods of the Tethyan realm show gradually younger from west to east and north to south. South China is located in the north belt and Yangtze segment of the Tethyan realm, and its polycyclic tectonic movements were governed by the Tethyan and Pacific realms. The blocks in South China rotated clockwise and counter-clockwise during their drift northward from Gondwana. The belts and segmentations of Tethys in South China are also clear, with six tectonic belts including: Chuxiong-Sichuan; middle Guizhou-Hunan-Hubei; lower Yangtze; Xuefeng-Jiangnan; Guangxi-Hunan-Jiangxi; and Cathaysia. Numerous faults, including compressional, compressional-shear, extensional, extensional-shear and shear are well developed in South China. The fault strikes are mainly NE, NW and NS, in which the NE is the dominant direction. Lower, middle and upper hydrocarbon assemblages, respectively corresponding to Proto-, Paleo- and Neo-Tethys, formed in the Tethyan realm of South China with the lower and middle having excellent hydrocarbon accumulation conditions. An integrated analysis of tectonic evolution, superimposed deformation and later hydrocarbon preservation shows that during the Neo-Tethyan stage in South China, continental sediments were deposited and experienced intense tectonic deformation, which had resulted in different hydrocarbon pool-forming features from those of the Neo-Tethyan realm.

    • Characterization of an Area Polluted by Copper and Zinc: the Relation between Soil Texture, Mineralogy and Pollutant Concentration

      2009, 83(6):1224-1231.

      Abstract (1321) HTML (0) PDF 4.58 M (42) Comment (0) Favorites

      Abstract:Abstract: Twenty-four soil samples were collected at three depths from an approximately 2.5 acre contaminated site in southern Piedmont (Italy) and then analyzed. The main soil parameters determined were: pH, Cation Exchange Capacity (CEC), particle size distribution, total organic carbon (TOC) content and retained metal concentration. The mineral phases were identified by X-Ray Powder Diffraction (XRPD). All of the samples contained Zn and Cu resulting from industrial contamination during the last century, and those obtained at depths of 20-40 cm consistently showed the highest levels. To determine which size fraction was most active in the retention process, the samples were separated into four fractions (≤2 mm, ≤63 μm, ≤30 μm and ≤2 μm) and the amount of pollutant measured in each. It was found that metal retention was the highest in the clayey fraction, whose clay minerals were identified by XRPD after K+ and Mg2+ saturation, glycerol treatment and heating to 550°C. The clayey fraction was also the richest in TOC, and a direct correlation between TOC amount and metal retention was observed.

Chief Editor:HOU Zengqian

Governing Body:China Association for Science and Technology

Organizer:Geological Society of China

start publication :1922

ISSN:ISSN 1000-9515

CN:CN 11-2001/P

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