伟晶岩中不同副矿物U-Pb同位素定年与示踪的问题与应用
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1.中国地质大学 地质过程与矿产资源国家重点实验室, 资源学院,紧缺战略矿产资源协同创新中心;2.中国地质大学 资源学院

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国家自然科学基金项目(面上项目,重点项目,重大项目)


The U-Pb isotope dating and tracing using different accessory minerals in pegmatite: Problems and application
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China University of Geosciences (Wuhan)

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    摘要:

    定年和示踪一直是伟晶岩成岩成矿过程和稀有金属富集机制研究的关键科学问题。副矿物不仅是伟晶岩中稀有稀土元素的重要载体,还蕴含丰富的微量元素并具有较高的U-Th含量,是研究伟晶岩年代学、成岩成矿过程和物质源区的“理想探针”。稀有金属伟晶岩中常用的U-Pb定年副矿物有锆石、铌钽铁矿、独居石、锡石、榍石、褐帘石、磷钇矿和磷灰石等。由于封闭温度、矿物学特性和不同性质流体中元素行为的差异,伟晶岩中不同副矿物的U-Pb系统常表现出复杂的年龄谱系,可能记录了伟晶岩中潜在的后期地质过程,如:自交代、后期变质与流体改造等。因此,基于前期光学显微镜、扫描电镜、冷阴极发光、激光拉曼光谱分析等矿物微观结构研究,对不同期次或世代的副矿物进行原位微区U-Pb定年及主微量元素和同位素地球化学分析,对于全面认知多期地质事件和伟晶岩成岩成矿过程演化历史,进而更准确地构建其构造-岩浆-热液-成矿作用时空框架具有重要的科学意义。

    Abstract:

    Dating and tracing have always been key scientific issues in the study of pegmatite petrogenesis and mineralization processes, as well as rare metal enrichment mechanisms. Accessory minerals are not only important carriers of rare metals and rare earth elements in pegmatites, but also contain abundant other trace elements such as high U-Th content, making them an ideal probe for studying pegmatite chronology, petrogenetic and mineralization processes, and to trace the magma sources. The accessory minerals that are commonly used for U-Pb dating in pegmatites include zircon, columbite-tantalite, monazite, cassiterite, titanite, allanite, xenotime, and apatite. Due to differences in closure temperature, mineralogical characteristics, and elemental behavior in fluids with different properties, U-Pb isotope systems of different accessory minerals in pegmatites often exhibit complex age spectra, which may record potential late geological processes in pegmatites, such as auto-metasomatism, late metamorphism, and fluid alteration. Therefore, based on previous studies on mineral microstructures such as optical microscopy, scanning electron microscopy, cold cathodoluminescence, and laser Raman spectroscopy, in-situ U-Pb dating and geochemical analysis of major and trace elements and isotopes of accessory minerals from different generations of pegmatites are carried out, which is beneficial for a comprehensive understanding of the evolution history of multiple geological events and pegmatite petrogenesis and mineralization processes. It is of great scientific significance to construct an accurate spatiotemporal framework of tectonic-magmatic-hydrothermal mineralization events related to pegmatite formation.

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  • 收稿日期:2024-01-22
  • 最后修改日期:2024-02-17
  • 录用日期:2024-02-21
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