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摘要:Gold deposits in Jiaodong, termed Jiaodong-type, are tectonically located in the southeastern margin of the North China Craton. Their major features are reviewed in this paper to highlight the differences between Jiaodong deposits and other genetic types of gold deposits. The mineralization was synchronized with asthenosphere upwelling indicated by syn-ore OIB-like mafic dike and large-scale crustal thinning suggested by decrease of Sr/Y from pre-ore to syn-ore granites. Asthenosphere upwelling induced by the roll-back of Paleo-Pacific Plate drove partial melting of lithospheric mantle and devolatilization, which induced the release of the ore-forming fluids. In concomitant with magmatic records, mineralization migrated from the western Jiaobei terrane (133–127 Ma) to the eastern Sulu orogenic belt (114–108 Ma), corresponding to the eastward roll-back of Paleo-Pacific Plate. Gold mineralization in Jiaodong formed in the transitions of ductile to brittle deformation, rapid to slow crustal uplift, and regional compression to extension. In the regional-scale, the gold deposits in the Jiaobei terrane are mostly situated at intersections between NE-trending faults and EW-trending basement faults, and gold orebodies dominantly controlled by the lithologic contacts between Precambrian metamorphic rocks and Mesozoic granites. The mineralization was dominated by the disseminated-veinlet ores related to quartz–sericite alteration in strong cataclasite-breccia zone, with subsidiary thick quartz-sulfide veins developed in secondary fault zones. The ore-forming fluids belong to a H2O–CO2–NaCl±CH4 system and show minor variations in salinity among different types of ore. Structure-fluid feedback involving fluid-rock reaction and hydrofracturing triggered the fluid phase separation and resultant gold deposition. The Jiaodong gold deposits are distinct from orogenic and intrusion-related gold deposits in terms of tectonic setting, origin of ore-forming fluids, and mechanism of gold deposition.

摘要:Systematic extinctions can leave major morphological gaps between living crown-group clades. Such morphological gaps would be perceived, from a neontological point of view, as major evolutionary transitions. In order to fill these morphological gaps and to map the evolutionary steps toward major evolutionary transitions, we need to integrate extinct stem-group taxa in phylogenetic studies. However, the recognition of stem group has not been widely adopted in the study of early animal fossils, despite that all fossils are stem groups at one level or another. Part of the difficulty is that stem groups may not have all features that collectively diagnose the respective crown group, and they can have unique (autapomorphic) features, making them tantalizingly similar to and frustratingly different from the crown group (e.g., stem-group eukaryotes can be prokaryotic and stem-group animals can be protistan). The need to embrace stem groups and to implement the PhyloCode, in order to achieve phylogenetic clarity and to offer key paleontological insights into the origin and early animal evolution, is illustrated in debates on several controversial Ediacaran and Cambrian fossils.

摘要:Individual coal seams formed in paleo-peatlands represent sustained periods of terrestrial carbon accumulation and a key environmental indicator attributed to this record is the rate of carbon accumulation. Determining the rate of carbon accumulation requires a measure of time contained within the coal. This study aimed to determine this rate via the identification of Milankovitch orbital cycles in the coals. The geophysical log is an ideal paleoclimate proxy and has been widely used in the study of sedimentary records using spectral analysis. Spectral analyses of geophysical log from thick coal seams can be used to identify the Milankovitch cycles and to calculate the period of the coal deposition. By considering the carbon loss during coalification, the long-term average carbon accumulation rate and net primary productivity (NPP) of paleo-peatlands in coal seams can be obtained. This review paper presents the procedures of analysis, assessment of results and interpretation of geophysical logs in determining the NPP of paleo-peatlands.

