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摘要:The variations in source rocks and melting conditions of granites can provide essential clues for the crustal magmatic response in orogenic process. Based on geochronology, whole-rock and mineral chemistry, this paper reveals two different granites in the Northern Qinling migmatite complex, which reveal obvious differences in source region and melting condition. The older granodiorite (402 ± 0.8 Ma) displays typical Na-rich adakite affinity, i.e., high Na2O/K2O (2.04 to 2.64) and Sr/Y (96 to 117) ratios, they have relative evolved isotopic compositions (εNd(t) = ?0.52 to ?0.04; zircon εHf(t) = ?0.06 to +7.78). The younger leucogranite (371 ± 2 Ma) displays higher SiO2 (72.32 to 73.45 wt%), lower (TFeO + MgO + CaO + TiO2) contents (<2 wt%) and depleted Sr-Nd-Hf isotopic compositions (i.e., εNd(t) = +2.6 to +3.0; zircon εHf(t) = +5.94 to +14.12), as well as high 10000 × Ga/Al and TFeO/MgO ratios, indicating that they represent highly fractionated I-type granites that derived from melting of juvenile crust. The variations in source rocks and melting condition of the two granites indicating a tectonic switch from compression to extension in 400 to 370 Ma, this switch is later than that in the eastern section of the North Qinling, indicating a scissor collision process between the South Qinling and North China Craton (NCC) in Devonian era.

摘要:Understanding the nature of parental melts for pyroxenite veins in supra-subduction zone (SSZ) ophiolites provides vibrant constraints on melt infiltration processes operating in subduction zones. The Zedang ophiolitic massif in the eastern Yarlung–Zangbo suture zone in Tibet consists of mantle peridotites and a crustal section of gabbro, diabase, and basalt. Veins of two pyroxenite varieties cut the southern part of the Zedang massif. These pyroxenite rocks have different geochemical characteristics, where the first variety (type-I) has relatively higher contents of SiO2 (51.82–53.08 wt%), MgO (20.08–23.23 wt%), and ΣPGE (3.42–13.97 ppb), and lower Al2O3 (1.59–2.28 wt%) and ΣREE (1.63–2.94 ppm). The second pyroxenite variety (type-II) is characterized by SiO2 (45.44–49.61 wt%), MgO (16.68–19.78 wt%), Al2O3 (4.24–8.77 wt%), ΣPGE (14.46–322.06 ppb), and ΣREE (5.82–7.44 ppm). Pyroxenite type-I shows N-MORB-like chondrite-normalized REE patterns. Zircon U-Pb ages of pyroxenite type-I (194 ± 10 Ma), associated ophiolitic gabbro (135.3 ± 2.0 Ma), and plagiogranite (124.2 ± 2.3 Ma) evidently imply episodic evolution of the Zedang ophiolites. The mineralogical and geochemical characteristics of the investigated pyroxenites can be explained by subduction-initiated hydrous melting of metasomatized sub-arc mantle, later overprinted by sub-slab mantle melting triggered by upwelling asthenosphere during the Jurassic–Early Cretaceous times. The geochemical variations in pyroxenite vein composition, coupled with age differences amongst the other ophiolite units, may correspond to intermittent emplacement of pyroxenite dikes and isotropic gabbroic intrusions where the geodynamic setting progressed from arc maturation and slab rollback to slab tearing and delamination.

