Abstract:A new Early Cretaceous enantiornithine bird from Liaoning Province of northeastern China, Shengjingornis yangi, gen. et sp. nov., is reported. This new bird possesses the following unique combination of features: a long rostrum, with some teeth in the front; short nasal; slender jugal; Y-shaped furcula, with expanded distal end of the hypocleidum; cake-like sternum, with a low and caudally distributed keel; strut-like and caudally concave coracoid. The derived features of the scapula and the wings suggest a powerful flapping flight capability.

Abstract:The Liangshan and Qixia formations in the Sichuan Basin of central China were formed in the earlier middle Permian. Based on outcrop observation of the Changjianggou section at Shangsi, Guangyuan region and 3rd-order sequence division in typical drillings, one-dimensional spectrum analysis has been used to choose the better curve between the natural gamma ray spectrometry log(ln(Th/K)) in Well-Long17 and the gamma ray log(GR) in Well-Wujia1, respectively, for identifying Milankovitch cycles in Sequence PSQ1 which comprises the Liangshan and Qixia formations, and then to identify the variation in the Milankovitch cycle sequences. On this basis, the system tract and 4th-order sequence interfaces in Sequence PSQ1 were found via two-dimensional spectral analysis and digital filtering. Finally, a high-frequency sequence division program was established. Among these cycles, long eccentricity (413.0 ka) and short eccentricity (123.0 ka) are the most unambiguous, and they are separately the major control factors in forming 4th-order (parasequence sets) and 5th-order (parasequences) sequences, with the average thicknesses corresponding to the main cycles being 11.47 m and 3.32 m in Well-Long17, and 14.21 m and 3.79 m in Well-Wujia1, respectively. In other words, the deposition rate in the beach subfacies is faster than that of the inner ramp facies. The ln(Th/K) curve is more sensitive than the GR as the index of relatively ancient water depth in carbonate deposition. One-dimensional spectrum analysis of ln(Th/K) curve could distinguish the Milankovitch cycle sequences that arose from the Precession cycle (20.90 ka), with a much higher credibility. Sequence PSQ1 in Well-Long17 contains 10 4th-order sequences, and the growth span of Sequence PSQ1 consisting of the Liangshan and Qixia formations is about 4.13 Ma. The single deposition thickness of the long eccentricity cycle sequence has the characteristics of thinning and then thickening in the two-dimensional spectrum, which could be used to identify the system tract interface of the 3rd-order sequence. The precession sequence thickness remains stationary. As a result, the early deposition rate in the mid-Permian of the Sichuan basin was very slow, remaining nearly stationary, and this reflects a sustained depositional environment. Whole-rock carbon and oxygen isotope curves could also prove this point. Milankovitch cycle sequence studies provide a basis for paleoenvironmental analysis and, as such, can be used to analyze ancient climate change, calculate deposition rate and deposition time, and carry out fine isochronous stratigraphic correlation.

Abstract:The Hefei Basin is the largest basin in the North China landmass with complete and well-preserved Mesozoic and Cenozoic strata. In the basin there developed a suite of extremely thick “red beds” in the Mesozoic. Owing to complex evolution processes and a lack of paleontological traces, there have been controversies regarding the division and correlation of this suite of red beds. Based on results obtained in recent years in drilling, seismic and surface geological investigations and in consideration of relationships between seismic sequences and regional tectonic events, as well as evidence in paleontology, petrology and isotopic dating, this paper preliminarily puts forward the following ideas about the sequence stratigraphic framework of the continental “red beds” in the Hefei Basin. (1) The Zhougongshan Formation and the Yuantongshan Formation have similar lithologic, geophysical and paleontological characteristics, so we incorporate them into a single formation, called the Yuantongshan Formation, and the original Zhougongshan and Yuantongshan Formations are regarded as the upper and the lower parts of the newly defined Yuantongshan Formation. Its age is the Middle Jurassic; (2) the Zhuxiang Formation belongs to the Upper Jurassic Series and (3) the age of the Xiangdaopu Formation is the Lower Cretaceous. Furthermore, signatures of depositional evolution are analyzed in the paper based on features of seismic reflection, outcrops and drilling data. The Early and Middle Jurassic is characterized by a foreland basin, which is influenced mainly by uplift and longitudinal compression of the Dabieshan Mountains; the Lower Jurassic System has a relatively small depositional area; the Middle Jurassic strata are distributed extensively over the whole basin, marking the summit of basin development; a flexure basin is characteristic of the Late Jurassic, manifesting a joint effect of the Dabieshan and Zhangbaling Mountains with the former being more significant. In the Early Cretaceous, the Xiangdaopu Formation was distributed in the Daqiao depression, evidently affected by extension of the Tanlu fault; in the Late Cretaceous, the Hefei Basin was subjected to dismembering and the Zhangqiao Formation was distributed in the east-west direction along the downthrown side of the fault.

