洞穴滴水、石笋中元素及元素比值对气候环境变化响应的研究进展
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本文为广西自然科学基金资助项目(编号:2020GXNSFAA159066)、重庆市自然科学基金项目(编号:cstc2019yszx-jcyjX0002)和中国地质科学院基本科研业务费项目(编号:2020006,2021002)的成果


Research progress on response of elements and their ratios in cave drip water and speleothems to climate and environmental change
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    摘要:

    滴水/石笋元素是除δ18O和δ13C,研究气候环境变化的又一重要代用指标。外界气候环境变化通过改变表层岩溶带和岩溶含水层中的水文环境,甚至洞穴环境,进而影响元素的溶解、运移和沉淀过程,从而使得滴水/石笋中元素表现一定的变化规律。本文通过分析影响洞穴滴水元素及元素比值变化的因素:元素来源、水—岩相互作用和滞留时间、差异性淋滤、先期碳酸盐沉淀及分配系数的基础上,从元素对岩溶区“二元结构”和极端天气/气候事件响应的角度,探讨了滴水/石笋中元素的气候环境指示意义。取得了以下认识:① 强降水带来的冲刷作用和溶解作用,促进土壤和基岩中元素、胶体和天然有机质(NOM:Natural Organic Matter)等物质在短时间内快速溶解和运移,使滴水中元素含量增加;但随着降水增多带来的稀释作用,使得滴水/石笋中Mg,Sr和Ba等元素含量降低,因此,单一元素的解译较为复杂;② 基岩/溶液中元素溶解和沉积的差异,导致元素相对含量的变化,使得元素X/Ca比值对外界环境的响应具有一致性,尤其是Mg/Ca和Sr/Ca比值:在干旱条件下,降水减少导致方解石先期沉积(PCP:Prior Calcite precipitation)作用增强,使Mg/Ca和Sr/Ca比值增大。但目前存在着一些问题:① Mg/Ca和Sr/Ca比值变化对强降水事件的响应并不明显,可能与新、老水混合及元素溶解过程中的溶解比例差别不大有关;② 多源、多期混合水源会导致洞穴滴水元素对极端事件响应减弱;③ Mg/Ca和Sr/Ca的变化为解释δ18O的“雨量效应”及“源效应”提供了见解,但元素变化能否反映季风强度的变化,仍有待进一步的研究。基于以上认识,笔者提出开展更加系统的大气—土壤—包气带—洞穴的监测;开展更高分辨率、更长时间尺度的洞穴监测;开展多区域、多洞穴系统对比研究来更加深入地开展洞穴石笋元素研究。

    Abstract:

    Elements are another important archives for the studying of climate change in addition to carbon and oxygen stable isotopes in speleothems. The dissolution, transport and precipitation processes of elements are affected by changes of climate, resulting in changes in the elements in drip water and speleothems. In this literature, the climatic indication significance of elements in drip and stalagmites is discussed from the perspective of the "Dual- Structure" on karst areas and extreme events, based on the factors affecting the variations of elements and elemental ratios of caves, including Sources, Resident time, Water—Rock Interaction, Differential leaching, Prior Carbonate Precipitation and Distribution Coefficient. The following recognition has been gained: ① the scourer and dissolution brought by heavy precipitation will promote the rapid dissolution and transport of elements in colloids and natural organic matter (NOM: Natural Organic Matter) and soil and bedrock in a short time, so that the increase of element content; however, the dilution effect produces the opposite effect; ② the difference of element dissolution and deposition in bedrock and/or solution leads to the relative variations of content, which makes the synchronous of element X/Ca ratios to the environment, especially the increase of Mg/Ca and Sr/Ca ratios because of the decrease of precipitation leads to the enhanced PCP. But there are still some problems: ① the response of element variations to heavy precipitation event is not obvious, and may be related to the little differences between the proportion of element dissolve and the mixing of fresh and old water; ② the variations of Mg/Ca and Sr/Ca ratios provide insights into "rainfall effect" and "source effect" of the δ18O, but whether or not they could reflect monsoon intensity remains to be further studied. Based on the above, this literature proposes to carry out more systematic monitoring of atmospheric—soil—vadose zone—cave, higher- resolution and longer- scale cave monitoring and multi- regional, multi- cave system comparative study to more in- depth study of elements.

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马源,殷建军,袁道先.2022.洞穴滴水、石笋中元素及元素比值对气候环境变化响应的研究进展[J].地质论评,68(3):2022062017,[DOI].
MA Yuan, YIN Jianjun, YUAN Daoxian.2022. Research progress on response of elements and their ratios in cave drip water and speleothems to climate and environmental change[J]. Geological Review,68(3):2022062017.

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  • 收稿日期:2021-10-07
  • 最后修改日期:2022-05-19
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  • 在线发布日期: 2022-06-20
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