滇中地区龙川江流域农田土壤重金属风险评价及来源解析
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1.中国地质调查局昆明自然资源综合调查中心;2.自然资源部自然生态系统碳汇工程技术创新中心

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中国地质调查局滇中楚雄地区土地质量地球化学调查项目(编号:ZD20220210)


Risk Assessment and Source Apportionment of Heavy Metals in Farmland Soils of the Longchuan River Basin, Central Yunnan
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1.Kunming General Survey of Natural Resources Center,China Geological Survey,Kunming;2.Technology Innovation Center for Natural Ecosystem Carbon Sink,Ministry of Natural Resources,Kunming

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    摘要:

    为掌握滇中地区龙川江流域农田土壤中重金属的分布状况,选取云南省楚雄市某农田集中区为研究对象,系统采集0~20 cm的表层土壤样品,分析土壤 pH 值以及 8 种重金属含量(As、Cd、Cr、Cu、Hg、Ni、Pb、Zn)。以农用地土壤污染风险筛选值为评价标准,采用内梅罗综合污染指数法和潜在生态危害指数法评估重金属污染风险,识别重金属污染物的主要来源。结果表明:研究区内土壤环境质量总体表现良好,pH平均值为6.78,呈中性。除龙川江两岸局部存在Cd含量超标外,土壤重金属污染风险总体较低。与云南省土壤背景值相比,As、Pb、Hg、Zn含量较低,处于贫化状态;Cr、Ni、Cu 含量与背景值基本持平;Cd呈相对富集的趋势。内梅罗综合污染指数均值为0.616,综合潜在生态风险指数均值为32.54,表明全区土壤重金属总体危害程度较低,但需警惕Cd的局部生态风险。源解析表明,土壤重金属首要来源为成土母质风化(自然源,贡献率29.65%),其次为大气沉降(23.33%)、农业活动与河流沉积混合源(17.75%)、农业活动源(17.54%)及与矿业活动相关的矿化地层源(11.74%)。

    Abstract:

    Objectives:This study examines the distribution of heavy metals in the agricultural soil of the Longchuan River basin, situated in central Yunnan. Methods:A concentrated farmland area in Chuxiong City, Yunnan Province was selected as the study site, and topsoil samples (0–20 cm) were systematically collected. The analysis encompassed evaluations of soil pH and the concentrations of eight heavy metals: arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), mercury (Hg), nickel (Ni), lead (Pb), and zinc (Zn). To assess the risk of heavy metal pollution, the study employed soil pollution risk screening values for agricultural land as a reference point, utilizing both the Nemerow Comprehensive Pollution Index and the Potential Ecological Risk Index methodologies. These approaches facilitated the assessment of pollution risk, identification of primary sources of heavy metal contaminants. Results:The overall soil environmental quality was good, with an average pH of 6.78 (neutral). Except for localized Cd exceedances along the Longchuan River banks, heavy metal pollution risk was generally low. Compared to Yunnan soil background values, As, Pb, Hg, and Zn were depleted; Cr, Ni, and Cu were similar; Cd was relatively enriched. The average Nemerow composite pollution index was 0.616, and the average comprehensive potential ecological risk index was 32.54, indicating overall low heavy metal hazard but notable local ecological risk from Cd. Conclusions:PMF analysis revealed five principal sources: pedogenic parent material weathering (natural source, 29.65%), atmospheric deposition (23.33%), a mixed source of agricultural activities and riverine sedimentation (17.75%), direct agricultural activities (17.54%), and a mineralized stratum source associated with mining activities (11.74%). The results underscore the combined influence of natural geology and human activities on soil heavy metal accumulation in this high-background area.

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  • 收稿日期:2024-12-06
  • 最后修改日期:2026-01-19
  • 录用日期:2026-02-04
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