川西甲基卡伟晶岩石英微量元素特征及高纯石英原料潜力
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本文为四川省科技厅揭榜挂帅科技计划项目(编号:2025YFNZH003),自然资源部“新一轮找矿突破战略行动科技支撑项目”(编号:ZKKJ202412),四川省自然科学基金资助项目(编号:24NSFSC0093)和四川省自然资源厅重大科技项目(编号:ZDKJ-2024-003)的成果


Quartz trace-element geochemistry in pegmatites of the west Sichuan Jiajika and its potential as high-purity raw material
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    摘要:

    川西甲基卡矿区是目前我国已发现的规模最大的以锂为主的花岗伟晶岩型稀有金属矿区,广泛分布有不同类型的伟晶岩脉。花岗伟晶岩型高纯石英原料是目前全球生产高纯石英最重要的原料。石英是伟晶岩中主要的造岩矿物,其微量元素组成、含量是评价伟晶岩型高纯石英硅质原料的关键指标,前人对矿区内伟晶岩石英微量元素组成的研究基本没有涉及。笔者等以矿区不同类型伟晶岩为研究对象,采用微区LA-ICP-MS 方法分析了石英微量元素组成及含量,对其作为高纯石英原料的潜力进行了评价,指出寻找伟晶岩型高纯石英硅质原料的方向,提出了甲基卡稀有金属矿产开发中对石英资源综合利用的建议。结果表明,不同类型伟晶岩脉石英中Al、Li等微量元素含量较高,Li含量为59.6×10-6~181×10-6,Al含量254×10-6~672×10-6,13个主要的杂质元素含量∑13=340×10-6~1005×10-6,除1件样品外,石英SiO2≥99.9%(3N),仅达到了低端高纯石英或高纯级别石英原料标准。在5种类型的伟晶岩中,锂辉石型伟晶岩是目前开采的工业矿床类型,石英中的杂质元素相对较低,SiO2含量>99.95%(3N5),在稀有金矿资源开发中应高度重视石英的高效利用。川西地区稀有金属矿区岩浆结晶分异形成的伟晶岩Al、Li等杂质元素含量较高,难以作为优质高纯石英硅质原料,未来寻找优质伟晶岩型高纯石英原料应着眼于丹巴地区变质成因的白云母花岗伟晶岩。

    Abstract:

    The Jiajika rare-metal mining area is currently the largest lithium-dominated granite-pegmatite type rare-metal field discovered in China, hosting a wide range of pegmatite dike types. Granite-pegmatite type high-purity quartz (HPQ) serves as one of the most important raw materials for global HPQ production. Quartz, as the principal rock-forming mineral in pegmatites, has trace-element compositions and concentrations that are critical indicators for evaluating its potential as a granite-pegmatite type HPQ siliceous raw material. However, previous studies have scarcely addressed the trace-element geochemistry of quartz in this field. Methods: In this study, quartz from representative pegmatite types was analyzed using in-situ LA-ICP-MS to determine trace-element concentrations and compositions, allowing evaluation of its potential as high-purity siliceous feedstock, identification of promising targets for HPQ exploration, and recommendations for the integrated utilization of quartz resources during rare-metal development. Results: The results indicate that quartz in different pegmatite types contains relatively high concentrations of trace elements such as Al and Li (Li = 59.6×10-6~181×10-6; Al = 254×10-6~672×10-6), with the total concentration of 13 major impurity elements (∑13) ranging from 340×10-6to1005×10-6. Except for one sample, quartz exhibits a SiO2 content ≥ 99.9% (3N), corresponding to the lower limit of HPQ or high-purity quartz feedstock standards. Among the five pegmatite types, the spodumene-type pegmatite, currently exploited as an industrial deposit, is characterized by relatively low impurity concentrations in its quartz, with SiO2 content exceeding 99.95% (3N5). Consequently, the efficient utilization of this quartz should be given high priority during rare-metal resource development. Conclusions: Pegmatites formed through magmatic differentiation in the Western Sichuan rare-metal fields generally display elevated Al and Li concentrations, reducing their suitability as high-quality HPQ siliceous feedstock. Therefore, future exploration for high-grade granite-pegmatite type HPQ should focus on muscovite granite-pegmatites of metamorphic origin in the Danba area.

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郝雪峰,唐屹,梁斌,杨振,潘蒙,王永洪,李琴友,付小方.2026.川西甲基卡伟晶岩石英微量元素特征及高纯石英原料潜力[J].地质论评,(1):2026010020,[DOI].
HAO Xuefeng, TANG Yi, LIANG Bin, YANG Zhen, PAN Meng, WANG Yonghong, LI Qinyou, FU Xiaofang.2026. Quartz trace-element geochemistry in pegmatites of the west Sichuan Jiajika and its potential as high-purity raw material[J]. Geological Review,(1):2026010020.

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  • 收稿日期:2025-09-14
  • 最后修改日期:2025-12-20
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  • 在线发布日期: 2026-02-12
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