Geochemical exploration is a very important exploration and evaluation methods in resource and environment field. In the past ten years, new progresses were achieved in the research of new methods of geochemical exploration, which fall in the following aspects: 1）Resolved the disturbances of the organic material and/or eolian sands to geochemical stream sediment survey which pervasively exist in landscape of forest-swamp, arid or semi-arid high-cold mountain, and high-cold lake-swamp hilly land, the grain size is -10 ~ +60 mesh for sampling in forest-swamp landscape and high-cold lake-swamp hilly land landscape, -10 ~ +40 or -10 ~ +80 mesh for sampling in arid or semi-arid high-cold mountain area, which largely improved geological and ore-finding results, find a group of influential large and super large deposits which take the Tuotuo He polymetallic ore field as representative and developed a new situation for mineral resources exploration. 2）Not only a kind of method system for muti-purpose regional geochemical survey in transported soil coveragearea was built: sampling surface soil samples(within 20cm) at density: 1 sample╱4km2 and sampling soil samples at 1.5m depth at density: 1 sample╱16km2, determined 54 elements or indicatrices, but also methods of anomaly verification and evaluation for agriculture, environment and urban geochemical survey were put forward, meanwhile, provided high-quality basic geochemistry date by mean of muti-purpose regional geochemical survey for the establishment of green and characteristic farming and grazing base and research of carbon cycling, and successfully completed from the geochemical field to the environment Survey field transition. 3）The theory and method of deep penetration geochemistry achieved some progress which discovered the nanoscale metal migration track from the surface to the deep crust, and initially established a special analysis technique for deep penetration geochemistry samples. 4）The development of oil and gas geochemical exploration technique is in the turns and twists to go forward which initially developed a kind of integrated exploration method system, and had spread and application in certain degree in oil-gas exploration, and provided some successful cases in oil and gas prospecting.