Abstract:Granitic rocks, widely developed in the Lamasu copper ore region, western Tianshan were formed at 390.5±7.7 Ma according to the SHRIMP zircon U-Pb dating of the plagioclase granite porphyry. Based on the regional tectonic evolution and published chronological data of both diagenesis and mineralization, the Biezhentao- Kokirqin region was rolled into the orogen associated with the closure of Yili Ocean during early Devonian. The N-S-trending thrust faults were formed during this period and accompanied by the intrusion of granitic rocks. On this stage, the paleo-Asian Ocean Plate entered into the early collision orogenic phase and the plagioclase granite porphyry intruded (390.5±7.7 Ma) and replaced with limestone of the Mesoproterozoic Kusongmuqieke Group, Jixianian System and formed the early phase of skarn-type copper mineralization in the Lamasu region. Furthermore, the subduction-melting of Bayingou Ocean Plate during Carboniferous generated a deep-seated magmatic chamber in the Lamasu copper ore region which located in the northwestern part of the Paleozoic Biezhentao-Kokirqin island arc. The magmatic chamber segregated Cu-bearing magmas, which transported upward to the shallow earth crust along the faults or fractures and formed the Cu-hosting porphyry. According to the research on the characteristics of the ore deposit and the ore-forming environment as mentioned above, the Lamasu Cu-Zn deposit was characterized by the superposing of mineralization at different geological settings and it was skarn-porphyritic type.

Abstract:This paper is briefly involved in distributions of China’s uranium metallogenic types, provinces, regions and belts. Eight target regions have been pointed out to be worthy of prospecting for uranium resources. The regional uranium metallogeny is discussed and great uranium potential pointed out from many aspects. Generally speaking, there are favorable conditions for uranium mineralization and good perspective to explore for uranium resources.

Abstract:This paper deals with the metallogenic model of the sandstone type uranium deposit in the northeastern Ordos Basin from aspects of uranium source, migration and deposition. A superposition metallogenic model has been established due to complex uranium mineralization processes with superposition of oil-gas reduction and thermal reformation.

Abstract:The superlarge Jinchang gold deposit is located in the joint area between the Taipingling uplift and the Laoheishan depression of the Xingkai Block in both eastern Jilin and eastern Heilongjiang Province. Wall rocks of the gold deposits are the Neoproterozoic Huangsong Group of metamorphic rocks. Yanshanian magmatism in this region can be divided into 5 phases, the diorite, the graphic granite, the granite, the granite porphyry and the diorite porphyrite, which resulted in the magmatic domes and cryptoexplosive breecia chimney followed by large-scale hydrothermal alteration. Gold mineralization is closely related to the fourth and fifth phase of magmatism. According to the occurrences, gold ores can be subdivided into auriferous pyritized quartz vein, auriferous quartz-pyrite vein, auriferous polymetallic sulfide quartz vein and auriferous pyritized calcite vein. The ages of the gold deposit are ranging from 122.53 to 119.40 Ma. The ore bodies were controlled by a uniform tectono-magmatic hydrothermal alteration system that the ore-forming materials were deep derived from and the ore-forming fluids were dominated by magmatic waters with addition of some atmospheric water in the later phase of mineralization. Gold mineralization took place in an environment of medium to high temperatures and medium pressures. Ore-forming fluids were the K+-Na+-Ca2+-Cl?-SO42? type and characterized by medium salinity or a slightly higher, weak alkaline and weak reductive. Au in the ore-forming fluids was transported as complexes of [Au(HS)2]?, [AuCl2]?, [Au(CO2)]? and [Au(HCO3)2]?. Along with the decline of temperatures and pressures, the ore-forming fluids varied from acidic to weak acidic and then to weak alkaline, which resulted in the dissociation of the complex and finally the precipitation of the gold.

