中国锆资源与成矿
doi: 10.19762/j.cnki.dizhixuebao.2024127
陈炳翰 , 余金杰 , 姚佛军
中国地质科学院矿产资源研究所,自然资源部成矿作用与资源评价重点实验室,北京, 100037
基金项目: 本文为国家重点研发计划项目(编号2023YFC2906401)、中国地质调查局项目(编号DD20230040,DD20230366)和科技基础资源调查专项课题(编号2022FY101703)联合资助的成果
Zirconium resources and mineralization in China
CHEN Binghan , YU Jinjie , YAO Fojun
MNR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, CAGS, Beijing 100037 , China
摘要
本文将中国锆矿划分为碱性花岗岩型、碱性杂岩型、伟晶岩型、风化壳残坡积型、滨海沉积型和河流冲积型,将锆矿预测类型划分为花岗岩型、伟晶岩型、滨海沉积型、河流冲积型、风化壳残坡积型。中国锆矿资源分布在内蒙古、海南、四川、广东等15个省(自治区)。中国锆矿形成于新元古代、晚古生代、中生代、新生代,主要形成于中生代和新生代。划分了14个锆矿成矿带,厘定出34个与锆矿有关的成矿系列,建立了中国锆矿成矿谱系。东南沿海的滨海沉积型和河流冲积型锆矿是将来锆矿找矿的重点。
Abstract
This article divides China's zirconium deposits into alkaline granite, alkaline complex, pegmatite, weathering crust-residual slope deposit, coastal sedimentary, and river alluvial types. The predicted types of zirconium deposits are divided into granite, pegmatite, coastal sedimentary, river alluvial, and weathering crust-residual slope deposits. China's zirconium resources are distributed across 15 provinces and autonomous regions, including Inner Mongolia, Hainan, Sichuan, and Guangdong. Statistical analysis delineates four principal metallogenic epochs: Neoproterozoic, Late Paleozoic, Mesozoic, and Cenozoic. This framework allows for the division of 14 zirconium metallogenic belts and the determination of 34 zirconium-related metallogenic series, culminating in the establishment of a national zirconium deposit metallogenic pedigree. The coastal sedimentary and river alluvial zirconium deposits along the southeastern coast constitute primary prospects for zirconium exploration.