摘要:The Hongshishan chromitite deposits are situated to the north of the Beishan orogenic collage, in the southern part of the Central Asian Orogenic Belt. This study describes the mineral chemistry, Re-Os isotopes and platinum-group elements geochemistry of the Hongshishan chromitites for the purpose of constraining the origin, evolution and composition of their parental melts. The restricted ranges of Al2O3, Cr2O3 and Cr#-Mg# variation of chromite-cores and chromites fall within the field of the mid-ocean ridge and ophiolitic podiform chromite settings. The (187Os/188Os)i ratios of the chromitites are in the range of 0.12449–0.12745 (average 0.12637) and the γOs are from ?1.92 to ?0.06 (average ?0.83). In the Re-Os isotope diagrams, all the samples fall in the field of chromitites and show a residual peridotitic trend. The range of Os isotopic compositions and γOs values indicate that they overlap the depleted MORB mantle (DMM) as well as being close to global Os isotopic data and γOs of ophiolite chromitites. The characteristics of the PGE contents can be roughly subdivided into two groups: podiform chromitites and Ural-Alaskan type complexes. For the ferritchromite cores, the calculated Al2O3 concentrations of the parental melt are higher (average 16.65 wt%) in high-Cr than high-Al chromitite (average 16.17 wt%) and for the chromite, the calculated Al2O3 concentrations are even higher (average 16.48 wt%) in the high-Cr than the high-Al examples (average 15.38 wt%). In the (TiO2)melt vs. TiO2 diagrams, most high-Al melts fall in the MORB, while the high-Cr melts fall in the ARC field. The calculated FeO/MgO ratios for the parental melt show the closest resemblance to a MORB magma composition. The inferred parental melt composition for studied chromitites falls in the field of mid-ocean ridge basalt (MORB) magmas and far away from boninite. The calculated degrees of partial melting producing the chromitites are 16%?22% (average 19%), which is around the range of those of the MORB magmas. The chromitites are suggested to have been formed in a MORB setting. The chromites and ferritchromite cores are mostly scattered along the MORB and SSZ harzburgite–dunite fields. Ferritchromite rims and ferritchromites with high YFes formed as a result of alteration during serpentinization.

摘要:The Bangbule skarn lead-zinc (Pb-Zn) deposit (>1 Mt Zn + Pb) is located in the western Nyainqentanglha polymetallic metallogenetic belt, central Tibet. Lenticular orebodies are all hosted in skarn and developed in the contact zone between the quartz porphyry and carbonate strata of the mid Paleozoic Middle to Upper Chaguoluoma Formation as well as in carbonate and sandstone beds of the Upper Paleozoic Laga Formation. As a newly discovered skarn deposit, the geological background and metallogenesis of this deposit remain poorly understood. Detailed petrological, geochemical and geochronological data of the ore-related quartz porphyry, helps constrain the mineralization age and contributes to discussion on the ore genesis of the Bangbule deposit. Both endoskarn and exoskarn are identified in the Bangbule deposit. From quartz porphyry to carbonate formation, the exoskarn is zoned from proximal garnet skarn to distal pyroxene skarn. Zircon U-Pb dating results show that the quartz porphyry formed at 73.9 ± 0.8 Ma. Geochemical analysis results show that the quartz porphyry has high contents of SiO2 (71.40–74.94 wt%) and K2O + Na2O (3.76–8.46 wt%) with A/CNK values of 0.69 to 1.06. Besides, the quartz porphyry is enriched in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) and have low εNd(t) (from ?8.25 to ?8.19) and high initial (87Sr/86Sr)i values (0.713611–0.714478). Major, trace elements and whole-rock F concentration analysis results from the endoskarn samples show higher TFe2O3, MgO, CaO, Pb + Zn, W, Sn, Mo and F etc., and lower alkalis (K2O, Na2O, Sr and Ba) than those of fresh quartz porphyry, indicating that the early ore-forming fluids were an Ca-Fe-F-enriched fluid. Massive ore in the proximal skarn might be related to the high F content in the magma, which lowered the solidus temperature of the quartz porphyry magma and caused a lower temperature of the ore-forming fluids, as well as facilitating the precipitation of sphalerite and galena. Based on the geochemical characteristics presented in this study, we propose that the ore-related quartz porphyry was formed by partial melting of crust materials with some juvenile crustal component input. The partial melting of the middle-upper crust after the initial enrichment of lead and zinc elements are important for the formation of Pb-Zn deposits. The case study of the Bangbule deposit has proven that there is still a crust-derived magmatic source region in the western segment of the central Lhasa terrane. Therefore, there is still great potential for Pb-Zn mineralization and Pb-Zn exploration.