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摘要:This paper introduces how crustal thickening controls the growth of the Himalaya by summarizing the P-T-t evolution of the Himalayan metamorphic core. The Himalayan orogeny was divided into three stages. Stage 60–40 Ma: The Himalayan crust thickened to ~40 km through Barrovian-type metamorphism (15–25 °C/km), and the Himalaya rose from <0 to ~1000 m. Stage 40–16 Ma: The crust gradually thickened to 60–70 km, resulting in abundant high-grade metamorphism and anatexis (peak-P, 15–25 °C/km; peak-T, >30 °C/km). The three sub-sheets in the Himalayan metamorphic core extruded southward sequentially through imbricate thrusts of the Eo-Himalayan thrust, High Himalayan thrust, and Main Central thrust, and the Himalaya rose to ≥5,000 m. Stage 16–0 Ma: the mountain roots underwent localized delamination, causing asthenospheric upwelling and overprinting of the lower crust by ultra-high-temperature metamorphism (30–50 °C/km), and the Himalaya reached the present elevation of ~6,000 m. Underplating and imbricate thrusting dominated the Himalaya’ growth and topographic rise, conforming to the critical taper wedge model. Localized delamination of mountain roots facilitated further topographic rise. Future Himalayan metamorphic studies should focus on extreme metamorphism and major collisional events, contact metamorphism and rare metal mineralization, metamorphic decarbonation and the carbon cycle in collisional belts.

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摘要:The oldest Asian record of alpheid shrimps, assigned to genus Alpheus, based on snapping claw fingertips from the Miocene Khari Nadi Formation in the Kutch Basin, western India reported herein, extends the fossil record of the family Alpheidae from Asia by ~22 million years. An early Miocene (Aquitanian) age is estimated based on the associated assemblage of calcareous nannofossils, Sphenolithus disbelemnos, Cyclicargolithus floridanus, and Reticulofenestra haqii. The co-occurring microbiota includes bony fish otolith remains, identified as “genus Gobiidarum”, isolated teeth of Dasyatis rays, Sphyrna sharks, and teleosts, ctenoid and placoid scales, ostracods, belonging to the genera Paractinocythereis, Alocopocythere, Ruggieria? Aglaiocypris, Bairdoppilata, and echinoid spines. Taken together, the microfossil assemblage and data from chemical analyses using Energy Dispersive Spectroscopy, X-Ray Diffraction and Wavelength Dispersive X-Ray Fluorescence of host and associated lithologies suggests prevalence of a shallow (neritic) to coastal marine (intertidal) depositional paleoenvironment.

摘要:Leaf fragments of Herbifolia antiqua A. Frolov et Enushchenko gen. et sp. nov. from the Middle Jurassic (Aalenian) of the Irkutsk Coal Basin (Eastern Siberia, Russia) are reported. The following features are characteristic of H. antiqua gen. et sp. nov.: the presence of leaf sheaths, linear smooth-edged leaves with parallel venation, anastomoses between the veins, anomocytic stomata, rhomb-shaped ordinary epidermal cells. Such a combination of characters is widespread in modern monocotyledonous plants and is absent in fossil and modern cryptogam and gymnosperms. Due to the lack of evidence of an enclosed ovule in H. antiqua gen. et sp. nov.we attribute it to a typological angiosperm, based on its unique leaf structure characteristic of monocotyledons. The leaf epidermal structure of Herbifolia gen. nov. is most similar to those of modern Asparagales and Liliales.

摘要:Early Paleozoic black organic sediments and bentonites occur widely in the craton basin within the Yangtze block and are generally believed to be genetically related to a specific tectonic setting on the cratonic boundary. However, the intimate relationship between their origins and the dynamic mechanisms are unclear, as exemplified by the genesis of the black shale series and bentonites from the Wufeng Formation during the Ordovician–Silurian transition (OST). In order to reveal the relationship between the Wufeng Formation and the convergence of the Yangtze and Cathaysia blocks (i.e., the intracontinental Kwangsian Orogeny), two stratigraphic sections respectively in Zhaotong area (Northeast Yunnan) and Puyi area (Northwestern Guizhou) that were located in the semi-restricted inner Yangtze Sea during the OST were systematically studied, on the basis of whole-rock geochemical composition, pyrite δ34S (δ34Spy), total organic carbon (TOC), stable Sr isotope, pyrite framboid size distribution and zircon U-Pb age, trace elements. The evidence shows that the paleo-oceanic environment changed significantly at the turn of the early–late Katian and formed the black shale series in the Wufeng Formation. These acritarch assemblages were formed in the transition process of the Upper Yangtze Basin from passive continental margin basin to foreland basin during this interval. Based on previous research on the genetic relationship between black shale series and plate tectonic movement, a basin-mountain evolution model suitable for South China in the Late Ordovician is presented. The two bentonites in the Wufeng Formation with U-Pb ages of 445.5 ± 0.8 Ma and 441.9 ± 2.4 Ma primarily originated from the intermediate–acid volcanic eruption during the collision and convergence between the Yangtze and Cathaysia blocks in the Late Ordovician, the provenance region probably being located in the Jiangnan orogenic belt. Thus, we believe that the appearance of the black shale series and bentonite in the Wufeng Formation at the turn of the early–late Katian may represent the initiation of basin-mountain transformation and the Kwangsian Orogeny in South China, which provides important evidence for the collision and convergence of the Yangtze and Cathaysia blocks in the Late Ordovician.

摘要:Daluo Mountains lie at front of the arcuate tectonic belt at the northeastern margin of the Tibetan Plateau, and are the landform boundary zone between the active Tibetan Plateau and the stable North China Craton. Studying of the late Cenozoic uplift evolution of Daluo Mountains is important for understanding the expansion mechanism of the northeastern margin of the Tibetan Plateau and its influence on the western North China Craton. In this study, the late Cenozoic uplift of Daluo Mountains is constructed from the development of the late Cenozoic alluvial fan around Daluo Mountains. The entire sedimentary sequence and framework of the fan was revealed by the newly obtained drilling core data. The cosmogenic nuclide, optically stimulated luminescence, and detrital zircon U-Pb dating results provide new evidences for discussion about the initial timing of the late Cenozoic uplift of Daluo Mountains and the key stages of uplift during the Pleistocene. The late Cenozoic alluvial fan at front of Daluo Mountains overlies a set of fluvial-facies strata; therefore, development of the alluvial-fan marks the start of late Cenozoic uplift of Daluo Mountains. The timing of this event can be constrained to ~4.64 Ma. Two extensive gravel layers (dated to ca. 0.76–0.6 Ma and ~0.05 Ma) developed during the Pleistocene, indicating two episodes of considerable uplift. This study provides a new time scale for the uplift and expansion of the arcuate tectonic belt at the northeastern margin of the Tibetan Plateau.

摘要:The Chuan-Dian Block (CDB) is located in the southeastern margin of the Tibetan Plateau, with a complex geological structure and active regional faults. The present tectonic condition with strong crustal deformation is closely related to the ongoing collision of the India and Eurasia plates since 65 Ma. The study of the crustal structure of this area is key to revealing the evolution and deep geodynamics of the lateral collision zone of the Tibetan Plateau. Deep seismic sounding is the most efficient method with which to unravel the velocity structure of the whole crust. Since the 1980s, 19 deep seismic sounding profiles have been captured within the CDB area. In this study, we systematically integrate the research results of the 19 profiles in this area, then image the 3D crustal velocity, by sampling with a 5 km spacing and 2D/3D Kriging interpolation. The results show the following. (1) The Moho depth in the study area deepens from 30 km in the south to 66 km in the north, whereas there is no apparent variation from west to east. The Pn wave velocity is higher in stable tectonic units, such as 7.95 km/s in the Lanping-Simao block and 7.94 km/s in the western margin of the Yangtze block, than in active or mobile tectonic units, such as 7.81 km/s in the Baoshan block, 7.72 km/s in the Tengchong block and 7.82 km/s in the Zhongdian block. (2) The crustal nature of the Tengchong block, the northern Lanping-Simao block and the Zhongdian block reflects a type of orogenic belt, having relatively strong tectonic activities, whereas the crustal nature of the central Lanping-Simao block and the western margin of the Yangtze block represents a type of platform. The different features of the upper-middle crust velocity, Moho depth and Pn wave velocity to both sides of the Red River fault zone and the Xianshuihe fault zone, reflect that they are clearly ultra-crustal. (3) Based on the distribution of the low velocity zones in the crust, the crustal material of the Tibetan Plateau is flowing in a NW–SE direction to the north of 26°N and to the west of 101°E, then diverting to flowing eastwards to the east of 101°E.

摘要:Structural and petrological data suggest that the Xigaze ophiolite from the Yarlung Zangbo Suture Zone (YZSZ) in south Tibet was a typical slow-spreading ridge. A new field, geochemical, mineral, and U-Pb zircon dataset of plagiogranite intrusions were used to constrain the dynamic processes of oceanic accretion in this slow-spreading ridge. Plagiogranites mainly occur as dykes or intrusions intruded into the whole sequence of the ophiolite and have a similar orientation to the dolerite dykes developed in the late stage of detachment faulting. U-Pb zircon ages of 122–123 Ma were obtained for two types of plagiogranites and associated dolerite dykes. Detailed geochemical and mineralogical examinations suggest that the plagiogranites are the product of low-pressure (2–3 kbar) fractional crystallization of mid-ocean ridge basalt-like magma and unlikely to have been derived from the partial melting of hydrous gabbroic rocks. The complex cross-cut relationship between the plagiogranites and ophiolite sequence reflects that they are controlled by small discontinued melt lenses rather than a big magma chamber under the ridge axis and reveals multiple injections during the oceanic crust accretion. The formation of plagiogranites possibly reflects the complex characteristic of oceanic accretion at slow-spreading ridges, time-dependent on structural (external) and magmatic (internal) processes.

摘要:The Baingoin batholith is one of the largest granitic plutons in the North Lhasa terrane. Its petrogenesis and tectonic setting have been studied for decades, but remain controversial. Here we report data on geochronology, geochemistry and isotopes of Early Cretaceous granitoids within the Baingoin batholith, which provide more evidence to uncover its petrogenesis and regional geodynamic processes. The Early Cretaceous magmatism yields ages of 134.4–132.0 Ma and can be divided into I-type, S-type and highly fractionated granites. The I- and S-type granites exhibit medium SiO2, high K2O/Na2O with negative εNd(t) and εHf(t) values, whereas, the albite granites have very high SiO2 (79.04%–80.40%), very low K2O/N2O, negative εNd(t) and a large variation in εHf(t). Our new data indicate that these granitoids are derived from unbalanced melting in a heterogeneous source area. The granodiorites involved had a hybrid origin from partial melting of basalt-derived and Al-rich rocks in the crust, the porphyritic monzogranites being derived from partial melting of pelitic rocks. The albite granites crystallized from residual melt separated from K-rich magma within the ‘mush’ process and underwent fractionation of K-feldspar. We believe that the Early Cretaceous magmatism formed in an extensional setting produced by the initial and continuous rollback of a northward-subducting slab of the NTO.

摘要:A comprehensive study of zircon U-Pb geochronology, in situ Hf isotopes, whole-rock major and trace element geochemistry, and Nd isotopes was carried out for two Early Jurassic two-mica granites (Longtang and Menglong) in the southern part of the Tengchong terrane, which is in the northern part of the larger Sibumasu terrane. We assess the origin of the granites and explore their possible genetic relationship to the Paleo-Tethyan regime. LA-ICP-MS zircon U-Pb dating shows that they were simultaneously emplaced in the Early Jurassic (ca. 199 Ma). They have SiO2 contents of 69.7–75.1 wt% and are mainly strongly peraluminous with alumina saturation index (ASI) values ranging from 1.06 to 1.46. They show similar Mg# (0.29–0.42) to experimental partial melts of metasedimentary rocks under continental pressure-temperature (P-T) conditions. They are enriched in light rare earth elements (LREEs) relative to heavy rare earth elements (HREEs), with moderately negative Eu anomalies and flat HREEs patterns. They show negative εNd(t) values (?9.0 to –12.4) and εHf(t) values (?8.0 to ?9.1). Elemental and isotopic data suggest that they most likely to formed by muscovite-dehydration melting of a metapelitic source at lower temperatures in the range of 700°C to 750°C. The granites might represent a post-collisional tectonic setting response to Paleo-Tethyan regime.