锆具有高熔点、高沸点、无毒环保、耐腐蚀等一系列优异的性能,被广泛应用于现代陶瓷、特种玻璃、原子能工业等战略性新兴产业以及化工、精密铸造和医疗等各个产业领域。限于技术经济、外部环境和生态环保约束,中国目前没有开采的锆矿山。中国是世界锆矿资源的进口大国和消费大国(刘劲松和高丽丽,2023)。随着中国经济已由高速增长阶段转向高质量发展阶段,在未来十几年内中国对锆矿资源需求仍将保持较大的规模,中国锆英砂供应将长期从澳大利亚和南非等国进口(智研咨询,2022)。前人对中国锆矿矿床类型、成矿时空展布特征、资源现状、开发利用和找矿远景进行了研究(张建文等,2019王汝成等,2020尹传凯等,2024)。研究结果表明,中国锆矿床主要分布于内蒙古、海南、四川、广东等15个省(自治区)。中国内生锆矿床在空间上常与铌钽矿床共伴生,时间上主要形成于晚古生代和中生代,与碱性—过碱性花岗岩、花岗伟晶岩和铝质花岗岩有关(王汝成等,2020),塔里木-华北克拉通北缘断裂带和大兴安岭南段具有较大找矿潜力(尹传凯等,2024),但中国内生锆矿资源禀赋较差,现有的技术经济条件下无法开采。中国可供开采的锆铪资源主要来源于滨海沉积型锆砂矿,海南岛东部海域、西部昌化江河口和胶东半岛东南沿海区有较大找矿潜力(刘洪树,1989迟洪纪等,2001王颖,2002)。中国锆矿资源长期自给不足,主要进口低品位的锆中矿和品位65%以上的锆精矿(张建文等,2019王汝成等,2020尹传凯等,2024)。然而,到目前为止,前人并未关注中国锆成矿区带划分、与锆成矿有关的成矿系列和成矿谱系等重要问题。
本文通过对全国锆矿床和矿产地、矿产勘查、科研成果、预测评价等资料进行综合整理和分析,在前人工作基础上,对中国锆矿床和矿产地中矿床类型进行归类,对中国锆矿资源概况进行了剖析,尝试对中国锆矿时空分布规律进行总结,共划分出14个锆成矿带,共划分出34个与锆成矿有关的成矿系列,建立了中国锆矿的成矿谱系图,希望能推动中国锆矿的找矿勘查和资源潜力评价工作,对中国锆矿的保护、监督和开发具有促进作用。
1 锆元素地球化学行为
锆具有强烈的亲氧性,自然界中锆大部分以氧化物形式存在,锆石是主要的含锆矿物。锆英砂常以晶体状态出现,呈四方柱结构,多与钛铁矿、金红石、独居石、磷钇矿等共生。锆英砂理论上含有67.1%的ZrO2,32.9%的SiO2。纯净的锆英砂为无色透明的晶体,常因产地不同、含杂质的种类与数量不同而呈黄、橙、红、褐等色,莫氏硬度为7.8,密度为4.6~4.71 g/cm3,折射率为1.93~2.01,熔点为2550℃。
大陆上地壳中锆含量约193×10-6Rudnick and Gao,2003),锆的富集成矿作用既可以发生于内生成矿过程,也可以与表生成矿过程有关(王汝成等,2020)。在内生成矿过程中,锆常富集在由岩浆结晶分异作用引起的残余岩浆中,尤其富集于碱性岩的造岩矿物中,如在碱性岩的霞石中,锆含量较高。高度演化的花岗质岩浆中常形成斜钠锆石和硅钠锆石等含锆矿物(Kynicky et al.,2011Gysi and Williams-Jones,2013),高度分异的花岗岩岩相中稀有副矿物为锆石、铌铁矿-钽铁矿、重钽铁矿、钍石、磷钇矿和独居石。因此,内生成矿过程中锆的超常富集与岩浆的高程度演化有关(Siegel et al.,2018吴鸣谦等,2024)。锆在热液流体中的溶解度非常低,很难发生大规模迁移与沉淀,流体只能对原生早先形成的含锆矿物进行原位再改造,导致锆元素的原位再分配(Migdisov et al.,2011)。
由于锆石耐风化和比重大特点,经表生成矿过程可形成外生矿床。高度分异的花岗岩富含含锆矿物,原岩遭受风化淋滤作用,结构已发生变化,活动性易迁移元素被移除,而耐风化的锆石被保留下来,在风化壳中形成风化壳残坡积型锆矿。在富含锆的的滨海地带,长期遭受风化剥蚀作用,为砂矿的形成提供了丰富的物质来源,由于锆石耐风化和比重大特点,易形成滨海沉积型锆砂矿。河水流速快,利于侵蚀切割岩石,部分河流受季节控制明显,其丰水期河水流速要比平时高数倍,流量也大大增加,有利于含锆、钛碎屑向河口及邻近海域的输运(杨奕等,2010)。
