安徽青阳—九华山复式岩体的成因及成矿潜力——来自锆石Hf同位素和微量元素的证据
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本文为国家自然科学基金资助项目(编号:41972076和91962218)和安徽省公益性地质工作项目(编号:2021- g- 2- 11)的成果


Magmatic genesis and mineralization potential of Qingyang—Jiuhuashan complex pluton:Evidence from zircon Hf isotopes and trace elements
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    摘要:

    青阳—九华山复式岩体是安徽南部地区出露面积最大、最具代表性的复式岩体,该复式岩体的岩浆源区、演化过程和成矿联系等问题仍需要进一步查明。在前期对青阳—九华山复式岩体的地质、地球化学特征研究基础上,本文进一步开展了锆石微量元素与Hf同位素分析与研究。结果显示,青阳—九华山复式岩体4个阶段从早到晚(花岗闪长岩二长花岗岩正长花岗岩细粒花岗斑岩),晚期(第三、第四阶段)比早期(第一、第二阶段)岩浆岩的锆石εHf(t)值呈显著增高趋势,岩浆形成温度升高(705.3℃ 715.9℃ 827.1℃ 805.5℃),氧逸度降低(93.8 149.170.1 69.9)。进一步分析认为,青阳—九华山复式岩体源于同一具有壳幔混源的岩浆源区,随着时间的演化,岩浆房中幔源组分比例逐渐增高,幔源物质的加入,不仅提高了晚期岩浆形成温度,一定程度改变了源区组成。青阳—九华山复式岩体4个阶段花岗岩均经历了榍石、角闪石、金红石、斜长石等矿物的分离结晶,晚期(第三、第四阶段)花岗岩相比早期(第一、第二阶段)花岗岩具有更高的分异程度。青阳—九华山复式岩体中第一、第二阶段花岗岩具有较好的W—多金属矿床成矿潜力。

    Abstract:

    Through the comparative analysis of the magmatic zircon trace elements and Hf isotopes of the intrusive rocks in the four stages of the Qingyang—Jiuhuashan complex pluton, the magmatic physical and chemical properties, magmatic properties of the four stages of the Qingyang—Jiuhuashan complex pluton was discussed evolution process, differences in magma source areas, and metallogenic potential, demonstrated the magmatic origin, magma source area and metallogenic connection of the four stages of the Qingyang—Jiuhuashan complex pluton, revealing the late Mesozoic crust—mantle interaction of the Yangtze block action process. Methods: On the basis of field work and whole- rock chemical analysis, zircon in- situ trace element and Hf isotope analysis was carried out on the four stages intrusive rocks of the Qingyang—Jiuhuashan complex pluton, and zircon Ti temperature calculation, oxygen for fugacity calculation, the Sr—Nd—O isotope data of the predecessors of the compound rock mass were collected for comparative analysis and source area simulation work. Results:The 4 stages of intrusive rocks in the Qingyang—Jiuhuashan complex pluton from early to late, zircon REE 558. 6×10-6 ~ 3222. 7×10-6971. 1×10-6 ~ 2364. 9×10-6 864. 9×10-6 ~ 4453. 6×10-6962. 2×10-6 ~ 4119. 1×10-6; δEu (mean value 0. 5 0. 4 0. 3 0. 2); magma formation temperature (mean value 705. 3℃ 715. 9℃ 827. 1℃ 805. 5℃) ; Ce4+/Ce3+ (mean value 93. 8 149. 1 70. 1 69. 9); εHf(t) value (-12. 3 ~ -5. 1 -12. 0 ~ -7. 5 -6. 6 ~ -2. 2 -8. 6 ~ -4. 9), intrusive rock at early stage (stage Ⅰ and Ⅱ) have lower REE content, magma formation temperature, εHf(t), higher δEu and oxygen fugacity than the later stages (stage Ⅲ and Ⅳ). By collecting the previous Sr—Nd—O isotope data, combined with the Hf isotope data made in this paper, the simulation analysis of the source area of the Qingyang—Jiuhuashan complex pluton shows that the proportion of mantle sources in the magma chamber in four stages from early to late gradually increase. Conclusions: We find that the Qingyang—Jiuhuashan complex pluton were derived from crust—mantle mixed source, where gradually increased mantle components. The four stages melt all experienced distinct minerals fractional crystallization (FC), such as titanite, amphibole, rutile and plagioclase, and the late (stage Ⅲ and Ⅳ) granite melt experienced higher FC degrees than the early ones (stage Ⅰ and Ⅱ). Compared with stage Ⅲ and Ⅳ intrusions, The stage Ⅰ and Ⅱ intrusions of Qingyang Jiuhuashan complex pluton have better metallogenic potential of the W—polymetallic deposit.

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叶龙翔,张达玉,汪方跃,陈雪锋,张飞,席晓晨,周涛发.2022.安徽青阳—九华山复式岩体的成因及成矿潜力——来自锆石Hf同位素和微量元素的证据[J].地质论评,68(3):2022062035,[DOI].
YE Longxiang, ZHANG Dayu, WANG Fangyue, CHEN Xuefeng, ZHANG Fei, XI Xiaochen, ZHOU Taofa.2022. Magmatic genesis and mineralization potential of Qingyang—Jiuhuashan complex pluton:Evidence from zircon Hf isotopes and trace elements[J]. Geological Review,68(3):2022062035.

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  • 收稿日期:2022-03-05
  • 最后修改日期:2022-05-18
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  • 在线发布日期: 2022-06-20
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