北喜马拉雅马拉山二云母花岗岩的石英提纯实验和找矿前景
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本文为国家重点研发计划课题(编号:2024YFC2910102),国家科技重大专项(编号: 2025ZD1008801; 2025ZD1006300),国家自然科学基金—地质联合基金(编号:U2444206)的成果


Evaluation of quartz purification and potential for high- purity quartz mineralization in Malashan two- mica granite, north Himalayan
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    摘要:

    高纯石英是半导体、光伏等战略性新兴产业的关键材料,其高端原料供应存在风险。北喜马拉雅带发育有全球规模最大的新生代淡色花岗岩带,具备形成白岗岩型高纯石英矿的理论潜力,但此前缺乏系统的矿物学和提纯实验验证。本研究旨在通过精细表征和系统实验,阐明马拉山二云母花岗岩石英的杂质赋存状态和提纯可行性,并评价其资源潜力。选取马拉山二云母花岗岩中的石英为研究对象,综合运用偏光显微镜、扫描电镜(SEM)和拉曼光谱进行矿物学和包裹体分析。采用“破碎—浮选—煅烧水淬—混合酸浸—氯化焙烧”全流程提纯工艺,并利用电感耦合等离子体质谱仪(ICP- MS)对提纯前后石英砂中15种关键杂质元素进行定量分析。结果表明:(1)石英原生流体包裹体含量极低,且以次生包裹体为主,指示其母岩浆演化停滞在流体大量出溶阶段之前;(2)经系统提纯,石英SiO2纯度(即质量分数)从99. 8969%提升至99. 9942%(4N4级),浮选和酸浸有效去除了共生长石、云母等矿物杂质,氯化焙烧显著降低了晶格中Li、Na含量;(3)最终产品中Al (43. 3×10-6)、Ti (8. 03×10-6)、Li (1. 69×10-6) 为主要残留杂质,以类质同象形式赋存于石英晶格,目前经济技术条件下,难以通过常规工艺彻底去除。马拉山二云母花岗岩石英具备形成白岗岩型高纯石英的矿物学基础。北喜马拉雅带内“高分异程度、低流体出溶、变质变形改造、不含金属矿产”的淡色花岗岩是寻找该类型高纯石英资源的有利目标区,为我国突破高端石英资源瓶颈提供了新的找矿方向。

    Abstract:

    High- purity quartz is a critical raw material for strategic emerging industries such as semiconductors and photovoltaics, yet the supply of its high- grade feedstock remains at risk. The North Himalayan Belt hosts the world’s largest Cenozoic leucogranite belt, which holds theoretical potential for hosting alaskite—granite- type high- purity quartz deposits. However, systematic mineralogical studies and experimental validation of purification methods have been lacking. This study aims to clarify the mode of occurrence of impurities and the purification feasibility of quartz from the Malashan two- mica granite through detailed characterization and systematic experiments, and to evaluate its resource potential.Methods: Quartz from the Malashan two- mica granite was selected for investigation. Analytical techniques including polarized light microscopy, scanning electron microscopy (SEM), and Raman spectroscopy were employed for mineralogical and fluid inclusion analysis. A comprehensive purification process—“crushing, flotation, calcination—water quenching, mixed- acid leaching, and chlorination roasting”—was applied. The concentrations of 15 key impurity elements in quartz sand before and after purification were quantitatively analyzed using ICP- MS.Results: (1) The primary fluid inclusion content in quartz is extremely low, with secondary inclusions dominating, suggesting that parental magma evolution stagnated prior to extensive fluid exsolution; (2) systematic purification increased quartz SiO2 purity from 99.8969% to 99.9942% (4N4 grade). Flotation and acid leaching effectively removed mineral inclusions such as coexisting feldspar and mica, while chlorination roasting significantly reduced lattice- bound Li and Na; (3) the main residual impurities in the final product—Al (43.3 ×10-6), Ti (8.03 ×10-6), and Li (1.69 ×10-6)—are present in the quartz lattice via isomorphism and are difficult to remove completely using conventional processes under current economic and technical conditions.Conclusions: The quartz from the Malashan two- mica granite possesses the mineralogical foundation for forming alaskite—granite- type high- purity quartz. This study confirms that leucogranites within the North Himalayan Belt characterized by "high differentiation, low fluid exsolution, metamorphic—deformational overprinting, and absence of metallic mineralization" represent favorable targets for exploring this type of high- purity quartz resource. The findings provide a new prospecting direction for China to overcome bottlenecks in the supply of high- end quartz resources.

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刘洪,李文昌,李光明,侯林,李萱知,付建刚,毛星星,樊博,郭伟康.2026.北喜马拉雅马拉山二云母花岗岩的石英提纯实验和找矿前景[J].地质论评,(1):2026010015,[DOI].
LIU Hong, LI Wenchang, LI Guangming, HOU Lin, LI Xuanzhi, FU Jiangang, MAO Xingxing, FAN Bo, GUO Weikang.2026. Evaluation of quartz purification and potential for high- purity quartz mineralization in Malashan two- mica granite, north Himalayan[J]. Geological Review,(1):2026010015.

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  • 收稿日期:2025-11-10
  • 最后修改日期:2026-01-20
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  • 在线发布日期: 2026-02-12
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