2 中国锆矿矿床类型
在分类中,一级划分是与三大类地质作用相对应,即分为内生矿床、外生矿床、变质矿床和叠生矿床四大类。有的研究将锆矿床划分为硬岩型和砂矿型。对锆矿而言,可划分为内生锆矿和外生锆矿(表1)。二级划分是按照在一定地质环境下的主要成矿作用系列来划分的,锆矿可划分为岩浆作用锆矿、表生作用锆矿和沉积作用锆矿。
三级划分则由于各类矿床形成环境的复杂性和成矿方式的多样性,很难采用统一的标志。考虑到岩浆作用锆矿床主要与岩浆岩(过碱性—碱性花岗岩、过铝质花岗岩和花岗伟晶岩)有关,根据与成矿有关的花岗质岩石岩性特征,岩浆作用锆矿可进一步划分为碱性花岗岩型锆矿、碱性杂岩型锆矿和伟晶岩型锆矿(表1)。碱性花岗岩型或碱性杂岩型锆矿形成于碱性花岗岩岩浆演化晚期或岩浆-热液过渡阶段,碱性(杂)岩岩体分布于陆内裂谷、板块边缘以及造山后等伸展构造环境(王汝成等,2020),主要矿床包括内蒙古扎鲁特旗巴尔哲铀稀土锆矿和辽宁凤城市赛马铀稀土锆矿。伟晶岩型锆矿床多产于由准铝质或过碱性质的A型花岗岩分异演化形成的NYF型花岗伟晶岩中,常呈层状或脉状产出,锆石常与铌铁矿族矿物、电气石等矿物共生(王汝成等,2020)。伟晶岩型锆矿主要分布于江西、新疆和内蒙古,如江西海罗岭,新疆可可托海、依兰里克,内蒙古察汗沟、汉营子。
1锆矿矿床类型划分表
Table1Classification of zirconium ore deposit types
沉积作用形成锆砂矿,包括滨海沉积型锆砂矿和河流冲积型锆砂矿(表2)。滨海岸砂矿主要形成于第四纪高海面及现代时期,具有工业价值的滨海砂矿中的重矿物主要来自沿岸出露的寒武系变质岩系和混合岩以及广泛出露的印支期—燕山期中酸性岩及部分第三纪—第四纪基性喷发岩(陈华祝,2018),砂矿主要分布在现代海滩区的上部,矿体沿海岸线呈条带状分布,其长度往往是宽度的数十倍(谭启新,1998)。矿石矿物主要有锆石、斜锆石、独居石、磷钇矿、铌钽铁矿等(王汝成等,2020),重要的矿床集中在海南省和广东省。河流冲积型锆矿多产于中小型河流,沿岸伴随残坡积物和海相沉积物,矿体呈层状或似层状,矿层厚度变化大(0.5~95 m),矿体埋藏浅(0~85 m),易开发(陈华祝,2018),一般产自于富含锆石的花岗岩、碱性岩以及混合岩地区,矿石矿物为锆石、钛铁矿、独居石等,重要矿床有海南乌石、广东合山、云南勐往和勐阿等。
表生作用可形成风化壳残坡积型锆矿。风化壳残坡积型锆矿一般产于风化剥蚀强烈的海蚀阶地、河流剥蚀阶地、海岸地带丘陵、河流两岸的低缓丘陵和陡峡谷切割的多山高原地区,母岩一般为碱性岩(如霞石正长岩)、花岗岩、花岗斑岩和混合岩等富含锆石等锆矿物的岩石,重要矿床分布于广西北流市520锆英石矿、湖南姑婆山稀土锆矿、江西省龙南县塔背锆矿等(王瑞江等,2015王汝成等,2020)。
2中国典型锆矿成矿时代一览表
Table2Ore-forming ages of large-and medium-sized zircon deposits in China
注:锆矿(锆英石)规模:小型<5万t,中型5~20万t,大型≥20万t,超大型一般为大型的5倍。
依据矿床预测类型的定义(王登红等,2013),凡是由同一地质作用形成的,成矿要素和预测要求基本一致,可以在同一预测底图上完成预测工作的矿床、矿点和矿化线索可以归为同一“矿产预测类型”,本次研究工作将锆矿预测类型划分为花岗岩型、伟晶岩型、滨海沉积型、河流冲积型、风化壳残坡积型。
3 中国锆矿资源概况
