锰金属的资源属性、地质特征及其利用
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本文为国家重点研发计划项目(编号2022YFC2903405)、天津市科技计划项目(编号24JCQNJC00840)、中国地质调查局项目(编号DD20230571)和自然资源部新一轮找矿突破战略行动科技支撑项目(编号ZKKJ202404)联合资助的成果


Resource attributes, geological characteristics, and utilization of manganese metal
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    摘要:

    锰当前已被多国列为战略性金属矿产,其地球化学行为、分布规律与成矿机制对资源勘探和工业应用至关重要。本文系统总结了锰的地球化学特性、矿床类型、成矿模式及资源潜力,探讨了全球锰矿的成矿分布规律与典型锰矿地质特征。详细阐述了锰的多价态(Mn2+/Mn3+/Mn4+)特性,指出锰在自然界中的存在形式受氧化还原条件、pH值以及温度等因素的控制。全球锰矿床可归纳为海相沉积型(主要包括BIF型、黑色页岩型和碳酸盐岩容矿型)、表生型、铁锰结核型和铁锰结壳型四大类,通过聚焦全球典型锰矿床,如南非卡拉哈里锰矿田、黑海地区副特提斯锰矿集区及中国高地锰矿床等,进一步归纳了各类型锰矿床的地质背景、矿床成因与地球化学特征,对构造背景与沉积环境的关系进行了初步探讨。结合前人的研究结果表明,这些矿床的形成,大多都受到古元古代、新元古代以及显生宙时期古海洋氧化还原环境变化的影响(如大氧化事件GOE、新元古代氧化事件NOE、显生宙冰- 温室气候交替等)。同时,对锰资源在钢铁冶金、新能源电池、农业肥料与环境催化等领域的广泛应用进行了梳理,指出随着新能源产业的发展,锰基电池材料(如锰酸锂、NCM三元材料)需求持续增长,锰资源开发的重要性日益凸显。

    Abstract:

    Manganeseis currently classified as a strategic metal by many countries; consequently, understanding its geochemical behavior, distribution patterns, and metallogenic mechanisms is crucial for resource exploration and industrial applications. This paper systematically summarizes the geochemical characteristics, deposit types, metallogenic models, and resource potential of manganese, and explores the spatial distribution patterns and typical geological features of global manganese deposits. The multivalent nature of manganese (Mn2+/Mn3+/Mn4+) is discussed in detail, highlighting that its mobility and precipitation are controlled by redox conditions, pH, and temperature. Global manganese deposits are classified into four main types: marine sedimentary (including BIF- type, black shale- hosted, and carbonate- hosted deposits), supergene, ferromanganese nodule, and ferromanganese crust. Focusing on typical global manganese deposits (such as the Kalahari Manganese Field in South Africa, the Peri- Tethyan manganese district in the Black Sea region, and the Gaodi manganese deposit in China), the geological setting, genesis, and geochemistry of each type are further summarized, and the relationship between tectonic background and sedimentary environment is preliminarily discussed. Based on previous research, the formation of these deposits was largely influenced by paleo- ocean redox fluctuations during the Paleoproterozoic (Great Oxidation Event), Neoproterozoic (Neoproterozoic Oxidation Event), and Phanerozoic (alternating ice- greenhouse climates). Finally, applications in steel metallurgy, new energy batteries, agricultural fertilizers, and environmental catalysis are reviewed. The expanding new energy industry continues to drive demand for manganese- based battery materials (e. g. , lithium manganate and Ni- Co- Mn ternary materials), reinforcing the strategic significance of manganese resource development.

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引用本文

郭馨莲,蔡为民,卢宜冠,任军平,孙凯,张起钻.2026.锰金属的资源属性、地质特征及其利用[J].地质学报,100(2):633-656.
GUO Xinlian, CAI Weimin, LU Yiguan, REN Junping, SUN Kai, ZHANG Qizuan.2026. Resource attributes, geological characteristics, and utilization of manganese metal[J]. Acta Geologica Sinica,100(2):633-656.

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  • 收稿日期:2025-06-27
  • 最后修改日期:2025-09-15
  • 录用日期:2025-09-29
  • 在线发布日期: 2025-11-10
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