基于LA-ICP-MS的微区原位U-Pb/裂变径迹双定年及前景展望
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1.中国地质科学院地质研究所;2.中国地质科学院地质力学研究所

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(编号42127801)和中国地质科学院地质力学研究所基本科研业务费专项(DZLXJK202504)联合资助的成果。第一作者及通讯作者张斌,男,1990年生。助理研究员,从事热年代学和火山学研究。E-mail: zhangbin@cags.ac.cn。共同通讯作者杨静,女,1984年生。副研究员,从事热年代学研究。Email: yangjing_cags@163.com。


In-situ U-Pb and fission-track double dating of apatite by LA-ICP-MS microanalysis: Methodology and prospects
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1.Key Laboratory of Isotope Geology,Ministry of Natural Resources,Institute of Geology,Chinese Academy of Geological Sciences;2.Key Laboratory of Active Tectonics and Geological Safety,Ministry of Natural Resources,Institute of Geomechanics,Chinese Academy of Geological Sciences

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    摘要:

    在同一矿物晶体上同时开展U-Pb和裂变径迹分析是近年来逐渐兴起并蓬勃发展的一种重要定年手段,能够有效约束地质体从高温结晶到低温冷却的热历史,是当前热年代学研究的重要前沿。本研究基于LA-ICP-MS技术,在建立锆石U-Pb定年流程的基础之上,经过样品制备、径迹统计和U、Pb同位素测试三大步骤,系统建立了针对磷灰石的微区原位U-Pb和裂变径迹双定年方法。Tanz, Ple?ovice和Qinghu三种锆石标样的实测U-Pb年龄分别为568.4±1.9 Ma、334.4±1.4 Ma及158.85±0.71 Ma,与推荐值一致。Durango、Mount Dromedary和Fish Canyon Tuff三种含有不同普通铅含量的国际常用磷灰石标样的分析结果则显示,U-Pb下交点年龄(分别为31.7±2.2 Ma、101.1±2.1 Ma和27.4±4.2 Ma)与裂变径迹中值年龄(分别为31.15±1.00 Ma、98.4±2.4 Ma和27.29±1.34 Ma)均在误差范围内与其推荐参考值一致,充分验证了本实验流程的准确性与可靠性。本研究建立的方法为精细反演造山带演化、盆地物源分析、地貌演化、矿床保存和改造、地球动力学等基础应用研究,以及热年学基本原理研究等提供了强有力的技术支撑。未来,将该方法与原位(U-Th)/He定年技术相结合,开发更高效率和更高精度的同一晶体三重定年技术将是重要的发展方向。

    Abstract:

    Conducting simultaneous U-Pb and fission-track analysis on the same mineral crystal has emerged as an important and rapidly developing dating method in recent years. This technique effectively constrains the thermal history of geological bodies from high-temperature crystallization to low-temperature cooling, representing a significant frontier in thermochronology. Based on LA-ICP-MS technology, and building upon the established zircon U-Pb dating procedure, this study systematically established an in-situ microanalysis method for double U-Pb and fission-track dating of apatite, following three main steps: sample preparation, track counting, and U-Pb isotope analysis. The U-Pb ages obtained for the three zircon standards—Tanz, Ple?ovice and Qinghu—are 568.4 ± 1.9 Ma, 334.4 ± 1.4 Ma, and 158.85 ± 0.71 Ma, respectively. While analyses of three international apatite standards with varying common Pb contents—Durango, Mount Dromedary, and Fish Canyon Tuff—yielded U-Pb lower intercept ages of 31.7 ± 2.2 Ma, 101.1 ± 2.1 Ma, and 27.4 ± 4.2 Ma, and fission-track central ages of 31.15 ± 1.00 Ma, 98.4 ± 2.4 Ma, and 27.29 ± 1.34 Ma, respectively. These results are consistent with recommended reference values within error, fully validating the accuracy and reliability of the established experimental procedure. The method developed in this study provides robust technical support for fundamental applied research—such as reconstructing orogenic belt evolution, basin provenance analysis, landscape evolution, ore deposit preservation and modification, and geodynamics—as well as for basic principles of thermochronology. In the future, an important direction will be to combine this method with in-situ (U-Th)/He dating to develop a more efficient and precise triple-dating approach on single crystals.

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  • 收稿日期:2025-11-23
  • 最后修改日期:2025-12-18
  • 录用日期:2025-12-29
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