Abstract:The sequence stratigraphy framework of Paleogene of Qikou Sag has been built in this paper. The evolution law of episodic subsidence in Qikou Sag has been expounded, with the analysis of the characteristic of sequence thickness, as well as the study of consedimental tectonic activity, subsidence history, paleogeomorphology and the coupling relationship among them. The faults controlling action was the dominant mechanism during rifting stage I , as the depression was the dominant mechanism during rifting stage III, which embodies a process from intense disparity fault depression to integral subsidence. Meanwhile, under the control of regional faulting and later stage depression, subsidence rate centers and paleogeomorphic concave centers are always corresponding to the sequence thickness centers, and the changes of subsidence centers and paleogeomorphology concave centers are consistent with the migration of thickness centers, which presents the restriction, coupling and response among them and clarifies the law that tectonic activity controls the basin fill by means of controlling the subsidence rate and paleogeomorphology from contributing factor angle. On this basis, the dynamic evolution of the composite pattern of structure-subsidence-deposition in the fault controlling actic region during the three rifting stages and their petroleum geological significance has been discussed.

Abstract:We outline the post-Late Paleozoic (latest Permian to Cenozoic) collisional framework of the southern Great Altai (Central Asia) produced by the convergence between the Tuva-Mongolia and Junggar continental terranes (microplates). The collisional structures in the region classified on the basis of their geometry and deformation style, dynamic metamorphism, and compositions of tectonites are of three main types: (1) mosaic terranes made up of large weakly deformed Paleozoic blocks separated by younger shear zones; (2) contractional deformation systems involving structures formed in post-Late Paleozoic time, parallel faults oriented along collisional deformation systems, and relict lenses of Paleozoic orogenic complexes; and (3) isolated zones of dynamic metamorphism composed mostly of collisional tectonites different in composition and alteration grade.

Abstract:The upper tertiary to quaternary is the main target layer for oil and gas exploitation in Mainland China, especially crude oil production in the Bohai Basin accounts for approximately 40% of China’s crude oil production. Therefore, a study of the Upper Tertiary to Quaternary has important significance for science and practical applications. In this study, using the receiver function method, Ps and later phase extraction, the sedimentary thickness and an accurate estimate of velocity ratio can be obtained. The technique is simple, its calculation results are unique, and it can be applied to a study of the sedimentary layer. The technique is promising for oil and gas exploration.

Abstract:Muscovite 40Ar-39Ar dating of muscovite-quartz schist, eclogite and retrograde eclogite indicates an Indosinian orogenesis occurred at 220–240 Ma in the Lhasa terrane, which is caused by the closure of Paleo-Tethyan ocean basin and the following collision of the northern Lhasa terrane and southern Gondwana land. This Indosinian orogenesis is further confirmed by the regional sedimentary characteristics, magmatic activity and ophiolite mélange. This evidence suggests that the Indosinian orogenic belt in the Lhasa terrane is widely distributed from the Coqen county in the west, and then extends eastward through the Ningzhong and Sumdo area, finally turning around the eastern Himalayan syntaxis into the Bomi county. Based on the evolutionary process, the geological development of Lhasa terrane from early Paleozoic to early Mesozoic can be divided into seven stages. All of the seven stages make up a whole Wilson circle and reveal a perfect evolutionary process of the Paleo-Tethys ocean between the northern Lhasa terrane and southern Gondwana land. The Indosinian orogenisis is a significant event for the evolution of the Lhasa terrane as well as the Tibetan Plateau.

