贵州石炭系“清镇式”铁矿沉积地球化学特征
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本文为贵州大学矿床学博士点基金资助项目的成果。


Sediment Geochemical Character of Carboniferous “Qingzhentype Fe Deposit” in Central Guizhou Area
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    摘要:

    贵州中部清镇、修文、开阳等地石炭系铝土矿底部的铁矿被称为“清镇式铁矿”,铁矿层被认为是湖泊沉积产物。笔者等对其地质地球化学研究发现,清镇林歹、卫城和龙里长冲等地“清镇式铁矿”的铁质岩主要由赤铁矿、菱铁矿组成; 在清镇含铁岩系中稀土元素具有较高的富集,ΣREE75.71×10-6~859.45×10-6, 铁质岩中Zr、Ga、Ge、Sc、Ti元素富集,其中金属Sc含量在20×10-6左右,具有开发利用价值。铁质岩的Sr/Ba值均大于1,Th/U值在2~7之间,与二叠系山西式铁矿类似,表明铁质岩沉积受到海水的影响,是潟湖环境下沉积的产物。稀土球粒陨石标准化曲线具有强烈的Eu负异常和Ce弱负异常。清镇式铁矿菱铁矿δ13CPDB为-3.21‰~-7.24‰,比其他沉积型、沉积变质型铁矿低。

    Abstract:

    The Febearing rocks under bauxite bed in Qingzhen, Xiuwen and Kaiyang Counties, Guizhou Province, was called as “Qingzhentype Fe deposit”, and considered lacustrine deposit. Writers discover with sedimentary geological, mineral association and geochemical study that the iron ores of “Qingzhentype Fe deposit” in Lindai and Weicheng, Qingzhen City, Changchong, Longli County, consists of hematite and siderite; the Febearing rocks are riched in rare earth element and trace element Zr, Ga, Ge, Sc, Ti, ΣREE from 75.71 to 859.45×10-6, Sc are up to 20×10-6, which are of very important value in economic; all Sr/Ba ratio values of Febearing rocks are >1, Th/U ratio values are 2 to 7, similar to those of the “Shanxi-type iron deposit”, which suggests that the Febearing rocks formed in lagoon and affected by sea water. Chondritenormalized rare earth element patterns of the Qingzhentype Fe deposit show that Eu is remarkable negative anomaly and Ce is weak negative anomaly. The δ13C PDB values of siderite are -3.21‰~-7.24‰, lower than those values of other sedimenttype Fe deposit and sediment metamorphic–type Fe deposit.

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杨瑞东,袁世婷,魏怀瑞,陈吉艳,程玛莉.2011.贵州石炭系“清镇式”铁矿沉积地球化学特征[J].地质论评,57(1):24-35,[DOI].
.2011. Sediment Geochemical Character of Carboniferous “Qingzhentype Fe Deposit” in Central Guizhou Area[J]. Geological Review,57(1):24-35.

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