据美国地调局(USGS)2023年资料,全球锆储量6800万t(氧化锆,下同),澳大利亚、南非、塞内加尔和莫桑比克4个国家锆含量合计占全球锆储量的85.7%,中国锆储量较少。
因矿体形态复杂、品位低、分离共生矿物成本高且开采难度较大等原因,全球极少原生锆矿达到经济开采级别(王汝成等,2020孙宏伟等,2023),目前全球工业上主要开采锆石砂床,全球90%工业开采多为砂矿型(孙宏伟等,2023)。砂矿主要包括滨海锆砂矿、河流冲积型锆砂矿和风化壳残坡积型锆砂矿,其中尤以滨海锆砂矿最具工业开采价值,规模和产量远大于河流冲积型锆砂矿和风化壳残坡积型锆砂矿(Peterson et al.,1986申正伟等,2016车东等,2016孙宏伟等,20192023任军平等,2021)。澳大利亚是全球锆英砂最丰富的国家,锆矿类型均为滨海砂矿型,多与金红石、钛铁矿共生,主要集中在Murray、Perth以及Eucla三大盆地(王汝成等,2020刘劲松和高丽丽,2023)。非洲已查明锆储量占全球的52%,其中莫桑比克、南非、马达加斯加、塞内加尔和肯尼亚集中了非洲几乎全部的锆矿资源。矿床类型以滨海锆砂矿为主,通常为上新世—全新世未固结的薄而平坦的砂层,重矿物以锆石、金红石和钛铁矿为主,含量2%~12%(张振芳等,2021)。
本次研究收集了全国主要的锆矿、矿产地信息。通过本次研究,中国锆矿资源分布在内蒙古、海南、四川、广东等15个省(自治区)。从矿床类型看,岩浆作用锆矿(碱性花岗岩型、碱性杂岩型和伟晶岩型锆矿)占全国总量的70%左右,沉积作用锆矿(滨海沉积型锆砂矿和河流冲积型锆砂矿)和表生作用锆矿(风化壳残坡积型锆矿)占30%。
岩浆作用锆矿(碱性花岗岩型、碱性杂岩型和伟晶岩型锆矿)均为伴生矿产,矿石品位低于边界品位或工业品位,矿石多属于难选冶矿石,现有技术经济条件下难以利用。风化壳残坡积型锆矿、滨海沉积型锆砂矿和河流冲积型锆砂矿在现有技术经济条件下可以开采利用,历史上也曾有过开采,近年来由于国家环保政策,锆砂矿矿山全部关闭。锆矿矿产地分布图见图1
4 锆矿成矿时代
本次研究收集了中国大部分矿床、矿点的成矿时代资料,大中型矿床成矿时代一览表见表2。锆英石是主要的赋锆矿物,碱性花岗岩、碱性杂岩和伟晶岩的形成时间近似代表了岩浆作用锆矿的成矿时代,外生锆矿(风化壳残坡积型锆矿、滨海沉积型锆砂矿和河流冲积型锆砂矿)形成于第四纪。
中国锆矿从新元古代到新生代均有产出,大致可以划分成新元古代、晚古生代、中生代、新生代,大部分矿床形成时代集中在新生代(表2图2)。伟晶岩型锆矿的主要成矿时代有新元古代、晚古生代、中生代、新生代,时间跨度较广,花岗岩型锆矿的主要成矿时代为中生代,这两种类型形成时代主要受其所处的大地构造位置影响,详见第5节。风化壳残坡积型锆矿、河流冲积型锆矿和滨海沉积型锆矿形成主要受其物源控制,成矿时代集中在新生代。物源、气候与水动力条件、海岸类型与地貌类型、第四纪沉积作用和海平面变化等因素控制砂矿的形成,其中物质来源是决定因素(Azmon and Golik,1995Dill,1998Carranza-Edwards et al.,2001Mark,2005Carling and Breakspear,2006Dill et al.,2006;Cascalho and Fradique,2007)。锆英石、金红石、钛铁矿等主要分布在中生代燕山期花岗岩区的滨海地带的砂矿中,砂矿的主要成矿期是更新世、全新世(黎广钊等,1988刘洪树,1989)。
5 锆矿空间分布规律