Abstract:The Hadamengou gold deposit is located in western part of the northern margin of the North China craton. It is a hydrothermal deposit related to alkaline magmatism. Dissolution of Au, Fe from pyrite and iron oxide (including magnetite and hematite) individual minerals in the three main types of ore shows: in iron oxides (magnetite and hematite), Au and Fe were dissolved simultaneously and their solubilities are positively correlated, which means Au is mainly chemical-bonded (lattice gold) and/or colloidal-adsorbed in iron oxides; while in pyrite, on the contrary, Au dissolution obviously lags behind Fe and the solubility of Au shows negative relationship with that of Fe, which indicates Au is mainly hosted as grains of elemental gold (or native gold) within pyrite. Previous studies revealed that the Hadamengou gold deposit is characterized by intensive K-feldspathization and holds high content of iron oxides occasionally replaced by sulfides, which was caused by oxidizing K-enriched alkaline fluids under a stretching geodynamic setting. These geological features, together with the high Au-content in iron oxides, comparable with that of the Olympic Dam deposit in South Australia, suggest that this deposit is the first example of iron oxide-type gold deposits in China.

Abstract:The Shangzhuang altered-rock type gold ore deposit is located in the middle segment of and controlled by the Wang’ershan fault zone in the northwestern part of the Jiaodong gold province, China. The deformation evolution, the structure of strain and stress fields and its ore-controlling effect in the Shangzhuang deposit are discussed in this paper. It is revealed that the deformation evolution has mainly undergone four phases: the early ductile deformation, the second NE-striking horizontal simple shear, the third NE-striking compression-shear and the final NW-striking compression. The mineralization happened during the third stage in which the maximum principal stress gradually transited from NE to NW. The 3-D numerical simulations of the stress field show that, on the condition that the maximum principal stress is NE-striking, the fracture development in the fault zone is favored, while when the maximum principal stress is NW-striking, the fault zone is relatively extensional and it is suitable for the influx and emplacement of ore-forming fluids. The compression-shear strain field during the mineralization is characterized by the λ-type structure, the positive flower structure, etc. Orebodies are mostly equidistantly located in the dilatational spaces, which are distributed in the integral compressional circumstances. And the dilatational spaces are developed where the fault attitude changes or shear joint systems develop. In the overall compression-shear stress field, the strain field bears self-similarity at multiple scales, including the orebody, ore deposit and orefield. The self-similarity of the structure comprises the subequidistant distribution of fractures at the same scale and the similar shape of the fractures at various scales. Yet, due to the special geological structure, the orebodies are mostly located in the hanging wall in the Shangzhuang deposit, which is different from most deposits in the Jiaodong gold province. Analyses of the ore-controlling stress and strain fields in the deposit provide an important basis for deposit seeking.

Abstract:Utilizing theories of minerageny and prospecting mineralogy, the authors studied the attitude, morphotype and chemical composition of metallic minerals of pyrite, gold, chalcopyrite, galena and sphalerite, non-metallic minerals of quartz, carbonate, dolomite and rutile in the Puziwan gold deposit. The study shows the following results. (1) The mineral assemblage is complex and the species of sulfide are abundant with occurrences of sulfosalt minerals. (2) The composition in the minerals is complex and there rich micro elements, including As, Sb, Bi, Se, Te, Au, Ag, Cu, Pb, Zn, and Cr, Ni, V. The typomorphic characteristics of the association of the elements and their specific value suggest that gold mineralization is associated with shallow magmatic hydrothermal activity, the ore-forming fluid is the mixture of abundant rising alkali magmatic water originating from the mantle or the lower crust and the descending acid atmospheric water. (3) Ankerite, Fe-rich sphalerite, granular Ti-rich rutile are widely distributed, which indicate great denudation depths, high mineralization temperature. The deposit is found in the middle and shallow positions of the porphyry series. The deep layers are not favorable for gold mineralization. (4) Copper minerals are rich in the ores and sulfides have high content of copper, suggesting possible porphyry-type Cu (Au) mineralization in deep positions and the surrounding areas.

