庐枞科钻XRF元素及红外光谱特征
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中国地质调查局自然资源实物地质资料中心

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国家科学技术部科技基础资源调查专项(我国代表性科学钻探岩心科学数据库建设-2022FY101800)、中国地质调查项目(实物地质资料采集更新与数字化应用-DD20230138)


XRF element and infrared spectrum characteristics of Luzong scientific drill
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Core and sample center of natural resources

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    摘要:

    庐枞矿集区是长江中下游成矿带重要多金属矿集区及花岗岩型铀矿成矿区,庐枞科学深钻首次揭示了高温型铀矿化,在该钻孔系统开展矿物学、地球化学及光谱学综合分析,对于指导铀矿找矿、研究矿物光谱及成分变化关系具有重要意义。本文主要采用短波-热红外光谱测试、XRF元素测试、电子探针元素分析等方法,系统开展了科钻矿物分布、FMI铁镁质变化,以及绿泥石波谱、成分及成矿指示性方面的研究。研究表明,红外光谱对于火山岩类岩浆岩矿物识别仍具有较好效果。热红外光谱FMI值可作为半定量区分岩浆岩中铁镁质相对含量变化的可靠依据,可以指示岩性区分、成矿环境变化,使用XRF元素数据进行钻孔主微量元素分析在整体变化趋势上具有较好参考指示意义。庐枞科钻绿泥石可分为弥散状、面状分布绿泥石及网脉状分布绿泥石。弥散状、面状分布绿泥石主要为蠕绿泥石,少量密绿泥石,而网脉状分布的绿泥石主要为密绿泥石及铁斜绿泥石,不同类型绿泥石均为三八面体绿泥石。绿泥石温度整体处于194~349℃范围内,相对来说弥撒状、面状分布的绿泥石温度更高,在300~349℃范围内,呈网脉状分布的绿泥石形成温度在190~324℃之间。庐枞科钻中绿泥石红外光谱Pos2250主要分布在2245~2257nm之间,整孔变化未呈现明显变化趋势。本文首次提出,在庐枞矿集区当深部出现较多波长小于2248.8nm的绿泥石时,可指示高温铀钍矿化。

    Abstract:

    The Lu-Zhong Mining District, situated within the Middle-Lower Yangtze River Metallogenic Belt, is significant for its polymetallic and granitic-hosted uranium deposits. This study presents the first discovery of high-temperature uranium mineralization through scientific deep drilling in the district. Utilizing shortwave to thermal infrared (SWIR-TIR) spectroscopy, X-ray fluorescence (XRF) elemental analysis, and electron microprobe techniques, we systematically analyzed the mineral distribution, ferromagnesian mineral variations using the FMI, and the spectroscopic and compositional characteristics of chlorite.Our findings indicate that infrared spectroscopy effectively identifies minerals in volcanic and igneous rocks. The FMI from TIR spectra reliably distinguishes relative changes in ferromagnesian content, aiding in lithological differentiation and understanding ore-forming environments. XRF data provide valuable insights into the major and trace element trends within the drill core.Chlorites in the drill core are classified as disseminated, sheet-like, and veinlet-distributed, primarily consisting of clinochlore and penninite, with all types being trioctahedral. Disseminated and sheet-like chlorites formed at higher temperatures (300-349°C) compared to veinlet-distributed chlorites (190-324°C). The Pos2250 feature in chlorite infrared spectra ranges from 2245nm to 2257nm without a clear trend throughout the core.Notably, this study proposes that the presence of chlorites with wavelengths less than 2248.8nm at depth may indicate high-temperature uranium-thorium mineralization in the Lu-Zhong district, providing a new indicator for exploration.

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  • 收稿日期:2024-10-10
  • 最后修改日期:2025-01-13
  • 录用日期:2025-01-27
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