在Ⅲ级成矿区带划分(徐志刚等,2008)的基础上,结合锆矿的预测类型、主要锆矿床的时空分布特征及其区域成矿地质条件和成矿要素,将中国锆矿划分为14个成矿带(表3图3)。花岗岩型锆矿主要分布在突泉成矿带、康滇成矿带,伟晶岩型锆矿主要分布在北阿尔泰成矿带、康滇成矿带、粤东成矿带,主要分布于陆内裂谷、板块边缘以及造山后等伸展构造环境(王汝成等,2020)。在突泉成矿带,成矿母岩经历了高度演化,与蒙古弧形构造带和大兴安岭北北东向构造带的构造活动耦合,锆得以富集成矿,形成了国内最大的巴尔哲花岗岩型锆矿(陈金勇等,2019)。在北阿尔泰、康滇等成矿带,陆内伸展减压背景下,母岩花岗岩经历高度分异结晶 (Wu Fuyuan et al.,20172020London,2018),或者深部地壳物质小比例部分熔融,发生高程度分离结晶(Muller et al.,2015Simmons and Falster,2016),锆富集成矿。
1中国锆矿矿产地分布图
Fig.1Distribution of zircon deposits in China
1—可可托海;2—巴尔哲;3-莲花山;4—勐往;5—勐阿;6—勐海县城郊;7—官井;8—520;9—东胜;10—合山;11—525;12-22—兴隆,南港,铺前,昌烈,木兰头(东段),沙老,保定,保定海,海尾—南罗,蓬莱,长安;部分资料来源:蔡廷青,1975史炎培,1976刘力文,1989李尚尧和张超群,1997幸世军,2009王勇义,2009a2009b杨智荣,2009胡论元等,2010黄卓广,2010刘俊生,2010吕胜青,2010童贵生等,2010Wu Fuyuan et al.,2010林清梅和黄子龙,2012刘明,2012徐海明等,2012党飞鹏等,2015汪一凡,2015孙伟,2016Zhu Yusheng et al.,2016杨富全等,2018李志丹等,2019钟军等,2020宋家伟等,2021雷跃增和杨红,2022
滨海沉积型锆矿、河流冲积型锆矿、风化壳与残坡积型锆矿分布范围广泛,成矿带较多,这些地区发育适合砂矿形成及保存的条件。华北板块吕梁运动的岩浆岩将古老的变质岩(泰山群、胶东群等)经区域变质和混合岩化作用变为基底岩石,在长期上升的胶北和胶南隆起发育大量燕山期岩浆岩,为山东的滨海砂矿提供物质来源(迟洪纪等,2001)。华南板块边缘基底为变质复理石-类复理石建造,受印支期、燕山期、喜马拉雅期三次大的构造影响,广布富钾的钙碱性侵入岩,原岩长期遭受风化剥蚀,可为该区滨海砂矿富集成矿提供大量物质来源(孙岩,1999)。江河口及其邻近海域的平坦浅缓海岸属于砂砾质平原海岸(王颖,2002),是滨海砂矿赋存的有利海岸类型(杨奕等,2010)。在长江中下游、江南成矿带等地,气候炎热湿润,物理-化学风化作用强烈,在多山地形中,降水和河流冲刷出大量的碎屑为砂矿的形成提供了充足的物源(刘英俊和曹励明,1987)。在粤西、粤中、粤东等成矿带内,原岩受风化淋滤作用,原岩结构大都已发生变化,矿石大都呈松散状或黏土块状产出,半风化岩石保留了部分原岩结构,形成风化壳型锆矿(幸世军,2009)。
2中国锆矿床形成时代
Fig.2Metallogenic ages of zirconium deposits in China
3中国锆矿成矿带划分表
Table3Zirconium metallogenic belts in China
注:Ⅲ级成矿区带编号引自徐志刚等(2008)
北阿尔泰成矿带(Zr1)代表性矿床为新疆可可托海锂-铍-铌-钽-铯矿床,伴生锆,矿床类型主要为伟晶岩型,成矿时代属于中生代。锆成矿与成矿带中偏碱性花岗岩-伟晶岩有关。可可托海成因存在不同认识,部分学者认为该矿床发育与花岗岩-伟晶岩有关的稀有金属成矿系统,地壳深部发生部分熔融,形成了巨大隐伏的母岩花岗岩,同源岩浆经历不同阶段岩浆分异作用,含矿母岩在矿区的不同位置就位(Shen Ping et al.,2022申萍等,2023曹冲等,2024);部分学者提出了变质深熔成因模式,认为伟晶岩来自壳幔混合源区(赵振华等,2022)。
