云南永善水竹地区宣威组底部稀土元素赋存状态研究
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本文为地质调查项目“滇东—黔西黄葛树等4幅1∶5万矿产地质调查”(编号:DD20220967),“云南乌蒙山苞谷脑等3幅1∶5万矿产地质调查”(编号:DD20240207104)的成果


Study on theoccurrence state of rare earth elements at the bottom of the Xuanwei Formation in the Shuizhu area, Yongshan, Yunnan
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    摘要:

    本文采用基本化学分析、X射线衍射分析、扫描电子显微镜分析、稀土浸出实验等多种岩矿测试技术手段,对云南昭通永善莲峰地区古陆相沉积型稀土矿进行详尽的矿物学研究。分析结果表明,稀土氧化物总量平均质量分数为0. 12%~0. 21%,单样最高为0. 23%,轻重稀土比值在1. 55~2. 88之间,具有以轻稀土为主的特点,轻稀土占稀土总量的61%~73%。矿物组成以黏土矿物为主,含量合计约75%,其中主要为高岭石(含量45%),其次为蒙脱石(含量36%)、绿泥石(含量19%)。其他矿物含量微少,含有稀土独立矿物极少。通过浸出试验和测定,其离子吸附相占稀土总量的0. 94%~3. 86%,呈离子相的稀土含量较少,研究结果表明,样品中的稀土元素可能以富稀土的纳米矿物颗粒赋存于高岭石等黏土矿物中。

    Abstract:

    This study intends to investigate the occurrence states of rare earth elements (REEs) in the paleo- terrigenous sedimentary rare earth deposits at the bottom of the Xuanwei Formation in the Shuizhu area, northeastern Yunnan, within the contiguous region of Sichuan, Yunnan and Guizhou. The research is expected to provide crucial clues and a scientific basis for mineral exploration and comprehensive resource utilization of the same type of sedimentary rare earth deposits in the study area and across China.Methods: In this paper, a variety of rock and mineral testing techniques including basic chemical analysis, X- ray diffraction (XRD) analysis, scanning electron microscopy (SEM) analysis, and rare earth leaching experiments were employed to conduct an in- depth mineralogical study on the paleo- continental sedimentary rare earth deposits in the Lianfeng area of Yongshan County, Zhaotong City, Yunnan Province.Results: The analysis results show that the average grade of total rare earth oxides (TREO) ranges from 0.12% to 0.21%, with the maximum content of a single sample reaching 0.23%. The ratio of light rare earths to heavy rare earths is between 1.55 and 2.88, indicating a light- rare- earth- dominated characteristic, where light rare earths account for 61%~73% of the total rare earth content. Mineralogically, the ore is dominated by clay minerals with a total content of approximately 75%, among which kaolinite is the predominant component (45%), followed by montmorillonite (36%) and chlorite (19%). The contents of other minerals are trace, and independent rare earth minerals are extremely scarce. Leaching tests and measurements reveal that the ion- adsorbed phase accounts for only 0.94%–3.86% of the total rare earths, suggesting a relatively low content of ion- exchangeable rare earths. The results indicate that the rare earth elements in the samples are likely to occur as rare- earth- enriched nanomineral particles hosted within clay minerals such as kaolinite.

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王东晖,吴亮,李德宗,肖长源,张浩,于一帆,李致伟,柳勇,李明,何松.2026.云南永善水竹地区宣威组底部稀土元素赋存状态研究[J].地质论评,72(1):2026010006,[DOI].
WANG Donghui, WU Liang, LI Dezong, XIAO Changyuan, ZHANG Hao, YU Yifan, LI Zhiwei, LIU Yong, LI Ming, HE Song.2026. Study on theoccurrence state of rare earth elements at the bottom of the Xuanwei Formation in the Shuizhu area, Yongshan, Yunnan[J]. Geological Review,72(1):2026010006.

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  • 收稿日期:2025-08-05
  • 最后修改日期:2025-12-24
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  • 在线发布日期: 2026-01-19
  • 出版日期: 2026-01-15