摘要:Since the Early Cenozoic, the Philippine Sea Plate (PSP) has undergone a complex tectonic evolution. During this period the Parece Vela Basin (PVB) was formed by seafloor spreading in the back-arc region of the proto-Izu-Bonin-Mariana (IBM) arc. However, until now, studies of the geological, geophysical, and tectonic evolution of the PVB have been rare. In this study, we obtained in situ trace element and major element compositions of minerals in basalts collected from two sites in the southern part of the PVB. The results reveal that the basalts from site CJ09-63 were likely formed via ~10% partial melting of spinel-garnet lherzolite, while the basalts from site CJ09-64 were likely formed via 15%–25% partial melting of garnet lherzolite. The order of mineral crystallization for the basalts from site CJ09-64 was olivine, spinel, clinopyroxene, and plagioclase, while the plagioclase in the basalts from site CJ09-63 crystallized earlier than the clinopyroxene. Using a plagioclase-liquid hygrometer and an olivine-liquid oxybarometer, we determined that the basalts in this study have high H2O contents and oxygen fugacities, suggesting that the magma source of the Parece Vela basalts was affected by subduction components, which is consistent with the trace element composition of whole rock.

摘要:Haitaite-(La), (La, Ce)(U4+, U6+, Fe2+)(Fe3+, Al)2(Ti, Fe2+, Fe3+)18O38, is a new member of the crichtonite group. It is named after the Haita Village in the Miyi County of Sichuan Province, China, where the mineral was discovered. The mineral occurs as black opaque centimeter-sized aggregates in the external contact zone between the Neoproterozoic (~800 Ma) alkali feldspar granite and the Mesoproterozoic (~1700 Ma) micaschist. In the studied sample, haitaite-(La) is associated with other minerals, including ilmenite, magnetite, rutile, zircon, brannerite and uraninite. The new mineral is a black, metallic phase and has a Mohs hardness of 6, with a density of 4.99 g/cm3 (calculated) and 5.03 g/cm3 (measured). Haitaite-(La) is opaque in transmitted light and grayish-white under reflected light, with a reflectivity between 22.5% and 16.42% in the 400–700 nm band (SiC, in the air). The compositions of the mineral were measured by EPMA, the U4+/U6+ ratio was determined by X-ray photoelectron spectroscopy and the Fe2+/Fe3+ ratio was determined by M?ssbauer spectroscopy. Haitaite-(La) is trigonal, belongs to R3ˉ and has unit-cell parameters a = 10.3678(5) ?, c = 20.8390(11) ?, V = 1939.9(2) ?3, Z = 3. The crystalline structure is composed of octahedra with 9 layers of close-packed octahedra (M1, M3, M4, M5), tetrahedra (M2) and contains large 12-coordinated M0 sites.

摘要:The Naruo porphyry copper deposit containing more than 2 Mt of copper is located in the Duolong ore district in the west of the Bangongco–Nujiang belt in central Tibet. New zircon U-Pb, biotite 40Ar/39Ar, zircon (U-Th)/He ages, published age data together with thermal modeling were presented in this paper to investigate the thermal history of Naruo deposit. Thermal modeling reveals a prolonged magmatic-hydrothermal evolution firstly cooling from ~700°C to ~350°C at 120 Ma, then cooling to 230°C at 106 Ma and maintaining at 200°C from 106 to 90 Ma which is attributed to multiple magmatic events and thermal effect of strike-slip fault. Affected by thrust nappe structure, the sample was consistent with 120°C from 70 to 63 Ma. The Naruo deposit started to experience exhumation at a rate of ~0.07 km/Myr since 60 Ma which is related to India-Asia collision. The prolonged magmatic-hydrothermal evolution process might have important influence on the Naruo deposit. The ore-related intrusions preserved in the foot walls of strike-slip fault and thrust nappe structure are the objects of future exploration in the Duolong ore district.

摘要:The Lanping?Simao Basin is located on the southeastern Tibetan Plateau, China, and contains massive evaporites. The origin of evaporites in the basin has been hotly debated because of the strong transformation by tectonic movement. Forty halite samples from borehole MK-3 in the Mengyejing area of the basin were collected and analyzed using XRD, Cl-Sr isotopes and chemical compositions to trace the origin of the evaporites in the basin. The Br × 103/Cl ratios of the halite samples are between 0 and 0.55, most of which are synchronized with the law of seawater evaporation and at the stage of halite precipitation from seawater, indicating that the evaporites are mainly of marine origin. The 87Sr/86Sr ratios range from 0.707489 to 0.711279; after correction, the 87Sr/86Sr 145 Ma ratios range from 0.704721 to 0.707611, equivalent with the 87Sr/86Sr ratios of seawater at 145 Ma, indicating a marine origin. The decay of 87Rb in the evaporite during deposition, change of the depositional environment and the unsealed environment at a later period resulted in the present 87Sr/86Sr ratios of some samples being high. The δ37Cl value compositions range from ?0.38‰ to 0.83‰, which is consistent with the δ37Cl value composition of the world marine halite (?0.6‰ to 0.4‰), further confirming that seawater is the main origin. In addition, the high δ37Cl value of some samples at the boundary of the upper and lower evaporite layers might be related to the influence of δ37Cl-rich brine and the incomplete dissolution of the halite.

摘要:Although the Mehdiabad zinc-lead deposit is one of the most well-known deposits in the central Iran structural zone, the genesis of the deposit remains controversial. The host rock of the ore is a dolomitic limestone of the Lower Cretaceous Taft Formation. In the two main orebodies of the deposit, which includes the Black Hill and East Ridge ore zones, the oxide and sulfide ores are observed at the surface and at depth, respectively. The elements Zn, Fe, Mn and Mg are more abundant in the East Ridge ore zone (in both sulfide and oxide ores), with Ba, Pb, Ag and Cu being more abundant in the Black Hill oxide ore. Based on the distribution of elements and their correlation with each other in these ore zones, the elements are divided into three general groups, that of terrigenous elements, chemically-deposited elements and ore-forming (hydrothermally deposited) elements, a division that is supported by the results of factor analyses. The spatial distribution of elements is jointly affected by contact with host rocks, the boundary of oxide-sulfide ores and fault zones. The main factors governing the distribution of elements are the mechanical transfer of detrital sediments, chemical sedimentation, transfer by hydrothermal fluids, oxidation and surface dissolution, all of which affected the spatial distribution of elements. The ore-forming elements are mostly affected by hydrothermal fluids and oxidation. This study not only provides additional information about the genesis of the Mehdiabad deposit, but also could assist in the exploitation of ore and further exploration purposes. The results of this study can aid in the exploration and exploitation of the Mehdiabad deposit and similar deposits in the region.

摘要:Pakistan is rich in coal resources, which amount to around 186 billion tons. The Paleocene Padhrar and Darra Adam Khel coalfields are located in the Central Salt Range Punjab Province and the Khyber Pakhtunkhwa Province, Pakistan, respectively. Padhrar coal has not been studied in detail and the Darra Adam Khel coalfields are newly-discovered, so no research has been done, due to security considerations. In this study, an attempt has been made to study the geochemical and mineralogical characteristics of the Padhrar and Darra Adam Khel coals, in order to learn about the coal quality, element enrichment mechanism, sedimentary medium conditions and potentially valuable elements for coal utilization. The Padhrar and Darra Adam Khel coals are low to medium ash, low moisture content, high in volatiles and high total sulfur coal. The vitrinite reflectance in Darra Adam Khel coal is higher than in Padhrar coal, indicating either a greater burial depth or the effects of Himalayan tectonism. The vitrinite content is dominant in the Padhrar and Darra Adam Khel coals, followed by inertinite and liptinite, the major minerals including quartz, clay minerals, calcite and pyrite. The trace elements Ni, As, Be Zn, Ge, Mo, Ta, W, Co and Nb, Sn, Hf, Ta, Pb, Th, Cd, In, Be, V, Cr, Zr, Ag, Li, W and Co are concentrated in some of the Padhrar and Darra Adam Khel coal samples, respectively. The Padhrar coal shows positive Ce, Eu and Gd anomalies, with most of the Darra Adam Khel coal showing negative Ce, Eu and positive Gd anomalies with high LREE. The Al2O3/TiO2 values indicate that the sediment source of the Padhrar and Darra Adam Khel coals is mostly related to intermediate igneous rocks. The Sr/Ba, SiO2 + Al2O3, Fe2O3 + CaO + MgO/SiO2 + Al2O3 and high sulfur content in the Padhrar and Darra Adam Khel coals indicate epithermal and marine water influence with a tidal flat, coal-forming environment and a deltaic coal-forming environment, respectively.

摘要:The Pearl River Mouth Basin (PRMB) is an important area for studying the evolution of continental marginal basins in the northern South China Sea (SCS), but the structural variability and spatiotemporal rifting process remains poorly understood. This study investigates the differential structural features of the eastern, middle and western PRMB, as well as the extensional deformation laws in operation during the rifting stage, according to an integrated analysis of geometric characteristics and kinematic parameters, i.e., horizontal displacement and stretching factors of basin and crust. The PRMB underwent at least three phases of intense extension, which varied in time and space. (1) During the middle Eocene, most sags in the PRMB were intensely stretched and high-angle planar to listric boundary faults controlled the wedge-shaped stratigraphic geometry. (2) During the late Eocene-to-early Oligocene, the stratigraphic geometry of the sags was slightly wedge-shaped and continuously controlled by boundary faults, however, the extensional strength decreased relatively in the Northern depression zone, but increased in the Southern depression zone. (3) During the late Oligocene, the extension was extremely weak in the northeast PRMB, but relatively strong in the southwest PRMB, leading to tabular stratigraphic geometry in the northeast PRMB, but localized slightly wedge-shaped stratigraphic geometry in the southwest. The southwest PRMB still underwent relatively strong extension during the early Miocene. The southwest PRMB that was induced by a small-scale localized mantle convection system constantly rifted during the late Oligocene, controlled by the weak lithosphere, westward (southwestward) diachronous opening and southward jump of the ocean ridge. The applied quantitative parameters and spatiotemporal rifting process may be used as a reference with which to study the segmented continental margin rifts.

摘要:The lack of preserved basement results in uncertain placements of many terranes in Southeast Asia. Here, we flag the first evidence of the oldest basement in Indonesian Borneo, which can help locate terranes in Borneo on the northern margin of Gondwana in the early Paleozoic and explain the regional tectonic setting of the island. Two schist samples from the Embuoi Complex in the Semitau Block, Northwest Kalimantan yielded zircon U-Pb dates of 453.3 ± 1.9 Ma and 462.4 ± 2.6 Ma, respectively, representing the formation time of the protolith. Petrographic, internal structural and high Th/U ratios of zircons indicate that the protolith of schists is of magmatic origin. The zircons have εHf(t) values of ?4.1 to +1.1 and Hf model ages of 1.37–1.69 Ga, indicating they were derived from a mixed source of juvenile crust with old components. By comparison of zircon age distribution, two-stage Hf model ages and εHf(t) variations of the early Paleozoic igneous rocks from Semitau with those of South China, Tengchong–Baoshan, and Indochina, the Semitau Block was most likely a part of or placed next to the Indochina Block of northern Gondwana during the early Paleozoic. Such a similar tectono-magmatic pattern on northern Gondwana formed a prolonged early Paleozoic arc-related belt associated with subduction of the Proto-Tethyan Ocean.

摘要:Paleoclimate reconstruction of continental environments has been hampered by the limited evidence. A thick sequence of Jurassic continental deposits in the Sichuan Basin, Southwest China yields abundant paleosols that may offer valuable insights regarding Jurassic climate scenarios. A succession of 169 paleosols belonging to Protosols, Calcisols, and Argillisols from 23 detailed stratigraphic sections was recognized and characterized macro- and micromorphologically and assessed for mineral and geochemical compositions. Quantitative paleoclimate reconstructions using bulk geochemical proxies, the depth to and the stable oxygen isotopic composition of paleosol carbonates indicated a predominant alternation of semiarid and arid cool/warm-temperate climatic conditions punctuated by several episodes of subhumid and humid climates that generally prevailed in the Sichuan Basin during the Jurassic. The estimated paleoatmospheric CO2 concentrations (pCO2) from calcic paleosols yielded a low range of ~104 ± 58 to ~610 ± 152 ppmv during the Middle Jurassic. The terrestrial paleotemperature changes in the Sichuan Basin coincided with the pCO2 variations, which probably resulted from global geological events (e.g., volcanic activities, magmatic and oceanic events, and the ephemeral caps development) in the Middle Jurassic. Jurassic climatic fluctuations in the basin were likely attributed to true polar wander due to global plate motion, megamonsoon effect linked to global and regional paleogeography, and regional paleotopography.

