梅县嵩溪银(锑)矿流体包裹体轻烃组成及其矿床成因意义
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本文为国家自然科学基金(编号49773195、49502029)、广东省自然科学基金(编号970123)、中山大学“211”基础性前沿课题基金、南京大学成矿作用国家重点实验室开放基金、国家教育部优秀青年教师培养基金和美国岭南基金会优秀青年教师培养基金联合资助。


Compositions of Light Hydrocarbons in Fluid Inclusions and Its Significance for Ore Genesis——A Case Study Of Songxi Ag(Sb) Deposit, Eastern Guangdong
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    摘要:

    嵩溪是一个新发现的大型银(锑)矿,位于永梅拗陷南段寨岗上火山沉积盆地的边缘。前人多认为其形成与火山活动有关,主要有海底基性火山喷流和中低温火山热液充填等成因观点。但矿物流体包裹体超高真空四极气相质谱系统测定表明其中存在多种轻烃气体,它们主要由C1~4饱和烷烃组成,仅含微量C2~4不饱和烯烃和芳烃,说明成矿过程基本未受到岩浆作用的影响。这些轻烃气为微生物作用成因和沉积岩围岩中Ⅱ类干酪根热解成因的混合气体。从有机气体组成看,嵩溪矿床的成矿背景属裂谷环境。本文的研究从一个侧面支持了作者等提出的嵩溪银(锑)矿可能属沉积热卤水改造型矿床的看法。

    Abstract:

    Being a newly discovered largescale Ag(Sb) deposit, the Songxi deposit is occurre d at the margin of Zhaigangshang volcanosedimentary basin, which belongs to sou t hern section of the Yongan—Meixian Depression. Most of previous researchers t ho ught that its genesis might have a close relationship to the volcanic activi ty , and several genetic opinions, such as submarine basic volcanic exhalation and lowmedium temperature volcanic hydrothermal fluid filling, have been proposed. In this work, a high vacuum quadrupole gas mass spectrometer system has been use d to analyses the compositions of organic gases in fluid inclusions in minerals, and nine light hydrocarbons have been recognized. The light hydrocarbons are mo stly composed of C1~4 saturated alkanes, while the contents of C2~4  unsaturated alkenes and aromatic hydrocarbons are very low, suggesting that magmatic activit ies might have not been involved in the metallogenic processes. C1/C1~2 ratios of the hydrocarbons show that they are mixture of organic gases produced by microo rganism activity and thermal cracking of type Ⅱkerogens(kukersite) in sedimenta ry host rocks. According to the compositions of light hydrocarbons, the tectonic setting of the Songxi deposit should be a rift. From one aspect, the analytical da ta support the newly proposed genetic model by the authors that the Songxi depos it may belong to a sedimentary hot brine transformed deposit.

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孙晓明,David I. Norman,孙 凯,陈炳辉,陈敬德.1999.梅县嵩溪银(锑)矿流体包裹体轻烃组成及其矿床成因意义[J].地质论评,45(7):817-822,[DOI].
Sun Xiaoming, David I. Norman, Sun Kai, Chen Binghui, Chen Jingde.1999. Compositions of Light Hydrocarbons in Fluid Inclusions and Its Significance for Ore Genesis——A Case Study Of Songxi Ag(Sb) Deposit, Eastern Guangdong[J]. Geological Review,45(7):817-822.

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