红层砂岩纳米级致色剂赋存状态及地质意义—以鄂尔多斯盆地下白垩统志丹群红层砂岩为例
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1.中国石油大学北京油气资源与工程全国重点实验室;2.中国石油辽河油田公司勘探开发研究院;3.内蒙古煤炭建设工程集团总公司

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(42173030、41802149)和内蒙古自治区地质勘查(编号:20-1-MT01)联合资助。


The occurrence state and geological significance of nanoscale colorants in red bed sandstones: a case study of red sandstone of Lower Cretaceous Zhidan Group, Ordos Basin
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1.National Key Laboratory of Petroleum Resources and Engineering,China University of Petroleum Beijing;2.Research Institute of Exploration Development,PetroChina Liaohe Oilfield Company,Panjin;3.Inner Mongolia Coal Construction Engineering Group Corporation,Huhhot,Inner Mongolia

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    摘要:

    红层是地球上广泛分布且具有特定指示环境意义的沉积物,一般认为在水体氧化环境下形成的赤铁矿胶结物是其主要致色矿物。目前针对红层致色矿物的研究多停留在矿物识别层面,缺乏对其微观赋存状态及成因机制的深入研究。本文以鄂尔多斯盆地下白垩统志丹群陆相红层为例,采用岩心-薄片-阴极发光-氩离子抛光扫描电镜的多尺度表征技术,首次揭示了红层砂岩纳米级致色剂—赤铁矿胶结物的微观赋存状态,并在此基础重新探讨了其成因机制。研究发现,红层砂岩致色剂—赤铁矿胶结物主要为针状或片状,具有两种微观赋存状态:一种呈包裹型发育在净砂岩的颗粒周缘,单个矿物颗粒长度在500-1000nm之间,宽度在50nm以下;另一种呈充填型发育在粘土矿物及云母等矿物颗粒的解理缝中,常常顺解理定向排列,受解理缝空间限制,单个矿物颗粒更小,长度一般小于500nm,宽度在30nm以下。红层砂岩中赤铁矿的产状和赋存状态表明其为褐铁矿早期脱水形成,在此之后又发育两期方解石胶结物,因此赤铁矿胶结物应主要形成于沉积和浅埋藏期,而非沉积后的抬升期。砂岩中赤铁矿胶结物的形成过程指示了一个干旱内陆沉积背景下大气水氧含量高的环境特征,这同样也是地质历史时期内的冰室状态,说明鄂尔多斯盆地下白垩统志丹群的红层砂岩对研究该时期全球冰室状态也具有重要启示意义。

    Abstract:

    Red beds are widely distributed sediments on Earth with specific environmental significance. It is generally believed that hematite cement formed under water oxidation conditions is the main color-producing mineral. At present, the research on red-bed coloring minerals mostly remains at the level of mineral identification, lacking in-depth study on their microscopic occurrence states and genetic mechanisms. Taking the continental red beds of the Lower Cretaceous Zhidan Group in the Ordos Basin as an example, this paper adopts multi-scale characterization techniques of core, thin section, cathodoluminescence, and argon ion polished scanning electron microscopy to reveal the microscopic occurrence of nano-scale colorant-hematite cement in red bed sandstone for the first time, and re-explore its genetic mechanism on this basis. The study found that the colorant of red bed sandstone, hematite cement, is mainly needle-like or sheet-like, with two microscopic occurrence states: one is encapsulated and developed around the edges of clean sandstone particles, with individual mineral particles ranging in length from 500-1000nm and width below 50nm; The other type of filling development occurs in the cleavage fractures of clay minerals and mica particles, often arranged in a directional manner along the cleavage. Due to the spatial constraints of the cleavage fractures, individual mineral particles are smaller, with lengths generally less than 500 nm and widths below 30 nm. The occurrence and occurrence state of hematite in red bed sandstone indicate that it was formed by the early dehydration of limonite, followed by the development of two phases of calcite cementation. Therefore, hematite cementation should mainly occur during the sedimentation and shallow burial periods, rather than during the uplift period after sedimentation. The formation process of hematite cement in sandstone indicates an environment characterized by high atmospheric water oxygen content under a dry inland sedimentary background, which is also a glacial state during the geological history. This suggests that the red sandstone of the Lower Cretaceous Zhidan Group in the Ordos Basin also has important implications for studying the global glacial state during this period.

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  • 收稿日期:2023-07-10
  • 最后修改日期:2023-09-17
  • 录用日期:2023-09-25
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