分散液态烃裂解气资源评价方法
DOI:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

基金项目:

国家科技攻关计划


Quantitative Assessment of Pyrolysis Gas Generated by Dispersed Liquid Hydrocarbon
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    分散液态烃裂解气资源评价涉及五方面内容,可概括为“五步法”的定量评价方法。步骤一:源内和源外液态烃的分配比例和数量研究。模拟实验及实际地质样品统计相结合的研究结果,烃源岩中滞留烃的数量可观,受有机质丰度、类型、演化程度、烃源岩岩性、物性以及与储集层的配置关系等因素影响。总体特征烃源岩排油率变化于20%~80%,以TOC 2%为界,排油率为50%上下;高TOC、类型优质的烃源岩排油率高。步骤二:源外分散液态烃的主要分布、富集区研究。通过数值模拟正演研究液态烃的优势运移通道及分布富集区;同时,通过热成因沥青的数量统计及分布、样品的荧光特征反演研究分散液态烃的分布富集区。步骤三:不同赋存状态液态烃裂解成气的转化率研究。模拟地质条件下碳酸盐岩、泥岩和砂岩中的分散液态烃裂解生气实验,反映碳酸盐岩、泥岩和砂岩对液态烃的裂解均有催化作用,作用强度依次减弱,主生气期对应的Ro值分别为12%~32%、13%~34%和14%~36%;超压抑制液态烃裂解生气,达到相同转化率温度滞后30℃左右。步骤四:研究区含油气系统研究:加强液态烃晚期规模生气和有效成藏的要素和关键时刻的分析。步骤五:分散液态烃裂解气的定量评价以及资源评估。以深层海相天然气成因研究为基础建立的分散液态烃“五步法”定量评价方法,实现了中国深层古老烃源岩源内分散液态烃裂解气、源外分散液态烃裂解气、古油藏裂解气、干酪根降解气的整体、系统评价。

    Abstract:

    The resource assessment of pyrolysis gas generated by dispersed liquid hydrocarbons involves 5 aspects, which can be summarized as “five steps methodology”. Firstly, the distribution ratio and amount of liquid hydrocarbon within and out of the source must be studied. The results of simulation experiments and statistical analysis on geological samples showed that a considerable number of hydrocarbons had been retained in source rocks while the quantity was controlled by various factors, including organic matter abundance, type and evolution degree, source rock’s lithology and source-reservoir allocation. Generally, the oil expulsion efficiency of different source rocks varied from 20% to 80%, and the data is less than 50% for source rocks with TOC lower 2% and more than 50% for those with high TOC (higher than 2%), which means that the source rocks with high organic matter abundance and excellent type will have high oil expulsion efficiency. Secondly, the distribution of major rich areas of dispersed liquid hydrocarbon inside and outside of the source rocks were studied through forward modeling and inversion method. The dominant migration pathway and distribution zone of the liquid hydrocarbons were conducted by numerical modeling while the distribution zone could also be tested through inversion method including statistics on thermogenic asphalt and fluorescence characteristics of reservoir samples. Thirdly, the conversion ratio of pyrolysis gas generated by liquid hydrocarbon of various occurrences should be known. Simulation experiments of gas cracking from dispersive liquid hydrocarbons mixed with carbonate, mudstone and sandstone showed that all of these three minerals had catalytic effect on the cracking process of liquid hydrocarbons, and their strength decreased one by one. The main gas generation periods of liquid hydrocarbons mixed with these three minerals are 1.2%~3.2%, 1.3%~3.4% and 1.4%~3.6% respectively. Moreover, overpressure could inhibit the process of gas generation. The mixture temperature lag is about 30℃ while comparing the experimental results of 200Mpa and 50Mpa. Fourthly, the study of petroleum system of the studied area, especially the analysis of key factors and critical moments for the late scale formation and accumulation of natural gas of the liquid hydrocarbon cracking gas. Fifthly, quantitative assessment and resource evaluation of pyrolysis gas generated by dispersed liquid hydrocarbon. The quantitative assessment method of “five steps”, which is based on genetic method, realized the integrated and systematic assessment of pyrolysis gas generated by dispersed liquid hydrocarbon inside and outside the source rock, by paleo-reservoirs, and degradation gas generated by kerogen.

    参考文献
    相似文献
    引证文献
引用本文

王兆云,赵文智,王东良,李永新,薛海涛,胡国义,姜华,郑红菊.2016.分散液态烃裂解气资源评价方法[J].地质学报,90(1):68-79.
WANG Zhaoyun, ZHAO Wenzhi, WANG Dongliang, LI Yongxin, XUE Haitao, HU Guoyi, JIANG Hua, ZHENG Hongju.2016. Quantitative Assessment of Pyrolysis Gas Generated by Dispersed Liquid Hydrocarbon[J]. Acta Geologica Sinica,90(1):68-79.

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2015-04-16
  • 最后修改日期:2015-06-23
  • 录用日期:2015-06-28
  • 在线发布日期: 2016-01-18
  • 出版日期: