天津蓟县东水厂锰方硼石矿床成因新认识
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The New Understanding of the Cause of Dongshuichang Chambersite Deposit in Jixian,Tianjin
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    摘要:

    天津蓟县东水厂锰方硼石矿床是世界上唯一一个具有经济开发价值的锰方硼石矿床,锰方硼石赋存与中元古代高于庄组二段泥晶白云岩中。本文通过微量元素分析探讨了锰方硼石的成矿环境,测定结果显示 Sr/Ba=0.125~0.128;V/(Ni+V)=0.230~0.320;Th/U=4.356~4.898;V/Cr=0.018~0.026,各微量元素对比值范围变化不大;LREE总量为66.12×10-6~6790×10-6,HREE总量(包含Y)为18.88×10-6~19.56×10-6,LREE/HREE值为3.38~3.60, Y/Ho值介于28.25~29.14之间,δCe介于0829~0854之间,显示为弱的负Ce异常,δEu值介于0831~0846之间,显示为弱的负Eu异常。地球化学数据指示其成矿环境属海相沉积环境,海水环境为相对氧化的状态,成矿过程中有陆源物质的加入。Sm/Nd Eu/Sm图解表明研究区与柴达木盆地第三系蒸发岩较为相似,反应锰方硼石成矿时具有类似的蒸发成因。通过对硼同位素(δ11B的数值范围为14‰~107‰)的解译进一步探讨了锰方硼石在原生成矿阶段的具体成因(海相蒸发沉积)。结合前人所做的锰方硼石地球化学数据,对东水厂锰方硼石矿床的成因做出了新的解释,即锰方硼石成矿时应属海相蒸发成因,而热液活动的过程则可能是发生于锰方硼石成矿之后,属后期热液改造作用,从而形成了锰方硼石复杂的地球化学特征。

    Abstract:

    The chambersite deposit in Jixian,Tianjin is the only one around the world with its economic development value,it occurred in putty crystal dolomites of the second segment of Mesoproterozoic Gaoyuzhuang Formation. In view of the speciality of the deposit,this paper discussesed the metallogenic environment of chambeisite through the analysis of the trace elements.The results showed that Sr/Ba=0125~01284,V/(V+Ni)=0230~0320,Th/U=4356~4898,V/Cr=0.018~0.026,and revealed the little change of the trace elements;the amount of LREE was 6612×10-6~67.90×10-6,the total HREE(including Y)was 18.88×10-6~19.56×10-6,LREE/HREE value ranged from 3.38 to 3.60,Y/Ho=28.25~29.14,δCe was between 0.829 and 0.854,shown as a slightly Ce negative anomaly,δEu ranged from 0.831~0.846,which reflected the slightly Eu negative anomaly.Geochemical data indicated that the metallogenic environment belong to marine facies sedimentary environment,the seawater may in the state of relative oxidation,some terrigenous material added in the metallogenic process of chambeisite.The diagram of Sm/Nd Eu/Sm show that the study area is close to the evaporite from Qaidam Basin in Tertiary,relfecting the chambersite has the similar cause .We further discussesed the specific causes(marine evaporation) of the chambersite formed in the original stage by the interpretation of the boron isotope(δ11B ranged from 1.4 ‰ to 10.7‰).Combined with previous chambersite geochemical data,we made a new explanation about the cause of Dongshuishang chambersite deposit.The deposite should be explained as the cause of marine evaporation,while the process of hydrothermal activity may occur after the formation of chambersite,belonging to the late hydrothermal alteration,and finally resulted the complex geochemical characteristics of chambersite.

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王富良,付勇,徐志刚,裴浩翔,江冉,周文喜.2016.天津蓟县东水厂锰方硼石矿床成因新认识[J].地质学报,90(2):398-408.
WANG Fuliang, FU Yong, XU Zhigang, PEI Haoxiang, JIANG Ran, ZHOU Wenxi.2016. The New Understanding of the Cause of Dongshuichang Chambersite Deposit in Jixian,Tianjin[J]. Acta Geologica Sinica,90(2):398-408.

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  • 收稿日期:2015-07-15
  • 最后修改日期:2015-11-11
  • 录用日期:2015-12-16
  • 在线发布日期: 2016-02-24
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