青藏高原盐湖铷铯资源现状、富集规律与提取技术
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本文为科技部第二次青藏高原综合科学考察研究专题“青藏高原盐湖铷、铯资源现状与远景评估”资助项目(编号:2022QZKK0201)的成果


Rubidium and cesium resources current status, enrichment pattern and extraction technology in salt lakes of Qinghai—Xizang(Tibet) Plateau, China
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    摘要:

    铷、铯是重要矿产资源,在航天、通讯、能源、医药、化学和电子设备等领域有着广泛用途。青藏高原盐湖铷铯资源主要分布于柴达木盆地和羌塘地块、拉萨地块的盆地,盐湖的铷铯资源主要来自于泉水和河水的补给。羌塘地块、拉萨地块的铷铯主要来自印度板块。笔者等收集了85个青藏高原盐湖铷铯含量和资源量数据,铷含量较高的盐湖有扎布耶和麻米错等,铯含量较高的盐湖有聂尔错和扎西错等。青藏高原盐湖氧化铷资源量共47. 50 kt,为大型铷矿床规模的23. 73倍;达到详查程度的资源量共37. 40 kt。盐湖氧化铯资源量共28. 53 kt,为大型铯矿床规模的14. 265倍;达到详查程度的资源量共27. 10 kt。85个盐湖中氧化铷的资源量达到大型矿床要求的盐湖有5个,达到中型矿床要求的盐湖有4个。氧化铯资源量达到大型矿床要求的盐湖有2个,达到中型矿床要求的盐湖有2个。盐湖铷铯在蒸发过程中基本处于浓缩阶段,残卤中铷铯浓度很高,扎布耶盐湖湖水蒸发残卤中铷、铯质量分数最高为0. 496‰和0. 372‰,拉果错残卤中铷、铯最高为0. 84‰和1. 76‰,麻米错残卤中铷、铯最高为0. 224‰和0. 297‰,这有利于铷铯的开发利用。目前,从盐湖卤水中提取铷、铯的方法以溶剂萃取法方法最具有应用前景。

    Abstract:

    Rubidium and cesium are important mineral resources in China, with wide applications in fields such as aerospace, communication, energy, medicine, chemistry, and electronic equipment. Rubidium and cesium, which exist in the form of ions, are widely distributed in salt lakes on the Qinghai—Xizang(Tibet) Plateau. Due to their relatively simple extraction process, low cost, and low energy consumption, they are the main objects for future extraction. This paper systematically collects data on rubidium and cesium resources in salt lake brines on the Qinghai Xizang Plateau, analyzes the content, resource quantity, and distribution of rubidium and cesium, studies the enrichment patterns of rubidium and cesium in salt lake brines, understands their extraction techniques, and provides a basis for the comprehensive utilization of salt lake resources. Methods: In this paper, the similarities and differences of rubidium and cesium are found out by analyzing their physical and chemical properties. Through research on the tectonic movement of the Qinghai—Xizang Plateau and processing of rubidium and cesium data in salt lakes, identifying their enrichment areas and reasons The enrichment and extraction of rubidium and cesium in Zabuye, Lago Co and Mami Co salt lakes were analyzed.Results: The amount of rubidium oxide resources in the salt lake on the Qinghai—Xizang Plateau is 47. 50 kt, which is 23. 73 times of the scale of large- scale rubidium deposit. The cesium oxide resources in the salt lake are 28. 53 kt, which is 14. 265 times the size of large- scale cesium deposit. There are 5 salt lakes with rubidium oxide resources that meet the requirements of large deposits and 4 salt lakes that meet the requirements of medium deposits. There are 2 salt lakes with cesium oxide resources that meet the requirements of large deposits and 2 salt lakes that meet the requirements of medium deposits. The highest rubidium and cesium contents were 0. 496‰ and 0. 372‰ in the brine of Zabye Salt Lake when the evaporation rate was 100%, which was 10. 33 and 31 times that of the original brine. The highest rubidium and cesium contents were 0. 84‰ and 1.76‰ in the brine of Lago Salt Lake when the evaporation rate was 85. 09%, which was 84 and 88 times that of the original brine. The highest rubidium and cesium contents were 0. 224‰ and 0. 297‰ when the evaporation rate was 86. 79% in Mami Co salt lake brine, which were 14 and 21. 21 times of the original brine. Conclusions: The rubidium and cesium resources in the salt lakes of the Qinghai—Xizang(Tibet) Plateau are mainly distributed in the Qaidam basin, Qiangtang block and Lhasa block, and the rubidium cesium in the Qiangtang block and Lhasa block mainly comes from the Indian plate. Rubidium and cesium in salt lake are basically concentrated in the evaporation process, and the concentration of residual halide is very high, which is conducive to the development and utilization of rubidium and cesium. The brine of Zabye Salt Lake was developed and utilized when the evaporation loss rate was about 80%. The brine of Lago Co salt lake was developed and utilized when the evaporation loss rate was about 70%. The brine of Mami Co salt lake was developed and utilized when the evaporation loss rate was about 70%. At present, the solvent extraction method is the most promising method for extracting rubidium and cesium from salt lake brine.

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引用本文

周潇,赵元艺,陈文西.2024.青藏高原盐湖铷铯资源现状、富集规律与提取技术[J].地质论评,70(2):705-716,[DOI].
ZHOU Xiao, ZHAO Yuanyi, CHEN Wenxi.2024. Rubidium and cesium resources current status, enrichment pattern and extraction technology in salt lakes of Qinghai—Xizang(Tibet) Plateau, China[J]. Geological Review,70(2):705-716.

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  • 收稿日期:2023-05-18
  • 最后修改日期:2023-10-18
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  • 在线发布日期: 2024-03-20
  • 出版日期: 2024-03-15