江西下瑶离子吸附型稀土矿成矿机制
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1.河北地质大学地球科学学院;2.河北省战略性关键矿产资源重点实验室;3.江西省地质局第七地质大队;4.江西职业应用技术学院;5.中国地质调查局自然资源实物地质资料中心

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本文受到国家自然科学基金(No. 41702352)、自然资源部离子型稀土资源与环境重点实验室(No.2022IRERE105)、河北省自然科学(No. D2024403084)、河北省战略性关键矿产协同创新中心开放项目(No. HGUXT-2023-15)、河北地质大学预研项目(No. KY2024QN24)、河北地质大学青年项目(No. QN202217)资助。


Metallogenic mechanism of ion-adsorbed rare earth deposit in Xiayao, Jiangxi Province
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1.Hebei GEO University;2.The Seventh Geological Brigade of Jiangxi Provincial Geological Bureau;3.Jiangxi College of Applied Technology;4.hysical Geological Data Center of China Geological Survey

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    摘要:

    为还原离子吸附型稀土矿形成过程中稀土元素富集的完整过程。本次工作利用电感耦合等离子体质谱(ICP-MS)、X射线衍射实验(XRD)、电子探针、短波红外光谱测试、锆石U-Pb测年和Hf同位素测试等技术方法对下瑶矿床中成矿母岩和风化壳样品进行测试。柯树北花岗岩体黑云母花岗岩具有高钾钙碱性、弱过铝质特征。其锆石U-Pb同位素年龄为196.26±1.53 Ma,194.72±1.1 Ma和197.18±1.77 Ma。εHf(t)值为-3.35~1.79。稀土矿物有磷灰石、锆石、氟碳铈矿和磷钇矿等。风化壳内稀土元素富集在中上部。表明柯树北岩体为印支期岩浆活动产物,产出于伸展构造环境下诱发的古长英质地壳重熔环境。其中稀土元素的富集过程主要与岩浆演化相关,辅以热液作用。风化壳中吸附元素的二次富集受黏土矿物、pH值和风化程度的制约。

    Abstract:

    To restore the complete process of rare earth element enrichment during the formation of Ion-adsorption rare earth type deposits. In this study, the ore-forming parent rock and weathered crust samples in the Xiayao ion-adsorption rare earth type deposit were studied by inductively coupled plasma mass spectrometry (ICP-MS), inductively coupled plasma spectroscopy (ICP-OES), X-ray diffraction experiment (XRD), electron probe, zircon U-Pb dating and Hf isotope test. The Keshubei granite is identifiedas high-K calc-alkaline and slightly peraluminous. Zircon grains from the Keshubei granite exhibit U-Pb ages of 196.26±1.53 Ma, 194.72±1.1 Ma, and 197.18±1.77 Ma. The value of zircon εHf(t) inKeshubei graniterangefrom-3.35to1.79. Rare earth minerals include apatite, zircon, bastnaesite and Xenotime. The rare earth elements in the weathered crust are enriched in the middle and upper parts. It is indicated that the Keshubei granite is the product of Indosinian magmatic activity, which is produced in the ancient felsic crustal remelting environment induced by the extensional tectonic environment. The enrichment process of rare earth elements is mainly related to magmatic evolution, supplemented by hydrothermal action. The secondary enrichment of adsorbed elements in the weathered crust is restricted by clay minerals, pH value and weathering degree.

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  • 收稿日期:2025-07-31
  • 最后修改日期:2025-11-05
  • 录用日期:2025-11-06
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