青藏高原盐湖硼矿沉积特征与地球化学约束条件
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

基金项目:

本文为国家自然科学联合基金重点项目(编号U21A2018)、第二次青藏高原综合科学考察“盐湖资源变化与远景评价”专题(编号2019QZKK0805)和青海省自然科学面上基金项目(编号2021- ZJ- 932)联合资助的成果


Sedimentary characteristics and geochemical constraints of borate deposits in salt lakes on Qinghai- Tibetan Plateau
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    硼是我国战略性关键非金属矿产,广泛用于新能源、新材料、电子信息等高新技术领域。盐湖型硼矿主要分布在青藏高原,是我国最主要、最具开采前景的硼矿类型。青藏高原富硼盐湖由南至北呈现水化学分带性和硼矿类型差异性,然而,不同区带富硼盐湖的对比研究仍然薄弱。本文系统对比总结青藏高原碳酸盐型(Ⅰ区)、硫酸钠亚型- 硫酸镁亚型(Ⅱ区)和硫酸镁亚型- 氯化物型(Ⅲ区)盐湖的固体硼矿沉积特征及富硼卤水地球化学参数,获得主要结论如下:① 硼酸盐矿物多沉积于碎屑物之上,呈现交互多层沉积特征,表明硼矿的沉积需要有淡咸水补给或水文环境的改变,符合“稀释成盐”硼矿理论;② 硼砂及钠硼解石的沉积均有大量芒硝共生,柱硼镁石及库水硼镁石的沉积多有大量含镁碳酸盐矿物(水菱镁矿、白云石)伴生,指示硼砂、钠硼解石沉积于高Na+水体,柱硼镁石、库水硼镁石沉积自高Mg2+水体;③ Ⅰ、Ⅱ、Ⅲ区盐湖硼矿析出条件具有相似性,表现为卤水pH值大于8,B含量大于400 mg/L,但在TDS、Mg和Na含量上,不同盐湖存在差异;④ 不同硼矿主要含B、Na、Mg化学元素组成,Ⅰ、Ⅱ、Ⅲ区B×10- Na- Mg三角当量图表明各区硼矿沉积时Na、B当量值分别在0. 2~0. 6、0. 4~0. 7范围,而Mg当量值有一定差异,Ⅰ区<0. 1,Ⅱ、Ⅲ区在0. 1~ 0. 4范围。

    Abstract:

    Boron is a strategically important non- metallic mineral in China, widely used in high- tech fields such as new energy, advanced materials, and electronic information. Salt lake- type borate deposits, mainly distributed across the Qinghai- Tibetan Plateau, represent the most important and promising boron resource type in the country. Boron- rich salt lakes on the plateau show hydrochemical zonation, with variations in borate deposit types across different hydrochemical environments from south to north. However, comparative studies of boron- rich salt lakes in these different zones remain limited. This paper summarizes and compares the sedimentary characteristics of solid boron deposits and the geochemical parameter differences of boron- rich brines among three types of salt lakes on the Qinghai- Tibetan Plateau: carbonate type (zone Ⅰ), sodium sulfate subtype- magnesium sulfate subtype (zone Ⅱ), and magnesium sulfate subtype- chloride type (zone Ⅲ). The main conclusions are obtained as follows: ① Borate minerals are mostly deposited directly on top of the clastic sediments and present interactive multilayer deposition characteristics, indicating that borate deposition requires brackish water recharge and hydrological fluctuations, which accords with the theory of “brine diluted into salt”. ② The deposition of borax and ulexite is closely associated with abundant mirabilite, whereas pinnoite and kurnakovite deposition is accompanied by a large number of magnesium- bearing carbonate minerals (e.g., hydromagnesite and dolomite). This indicates that borax ulexite formation depends on Na+- rich water recharge, while pinnoite and kurnakovite precipitation requires Mg2+- rich inflows. ③ The boron precipitation thresholds in zones Ⅰ, Ⅱ, and Ⅲ are similar, with brine pH>8 and B content exceeding 400 mg/L. However, notable differences exist in total dissolved solids (TDS), Mg, and Na content among the lakes. ④ B×10- Na- Mg ternary equivalent diagram, combined with borate deposit chemistry, reveals that Na and B equivalents in zones Ⅰ~Ⅲ range between 0. 2~0. 6 and 0. 4~0. 7, respectively. In contrast, Mg equivalence varies: zone Ⅰ values remain below 0.1, while zones Ⅱ and Ⅲ range between 0. 1 and 0. 4.

    参考文献
    相似文献
    引证文献
引用本文

向鸿潞,樊启顺,李庆宽,陈天源,杨浩田.2025.青藏高原盐湖硼矿沉积特征与地球化学约束条件[J].地质学报,99(9):3084-3095.
XIANG Honglu, FAN Qishun, LI Qingkuan, CHEN Tianyuan, YANG Haotian.2025. Sedimentary characteristics and geochemical constraints of borate deposits in salt lakes on Qinghai- Tibetan Plateau[J]. Acta Geologica Sinica,99(9):3084-3095.

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2023-09-11
  • 最后修改日期:2023-11-30
  • 录用日期:2023-12-04
  • 在线发布日期: 2025-09-23
  • 出版日期: