燕辽地区下马岭组内基性岩床侵位过程中CO2释放量估算及对表生环境影响的探讨
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本文为国家自然科学基金资助项目(编号:41725011、41920104004)的成果


Estimation of carbon dioxide released during emplacement of ca. 1. 32 Ga mafic sills into the Xiamaling Formation in Yanliao (northern Hebei—western Liaoning) area in the North China Craton and its potential environmental effect
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    摘要:

    大火成岩省对全球性环境巨变及大规模生物灭绝的影响是国际地学界关注的主要前缘科学问题之一。一般认为大火成岩省中熔岩流喷发所释放的温室及有毒气体、火山灰及其它流体是导致环境巨变及生物灭绝的最主要原因之一。但近年来研究表明,作为大火成岩省重要组成部分之一的大规模基性岩床(辉绿岩为主),其侵位到黑色页岩、煤层、蒸发岩及碳酸盐岩中释放出了巨量的温室及有毒气体,并对表生环境及生物灭绝有重要的驱动作用。在华北克拉通北缘近年来发现的约1. 32 Ga燕辽大火成岩省由大规模辉绿岩床群组成,这些辉绿岩床主要侵位于下马岭组黑色页岩(TOC含量0. 6~20 %, 平均值约6. 0 %)中,部分侵位到雾迷山组及高于庄组白云岩或白云质灰岩中。野外调查结果表明,受岩床侵位的影响,辉绿岩床与下马岭组接触带附近黑色页岩有强烈的角岩化及脱碳现象。在接触带厚度及辉绿岩岩床与黑色页岩分布范围调查的基础上,根据受不同程度影响黑色页岩内总有机碳(TOC)含量分析结果,初步估算出岩床侵位到下马岭组黑色页岩过程中CO2的释放量可达1. 10×1012t。如果考虑到华北克拉通燕辽地区侵入到高于庄组和雾迷山组碳酸盐岩中的岩床,以及北澳大利亚克拉通麦克阿瑟盆地Velkerri组中1. 32 Ga的大规模代里姆辉绿岩床群,这一时期辉绿岩岩床侵位所释放的CO2等温室气体量可能会更大。华北克拉通燕辽及北澳大利亚克拉通代里姆1. 32 Ga大规模辉绿岩床侵位热接触变质中CO2等气体的释放可能对大气—海洋环境有显著的影响,但由于华北及北澳大利亚克拉通缺少这一时期的沉积,其地质记录(如碳同位素负漂移,元素或其它同位素异常、生物量指标的差异等)可能存在于全球其它克拉通(如西伯利亚、波罗地等)约1. 32 Ga沉积地层中,需要开展更为深入的研究工作。

    Abstract:

    The environmental effects of large igneous provinces (LIPs) on global climate changes and mass extinction events have became one of the most important topics in geosciences. Most researchers believe that greenhouse and toxic gases, sulfur aerosols and other volatiles released during eruption of flood basalt in LIPs are main reasons for driving global climate changes and mass extinctions. However, recent results suggest that contact metamorphism during emplacement of large volumes of mafic sill swarms as main component of LIPs has significant environmental effects. Emplacement of large volumes of mafic sill swarms into black shales, coal, evaporate and carbonate will release huge volumes of greenhouse and toxic gases and other volatiles, which may trigger and drive the environmental perturbations and mass extinctions. The ~1.32 Ga Yanliao (northern Hebei—western Liaoning) LIP in the northern North China Craton (NCC) consists mainly of large volumes of diabase sill swarms and has an areal extent over 1.2×105km2. Most of the diabase sills emplaced into the black shales of the Xiamaling Formation with total organic carbon (TOC) values of 0.6%~20% and average TOC values of ~6.0%; other emplaced into the dolostone and dolomitic limestone of the Wumishan and Gaoyuzhuang formations. Field investigations show that both sides of the black shales were affected by emplacement of sills and the thicknesses of the hornfelsing and decarbonation zones could be 5 to 10 meters. TOC analytical results of the black shales near or far from the contact zones suggest that emplacement of the ~1.32 Ga diabase sills into the black shales in the NCC could have generated ~1,098 Gton CO2. If the diabase sills emplaced into the carbonates of Wumishan and Gaoyuzhuang formations in the northern NCC and the ~1.32 Ga Derim Derim diabase sills emplaced into the black shales of the Velkerri Formation in the McArthur Basin in the North Australian Craton were considered together, the greenhouse and toxic gases generated by emplacement of ~1.32 Ga diabase sills could be more huge than present estimation. Release of CO2 and other gases during emplacement of the large volumes of Yanliao diabase sills in the northern NCC and the Derim Derim diabase sills in the North Australian Craton may have significant environmental effects on atmosphere and oceans. Since the ~1.32 Ga depositions in the NCC and North Australian Craton are absent, geological records for environmental effects such as negative carbon isotope excursion, element or other isotopic anomalies due to emplacement of diabase sill swarms may exist in other cratons such as Siberia, Baltica, etc., and more researches are needed to test this hypothesis.

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引用本文

税国豪,张拴宏,胡国辉,张琪琪.2020.燕辽地区下马岭组内基性岩床侵位过程中CO2释放量估算及对表生环境影响的探讨[J].地质论评,66(4):909-917,[DOI].
SHUI Guohao, ZHANG Shuanhong, HU Guohui, ZHANG Qiqi.2020. Estimation of carbon dioxide released during emplacement of ca. 1. 32 Ga mafic sills into the Xiamaling Formation in Yanliao (northern Hebei—western Liaoning) area in the North China Craton and its potential environmental effect[J]. Geological Review,66(4):909-917.

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  • 收稿日期:2019-12-15
  • 最后修改日期:2020-06-08
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  • 在线发布日期: 2020-07-16
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