摘要:Tin (Sn) isotope geochemistry has great potential in tracing geological processes. However, lack of equilibrium Sn isotope fractionation factors of various Sn species limits the development of Sn isotope geochemistry. Equilibrium Sn isotope fractionation factors (124Sn/116Sn and 122Sn/116Sn) among various Sn(II, IV) complexes in aqueous solution were calculated using first-principles calculations. The results show that the oxidation states and the change of Sn(II, IV) species in hydrothermal fluids are the main factors leading to tin isotope fractionation in hydrothermal systems. For the Sn(IV) complexes, Sn isotope fractionation factors depend on the number of H2O molecules. For the Sn(II) complexes, the Sn isotope fractionation between Sn(II)?F, Sn(II)?Cl and Sn(II)?OH complexes is mainly affected by the bond length and the coordination number of anion, whereas the difference in 1000lnβ values of Sn(II)?SO4 and Sn(II)?CO3 complexes is insignificant with the change of anion coordination number. By comparing the 1000lnβ values of all Sn(II, IV) complexes, the enrichment trend in heavy Sn isotopes is Sn(IV) complexes > Sn(II) complexes. The equilibrium Sn isotopic fractionation factors enhance our understanding of the tin transportation and enrichment processes in hydrothermal systems.

摘要:Determination of Fe2+/Fe3+ ratios from metallogenic belts to explore controlling physical and chemical conditions of rock formation is of great significance. In order to explore magnetite Fe2+/Fe3+ ratios of the Qimantag metallogenic belt, part of the Eastern Kunlun orogenic belt in the northeastern margin of the Qinghai–Tibetan plateau, western Central Orogenic Belt of China, and overcome the limitation of the traditional electronic probe, five different measurement methods are proposed and their respective advantages and disadvantages evaluated, with the composition data of the magnetite obtained using electron probe microanalysis (EPMA). The direct oxygen measurement method has a significant impact on the determination results of FeO and Fe2O3, but the accuracy and uniformity of the results are low. The valence method (Flank method) based on the spectral intensity ratio of Lα to Lβ for iron is also unreliable for FeO and Fe2O3 measurements because it is difficult to establish a relationship between Lβ/Lα, the spectral intensity ratio, and the Fe2+/Fe3+ content ratio. In comparison, the charge difference method, the surplus-oxygen method and the M?ssbauer spectrum method are still the most favorable. M?ssbauer spectroscopy, with its isomer movement particularly sensitive to the oxidation state of iron, yields results closer to 0.5, which is relatively reliable. Earlier magnetite deposits are located in intrusions or contact zones and formed by magmatic fluids with high Fe2+/Fe3+ ratios, whereas later magnetite deposits are farther away from intrusions and have low Fe2+/Fe3+ ratios. The transformation mechanism of hematite and magnetite in the Qimantage metallogenic belt is also studied. No large volume changes, such as pore filling and shrinkage fracture, were detected in the metallogenic belt, and the transformation mechanism is more similar to a reoxidation and reduction mechanism.

摘要:Garnet occurs in a wide range of rock types, from mantle peridotites to granites, from eclogites to skarns. In recent years, garnet LA-ICP-MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry) U-Pb dating has provided a powerful solution for retrieving the ages of rock formations, but successful dating is often prohibited by the low concentration of U. However, the concentration of U, a trace element of garnet, is unknown prior to the LA-ICP-MS analysis. In this study, we propose that the U concentration in garnet can be predicted by the contents of major and minor elements, which can be quantitatively obtained by EPMA (electron probe microanalysis). Using a supervised machine learning method (neural network), a model is trained to discriminate U-rich (>2 ppm) and U-poor (<2 ppm) garnets, based on EPMA results. Results of cross validation shows that the model has an average accuracy of ~92% and is a powerful tool in detecting datable U-rich garnet. To facilitate the use of the discriminator, it is programmed as a stand-alone Microsoft Excel spreadsheet (HighUGarnet) and users directly paste the molar proportions of garnet end members into it and obtain the discrimination result.

摘要:The above article from Acta Geologica Sinica (English Edition), published online on 27 December 2018 in Wiley Online Library (wileyonlinelibrary.com) and in Volume 92, Issue 6, pp. 2297–2309, has been retracted by agreement between the authors, the journal Editor in Chief, Professor Zengqian Hou and John Wiley & Sons Ltd. The retraction has been agreed due to major overlap with a previously published article from the same group of authors published in Chinese.