摘要:The Sinongduo mining region includes two types of mineralizations: the epithermal and the carbonate-hosted Pb-Zn-Ag deposits. Despite being studied for many years, the ore formation process and genesis of the carbonate-hosted Pb-Zn-Ag deposits remain poorly understood. The Pb-Zn-Ag ore bodies occur as veins and are hosted by limestone and dolostone of the Permian Xiala Formation. Three sulfide mineralization substages have been identified at the Sinongduo carbonate-hosted deposit. Indium coupled with Cu, Co and Sn was incorporated into sphalerite as substitutions: 2Zn2+ ? Cu+ + In3+, (3n/2 + 1)Zn2+ ? Co2+ + nIn3+ or (2n + 1)Zn2+ ? Co2+ + n(Cu+ + In3+) (n > 1) and 4Zn2+ ? Sn2+ + 2In3+. Sphalerite and pyrite in the mineralization stage display δ34S values in a narrow range of +5.7‰ to +11.3‰, which are similar to those of Palaeocene igneous rocks, indicative of a magmatic source of sulfur. We present systematic carbon-hydrogen-oxygen isotope results that further support a magmatic source for the ore-forming fluids that were influenced by meteoric water. Furthermore, the Pb isotope compositions of sulfide minerals in the Sinongduo carbonate-hosted deposit overlap with the values of coeval Linzizong volcanic rocks and are similar to those of Indian Ocean sediments, indicating upper crustal sources of metals. We conclude that the Sinongduo carbonate-hosted Pb-Zn-Ag deposit is a medium- to low-temperature magmatic-hydrothermal deposit related to Linzizong magmatism.

摘要:The origin and source of the petroleum in the Jurassic reservoirs within the eastern Fukang sub-depression were geochemically investigated. They show thermal maturities matching the peak generation stage, while the condensates are at the early stage of intense cracking. Oils and condensates may have experienced mild evaporative fractionation, while mixing of severely biodegraded with non-biodegraded oils has occurred. Using biomarkers and isotopes, petroleums were classified into Group I, II and III genetic groups, with Group III further divided into IIIa and IIIb subgroups. Group I petroleum displays heavy carbon isotopes, a strong predominance of pristine over phytane, high C19 and C20 tricyclic and C24 tetracyclic terpanes, low gammacerane, and dominant C29 steranes, while Group II shows light carbon isotopes, a predominance of phytane over pristine, high C21 and C23 tricyclic with low C24 tetracyclic terpanes, high gammacerane and dominant C27 steranes. Group IIIa petroleum shows mixing compositions of Group I and II, while Group IIIb displays similar compositions to Group I, but with significantly higher Ts, C29Ts and C30 diahopane proportions. Oil-source rock correlation suggests Group I and II petroleums originate from Jurassic and Permian source rocks, respectively, while Group IIIa are mixtures sourced from these rocks and IIIb are mixtures from Jurassic and Triassic source rocks.

摘要:Large numbers of gas reservoirs have been discovered in overpressure basins. Fluid charging has a close relationship with paleo-pressure evolution, affecting the migration of gas reservoirs. To study fluid charging and the related pressure system, we analyzed burial histories and fluid inclusion (PVTx) simulations and conducted basin modeling of the Ledong Slope Zone in the Yinggehai Basin as an example. On the basis of fluid-inclusion assemblages (FIAs), homogenization temperature (Th), final melting temperature (Tm, ice) and Raman spectroscopy in fluid inclusions, there are three stages of fluid charging: during the first and second stage, methane-dominated fluid was charged at 2.2–1.7 Ma and 1.7–0.9 Ma, respectively. In the third stage, CO2-rich hydrothermal fluid was charged since 0.9 Ma. It could be concluded from the well-logging data that the disequilibrium compaction in the Yinggehai Fm., along with the fluid expansion and clay diagenesis in the Huangliu and Meishan formations, resulted in the overpressure in the Ledong slope zone. The evolution of paleo-pressure was affected by the sedimentation rate of the Yinggehai Fm., as well as the hydrocarbon generation rate. Additionally, the Ledong Slope Zone is less affected by diapir activity than the nearby diapir area. Based on fluid inclusions, paleo-pressure, basin modeling and geological background, the gas migration history of the Ledong Slope Zone can be divided into four stages: in the first stage, excess pressure was formed around 5 Ma; from 2.2 to 1.7 Ma, there was a reduction in the charging of hydrocarbon fluid and steadily increasing excess pressure; during the 1.7–0.9 Ma period a large amount of hydrocarbon was generated, excess pressure increasing significantly and hydraulic fractures forming in mudstones, With gas reservoirs developing in structural highs; since 0.9 Ma, CO2-rich hydrothermal fluid accumulated in reservoirs adjacent to faults and the pressure coefficient remained stable. The research results are helpful in the study of fluid migration and accumulation mechanisms in overpressure basins.