Abstract:Xiba granitic pluton is located in South Qinling tectonic domain of the Qinling orogenic belt and consists mainly of granodiorite and monzogranite with significant number of microgranular quartz dioritic enclaves. SHRIMP zircon U–Pb isotopic dating reveals that the quartz dioritic enclaves formed at 214±3 Ma, which is similar to the age of their host monzogranite (218±1 Ma). The granitoids belong to high-K calc-alkaline series, and are characterized by enriched LILEs relative to HFSEs with negative Nb, Ta and Ti anomalies, and right-declined REE patterns with (La/Yb)N ratios ranging from 15.83 to 26.47 and δEu values from 0.78 to 1.22 (mean= 0.97). Most of these samples from Xiba granitic pluton exhibit εNd(t) values of ?8.79 to ?5.38, depleted mantle Nd model ages (TDM) between 1.1 Ga and 1.7 Ga, and initial Sr isotopic ratios (87Sr/86Sr)i from 0.7061 to 0.7082, indicating a possible Meso- to Paleoproterozoic lower crust source region, with exception of samples XB01-2-1 and XB10-1 displaying higher (87Sr/86Sr)i values of 0.779 and 0.735, respectively, which suggests a contamination of the upper crustal materials. Quartz dioritic enclaves are interpreted as the result of rapid crystallization fractionation during the parent magmatic emplacement, as evidenced by similar age, texture, geochemical, and Sr-Nd isotopic features with their host rocks. Characteristics of the petrological and geochemical data reveal that the parent magma of Xiba granitoids was produced by a magma mingling process. The upwelling asthenosphere caused a high heat flow and the mafic magma was underplated into the bottom of the lower continent crust, which caused the partial melting of the lower continent crustal materials. This geodynamic process generated the mixing parent magma between mafic magma from depleted mantle and felsic magma derived from the lower continent crust. Integrated petrogenesis and tectonic discrimination with regional tectonic evolution of the Qinling orogen, it is suggested that the granitoids are most likely products in a post-collision tectonic setting.

Abstract:The lower Cambrian Niutitang Formation, a widespread black shale deposition, is of geological interest because of its polymetallic beds, Cambrian explosion, depositional ages, dramatic environmental changes and so on. Previous study focused mainly on inorganic geochemistry and few studies have investigated the organic fractions of upper Neoproterozoic-lower Cambrian strata in South China. Here we report a study of biomarkers plus organic carbon isotopes for black shales from Ganziping, Hunan Province (China). All the saturated hydrocarbon fractions have a unimodal distribution of n-alkanes, a high content of short-chain alkanes and maximize at C19 or C20 (C23 for sample Gzh00-1). The C27/C29 sterane ratio ranges from 0.77 to 1.20 and 4-methylsteranes are in low abundance. These parameters indicate that algae and bacteria are the important primary producers. Furthermore, biomarker maturity proxies show the samples to be higher maturity. The low Pr/Ph values (<0.7) suggest that the samples were deposited under anoxic conditions and, likely, under stratified water columns. In addition, 25-norhopanes and gammacerane are present as diagnostic indicators of normal marine salinity and dysoxic to anoxic conditions. During the Early Tommotian, known to coincide with a transgression event, small shelly fossils increased in abundance and diversity. Moreover, positive δ13Corg excursions close to 1.4‰ occur at the base of the Tommotian stage. In summary, the Early Cambrian black shales were deposited under dramatic paleoenvironmental changes, including oceanic anoxia, higher primary productivity and sea-level rise.

