皖南姚村岩体花岗岩风化壳稀土元素赋存特征
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本文为国家自然科学基金资助项目(编号: 42030801)的成果


Occurrence characteristics of REE in granite weathering crust of Yaocun granite in southern Anhui
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    摘要:

    皖南地区花岗岩风化壳中稀土元素普遍富集,局部已成为矿床,其中,郎溪县姚村岩体风化壳富集程度较高。LA- ICP- MS锆石U- Pb定年表明,姚村花岗岩体的形成年龄为127.9±1.4 Ma,属于皖南地区燕山期晚期岩浆作用的产物。风化壳可细分为残坡积层(A)、强半风化层(C1)、过渡层(C2)、弱半风化层(C3)和基岩(D)五层。稀土总量在纵向剖面上呈“波浪式”分布,各层稀土分布型式表现出对原岩的继承性。风化壳稀土配分型式与基岩一致, 富集LREE,轻重稀土分馏明显(La/Yb)N=15.6),但总含量明显更高。基岩∑REE为338×10-6,半风化层∑REE最高达642×10-6,富集约两倍。风化壳物质由风化残余主矿物(石英、钾长石、斜长石、黑云母)、黏土矿物(高岭石、埃洛石、伊利石、三水铝石等)和副矿物(锆石、磷灰石、榍石等)等组成。黏土矿物以伊利石含量最高,指示风化壳发育不成熟。REE与埃洛石含量明显正相关,与其他黏土矿物关系不明显。(含)稀土矿物(尤其是榍石)对风化壳中稀土元素的贡献量超过百分之五十,其次为斜长石,是风化壳中REE的重要来源。

    Abstract:

    In order to study the mineral composition of weathering crust and the geochemical characteristics of trace elements and rare earth elements of the weathering section from Yaocun granite, Langxi, southern Anhui. Analyze the geochemical behavior of trace elements and the occurrence characteristics of rare earth elements. And further define the genetic mechanism of ion- adsorbed rare earth deposits in this area .Methods:Combined with field work and microscope observation, the weathering crust of Yaocun granite is stratified. Using LA- ICP- MS zircon U- Pb dating, XRD, whole rock trace element analysis and other methods, the geochemical behavior of trace elements and rare earth occurrence characteristics in the weathering crust of Yaocun granite were studied.Results: The LA- ICP- MS zircon U- Pb dating shows that the formation age of the Yaocun granite is 127.9±1.4 Ma, which is the product of the late Yanshanian magmatism in southern Anhui. The weathering crust can be subdivided into five layers: residual slope accretion (A), Strong semi- regolith (C1), transition layer (C2), Weak semi- regolith (C3) and bedrock (D). The total amount of rare earths is distributed in a "wave" pattern on the longitudinal section, and the distribution pattern of REE in each layer shows the inheritance of the bedrock. The REE of the bedrock is 338×10-6, and the REE of the semi- regolith is up to 642×10-6, which is about twice than bedrock. The weathering crust is enriched in LREE, and the fractionation of light and heavy rare earths is obvious (La/Yb)N=15.6). XRD results show that the weathering crust material is mainly composed of weathering residual main minerals (quartz, K- feldspar, plagioclase, biotite), clay minerals (kaolinite, halloysite, illite, gibbsite, etc.) and accessory minerals (zircon, apatite, titanite, etc.). Conclusions:The content of REE in the semi- regolith of the weathering crust of the Yaocun granite is significantly higher than bedrock, and the distribution patterns are consistent, indicating that the REE in the weathering crust have obvious inheritance during the development of the weathering crust. The clay minerals in the weathering crust are mainly illite, kaolinite and halloysite, and there is a positive correlation between REE and halloysite content. The weathering crust in this area is immature and is in an open system, and the migration of elements is seriously affected by environmental factors. The contribution of (including) rare earth minerals (especially titanite) to the REE in the weathering crust exceeds 50%, followed by plagioclase.

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高玲,闫峻,李全忠,谢建成.2022.皖南姚村岩体花岗岩风化壳稀土元素赋存特征[J].地质论评,68(3):2022062013,[DOI].
GAO Ling, YAN Jun, LI Quanzhong, XIE Jiancheng.2022. Occurrence characteristics of REE in granite weathering crust of Yaocun granite in southern Anhui[J]. Geological Review,68(3):2022062013.

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  • 收稿日期:2022-01-17
  • 最后修改日期:2022-06-07
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  • 在线发布日期: 2022-06-20
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