Abstract:There are four deposit types related to a Permian mafic complex in northern Xinjiang, i.e., copper-nickel sulfide deposit, vanadic titanomagnetite deposit, magnetite (-cobalt) deposit and Cu-Ni-VTiFe composite deposit. The deposits are distributed spanning tectonic units with close and consecutive metallogenic ages. A transitional deposit type can occur among the end-member deposits. Trace elements of host rocks show that they can derive from similar source area. Hence, they constitute a particular metallogenic series related to a mafic-ultramafic complex that is also a symbol series of the post-collisional stage of the Central Asia Metallogenic Province (CAMP). The metallogenic ages of the series are between 260 Ma and 300 Ma throughout the Permian. Unlike mineralization from a mantle plume, the metallogenic period of this series spans at least 40 Ma. Compared with related deposits of the Emeishan mantle plume, the North Xinjiang series has a similar ore-forming element assemblage but has preferably developed Cu-Ni sulfide deposits rather than vanadic titanomagnetite deposits. In concomitance with this series, North Xinjiang area has developed a set of syntectonic Au-Cu-Mo metallogenic series related to a felsic volcanic-intrusive complex, which might indicate that there is no direct relationship with mantle plume activity. From early to late, i.e., the sequence of copper-nickel sulfide to magnetite (-cobalt) to vanadic titanomagnetite deposit, the host rock series evolves from mafic-ultramafic and tholeiite series to mafic and alkalic series, the ΣREE content tends to increase with increasing of REE fractionation, and some of the trace elements (particularly LIL) also show an increasing tendency. The above evolutionary regularity possibly reflects a course where the magma source deepens and thermal interface moves down, energy gradually exhausts, and neo-continental crust forming in the post-collision stage tends to stabilize.

Abstract:Based on the survey data of five submarine seamount provinces (chains) in the Western Pacific, the distribution characteristics of cobalt-rich ferromanganese crust resources have been researched in this paper by using the relative reference data and applying the theories of hotspot and seafloor spreading. The main research results obtained are as follows: The Co-rich crust thickness in the study area is gradually increasing from east to west and from south to north having a negative correlation (r = ?0.59) with longitude and a positive correlation (r = 0.48) with latitude. The crust thickness varying along longitude and latitude is influenced by the hotspot and seafloor spreading. The oceanic crusts and seamounts in the northwest part of the study area are older, and the crust resources are superior to those in the southeast part. In the depth of <1500 m, 1500–2000 m, 2000–2500 m in the study area, the cobalt crust thickness is respectively 5.45 cm, 4.34 cm and 3.55 cm, and in the depth of 2500–3000 m and 3000–3500 m, it drops respectively to 2.84 cm and 3.37 cm. The Co-rich crust resources are mainly concentrated in the seamount summit margins and the upper flanks in the depth of <2500 m. There is a strong negative correlation (r = ?0.67) between the cobalt crust abundance and the slope of the seamount, 75 kg/m2 and 50 kg/m2 at the slopes of 0°–20° and 20°–34° respectively. Cobalt crusts are mainly distributed in the parts whose slopes are less than 20°. It is consistent with the fractal result that the slope threshold of cobalt crust distribution is 19°, and slopes over 20° are not conducive to the crust growth. The cobalt crusts of high grade are mainly enriched in the region within 150°E–140°W and 30°S–30°N in the Pacific, where there are about 587 seamounts at the depth of 3500–6000 m and over 30 Ma of the oceanic crusts. The perspective area rich in cobalt crust resources is about 41′104 km2 and the resource quantity is approximately 27 billion tons.

Abstract:Gold Headquarter of the CAPF has discovered the Yangshan super large-scale gold deposit in Gansu Province, which is a great breakthrough of gold exploration and prospecting in Western Qinling Mountains of China. The gold resources of this deposit achieved 308 tons with increasing potentials. Preliminary geological investigations indicate that the Yangshan gold deposit is located in the intra-continental collision orogenic belt; and the deposit was formed during the continent-continent collision orogenic processes. The geological characteristics of the deposit are similar to that of the typical Carlin-type gold deposits, while differences still exist. The ore-forming background is notably different from the Carlin gold deposit province in the United States; and the ore-forming fluids are similar with that of the orogenic-type gold deposit. Accordingly, the Yangshan gold deposit is a transitional type between the Carlin-type and the orogenic type gold deposits. At present, the Yangshan gold deposit is the largest Carlin and Carlin-like type gold deposit that is ever discovered in China. Researches on metallogeny, metallogenic model and ore-enrichment regularities of the Yangshan gold deposit are crucial to meet the pressing needs of the current geological investigation and ore exploration of the deposit.

Abstract:SEDEX-type lead-zinc deposits in the southern belt of the Xicheng Devonian basin, Gansu Province has been already identified. However, the sedimentary environment of the limestone and philite of the Xihanshui Group within which the lead-zinc deposits occur is littoral and shallow sea. This is different from those in the northern belt such as the Changba-Lijiagou lead-zinc deposits, which were formed in deep sea. The reef and bioclastic limestone are widespread in the southern belt. Particularly they are associated with lead-zinc ores and there are no striae and banding but massive or disseminated structures. It is discovered that the black chimney consists of sphalerite, ankerite, pyrite and galena, in which black, coarse and radial sphalerite occurs as irregularly veins or cylindricality with a width of 10-40 cm in the center, and it is surround by fine ankerite and minor celestite with ribbon structure. The immediate wall rock of the chimney, reef limestone, was unaltered and the outside reef and bioclastic limestone were intensively silicified. Those silicified reef and bioclastic limestone host disseminated lead-zinc ores of the Luoba and Bijiashan type. It is concluded that the exhalative system occurred in a shallow sea in the Givetian of the middle Devonian. Brine is boiled due to low pressure, and a great deal of lead and zinc was dispersed in the interface between the limestone and phyllite and formed a source bed. In the Triassic period, meta-hydrothermal fluids leached and extracted metals from the source bed, and then moved and mineralized in open space such as arches and inverse limbs of anticlines, and formed massive and vein ores such as the Jianyagou and Dengjiashan type deposits.

Abstract:The Yaogangxian tungsten deposit is located in the central part of the Nanling polymetallic metallogenic province. The orebodies occur as veins. Wolframite and molybdenite are the dominant ore minerals. Two samples were selected for molybdenite Re-Os dating in order to elucidate the timing of mineralization. Re-Os datings of molybdenite from quartz-wolframite veins and disseminated in granite yield ages of 153±7 Ma and 163.2±4.2 Ma respectively. The results indicate that the Yaogangxian tungsten deposit is the product of large-scale metallogenesis in the middle Yanshanian period in South China, and that the evolution from late magmatic to postmagmatic hypothermal mineralization occurred at about 10 Ma. The rhenium content of molybdenite in the Yaogangxian tungsten deposit suggests that the ore materials originated from the crust.

Abstract:Central Fujian Rift is another new and important volcanogenic massive sulfide Pb-Zn polymetallic metallogenetic belt. In order to find out the material genesis and mineralization period of Meixian-type Pb-Zn-Ag deposits, S and Pb isotope analysis and isotope geochronology of ores and wall rocks for five major deposits are discussed. It is concluded that the composition of sulfur isotope from sulfide ore vary slightly in different deposits and the mean value is close to zero with the d 34S ranging from ?3.5‰ to +5.6‰ averaging at +2.0‰, which indicates that the sulfur might originate from magma or possibly erupted directly from volcano or was leached from ore-hosted volcanic rock. The lead from ores in most deposits displays radioactive genesis character (206Pb/204Pb>18.140, 207Pb/204Pb>15.584, 208Pb/204Pb>38.569) and lead isotope values of ores are higher than those of wall rocks, which indicates that the lead was likely leached from the ore-hosted volcanic rocks. Based on isotope data, two significant Pb-Zn metallogenesis are delineated, which are Mid- and Late-Proterozoic sedimentary exhalative metallogenesis (The single zircon U-Pb, Sm-Nd isochronal and Ar-Ar dating ages of ore-hosted wall rocks are calculated to be among 933–1788 Ma.) and Yanshanian magmatic hydrothermal superimposed and alternated metallogenesis (intrusive SHRIMP zircon U-Pb and Rb-Sr isochronal ages between 127–154 Ma).