Abstract:The Central Indian Ocean Basin (CIOB) basalts are plagioclase-rich, while olivine and pyroxene are very few. The analyses of 41 samples reveal high FeOT (~10–18 wt%) and TiO2 (~1.4–2.7 wt%) indicating a ferrobasaltic composition. The basalts have high incompatible elements (Zr 63–228 ppm; Nb ~1–5 ppm; Ba ~15–78 ppm; La ~3–16 ppm), a similar U/Pb (0.02–0.4) ratio as the normal mid-oceanic basalt (0.16±0.07) but the Ba/Nb (12.5–53) ratio is much larger than that of the normal mid-oceanic ridge basalt (~5.7) and Primitive Mantle (9.56). Interestingly almost all of the basalts have a significant negative Eu anomaly (Eu/Eu*=0.78–1.00) that may have been a result of the removal of feldspar and pyroxene during crystal fractionation. These compositional variations suggest that the basalts were derived through fractional crystallization together with low partial melting of a shallow seated magma.

Abstract:Petroleum geologists have debated whether the hydrocarbons from Jurassic coal measures are derived from the coals, carbonaceous mudstones or coal-measure mudstones in the Turpan Basin. Based on the geochemistry analysis of the 20 crude oils and 40 source rocks from the Turpan Basin, some data have been obtained as follows: carbon preference index and methylphenanthrene index of the Jurassic oils are 1.16–1.45 and 0.28–0.80, and the ααα C29 sterane 20S/(20S+20R) and C29 sterane ββ/(ββ+αα) are 0.44–0.51 and 0.4–0.54 respectively, which show the normal maturity of oils; the vitrinite reflectance of the source rocks from the Xishanyao to Badaowan Formations range from 0.47% to 0.97%, which indicate immature to mature thermal evolutionary stage and sufficient conditions for generating mass mature oil. The effect of hydrocarbon expulsion should be considered when studying the source of coal-derived oil by using Biomarkers. Biomarkers in the Jurassic oils from the basin are similar to those in the coals and carbonaceous mudstones, with a strong predominant content of pristane, relatively high ratio of C15/C16 sesquiterpenoids (>1), a relatively high content of low carbon number tricyclic terpanes and C24 tetracyclic terpane, little gammacerane and C29 Ts detected, an absolute predominant content of C29 sterane and a relatively high content of diasterane. However, the opposite characteristics are shown in mudstones, with an approximately equal content of pristane and phytane, relatively low ratio of C15/C16 sesquiterpenoids (<1), a relatively high content of high carbon number tricyclic terpanes and a low content of C24 tetracyclic terpane, peaks of gammacerane and C29 Ts detected obviously and an increasing C27 sterane content. All of these characteristics identify the coals and carbonaceous mudstones as the possible major oil source rocks in this area, and they were formed in the stronger oxidizing environment with shallower water than mudstones.

Abstract:The Napo-Qinzhou Tectonic Belt (NQTB) lies at the junction of the Yangtze, Cathaysia and Indochina (North Vietnam) Blocks, which is composed of five major lithotectonic subunits: the Qinzhou-Fangcheng Suture Zone (QFSZ), the Shiwandashan Basin (SB), the Pingxiang-Nanning Suture Zone (PNSZ), the Damingshan Block (DB) and the Babu-Lingma Suture Zone (BLSZ). On the basis of geochemical compositions, the Permian mafic igneous rocks can be divided into three distinct groups: (1) mafic igneous rocks (Group 1) from the Longjing region in the PNSZ and Hurun region in the BLSZ, which are characterized by intermediate Ti, P and Zr with low Ni and Cr contents; (2) mafic igneous rocks (Group 2) from the Naxiao and Chongzuo region in the DB, characterized by low-intermediate Ti, P and Zr with high Ni and Cr concentrations; and (3) mafic igneous rocks (Group 3) from the Siming region in the Jingxi carbonate platform of the northwestern margin of the NQTB, with intermediate-high Ti, P and Zr and low Ni and Cr contents. The Group 1 rocks yield a weighted mean 206Pb/238U age of 250.5±2.8 Ma and are geochemically similar to basalts occurring in back-arc basin settings. The Group 2 rocks exhibit geochemical features to those basalts in island arcs, whereas the Group 3 rocks show geochemical similarity to that of ocean island basalts. All three groups are characterized by relatively low εNd(t) values (–2.61 to +1.10) and high initial 87Sr/86Sr isotopic ratios (0.705309–0.707434), indicating that they were derived from a subduction-modified lithospheric mantle and experienced assimilation, fractional crystallization, and crustal contamination or mixing during magmatic evolution. Accordingly, we propose the existence of an arc-back arc basin system that developed along the NQTB at the border of SW Guangxi Province (SW China) and northern Vietnam, and it was formed by continued northwestward subduction of the Cathaysian (or Yunkai) Block under the Yangtze Block, and northeastward subduction of the Indochina Block beneath the Yangtze Block during Permian time.