摘要:Electrical properties are important physical parameters of natural gas hydrate, and, specifically, resistivity has been widely used in the quantitative estimation of hydrate saturation. There are three main methods to study the electrical properties of gas hydrate-bearing sediments: experimental laboratory measurements, numerical simulation, and resistivity logging. Experimental measurements can be divided into three categories: normal electrical measurement, complex resistivity measurement, and electrical resistivity tomography. Experimental measurements show that the resistivity of hydrate-bearing sediment is affected by many factors, and its distribution as well as the hydrate saturation is not uniform; there is a distinct non-Archie phenomenon. The numerical method can simulate the resistivity of sediments by changing the hydrate occurrence state, saturation, distribution, etc. However, it needs to be combined with X-ray CT, nuclear magnetic resonance, and other imaging techniques to characterize the porous characteristics of the hydrate-bearing sediments. Resistivity well logging can easily identify hydrate layers based on their significantly higher resistivity than the background, but the field data of the hydrate layer also has a serious non-Archie phenomenon. Therefore, more experimental measurements and numerical simulation studies are needed to correct the parameters of Archie's formula.

摘要:The production efficiency of shale gas is affected by the interaction between hydraulic and natural fractures. This study presents a simulation of natural fractures in shale reservoirs, based on a discrete fracture network (DFN) method for hydraulic fracturing engineering. Fracture properties of the model are calculated from core fracture data, according to statistical mathematical analysis. The calculation results make full use of the quantitative information of core fracture orientation, density, opening and length, which constitute the direct and extensive data of mining engineering. The reliability and applicability of the model are analyzed with regard to model size and density, a calculation method for dominant size and density being proposed. Then, finite element analysis is applied to a hydraulic fracturing numerical simulation of a shale fractured reservoir in southeastern Chongqing. The hydraulic pressure distribution, fracture propagation, acoustic emission information and in situ stress changes during fracturing are analyzed. The results show the application of fracture statistics in fracture modeling and the influence of fracture distribution on hydraulic fracturing engineering. The present analysis may provide a reference for shale gas exploitation.

摘要:The northeastern margin of the Tibetan Plateau is the youngest part of the Tibetan Plateau where tectonic activity is intense and climate change is complex. In this study, combined with field investigations, we explored accelerator mass spectrometry 14C and optically stimulated luminescence dating and palynological analysis of the sedimentary sequence in the Qingshuihe Basin to explain the origin of soft-sediment deformation layer. Dating and palynological results from the Sanchahe section in the basin revealed a detailed history of vegetation variation and associated climate change from ~18 to ~5 ka BP. The results indicate that the permafrost developed at ~18–11.7 ka BP, and the soft-sediment deformation structures formed at ~11.7–5 ka BP. Together with the characteristics of the deformation (meter-scale, continuous symmetrical wave) and paleoclimate, we suggest that the soft-sediment deformation layer in the late Pleistocene was cryoturbated under climatic conditions. The discovery of a series of cryoturbations in the Qingshuihe Basin has further enriched the regional distribution of periglacial phenomena in the west of the Ordos Plateau, expanded the distribution range of periglacial phenomena, and provided evidence for exploring the temporal and spatial changes in permafrost in northern China at the end of the late Pleistocene.

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摘要:Based on literature research in combination with the practice of CO2 flooding and storage in Jilin Oilfield, this study assesses the key problems in CO2 flooding and storage, proposing the corresponding countermeasures from five aspects of CO2 gas source condition, namely geological condition evaluation, scheme design incoordination with other production methods, economic and effectiveness evaluation, together with dynamic monitoring and safety evaluation. The results show that CO2 flooding is the most economic and effective CO2 storage method. In eastern China, inorganic origin CO2 gas reservoirs are widely developed and are especially the most enriched in the Paleozoic carbonate rock strata and the Cenozoic Paleogene–Neogene system, which provide a rich resource base for CO2 flooding and storage. In the future, CO2 generated in the industrial field will become the main gas source of CO2 flooding and storage. The evaluation of geological conditions of oil and gas reservoirs is the basis for the potential evaluation, planning scheme design and implementation of CO2 flooding and storage. CO2 storage should be below the depth of 800 m, the CO2 flooding and storage effects in low-permeability oil reservoirs being the best. CO2 geological storage mechanisms primarily consist of tectonic geological storage, bound gas storage, dissolution storage, mineralization storage, hydrodynamic storage and coalbed adsorption storage. The practice of CO2 flooding and storage in Jilin Oilfield demonstratesthat the oil increment by CO2 flooding is at least 24% higher than by conventional water flooding. The most critical factor determining the success or failure of CO2 flooding and storage is economic effectiveness, which needs to be explored from two aspects: the method and technology innovation along with the carbon peaking and carbon neutrality policy support. After CO2 is injected into the reservoir, it will react with the reservoir and fluid, the problem of CO2 recovery or overflow will occur, so the dynamic monitoring and safety evaluation of CO2 flooding and storage are very important. This study is of great significance to the expansion of the application scope of CO2 flooding and storage and future scientific planning and deployment.

