Isotopic Geochemistry of Cadmium: A Review

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Isotopic Geochemistry of Cadmium: A Review
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                        ZHU ChuanweiZHU Chuanwei
1 State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China;
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WEN HanjieWEN Hanjie
1 State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
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ZHANG YuxuZHANG Yuxu
1 State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
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LIU YizhangLIU Yizhang
2 State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
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WEI RongfeiWEI Rongfei
3 Center for Environment Remediation, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101, China
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Fund Project:This project was financially supported by National Natural Science Foundation of China (Grant Nos. 41503011 40930425, 41573007, 41173026), 973 Program (2014Cb440904), CAS/SAFEA International Partnership Program for Creative Research Teams (KZZD-EW-TZ-20), the 12th Five-Year Plan project of State Key Laboratory of Ore-deposit Geochemistry, Chinese Academy of Sciences (SKLODG-ZY125-07).

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Abstract:

Cadmium (Cd) is a scarce, but not an extremely rare element in the Earth’s crust (crustal average: 0.2 ppm Cd). Geochemically, Cd exhibits thiophile, lithophile, and volatile behavior in different geologic processes. Biologically, it is a nutrient-like element that is closely related to P and Zn and is toxic element to organisms. Presently, Cd isotopes have been successfully utilized to trace Cd sources and nutrient cycling in marine systems in addition to unearthing other geochemical processes. Using published studies and our recent work, this survey summarizes the chemical preparation and mass spectrometry of Cd isotopes. It also reviews Cd isotopic compositions and fractionation mechanisms in nature as well as experiments.

Key words:Cadmium, non-traditional stable isotopes, stable isotopic fractionation, geochemical tracer

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ZHU Chuanwei, WEN Hanjie, ZHANG Yuxu, LIU Yizhang, WEI Rongfei.2015. Isotopic Geochemistry of Cadmium: A Review[J]. Acta Geologica Sinica(),89(6):2048-2057

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Received:September 24,2015
Revised:October 25,2015
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Online: December 16,2015
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