玄武岩纤维原料特征的统计及分析研究
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1.成都理工大学地球科学学院;2.海南省海洋地质资源与环境重点实验室

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海南省海洋地质资源与环境重点实验室开放课题 - 海南玄武岩石粉废渣制备连续玄武岩纤维的试验研究(HNHYD22YHJKF016)


Statistics and analysis of basalt fiber raw material characteristics
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1.School of Earth Sciences,Chengdu University of Technology;2.Hainan Key Laboratory of Marine Geological Resources and Environment

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    摘要:

    玄武岩纤维是以玄武岩或它种成分相近的岩石为主要原料,经熔融后拉制而成的一种高性能纤维。天然矿石的成分波动会造成拉丝困难或纤维性能不稳定,本文收集了54组原料岩石以及114组玄武岩纤维样品的化学成分数据,研究归纳了玄武岩纤维所需原料的岩石学特征、参数指标特征和其他特征,分析提出了可拉丝岩石相关参数指标的最佳区间。适于生产玄武岩纤维的原料矿石,其特征可总结如下:岩石学方面,以基性岩以及SiO2含量为53%~57%的中性岩为佳,岩石类型最佳为玄武岩或安山玄武岩;岩石结构最佳为间隐结构、玻基斑状结构或玻璃质结构;构造的影响是间接的,主要为气孔或杏仁构造中可能含有的一些不利矿物的影响;矿物组成方面,蛇纹石、沸石等含水矿物会在熔融过程中产生气泡,影响纤维制备连续性的同时也有利于原料的充分熔融,镁橄榄石、磁铁矿等高熔点矿物会使原料在熔融阶段难以完全熔化,导致熔体不均匀并容易析晶。参数指标方面,可拉丝岩石的酸度系数(Mk)最佳区间为4.0~5.5;黏度系数(Mv)为2.0~3.0;硅铝氧化物与其他氧化物比值为1.5~3.0;氧化物组成的物质的量分数分布为n(RO)=20%~30%,n(RO2)=57%~70%,n(R2O3)=10%~16%(R为阳离子)。

    Abstract:

    Basalt fiber is a kind of high-performance fiber manufactured by melting and drawing from basalt or rocks of similar composition. Fluctuation in the composition of natural rocks can cause difficulties in drawing and instability of fiber properties. This paper collected data on the chemical composition of 54 groups of raw rock and 114 groups of basalt fiber samples. The petrological, parameter index and other characteristics of the raw material needed for basalt fiber were summarized, and the optimal range of related parameter indexes of raw materials were proposed. The characteristics of raw rock which is suitable for the production of basalt fiber can be summarized as follows: from the perspective of petrology, basic rocks or intermediate rock with a SiO2 content of 53% to 57% are the optimal; the most suitable rock type is basalt or andesite; the most appropriate rock texture is intersertal texture, vitrophyric texture or hyaline texture. The influence of structure is indirect, mainly due to some adverse minerals which may be contained in fumarolic structure or amygdaloidal structure. From the perspective of mineral composition, hydrous minerals such as serpentine and zeolite will cause bubbles in the melt, which will affect the continuity of fiber preparation but will be conducive to the full melting of raw materials. High melting point minerals such as forsterite and magnetite will make it difficult for raw materials to melt completely, resulting in uneven melt and easy crystallization. From the perspective of parameter index, the optimal range of acidity coefficient (Mk) is 4.0 to 5.5. The viscosity coefficient (Mv) is 2.0 to 3.0. The ratio of silicon aluminum oxides to other oxides is 1.5~3.0. The molar fractions of oxides are n(RO) = 20% to 30%, n(RO2) = 57% to 70%, and n(R2O3) = 10% to 16% (R stands for cations).

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  • 收稿日期:2023-03-09
  • 最后修改日期:2023-07-31
  • 录用日期:2023-08-26
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