四川冕宁牦牛坪稀土矿床成岩成矿年代学及其找矿意义
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1.成都理工大学地球与行星科学学院,四川 成都 610059;2.中国地质科学院矿产资源研究所,深地探测与矿产勘查全国重点实验室,自然资源部成矿作用与资源评价重点实验室,北京 100037;3.中国地质科学院矿产资源研究所,深地探测与矿产勘查全国重点实验室,自然资源部成矿作用与资源评价重点实验室;4.中稀(凉山)稀土有限公司

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中国稀土集团有限公司科技项目“四川省牦牛坪、大陆槽稀土矿成矿规律与找矿预测”(编号:HE2310);中国地质调查局“战略新兴产业矿产地质调查工程”(编号:DD20230034)、“四川康定一云南个旧稀有稀土矿产地质调查”(编号:DD20230290)和“中国矿产地质志续编与产品服务”(编号:DD20221695)项目联合资助。


Diagenetic and Metallogenic Chronology and Prospecting Significance in Sichuan Mianning Maoniuping Rare Earth Deposit
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1.College of Earth and Planetary Sciences, Chengdu University of Technology, Chengdu;2.MNR Key Laboratory of Metallogeny and Mineral Assessment, State Key Laboratory of Deep Earth and Mineral Exploration, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing;3.College of Earth and Planetary Sciences, Chengdu University of Technology, Chengdu 610059, China;4.3)China Rare Earth Group (Liangshan) Co., Ltd.;5.China Rare Earth Group (Liangshan) Co., Ltd.;6.MNR Key Laboratory of Metallogeny and Mineral Assessment, State Key Laboratory of Deep Earth and Mineral Exploration, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China

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    内容:四川冕宁牦牛坪稀土矿床是中国最重要的稀土矿床之一,位于中国西南部冕宁—德昌喜马拉雅稀土成矿带。前人研究表明稀土成矿作用与区内碱性岩—碳酸岩杂岩体密切相关,但现阶段对杂岩体成因及稀土矿化时代仍存在众多争议。本文测得碱长花岗斑岩年龄为25.41±0.27 Ma(MSWD=4.3, n=12),碱性正长岩年龄为26.05±0.36 Ma(MSWD=2.0, n=16),均与区内碱性岩—碳酸岩杂岩体成岩时代误差范围一致,表明碱长花岗斑岩与杂岩体存在成因联系,进一步证明含矿的碱性杂岩体形成于新生代古近纪向新近纪转折时期。不同矿石类型氟碳铈矿LA-ICP-MS U-Pb 测年结果显示,角砾状矿石年龄为(32.68±0.66 Ma, n=21)、霓辉石型矿石年龄为(30.2±0.89 Ma, n=16; 30.19±0.77 Ma, n=19)、方解石型矿石年龄为(27.61±3.43 Ma, n=23)。从角砾状矿石→霓辉石型矿石→方解石型矿石→碱性正长岩→碱长花岗斑岩,越来越年轻,但变化连续,表明成矿作用发生在6~7 Ma的时间范围内,由构造活动开道,富含流体的含矿岩浆从地壳深部甚至可能深达地幔的深度上侵到接近地表的浅部,形成次火山岩(斑岩),岩浆与岩浆热液同时作用,导致矿石与岩石逆序结晶而破碎、蚀变强烈。这一特点也说明,富含稀土及F的成矿熔—流体并非碱性正长岩和碱长花岗斑岩结晶分异的产物,而是岩浆熔—流体直接结晶形成的。因此,碱性正长岩和碱长花岗斑岩可以作为牦牛坪式稀土矿床的找矿标志。碱性正长岩和碱长花岗斑岩如果呈喷发状态进入到海水环境,则有可能形成的是类似于白云鄂博H8的粗面岩或富钾凝灰岩。也就是说,白云鄂博与牦牛坪两大稀土矿床的成矿机制有共性,但其成矿环境截然不同。

    Abstract:

    The Maoniuping deposit in Mianning, Sichuan, is one of the most significant rare earth element (REE) deposits, situated within the Mianning-Dechang Himalayan REE metallogenic belt in southwestern China. Previous studies on Homo sapiens have indicated that REE mineralization is closely associated with alkaline-carbonatite complexes in the region, but there remains considerable debate regarding the genesis of these complexes and the timing of REE mineralization. This study obtained ages of 25.31±0.26 Ma (MSWD=4.3, n=12) for alkali-feldspar granite porphyry and 26.0±0.3 Ma (MSWD=2.0, n=15) for alkaline syenite, both of which fall within the error range of the magmatic age of the alkaline-carbonatite complexes in the area. This suggests a genetic link between the alkali-feldspar granite porphyry and the complexes, further supporting the formation of ore-bearing alkaline complexes during the transition from the Paleogene to the Neogene in the Cenozoic era. LA-ICP-MS U-Pb dating of bastn?site from different ore types ages of 32.68±0.66 Ma (n=21) for breccia-type ores, 30.2±0.89 Ma (n=16) and 30.19±0.77 Ma (n=19) for aegirine-augite-type ores, and 27.61±3.43 Ma (n=23) for calcite-type ores. The sequence from breccia-type ores → aegirine-augite-type ores → calcite-type ores → alkaline syenite → alkali granite porphyry shows progressively younger but continuous ages, indicating that mineralization occurred over a span of 6~7 Ma. This process was initiated by tectonic activities, which facilitated the upward migration of ore-bearing, fluid-rich magmas from deep crustal or possibly even mantle depths to shallow subsurface levels, forming subvolcanic rocks (porphyry). The simultaneous interaction of magma and magmatic hydrothermal fluids led to intense fracturing, alteration, and reverse crystallization of ores and rocks. This characteristic also suggests that the REE and F-rich metallogenic melts-fluids were not products of fractional crystallization of alkaline syenite and alkali-feldspar granite porphyry but rather resulted from direct crystallization of magmatic melt-fluids. Therefore, alkaline syenite and alkali-feldspar granite porphyry can serve as prospecting indicators for Maoniuping-type REE deposits. If alkaline syenite and alkali-feldspar granite porphyry were erupted into a marine environment, they might form trachyte or K-rich tuff similar to the H8 unit in the Bayan Obo deposit. In other words, while the Bayan Obo and Maoniuping REE deposits share common metallogenic mechanisms, their mineralization environments are fundamentally distinct.

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  • 收稿日期:2025-09-14
  • 最后修改日期:2025-12-08
  • 录用日期:2026-01-07
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