Cenozoic potassic–ultrapotassic igneous rocks are widespread in the southeastern Tibetan Plateau. Their petrogenesis and magmatic processes remain subject to debate in spite of numerous publications. Almost all of the Cenozoic extrusive and intrusive rocks in the Yao’an area, western Yunnan Province, SW China, are geochemically shoshonitic, collectively termed here the Yao’an Shoshonitic Complex (YSC). The YSC is located in the (south)easternmost part of the ENE?WSW-trending, ~550 km-long and ~250 km-wide Cenozoic magmatic zone; the latter separates the orthogonal and oblique collision belts of the India–Eurasia collision orogen. Previously published geochronological and thermochronological data revealed that the rocks of the YSC were emplaced over a short timespan of 34–32 Ma. This and our new data suggest that the primary magma of the YSC likely was formed by partial melting of ancient continental lithospheric mantle beneath the Yangtze Block. This part of the continental lithospheric mantle had likely not been modified by any oceanic subduction. Fractionation crystallization of an Mg- and Ca-bearing mineral and Ti-Fe oxides during the magmatic evolution probably account for the variable lithologies of the YSC.