Discovery and Significance of High CH4 Primary Fluid Inclusions in Reservoir Volcanic Rocks of the Songliao Basin, NE China
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P618.13

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This research received financial support from M0ST (Grant No. 2006CB701403), NSF (Grant No. 40372066) and from SRFDP (Grant No. 20030183042) of China and was attained with the assistance of the Alexand von Humboldt-Stiftung, Germany. Claire Ramboz and two other anonymous reviewers are kindly thanked for their constructive comments and detailed suggestions to improve the manuscript.


Discovery and Significance of High CH4 Primary Fluid Inclusions in Reservoir Volcanic Rocks of the Songliao Basin, NE China
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    摘要:

    Comparing compositions of the fluid inclusions in volcanic rocks to the contents and isotopes of the gases in corresponding volcanic reservoirs using microthermometry, Raman microspectroscopy and mass spectrum analysis, we found that: (1) up to 82 mole% methane exists in the primary inclusions hosted in the reservoir volcanic rocks; (2) high CH4 inclusions recognized in the volcanic rocks correspond to CH4-bcaring CO2 reservoirs that are rich in helium and with a high ^3He/^4He ratio and which show reversed order of 813C in alkane; (3) in gas reservoirs of such abiotic methane (〉80%) and a mix of CH4 and CO2, the enclosed content of CH4 in the volcanic inclusions is usually below 42 mole%, and the reversed order of δ^13C in alkane is sometimes irregular in the corresponding gas pools; (4) a glassy inclusion with a homogeneous temperature over 900℃ also contains a small portion of CH4 although predominantly CO2. This affinity between gas pool and content of inclusion in the same volcanic reservoirs demonstrates that magma-originated gases, both CH4 and CO2, have contributed significantly to the corresponding gas pools and that the assumed hydrocarbon budget of the bulk earth might be much larger than conventionally supposed.

    Abstract:

    Comparing compositions of the fluid inclusions in volcanic rocks to the contents and isotopes of the gases in corresponding volcanic reservoirs using microthermometry, Raman microspectroscopy and mass spectrum analysis, we found that: (1) up to 82 mole% methane exists in the primary inclusions hosted in the reservoir volcanic rocks; (2) high CH4 inclusions recognized in the volcanic rocks correspond to CH4-bcaring CO2 reservoirs that are rich in helium and with a high ^3He/^4He ratio and which show reversed order of 813C in alkane; (3) in gas reservoirs of such abiotic methane (〉80%) and a mix of CH4 and CO2, the enclosed content of CH4 in the volcanic inclusions is usually below 42 mole%, and the reversed order of δ^13C in alkane is sometimes irregular in the corresponding gas pools; (4) a glassy inclusion with a homogeneous temperature over 900℃ also contains a small portion of CH4 although predominantly CO2. This affinity between gas pool and content of inclusion in the same volcanic reservoirs demonstrates that magma-originated gases, both CH4 and CO2, have contributed significantly to the corresponding gas pools and that the assumed hydrocarbon budget of the bulk earth might be much larger than conventionally supposed.

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WANG Pujun HOU Qijun WANG Keyong CHEN Shumin CHENG Rihui LIU Wanzhu LI Quanlin.2007. Discovery and Significance of High CH4 Primary Fluid Inclusions in Reservoir Volcanic Rocks of the Songliao Basin, NE China[J]. ACTA GEOLOGICA SINICA(English edition),81(1):113~120

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  • 收稿日期:2005-12-22
  • 最后修改日期:2006-05-29
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