青藏高原盐湖硼矿沉积特征与地球化学约束条件
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中国科学院青海盐湖研究所

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Sedimentary characteristics and geochemical constraints of borate deposits in salt lakes on Qinghai-Tibetan Plateau
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Qinghai Institute of Salt Lakes Chinese Academy of Sciences

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    摘要:

    内容提要:硼是我国战略性关键非金属矿产,广泛用于新能源、新材料、电子信息等高新技术领域。盐湖型硼矿主要分布在青藏高原,是我国最主要、最具开采前景的硼矿类型。青藏高原富硼盐湖由南至北呈现水化学分带性和硼矿类型差异性,然而,不同区带富硼盐湖的对比研究仍然薄弱。本文系统总结对比青藏高原碳酸盐型(Ⅰ区)、硫酸钠-硫酸镁亚型(Ⅱ区)、硫酸镁-氯化物型(Ⅲ区)盐湖的固体硼矿沉积特征及富硼卤水地球化学参数,获得主要认识如下:①硼酸盐矿物多沉积于碎屑物之上,呈现交互多层沉积特征,表明硼矿的沉积需要有淡咸水补给或水文环境的改变,符合“稀释成盐”硼矿理论;②硼砂及钠硼解石沉积均有大量芒硝共生,柱硼镁石及库水硼镁石的沉积多有大量含镁碳酸盐矿物(水菱镁矿、白云石)伴生,指示硼砂、钠硼解石的沉积于高Na+水体,柱硼镁石、库水硼镁石沉积自高Mg2+水体;③Ⅰ、Ⅱ、Ⅲ区盐湖硼矿析出条件具有相似性,表现为卤水pH值大于8、B含量大于400 mg/L;但在TDS、Mg和Na含量上,不同盐湖存在差异;④结合硼矿类型主要含Na+、Mg2+化学组成,Ⅰ、Ⅱ、Ⅲ区B×10-Na-Mg三角当量图表明各区硼矿沉积时Na、B当量值分别在0.2-0.6、0.4-0.7范围,而Mg当量值有一定差异,Ⅰ区<0.1,Ⅱ、Ⅲ区在0.1-0.4范围。

    Abstract:

    Boron is a strategic key non-metallic mineral in China, widely used in new energy, new materials, electronic information and other high-tech fields. The salt lake type borate deposits are mainly distributed on the Qinghai-Tibetan Plateau and the most important and promising boron resource type in China. Boron-rich salt lakes in the Qinghai-Tibetan Plateau show hydrochemical zones and differences of borate deposit types in different hydrochemical of salt lakes from south to north, but there is lack of comparative study of boron-rich salt lakes in different zones.This paper summarizes and compares the sedimentary characteristics of solid boron deposits and the differences of geochemical parameters of boron-rich brines in carbonate type (I region), sodium sulfate-magnesium sulfate subtype (II region) and magnesium sulfate-chloride type (III region) salt lakes on the Qinghai-Tibetan Plateau. The main conclusions are obtained as follows:① Borate minerals are mostly deposited directly on top of the clastic sediments, and present interactive multilayer deposition characteristics, indicating that the deposition of borate deposits requires brackish water recharge and hydrological environment changes, which accords with the theory of "Brine diluted into salt";② The deposition of borax and ulexite is associated with a large number of mirabilite, and the deposition of pinnoite and Kurnakovite is accompanied by a large number of magnesium-bearing carbonate mineral (Hydromagnesite and dolomite), which indicates that the deposition of borax and ulexite requires the recharge of waters high in Na+, and that the deposition of pinnoite and Kurnakovite requires the recharge of waters high in Mg2+;③ The boron precipitation conditions of salt lakes inⅠ,Ⅱ, and Ⅲ zones are similar, as shown by the brine pH value of more than 8 and the B content of more than 400 mg/L; however, there are differences between different salt lakes in terms of TDS, Mg, and Na content;④ Combined with the chemical composition of borate deposits types mainly containing Na+ and Mg2+.The B×10-Na-Mg terminary equivalent diagram in zones Ⅰ, Ⅱ and Ⅲ shows that the equivalent of Na and B are in the range of 0.2-0.6 and 0.4-0.7, respectively, whereas there are some differences in the Mg equivalence values, with zones Ⅰ < 0.1, and zones Ⅱ and Ⅲ in the ranges of 0.1-0.4.

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  • 收稿日期:2023-09-11
  • 最后修改日期:2023-11-30
  • 录用日期:2023-12-04
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