大陆俯冲带碳循环的差异驱动机制研究:以柴北缘超高压变质带为例
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1.中国海洋大学海洋地球科学学院;2.天津大学表层地球系统科学研究院地球系统科学学院;3.中国海洋大学海洋地球科学学院,崂山实验室,海洋矿产资源评价与探测技术功能实验室

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国家自然科学基金重点项目(编号42530303)和泰山学者特聘专家项目(编号tstp20231214)


Differential driving mechanisms of carbon cycling in continental subduction zones: A case study of the North Qaidam ultrahigh-pressure metamorphic belt
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1.MOE Key Lab of Submarine Geosciences and Propecting Techniques,Insitute for Aduanced Ocean Study,College of Marine Geosciences,Ocean University of China,Qingdao;2.Institute of Surface-Earth System Science, Tianjin University;3.MOE Key Lab of Submarine Geosciences and Propecting Techniques,Insitute for Aduanced Ocean Study,College of Marine Geosciences,Ocean University of China,Qingdao.Laoshan Laboratory, Functional Laboratory for Marine Mineral Resource Assessment and Detection Technology

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    摘要:

    俯冲带碳循环是调控地球深部-浅部碳平衡的关键过程,其循环路径与时间尺度直接影响着地球大气的长期演化。以往研究多聚焦于单一循环路径的识别,尚未系统揭示不同碳循环路径在同一构造体系中的共存机制与演化特征。为此,本文选取柴北缘超高压变质带中鱼卡地体的大理岩及绿梁山碳酸岩为研究对象,开展了系统的岩石学、地球化学与锆石U-Pb年代学分析。结果显示:鱼卡大理岩记录了约443 Ma的超高压变质年龄,其低磷含量与稀土丰度指示其原岩为沉积成因碳酸盐岩;绿梁山碳酸岩则呈现430~410 Ma的碎屑锆石年龄峰值,其富集大离子亲石元素、亏损高场强元素的特征,以及与全球壳源碳酸岩一致的稀土配分模式,共同支持其壳源火成成因。结合区域构造背景,本文提出:鱼卡大理岩代表俯冲碳酸盐岩经超高压变质后沿“俯冲隧道”折返的固体循环路径;绿梁山碳酸岩则可能为俯冲板片拆离碳酸盐岩在碰撞后阶段部分熔融形成的熔体循环路径。两者共同揭示了造山带内碳以不同形式(固体 vs. 熔体)从深部返回地表的多样循环机制,为理解俯冲带碳的命运及造山带碳循环提供了新的约束。

    Abstract:

    Subduction zone carbon cycling is a key process that regulates the carbon balance between Earth’s deep interior and shallow reservoirs. The pathways and timescales of this cycling directly influence the long-term evolution of the atmosphere. Previous studies have predominantly focused on identifying individual carbon pathways, leaving the coexistence and evolution of multiple pathways within a single tectonic system poorly understood. To address this, we conducted an integrated petrological, geochemical, and zircon U-Pb geochronological study on marbles from the Yuka terrane and carbonatites from the Lülangshan terrane in the North Qaidam ultrahigh-pressure (UHP) metamorphic belt. Our results show that the Yuka marbles recorded a UHP metamorphic age of ~443 Ma. Their low phosphorus contents and low rare earth element (REE) abundances suggest a sedimentary carbonate protolith. In contrast, the Lülangshan carbonatites display a dominant detrital zircon age peak of 430~410 Ma. Their geochemical features including enrichment in large-ion lithophile elements (LILEs), depletion in high-field-strength elements (HFSEs), and REE patterns consistent with global average crust-derived carbonatites collectively support a crust-derived igneous origin. Combined with the regional tectonic setting, we propose that the Yuka marbles represent a solid-state return pathway, where subducted carbonates were metamorphosed under UHP conditions and subsequently exhumed via a subduction channel. In contrast, the Lülangshan carbonatites likely represent a melt pathway, formed by the partial melting of carbonate rocks detached from the subducted slab during the post-collisional stage, facilitated by upwelling asthenosphere. These two distinct rock types reveal diverse mechanisms solid versus melt for the return of carbon from depth to the surface in an orogenic belt, providing new constraints for understanding the fate of carbon in subduction zones and orogenic carbon cycling.

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  • 收稿日期:2025-11-07
  • 最后修改日期:2026-01-10
  • 录用日期:2026-01-13
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