Abstract:Geochemical analysis of sandstones from the Sardar Formation (from two stratigraphic successions) in east-central Iran were used for identification of geochemical characterization of sandstones, provenance and tectonic setting. Sandstones in the two lithostratigraphic successions have similar chemical compositions suggesting a common provenance. Bulk-rock geochemistry analysis of Carboniferous sandstones from Sardar Formation indicates that they are mainly quartz dominated and are classified as quartzarenites, sublitharenites and subarkoses, derived from acid igneous to intermediate igneous rocks. Discrimination function analysis indicates that the sandstones of Sardar Formation were derived from quartzose sedimentary provenance in a recycled orogenic setting. Also, major and trace elements in sandstones of Sardar Formation (e.g., K2O/Na2O vs. SiO2) indicate deposition in a stable passive continental margin (PM). Chemical index of alteration (CIA) for these rocks (> 65%) suggests a moderate to relatively high degree of weathering in the source area.

Abstract:The Shihu gold deposit, situated in the Taihang Mesozoic orogen of the North China Craton (NCC), is hosted by ductile-brittle faults within Archean metamorphic core complex. The deposit is characterized by gold-bearing quartz-polymetallic sulfides veins. The Mapeng granitoids stock and intermediate-basic dikes intruded the metamorphic basement rocks, and are spatially related to gold mineralization. Detailed laser ablation inductively coupled plasma mass spectrometry (LA ICP-MS) U-Pb zircon ages of the granitic rocks, dykes and mineralized quartz veins in the studied area reveal its magmatic and mineralized history. The mineralized quartz veins contain inherited zircons with ages of about 2.55 Ga and 1.84 Ga, probably coming from the basement. These two Precambrian events are coeval with those in other parts of the NCC. The Mapeng granitoid stock, the largest intrusion in the area, was emplaced at ca. 130 Ma, and is coeval with magmatic zircon populations from diorites and quartz diorite pophyrites in the same region. The ca. 130 Ma magmatism and gold mineralization were most likely related to an underplating event that took place in the Taihang orogen at Late Mesozoic. The timing of gold mineralization with respect to felsic magmatism in the area is similar to those observed in other major gold-producing provinces in the NCC. This episode is simultaneous with those in the eastern margin of NCC, indicative of a widespread late Yanshanian metallogenic event that was a response to the Early Cretaceous lithosphere in the eastern NCC, in which the mesothermal gold deposits were formed from similar tectono-magmatic environments.