Abstract:The Xitieshan lead-zinc deposit is located at the northern margin of the Qaidam Basin, Qinghai Province, China, and had developed a complete marine sedimentary-exhalative system. Our preliminary study of ore-forming fluids shows that fluid inclusions in quartz from altered stockwork rocks that represent the pipe facies have a wide range of temperature and salinity. The intense fluid activities are characteristics of the pipe facies of the exhalative system. Fluid inclusions in carbonates near the unstratified ore bodies hosted in the thick-bedded marble which represents vent-proximal facies are large in size and have moderate to high temperatures. They represent unerupted sub-seafloor fluid activity. Fluids in altered stockwork rocks and carbonates have similar H2O-NaCl-CO2 system, both belonging to the sedimentary-exhalative system. The fluids migrate from the pipe facies to the unstratified ore bodies. Boiling of the fluids causes the separation of CO2 vapor and liquid H2O. When the fluids migrate into the unconsolidated thick-bedded marble, the escape of CO2, decreasing temperature and pressure as well as some involvement of seawater into the fluids result in the unmixing of fluids with high and low salinity and deposition of ore-forming materials. The two unmixed fluids were trapped in unconsolidated carbonates and the ore-forming materials were deposited in the unconsolidated carbonates to form the sedimentary-exhalative type unstratified ore bodies. The ore-forming temperature of unstratified ore bodies is up to high temperature indicating that there is a huge ore-forming potential in its deep.

Abstract:The Bainiuchang deposit in Yunnan Province, China, is located geographically between the Gejiu ore field and the Dulong ore field. In addition to the >7000 t Ag reserves, the deposit also boasts of large-scale Pb, Zn and Sn reserves with a lot of dispersed elements (In, Cd, Ge, Ga, etc.). We have determined systematically the Pb isotope composition of the deposit. The Pb isotope ratios of the ores that are of sea-floor exhalative sedimentary origin in the northwest of the mining district, are 206Pb/204Pb = 17.758?18.537, 207Pb/204Pb = 15.175?15.862 and 208Pb/204Pb = 37.289?39.424, while those of ores that are of magmatic hydrothermal superimposition origin in the southeast of the mining district, are 206Pb/204Pb = 17.264?18.359, 207Pb/204Pb = 14.843?15.683 and 208Pb/204Pb = 36.481?38.838, respectively. In terms of the Pb isotope composition of feldspar in magmatic rocks or magmatic whole-rock samples from the mining district, we have determined the Pb isotope composition and acquired the Pb isotope ratios as: 206Pb/204Pb = 18.224?18.700, 207Pb/204Pb = 15.595?15.797 and 208Pb/204Pb = 38.193?39.608. Then, in the light of the Pb isotope composition of metamorphic rock samples from the Proterozoic basement exposed in the Dulong ore field, we have determined the Pb isotope composition and obtained the isotope ratios as: 206Pb/204Pb = 18.434?19.119, 207Pb/204Pb = 15.644?15.693, and 208Pb/204Pb = 38.514?38.832. And the Pb isotope ratios of Cambrian sedimentary rocks, which are exposed in the Bainiuchang mining district, are 206Pb/204Pb = 18.307?19.206, 207Pb/204Pb = 15.622?15.809, and 208Pb/204Pb = 38.436?39.932. By comparing the two types of ores with respect to their Pb isotope compositions, it is indicated that lead in the Bainiuchang deposit was derived largely from the lower-crust granulite which is earlier than Neoproterozoic in age, but the Yanshanian magmatic hydrothermal fluids probably provided a part of ore-forming elements such as Sn for the ore blocks in the south of the mining district.

Abstract:A sulfide black smoker chimney exists in the Gaobanhe seabed exhalation massive sulfide deposit in the Xinglong-Kuancheng secondary fault basin of the Proterozoic Yanliao rift trough in Hebei Province, taking the shape of mounds, individually about 2–3 cm high. Abundant fossils of thermophilous bacteria and algae in perfect preservation are found in the ore surrounding the black smoker chimney. Scanning electron microscopy (SEM) and molecular biomarker studies on the microorganismal ore fabric show that the microorganism in the sulfide ore is in fact a sedimentary product of probiotic bacteria and algae. In the special food chain based on black smoker chimney at ancient seabed- thermophilous bacteria, the thermophilous bacteria and algae reproduce in large quantity. Intermittently erupting of fluid from the chimney creats conditions for formation of sulfide deposit. In the process of exhalation action of hot fluid, thermophilous bacteria and algae grow and reproduce around the sulfide black smoker chimney, absorbing mineralizing substances brought by the fluid. Massive sulfide deposits are formed in this process of absorption of seabed black smoker chimney exhalation-mineralizing fluid pulsation-thermophilous microorganism.