突泉成矿带(Zr2)代表性矿床为内蒙古巴尔哲稀土-铀-铌-铍-锆矿床(丘志力等,2014),矿床类型主要为花岗岩型,成矿时代属于中生代。巴尓哲碱性花岗岩体岩浆来源于下地壳和亏损地幔的混合源区,经历了较高程度的分异演化(Jahn et al.,2001;杨武斌等,2011),成矿作用与碱性花岗岩(A型花岗岩)岩浆演化密切相关,受高度演化岩浆后期阶段熔体-流体相互作用控制(Wu Mingqian et al.,20212023丁腾飞等,2023马甲栋等,2023;吴明谦等,2024)。
苏鲁成矿带(Zr3)代表性矿床为山东石岛锆英石砂矿床,矿床类型主要为河流冲积型,成矿时代属于新生代。锆成矿与该成矿带中洪积、冲积作用有关。
澜沧成矿带(Zr4)代表性矿床为云南勐往独居石矿床,矿床类型主要为河流冲积型,成矿时代属于新生代。锆成矿与成矿带中洪积、冲积作用有关。
康滇成矿带(Zr5)代表性矿床为四川甘洛地、四川德昌茨达、云南水桥、四川路枯白草、脚基坪、莲花山矿床,矿床类型主要为河流冲积型、风化壳残坡积型、花岗岩型、伟晶岩型,成矿时代属于中生代、新生代。花岗岩型锆矿与碱性花岗岩具有密切的成因联系,风化壳残坡积型和河流冲积型锆成矿分别与成矿带中风化残积淋滤富集作用和洪积、冲积作用有关。
长江中下游成矿带(Zr6)代表性矿床为安徽张家冲矿床,矿床类型主要为河流冲积型,成矿时代属于新生代。锆成矿与成矿带中洪积、冲积作用有关。
江南成矿带(Zr7)代表性矿床为湖南南江桥矿床,矿床类型主要为河流冲积型,成矿时代属于新生代。锆成矿与成矿带中洪积、冲积作用有关。
南岭成矿带(Zr8)代表性矿床为江西大峰脑、湖南姑婆山矿床,矿床类型主要为风化壳残坡积型、河流冲积型,成矿时代属于新生代。风化壳残坡积型、河流冲积型锆矿分别与成矿带中浅成花岗岩类有关的陆相表生风化残积作用和洪积、冲积作用有关。
武夷山成矿带(Zr9)代表性矿床为福建盖洋、福建雷钵岭矿床,矿床类型主要为河流冲积型、风化壳残坡积型,成矿时代属于新生代。锆成矿与成矿带中酸性花岗岩类表生风化作用残积带和洪积、冲积作用有关。
粤西成矿带(Zr10)代表性矿床为广东512、沙尾、博贺矿床,矿床类型主要为滨海沉积型、河流冲积型、风化壳残坡积型,成矿时代属于新生代。锆成矿与成矿带中酸性花岗岩类表生风化残积作用和洪积、冲积作用有关。
粤中成矿带(Zr11)代表性矿床为广东合山、丹南、高村等,矿床类型主要为河流冲积型、滨海沉积型、风化壳与残坡积型,成矿时代属于新生代。锆成矿与成矿带中酸性花岗岩类表生风化作用和洪积、冲积作用有关。
粤东成矿带(Zr12)代表性矿床为广东白石坑、江西海罗岭、福建五里桥等,矿床类型主要为伟晶岩型、河流冲积型、风化壳残坡积型,成矿时代属于中生代、新生代。锆成矿主要与成矿带中伟晶岩成矿作用,洪积、冲积作用有关。
3中国锆矿床成矿带分布图(底图据徐志刚等,2008
Fig.3Zirconium metallogenic belts in China (modified after Xu Zhigang et al., 2008)
浙闽粤成矿带(Zr13)代表性矿床为福建曾厝安、黄厝等,矿床类型主要为滨海沉积型、河流冲积型,成矿时代属于新生代。锆成矿与成矿带中滨海沉积作用及洪积、冲积作用有关。
海南成矿带(Zr14)代表性矿床为海南兴隆、海南翁田-昌洒等,矿床类型主要为滨海沉积型、河流冲积型,成矿时代属于新生代。锆成矿与成矿带中滨海沉积作用及洪积、冲积作用有关。
6 锆矿成矿系列与成矿谱系
矿床的成矿系列是指在一定的地质历史时期或构造运动阶段,在一定的地质构造单元及构造部位,与一定的地质成矿作用有关的一组具有内在成因联系的矿床的自然组合(陈毓川等,20062007)。在陈毓川、王登红等对全国重要矿床成矿系列厘定(陈毓川等,2010a2010b)的基础上,本次工作对与锆成矿有关的矿床成矿系列进行了重新整理,共划分出34个与锆成矿有关的成矿系列(表4),并依此建立了中国锆矿成矿谱系图(图4),从时空角度反映了区域锆成矿演化规律。从锆矿成矿谱系图(图4)可以看出,锆矿形成时代集中在新生代。北方地区的锆矿最早发育于新元古代,锆矿发育时间延续到新生代,主要成矿时间集中在晚古生代和中生代,主要为内生型锆矿;中部地区仅在长江中下游新生代形成锆矿;南方地区锆矿集中在新生代形成外生型锆矿,分布范围较广,中生代主要发育内生型锆矿。在华北陆块北缘、江南隆起东段等地区,晚古生代、中生代、新生代均有锆成矿,锆矿成矿系列的产出具有延续性。北方地区以中生代突泉花岗岩型锆矿为主,南方地区集中在新生代东南沿海滨海沉积型、河流冲积型、风化壳残坡积型锆矿。东南沿海的滨海沉积型、河流冲积型锆矿,是主要的锆矿产出类型,在今后的找矿和预测工作中,应加强这些地区的工作。
4中国锆矿床有关的成矿系列简表
Table4Related metallogenic series of zirconium deposits in China
注:系列名称和系列编号依据陈毓川等(2010a2010b),系列名称略有修改;Q代表第四纪。
4中国锆矿成矿谱系图(底图依据王成辉等,2014
Fig.4Metallogenic lineage figure of zirconium deposits in China (modified after Wang Chenghui et al., 2014)
7 结论
(1)中国锆矿资源分布在内蒙古、海南、四川、广东等15个省(自治区)。
(2)锆矿可划分为碱性花岗岩型、碱性杂岩型、伟晶岩型、风化壳残坡积型、滨海沉积型和河流冲积型。碱性花岗岩型、碱性杂岩型和伟晶岩型锆矿中矿石品位低于边界品位或工业品位,矿石属于难选冶矿石,现有技术经济条件下无法利用。在现有技术经济条件下,滨海沉积型和河流冲积型锆矿属于可利用矿床类型。
(3)中新生代是锆矿形成的主要时代。划分了14个锆矿成矿带,厘定出34个与锆矿有关的成矿系列,建立了中国锆矿成矿谱系。东南沿海的滨海沉积型和河流冲积型锆矿是今后的找矿和预测的重点。
致谢:感谢所有对“矿产资源国情调查与潜力动态评价”工作给予支持的领导、专家和技术人员,对匿名审稿人提出的宝贵意见表示感谢,他们提出的富贵修改意见使得本文质量有所提升。
1中国锆矿矿产地分布图
Fig.1Distribution of zircon deposits in China
2中国锆矿床形成时代
Fig.2Metallogenic ages of zirconium deposits in China
3中国锆矿床成矿带分布图(底图据徐志刚等,2008
Fig.3Zirconium metallogenic belts in China (modified after Xu Zhigang et al., 2008)
4中国锆矿成矿谱系图(底图依据王成辉等,2014
Fig.4Metallogenic lineage figure of zirconium deposits in China (modified after Wang Chenghui et al., 2014)
1锆矿矿床类型划分表
Table1Classification of zirconium ore deposit types
2中国典型锆矿成矿时代一览表
Table2Ore-forming ages of large-and medium-sized zircon deposits in China
3中国锆矿成矿带划分表
Table3Zirconium metallogenic belts in China
4中国锆矿床有关的成矿系列简表
Table4Related metallogenic series of zirconium deposits in China
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