Through lead isotope geochemical mapping in the Yunnan-Guizhou area geochemical steep zones (GSZ) have been established, which clearly reveal the junction relationship of the Cathaysian, Yangtze and Indo-China plates. GSZ are closey related to gravity Mono gradient zones and lithospheric thickness. The GSZ between the Yangtze and Cathaysian plates is consistent with the Shizong-Mile tectonic belt, where island arc basalts are well developed. The Yangtze-Indo-China GSZ is parallel to the Jingdong-Mojiang volcanic belt in rift-island arc environments. The evidence of geology, geophysics and geochemistry all indicates that Cathaysia was subducted towards the Yangtze plate and that the Yangtze plate was underthrust beneath the Indo-China, which took place from the Early Carboniferous to the Early Triassic.