Abstract:Emplacement ages, geochemical characteristics and analysis of continental dynamics on gabbroic intrusions in Luodian County, Guizhou Province, have been discussed based on studies of isotopic chronology (the whole-rock Sm-Nd and Rb-Sr isochron methods), major elements, trace elements and PGE. Intrusive activities of the gabbroic intrusions in the study area took place during the Late Yanshanian Orogenic Movement (the Cretaceous Period), as indicated by the Sm-Nd isochron ages (t)=(99.6±4.5) (2σ) Ma and by the Rb-Sr isochron ages t=(97±1.6) (2σ) Ma. The gabbroic intrusions are attached to mafic rocks in cal-alkaline basaltic series. They occurred as dikes and might be formed under an extensional background of the continent. Differentiation of their magmatic crystallization resulted in obvious zonation of petrography. In the gabbroic intrusions of this study, large ion lithophile elements and LREE are enriched, and the chondrite-normalized REE distribution pattern is leftward inclined without anomalies of δCe or δEu, and there are high concentrations of PGE and ratios of Pd/Ir (averaging 4.21). All of these imply that their source areas may be basaltic magma in the upper mantle with high-level partial melting, derived from EM1-type enriched mantle. It is different from Emeishan basalt, which may be related to the upper mantle at low-grade partial melting. Emplacement mechanism of the gabbroic intrusions in this study may suppose to be asthenosphere upheaving as an isolated hot wave in the presence of mantle fluid, resulting in basaltic magma intruded into the continental crust as a diapiric intrusion. Therefore, uplifting of faulting-block and extensional deformation could take place in the shallow part of the continental crust while vertical amassing and accretion of magmatic materials in the deep part of the continental crust. These special processes could supposed to be a special background of continental dynamics for this large-scale epithermal metallogenic domain, such as Au, As, Sb and Hg deposits, and vertical uplifting of the Yunnan-Guizhou Plateau in the Cretaceous Period.

Abstract:This study focuses on experiments of Au and Cu dissolved in vapor phase in hydrothermal fluids. Experiments prove that Au and Cu can re-distribute in vapor phase and liquid phase during separation of Au- and Cu-bearing supercritical fluids to vapor and liquid phases. These experimental results can illustrate some ore geneses, where boiling phenomena of ore fluids were found. Au- and Cu-bearing NaHCO3-HCl solutions were heated up to more than 350°C in the main vessel, and then passed through a phase separator in a temperature range from 250°C to 300°C, separated into vapor and liquid phases. We collected and analyzed the liquid and vapor samples separately, and found that Au and Cu dissolved and distributed in vapor phase. In some cases, the concentrations of Au and Cu in vapor are higher than those in liquid phase. Those experiments are used to interpret field observations of fluid inclusion data of some Au and Cu deposits, and demonstrate that some Au and Cu ore deposits are derived from metals transportation in vapor phase.

Abstract:Fifteen samples from three study areas (the Bancun diabase dykes, the Bali hornblende gabbro dykes, the Linzifen gabbro-diabase dykes) were collected and analyzed for selenium (Se), sulfur (S), copper (Cu), major and trace elements. In general, Se, S and Cu do positively correlate to each other. The concentration of S and Se and the S/Se ratio are higher than the corresponding value of primitive mantle (PM), and the Cu/S ratio falls in a narrow range (0.04–0.29), which is consistent with that of primitive mantle (0.05–0.20). The Bancun diabase dykes and the Bali hornblende gabbro dykes were located in an intraplate environment during the Late Mesozoic. Oceanic subduction was closely related to magmatic activities. The magmatic activities play an important role in the transportation mechanism of Se and S. Because those two groups were closer to fault zones, which may affect the distribution of S and Se and other elements. In the two groups, no crustal contamination was observed, indicating that all analyzed elements may come from enriched mantle metasomtism associated with slab subduction. However, the Linzifen gabbro-diabase dykes were located in an intraplate rift environment, and its invading age is older than the other two groups, the primitive magma comes from mantle, and there is an anomalous relation between S, Se and Al2O3, (La/Sm)N, and all these factors could result in higher S and Se concentration.