Abstract:The multi-stage intrusions of intermediate-acid magma occur in the Bangpu mining district, the petrogenic ages of which have been identified. The times and sequences of their emplacement have been collated and stipulated in detail in this paper by using the laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) zircon U-Pb dating method. The ages of biotite monzogranite that were formed before mineralization in the southwest of this mining district are 70±1?Ma (mean square of weighted deviates (MSWD) =9.5, n=8) and 60.60±0.31?Ma (MSWD=3.8, n=16), which belong to the late Cretaceous–early Paleocene in age. That means, they are products of an early tectonic-magmatic event of the collision between the Indian and Asian continentals. The ages of ore-bearing monzogranite porphyry and ore-bearing diorite porphyrite are 16.23±0.19?Ma (MSWD=2.0, n=26) and 15.16±0.09?Ma (MSWD=3.9, n=5) separately, which belong to the middle Miocene in age; namely, they are products of the Gangdese post-collision extensional stage when crust-mantle materials melted and mixed as well as magmatic intrusion simultaneously occurred. Some zircons with ages of 203.6±2.2?Ma (MSWD=1.18, n=7) were captured in the ore-bearing diorite porphyrite, which shows that there had been tectono-magmatic events in the late Triassic–early Jurassic. Molybdenum (copper) ore-bodies produced in the monzogranite porphyry and copper (molybdenum) ore-bodies produced in the diorite porphyrite are the main ore types in this ore deposit. The model ages of Re-Os isotopic dating for the 11 molybdenite are 13.97–15.84?Ma, while isochron ages are 14.09±0.49?Ma (MSWD=26). The isochron ages of seven molybdenite from molybdenum (copper) ore with monzogranite porphyry type are 14.11±0.31?Ma (MSWD=5.2). There is great error in the isochron ages of four molybdenite from copper (molybdenum) ore with diorite porphyrite type, and their weighted average model ages of 14.6±1.2?Ma (MSWD=41), which generally represent the mineralization age. The results about the Re-Os isotopic dating of molybdenite in the ore of different types have limited exactly that, the minerlazation age of this ore deposits is about 14.09?Ma, which belongs to the middle Miocene mineralization. The Bangpu deposit has a uniform metallogenic dynamics background with the porphyry type and skarn-type deposits such as Jiama, Qulong and others.

Abstract:Constraints from P-T pseudosections (MnNCKFMASH system), foliation intersection/inflection axes preserved in porphyroblasts (FIAs), mineral assemblages and textural relationships for rocks containing all three Al2SiO5 polymorphs indicate a kyanite→ andalusite→ sillimanite sequential formation at different times rather than stable coexistence at the Al2SiO5 triple point. All three Al2SiO5 polymorphs grew in the Chl, Bt, Ms, Grt, St, Pl and Crd bearing Ordovician Clayhole Schist in Balcooma, northeastern Australia separately along a looped P-T-t-D path that swaps from clockwise to anticlockwise in the tectono-metamorphic history of the region. Kyanite grew during crustal thickening in an Early Silurian Orogenic event followed by decompression/heating, andalusite and fibrolitic sillimanite growth during Early Devonian exhumation.

Abstract:Early Paleozoic granodiorite has been identified on the northern margin of the North China craton in the east section of the central-Asian orogenic belt, which was previously known as early Indosinian in age. By using the LA-ICP-MS method, the obtained zircon U-Pb age is 445.6±2.7 Ma, which represents the crystallization age of the granodiorite. The granodiorite near the east of the large-sized Bilihe gold deposit is of the tholeiite series with low potassium. It is quasi-aluminous I-type granite, enriched in sodium (Na2O/K2O=7.29-9.77) and magnesium (Mg#=0.51-0.67). The ΣREE value is relatively low, obvious differentiation is shown between LREE and HREE and within LREE, and the Eu anomaly is low and negative (δEu=0.74-0.91). In the primitive-mantle normalized spider diagrams of trace elements, the granodiorite is relatively rich in LREE and LILE (Ba, Sr, Th), and strongly depleted in HFSE (Nb, Ta, Ti and P), which shows features of subduction zone components (SZC). In the discrimination diagrams of tectonic settings of granite for Rb vs. (Nb+Y), Rb vs. (Ya+Ta), La/Nb vs. Ba/Nb and Th/Nb vs. Ba/Nb, the granodiorite exhibits typical features of island arc granite. The normalized values of K and Rb are extremely low, while the values of Sr and Eu are very high, which are similar to those of island arc magma that has undergone metasomatism of fluid from the oceanic crust. The granodiorite is relatively depleted in εHf(t) (5.1-7.1) and low in εHf(t) model ages (1089-921 Ma). In the εHf(t) vs. age (T) diagram, the distribution area of the granodiorite is accordant with the field of the Xing’anling-Mongolia orogenic belt, which indicates that the magmatic sources are mainly the mixture of partial melting of wedged mantle subjected to metasomatism of fluid from the oceanic crust and young substance from the crust. The granodiorite is similar to the felsic arc magma in the Damao Banner, Bate Obon, Boin Sum and Ordor Sum regions, and they altogether constitute an early Paleozoic accretionary island arc magmatic belt on the northern margin of the North China craton. A number of early Paleozoic zircons trapped in late Paleozoic intrusions in the Hadamiao and Bilihe regions and the discovery of the early Paleozoic island arc magmatic belt near the east of the Bilihe gold deposit suggest that the late Paleozoic volcanic-intrusive rocks have a basement of early Paleozoic arc accretionary complexes. This is just the evident of the multiphase subduction and accretion model of the Paleo-Asian Ocean (PAO). Paleozoic structures and magmas on the northern margin of the North China craton are shown from south to north as the late Paleozoic Andes-type arc magmatic belt in the Inner Mongolia plateau, the Chifeng-Bayan Obo fault and the late and early Paleozoic arc magmatic belt, which shows that after the early Paleozoic arc-continent collisional orogeny and at the stage of the late Paleozoic accretionary orogeny, the PAO plate was likely to continuously pulsate and underthrust beneath the early Paleozoic island arc accretionary complex belt and its front, i.e. the North China craton. During the early Paleozoic collisional orogeny, the PAO plate might not experience large-scale breakup or delamination. The characteristics of the early Paleozoic island arc accretionary complex basement have a significant control on late Paleozoic diagenesis and metallization in the Hadamiao and Bilihe gold concentrated areas.