摘要:Because it is necessary to focus on differences in regional oil reservoirs and determine the priority of the CCUS-EOR (Carbon capture, utilization, and storage-enhanced oil recovery) deployment under China’s net-zero CO2 emission target, systematic and regional evaluations of CO2 sequestration capacity in major oil basins are needed considering the geofluid properties―carbon sequestration capacity in place (CSCIP)―where the ‘in place’ indicates actual geological formation conditions underground, e.g., formation temperature and pressure. Therefore, physical properties of geofluids at different depths with different geologic temperatures and pressure conditions are considered for the CO2 sequestration capacity evaluation in place, including shallow (800–2000 m), medium (2000–3500 m), deep (3500–4500 m) and ultra-deep (4500–8000 m) depth intervals. A modified evaluation model with four grading levels is proposed, combining the P-V-T equations of state (EOS) and evaluation equations of the Carbon Sequestration Leadership Forum (CSLF), including theoretical, effective, practical, and CCUS-EOR CSCIP, which is more consistent with geofluid physical properties underground, to make the grading evaluation and ranking of the CSCIP in China’s major oil basins. Then, the grading CSCIP of 29 major oil basins in China was evaluated based on the petroleum resources evaluation results of the Ministry of Natural Resources of China (MNRC) during China’s 13th Five-Year Plan period. According to the grading evaluation results, suggestions for China’s CCUS-EOR prospective regions are given as follows: shallow oil fields of the Songliao Basin in Northeast China, shallow–medium oil fields of the Bohai Bay Basin in East China, medium oil fields of the Zhungeer Basin in West China, and medium oil fields of the Ordos Basin in Central China; all are potential areas for the CCUS-EOR geological sequestration in China’s onshore oil basins. In addition, in China’s offshore oil basins, shallow–medium oil fields of the Bohai Sea and shallow oil fields of the Pearl River Mouth Basin have potential for CCUS-EOR geological sequestration.

摘要:Thermo-hydro-mechanical-chemical (THMC) interactions are prevalent during CO2 geological sequestration (CGS). In this study, a sequential coupling THMC numerical simulation program was constructed, which can be used to explore the following issues of CGS: fluid and heat flow, solute transport; stresses, displacements and rock failures related to geo-mechanical effects; equilibrium and kinetic chemical reactions; chemical damage to mechanical properties of the rock. Then, the coupling program was applied to the Ordos CGS Project to study the formation response under the multi-field interaction caused by CO2 injection. The simulation results show that the mechanical process dominates the short CO2 injection period. Specifically, the formation’s permeability near the injection well increases by 43%, due to the reduction of effective stress, which significantly promotes the lateral migration of CO2. When the injection rate exceeds 0.15 million tons per year, the cohesion of the reservoir rock is not enough to resist the shear force inside the rock and rock failure may occur. During the subsequent long-term sequestration period (200 years), the influence of mineral reactions gradually increases. Due to calcite dissolution, the shear modulus of caprock is predicted to decrease by 7.6%, which will to some extent increase the risk of rock failure.

摘要:Gas breakthrough pressure is a key parameter to evaluate the sealing capacity of caprock, and it also plays important roles in safety and capacity of CO2 geological storage. Based on the published experimental results, we present numerical simulations on CO2 breakthrough pressure in unsaturated low-permeability rock under 9 multiple P-T conditions (which can keep CO2 in gaseous, liquid and supercritical states) and thus, a numerical method which can be used to accurately predict CO2 breakthrough pressure on rock-core scale is proposed. The simulation results show that CO2 breakthrough pressure and breakthrough time are exponential correlated with P-T conditions. Meanwhile, pressure has stronger effects on experimental results than that of temperature. Moreover, we performed sensitivity studies on the pore distribution index λ (0.6, 0.7, 0.8, and 0.9) in van Genuchten-Muale model. Results show that with the increase of λ, CO2 breakthrough pressure and breakthrough time both show decreasing trends. In other words, the larger the value of λ is, the better the permeability of the caprock is, and the worse the CO2 sealing capacity is. The numerical method established in this study can provide an important reference for the prediction of gas breakthrough pressure on rock-core scale and for related numerical studies.

摘要:Supercritical carbon dioxide (ScCO2) fracturing has great advantages and prospects in both shale gas exploitation and CO2 storage. This paper reviews current laboratory experimental methods and results for sedimentary rocks fractured by ScCO2. The breakdown pressure, fracture parameters, mineral composition, bedding plane angle and permeability are discussed. We also compare the differences between sedimentary rock and granite fractured by ScCO2, ultimately noting problems and suggesting solutions and strategies for the future. The analysis found that the breakdown pressure of ScCO2 was reduced 6.52%–52.31% compared with that of using water. ScCO2 tends to produce a complex fracture morphology with significantly higher permeability. When compared with water, the fracture aperture of ScCO2 was decreased by 4.10%–72.33%, the tortuosity of ScCO2 was increased by 5.41%–70.98% and the fractal dimension of ScCO2 was increased by 4.55%–8.41%. The breakdown pressure of sandstone is more sensitive to the nature of the fracturing fluid, but fracture aperture is less sensitive to fracturing fluid than for shale and coal. Compared with granite, the tortuosity of sedimentary rock is more sensitive to the fracturing fluid and the fracture fractal dimension is less sensitive to the fracturing fluid. Existing research shows that ScCO2 has the advantages of low breakdown pressure, good fracture creation and environmental protection. It is recommended that research be conducted in terms of sample terms, experimental conditions, effectiveness evaluation and theoretical derivation in order to promote the application of ScCO2 reformed reservoirs in the future.

摘要:In order to improve CO2 capture, utilization and storage (CCUS) to solve carbon emission, sandstone from the Triassic Liujiagou Formation (LF) from the Ordos Basin in China was investigated using permeability tests and computed X-ray tomography (CT) scanning. The presence of reactive minerals within the geological CO2 sequestration target storage formation can allow reaction with injected CO2, which changes the porosity and permeability of the LF beds, affecting storage effectiveness. To investigate the effect of chemical reactions on the pore structure and permeability of sandstone cores representing the LF CO2 storage, tests were conducted to analyze the changes in porosity and permeability of sandstone cores induced by CO2-saturated brine at different reaction times (28-day maximum reaction period). Porosity and permeability of the sandstone increased after reaction with CO2-saturated brine due to mineral dissolution. The sandstone exhibited an increase in porosity and permeability after 15 days of reaction with CO2-saturated brine. Moreover, there was an increase in the volume of large pores in the sandstone after the 28-day period. The pore network of the sandstone was established through CT results, and the porosity calculated based on the obtained pore network was close to that measured in the test, demonstrating the feasibility to use CT to study the evolution of the microstructure of sandstone after long-time exposure to CO2-saturated brine.

摘要:To investigate the impacts of mineral composition on physical and mechanical properties of carbonate rocks, limestone specimens containing different contents in calcite and dolomite are selected to perform CO2-water-rock reaction experiments. The X-ray Diffraction (XRD) and Nuclear Magnetic Resonance (NMR) are carried out to examine the change characteristics of mineral dissolution and pore structure after reaction. The core flooding experiments with Fiber Bragg gratings are implemented to examine the stress sensitivity of carbonate rocks. The results show that the limestones containing pure calcite are more susceptible to acid dissolution compared to limestone containing impure dolomite. The calcite content in pure limestone decreases as the reaction undergoes. The dissolution of dolomite leads to the formation of calcite in impure limestone. Calcite dissolution leads to the formation of macropore and flow channels in pure limestone, while the effects of impure dolomite in impure limestone results in mesopore formation. When confining pressure is lower than 12 MPa, pure limestones demonstrate higher strain sensitivity coefficients compared to impure limestone containing dolomite after reaction. When confining pressure exceeds 12 MPa, the strain sensitivity coefficients of both pure and impure limestones become almost equal.