Abstract:A series of element concentrations sampled from four drill cores with a length about 1000 m into different skarn-type deposits were selected from the Shizishan orefield, central Tongling, southeastern part of Anhui Province. Using the multifractal method, the distribution and migration characteristics of the major and trace elements are analyzed. The multifractal spectrum of the major elements is left-skewed, whereas the spectrum of the trace elements is right-skewed, which shows that in the process of skarn formation, the trace elements were enriched only locally, and major elements transported within a much larger range. The correlation coefficients of the multifractal parameters Δa (width of the multifractal spectrum) of the four drill cores are relatively low, but the correlation coefficients of the multifractal parameters R (spectrum symmetry parameter) and Δf are relatively higher, indicating that although the non-homogeneous intensity of the distribution of elements is inconsistent, their spatial accumulation patterns are almost the same during the ore-forming process. The statistics of the multifractal parameters of various elements in the different locations show that the ore-forming processes and element migration pattern in the Shizishan orefield are consistent, and that the migrations of trace elements and major elements exhibit some differences.

Abstract:The new type hot water sedimentary rock — magnetite-fluorite rock occurs as quasi-layers in flat parts of contact zones between rock body and strata in Bamianshan of Changshan County, Zhejiang Province, China. The main mineral assemblage is fluorite+magnetite+cassiterite. The rock shows typical laminated structure and obvious mosaic texture. Its formation temperature is between 123°C–160°C, averaging at 142°C. The major chemical composition of the rock includes CaF2, SiO2, Al2O3, FeO, and Fe2O3; the high-content microelement association includes W, Sn, Be, Rb, Sr, S, and Cl; and the total content of REE is low (ΣREE between 35.34×10?6–38.35×10?6), showing LREE enrichment type of distribution pattern. Diagenesis: driven by the tectonic stress, the formation water heated in the deep strata had moved along the fissures or fractures in strata and had extracted components from the strata on the way, and finally stagnated in the flat parts of contact zones between rock body and strata. With drop in temperature, magnetite and fluorite were separated from the hot water and precipitated alternately, forming this hot water sedimentary rock with new type mineralogical composition, typical laminated structure, obvious mosaic texture and sub-horizontal occurrence. The characteristics of the new type mineralogical composition, sedimentary tectonic environment and chemical composition are different from that of the well-known traditional hydrothermal sedimentary rocks.

Abstract:A series of batch-type experiments with acetate acid as the primary substrate were performed using enrichment cultures developed from the anaerobic sludge to investigate the effect of acetate acid on tetrachloroethylene (PCE) biodegradation. Experimental results indicated that acetate acid was an efficient electron donor in affecting the biotransformability of PCE. Trichloroethylene (TCE) was the primary dehalogenation product, and small amounts of dichloroethylenes (DCEs) were also detected. No significant further DCEs degradation was detected. PCE degradation rate in the experiment was 36.6 times faster than background rate in natural groundwater.

Abstract:We used illite and chlorite crystallinities, index minerals, mineral assemblages, polytype and domain size of white mica, electron microprobe analysis (EMPA), b0 geobarometer and chlorite geothermometer to quantify the diagenetic and metamorphic overprint on the Triassic flysch formations in the Songpan-Garzê orogen along profile Zoigê-Lushan, northwest Sichuan. Two anchizones, two epizones, one diagenetic zone and a transition belt in-between them are defined on the basis of the obtained data. Illite crystallinity correlates strongly with the best mean domain size of mica and moderately with chlorite crystallinity. 2M1 white mica polytype are observed within the epizone whilst 2M1 and 1M polytypes occur in the anchizone and diagenetic zone. Epizonal metamorphism reached maximum temperatures of 370oC±21oC at low-to intermediate pressure conditions. Clay minerals underwent Ostwald ripening during metamorphism. Rocks from both sides of the Longmenshan fault reveal contrasting degrees of metamorphic overprint: on the northwest side of the Longmenshan fault, epimetamorphic conditions contrast with diagenetic rocks on the southeast side.