Abstract:Paired stable oxygen isotope and Mg/Ca analyses in calcite tests of the mixed-layer-dwelling planktic foraminifer Globigerinoides ruber has been used to reconstruct equatorial Indian Ocean δ18O of seawater (δ18Osw) over the last ~137 thousand years. On the basis of ice-volume-corrected δ18Osw (δ18Osw–ivc), relative changes in sea surface salinity (SSS) have been estimated. The SSS estimates suggest three episodes of higher SSS (131–113 thousand years before present (kyr BP), 62–58 kyr BP, and 30–24 kyr BP) within the last glacial period as compared with the present. SSS comparison between interglacial episodes reveals that the surface seawater over the core site was significantly saltier during the penultimate interglacial than the Holocene. We suggest that the evolution of a seasonal insolation gradient between the Indian monsoon areas and the equator over the investigated time interval was instrumental in shaping the strength of the Indian winter and summer monsoons that left their imprints on the equatorial Indian Ocean SSS via freshwater input and wind-induced mixing. The study shows that the insolation difference between northern latitudes and the equator during winter affects monsoon strength in the Indian region, especially during cold intervals.

Abstract:A detailed paleomagnetic and rock-magnetic investigation spanning loess L7 to paleosol S8 has been carried out at the Baoji and Xifeng sections. Results of anisotropy of magnetic susceptibility confirm that the studied loess–paleosol sediments retain primary sedimentary fabrics. Stepwise thermal demagnetization shows that two well-defined magnetization components can be isolated from both loess and paleosol specimens. A low-temperature component, isolated between 100°C and 200°C, is consistent with the present geomagnetic field direction, and a high-temperature component, isolated between 200–300°C and 620–680°C, includes clearly normal and reversed polarities. Isothermal remanent magnetization and thermomagnetic analyses indicate that characteristic remanent magnetization is mainly carried by magnetite and hematite. The Day plot, together with the stratigraphic variations of rock-magnetic parameters, shows that the uniformity of magnetic mineralogy and grain size fulfills the criteria for relative paleointensity (RPI) studies. RPI records have been constructed using natural remanent magnetization (NRM) intensity after thermal demagnetization at 300°C normalized by low-frequency magnetic susceptibility (NRM300/χ). The results show that the RPI record from the Baoji section, where pedogenesis is quite weak, is compatible with the stacked PISO-1500 paleointensity record, suggesting that it might reflect the paleointensity variation of the geomagnetic field. The RPI record from the Xifeng section, where pedogenesis is rather strong, indicates a clear dissimilarity with the stacked PISO-1500 paleointensity record, implying that it does not reflect the paleointensity variation of the geomagnetic field. Our new results show that the NRM300/χ from the strongly pedogenetic paleosols does not completely eliminate the pedogenetic (climatic) influence, so it might be unsuitable for a reliable paleointensity study.

