Complex hydrocarbon reservoirs developed widely in the superimposed basins of China formed from multiple structural alterations, reformation and destruction of hydrocarbon reservoirs formed at early stages. They are characterized currently by trap adjustment, component variation, phase conversion, and scale reformation. This is significant for guiding current hydrocarbon exploration by revealing evolution mechanisms after hydrocarbon reservoir formation and for predicting remaining potential resources. Based on the analysis of a number of complex hydrocarbon reservoirs, there are four geologic features controlling the degree of destruction of hydrocarbon reservoirs formed at early stages: tectonic event intensity, frequency, time and caprock sealing for oil and gas during tectonic evolution. Research shows that the larger the tectonic event intensity, the more frequent the tectonic event, the later the last tectonic event, the weaker the caprock sealing for oil and gas, and the greater the volume of destroyed hydrocarbons in the early stages. Based on research on the main controlling factors of hydrocarbon reservoir destruction mechanisms, a geological model of tectonic superimposition and a mathematical model evaluating potential remaining complex hydrocarbon reservoirs have been established. The predication method and technical procedures were applied in the Tazhong area of Tarim Basin, where four stages of hydrocarbon accumulation and three stages of hydrocarbon alteration occurred. Geohistorical hydrocarbon accumulation reached 3.184 billion tons, of which 1.271 billion tons were destroyed. The total volume of remaining resources available for exploration is ~1.9 billion tons.