摘要:The Lucaogou Formation, located in the Jimsar Sag, Junggar Basin, NW China, has great potential for shale oil resources. In the process of CO2-EOR (CO2 enhance oil recovery), mineral dissolution, precipitation and transformation, leading to the local corrosion or blockage of reservoirs, have a significant influence on recovery. In this study, a combination of high-temperature and high-pressure laboratory experiments and coupled temperature/fluid-chemistry multi-field numerical simulations are used to investigate CO2-water-rock reactions under various reservoir conditions in the upper and lower ‘sweet spots’, to reveal the mechanisms underlying CO2-induced mineral dissolution, precipitation and transformation. In addition, we quantitatively calculated the evolution of porosity over geological timescales; compared and analyzed the variability of CO2 transformation in the reservoir under a variety of temperature, lithology and solution conditions; and identified the main factors controlling CO2-water-rock reactions, the types of mineral transformation occurring during long-term CO2 sequestration and effective carbon sequestration minerals. The results demonstrate that the main minerals undergoing dissolution under the influence of supercritical CO2 are feldspars, while the main minerals undergoing precipitation include carbonate rock minerals, clay minerals and quartz. Feldspar minerals, especially the initially abundant plagioclase in the formation, directly affects total carbon sequestration, feldspar-rich clastic rocks therefore having considerable sequestration potential.

摘要:Under the new development philosophy of carbon peaking and carbon neutrality, CO2 and O2 in situ leaching (ISL) has been identified as a promising technique for uranium mining in China, not only because it solves carbon dioxide utilization and sequestration, but it also alleviates the environmental burden. However, significant challenges exist in assessment of CO2 footprint and water-rock interactions, due to complex geochemical processes. Herein this study conducts a three-dimensional, multicomponent reactive transport model (RTM) of a field-scale CO2 and O2 ISL process at a typical sandstone-hosted uranium deposit in Songliao Basin, China. Numerical simulations are performed to provide new insight into quantitative interpretation of the greenhouse gas (CO2) footprint and environmental impact (SO42–) of the CO2 and O2 ISL, considering the potential chemical reaction network for uranium recovery at the field scale. RTM results demonstrate that the fate of the CO2 could be summarized as injected CO2 dissolution, dissolved CO2 mineralization and storage of CO2 as a gas phase during the CO2 and O2 ISL process. Furthermore, compared to acid ISL, CO2 and O2 ISL has a potentially smaller environmental footprint, with 20% of SO42– concentration in the aquifer. The findings improve our fundamental understanding of carbon utilization in a long-term CO2 and O2 ISL system and provide important environmental implications when considering complex geochemical processes.

摘要:CO2 capture and storage (CCS) has the risk of CO2 leakage, and this leakage always increases soil CO2 concentration, and the long-term CO2 stress damages crop production in farmland. Using maize, the growth characteristics, such as plant height and yield, and physiological indexes (osmoregulation substances and antioxidant enzymes) were explored under different simulative CO2 leakage conditions. Further, the relationship between maize physiological indexes and soil CO2 concentration was analyzed, showing that soil CO2 stress inhibited maize growth to a certain extent, resulting in shorter plants, thinner stems and lower kernel yield. With an increase in soil CO2 concentration, the contents of malondialdehyde, soluble sugar and soluble protein in maize leaves increased; with continuing stress, the increase rate of malondialdehyde was greatly augmented, whereas the increase rates of soluble sugar and soluble protein decreased. With extended CO2 stress, the activity of the enzyme superoxide dismutase (SOD) increased continuously, while the activities of catalase and peroxidase first increased and then decreased. Superoxide dismutase activity was closely correlated with soil CO2 concentration (r = 0.762), and responded quickly to the change of soil CO2 concentration (R2 = 0.9951). Therefore, SOD plays an important role in maize resistance to soil CO2 stress. This study will help further understanding of the mechanism of maize tolerance to soil CO2 stress, providing a theoretical basis for agricultural production in CCS project areas.

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