浙东南沿海龙港地区地下水化学特征及成因
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本文为浙江省地质专项资金“温州龙港市城市地质调查示范项目”(项目编号:[省资]2022008)的成果


Hydrochemical characteristics and formation mechanisms of groundwater in coastal Longgang area,southeastern Zhejiang
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    摘要:

    浙东南沿海龙港地区属滨海平原地貌,受古海侵咸化和人类活动影响,地下水渗流场演化过程较为复杂。为了研究浙东南沿海龙港地区地下水化学特征及演化规律,采集区内地表水、潜水、第Ⅰ、Ⅱ承压水水样43组,并结合4眼监测井水样及历史水样资料综合分析的基础上,综合运用多元统计分析、水化学图、离子比例系数、饱和指数和反向水文地球化学模拟等方法对该地区水化学时空演化特征进行分析,并探讨水质成因。结果表明:①研究区潜水水化学类型以Cl-·HCO-3—Na+、HCO-3·Cl-—Ca2+·Na+型为主;第Ⅰ承压水为Cl-—Na+型;第Ⅱ承压水以HCO-3·Cl-—Na+型为主。②研究区水体环境总体呈中—弱碱性,水体阳离子平均浓度由大到小依次为Na+>Ca2+>Mg2+>K+,阴离子浓度由大到小为Cl->HCO-3>SO2-4。③研究区内地表水和潜水(民用井)主要受岩石风化溶解作用控制;第Ⅱ承压水和少数潜水受到蒸发浓缩和岩石风化综合作用的共同影响;第Ⅰ承压水和多数潜水受蒸发作用明显。④研究区地下水化学组分主要为硅酸盐、岩盐的溶解,方解石和白云石的溶解或沉淀,阳离子交替吸附后形成。研究结果对浙东南沿海龙港地区地下水可持续开发利用具有重要指导意义。

    Abstract:

    The Longgang area, located in the coastal plain of southeastern Zhejiang, has a complex groundwater seepage field evolution due to historical seawater intrusion and anthropogenic impacts. This study examines its groundwater hydrochemical characteristics and evolution trends.Methods:The study collected a total of 43 water samples (surface water, phreatic water, confined aquifers Ⅰ and Ⅱ) in the study area. Combined with the data from four monitoring wells and historical water samples for comprehensive analysis. Multiple analytical methods were employed—including multivariate statistical analysis, hydrochemical diagrams, ionic ratios, saturation indices, and inverse hydrogeochemical modeling to investigate the spatiotemporal evolution characteristics of hydrochemistry in the region and elucidate the formation mechanisms of water quality.Results: ① Hydrochemical types of the study area: Phreatic water are dominated by Cl-·HCO-3—Na+ and HCO-3·Cl-—Ca2+·Na+ types; Confined groundwater I are Cl-—Na+ type; Confined groundwater II are mainly HCO-3·Cl-—Na+ type. ② The aquatic environment of the study area is generally weakly to moderately alkaline, Cation abundance (avg.): Na+>Ca2+>Mg2+>K+, Anion abundance (avg.): Cl->HCO-3>SO2-4. ③ Surface water and phreatic water(domestic well) Primarily controlled by rock weathering and dissolution; Confined groundwater(II) and some phreatic water influenced by combined evaporative concentration and rock weathering; Confined groundwater(I) and most phreatic water significantly affected by evaporation. ④ Major groundwater components result from: dissolution of silicates and halite (rock salt), dissolution/precipitation of calcite and dolomite, formation via cation exchange adsorption.Conclusions: The findings provide significant guidance for the sustainable development and utilization of groundwater resources in the Longgang coastal area of southeastern Zhejiang.

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曾丽,叶文荣,黄冀,袁静,许鹏飞,张育志,李梦碧.2025.浙东南沿海龙港地区地下水化学特征及成因[J].地质论评,71(4):2025040013,[DOI].
ZENG Li, YE Wenrong, HUANG Ji, YUAN Jing, XU Pengfei, ZHANG Yuzhi, LI Mengbi.2025. Hydrochemical characteristics and formation mechanisms of groundwater in coastal Longgang area,southeastern Zhejiang[J]. Geological Review,71(4):2025040013.

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  • 收稿日期:2025-05-24
  • 最后修改日期:2025-08-07
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  • 在线发布日期: 2025-08-19
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