Abstract:The purpose of this study is to evaluate the Spectral Angle Mapper (SAM) classification method for determining the optimum threshold (maximum spectral angle) to unveil the hydrothermal mineral assemblages related to mineral deposits. The study area indicates good potential for Cu-Au porphyry, epithermal gold deposits and hydrothermal alteration well developed in arid and semiarid climates, which makes this region significant for Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) image processing analysis. Given that achieving an acceptable mineral mapping requires knowing the alteration patterns, petrochemistry and petrogenesis of the igneous rocks while considering the effect of weathering, overprinting of supergene alteration, overprinting of hypogene alteration and host rock spectral mixing, SAM classification was implemented for argillic, sericitic, propylitic, alunitization, silicification and iron oxide zones of six previously known mineral deposits: Maherabad, a Cu-Au porphyry system; Sheikhabad, an upper part of Cu-Au porphyry system; Khoonik, an Intrusion related Au system; Barmazid, a low sulfidation epithermal system; Khopik, a Cu-Au porphyry system; and Hanish, an epithermal Au system. Thus, the investigation showed that although the whole alteration zones are affected by mixing, it is also possible to produce a favorable hydrothermal mineral map by such complementary data as petrology, petrochemistry and alteration patterns.

Abstract:Lithium separation technique for three reference materials has been established together with precise determination of lithium isotope using a Neptune multi collector-inductively coupled plasma mass spectrometry (MC-ICP-MS). The solutions of lithium element standard reference materials, potassium, calcium, sodium, magnesium and iron single element, were used to evaluate analytical methods applied. Three separate stages of ion-exchange chromatography were carried out using organic cation-exchange resin (AG 50W-X8). Lithium was enriched for the three stages using different eluants, which are 2.8 M HCl, 0.15 M HCl and 0.5 M HCl in 30% ethanol, respectively. The columns for the first and second stages are made of polypropylene, and those for the third stage are made of quartz. Total reagent volume for the entire chemical process was 35 mL for three reference materials. The recovery yielded for the three stages is 98.9–101.2% with an average of 100.0%, 97.6–101.9% with an average of 99.9%, and 99.8–103.3% with an average of 100.6%, respectively. The precision of this technique is conservatively estimated to be ±0.72–1.04‰ (2σ population), which is similar to the precision obtained by different authors in different laboratories with MC-ICP-MS. The δ7Li values (7Li/6Li relative to the IRMM-016 standard) determined for andesite (AGV-2) and basalt (BHVO-2) are 5.68‰ (n=18), 4.33‰ (n=18), respectively. The δ7Li value (7Li/6Li relative to the L-SVEC standard) determined for IRMM-016 is –0.01‰ (n=15). All these analytical results are in good agreement with those previously reported. In addition, the results for the same kinds of samples analyzed at the MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, are consistent with those obtained at the Plasma Laboratory, University of Maryland, within analytical uncertainty. According to these experiment results, it is concluded that this proposed procedure is a suitable method for determining the lithium isotopic composition of natural samples.

Abstract:This paper shows the presence of noises and technique to reduce these noises during the surface wave analysis. The frequency-dependent properties of Rayleigh-type surface waves can be used for imaging and characterizing the shallow subsurface. Interference by coherent source-generated noise inhibits the reliability of shear-wave velocities determined through inversion of the phase velocities of Rayleigh waves. Among these interferences by non-planar, non-fundamental mode Rayleigh waves (noise) are body waves, scattered and non-source-generated surface waves, and higher-mode surface waves. For the reduction of noise, the filtering technique is implemented in this paper for the multichannel analysis of surface wave method (MASW). With the de-noising technique during the MASW method, more robust and reliable outcome is achieved. The significance of this paper is to obtain pre-awareness about noises during surface wave analysis and take better outcomes with de-noising performance in near surface soil investigations.

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