青海海德乌拉铀矿床萤石微量元素地球化学特征及其地质意义
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1.东华理工大学地球科学学院;2.东华理工大学核资源与环境国家重点实验室;3.青海省核工业地质局

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Characteristics of trace element geochemistry and the geological significance of fluorites from the Haidewula uranium deposit in Qinghai
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1.East China University of Technology;2.State Key Laboratory of Nuclear Resources and Environment, East China University of Technology;3.Qinghai Nuclear Industry Geological Bureau

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    摘要:

    青海德乌拉铀矿床是目前西北地区唯一探明的单铀型火山岩型热液铀矿床,查明该矿床成矿流体性质与成矿机制,有利于矿床成因的认识和找矿实践的开展。本文首次对青海德乌拉铀矿床中与成矿作用关系密切的脉石矿物——萤石开展了详细的矿物学、岩相学和微量元素(含稀土元素)研究,以探讨成矿流体特征。研究表明,海德乌拉铀矿床产出有紫黑色、紫色两期热液萤石脉,其中紫黑色萤石与成矿关系更为密切。两期萤石的微量元素特征和稀土配分模式明显不同,成矿期紫黑色萤石相对富集Sr和Ba,而成矿后期紫色萤石相对富集REE以及Co、Ni、Cu、Zn、Ga、Rb、Y、Zr、Nb、Mo、Cs、Pb、Th和U等微量元素。其中,成矿期紫黑色萤石ΣREE变化范围较大(59.98×10-6~118.31×10-6),中值为75.02×10-6,稀土配分模式呈轻稀土富集的右倾型(ΣLREE/ΣHREE中值为5.06),轻重稀土分异明显((La/Yb)N中值为12.24),具有中度铕负异常(δEu中值为0.56),铈异常不明显(δCe中值为0.99)和钇正异常(δY值中值为2.21);成矿后期紫色萤石ΣREE含量较高(194.12×10-6~207.67×10-6),中值为195.55×10-6,稀土配分模式呈轻稀土富集的右倾型(ΣLREE/ΣHREE中值为4.76),轻重稀土分异较明显((La/Yb)N中值为6.37),具有强烈铕负异常(δEu中值为0.09)、明显的铈正异常(δCe中值为1.33)和钇正异常(δY值中值为1.90)。根据与围岩和沥青铀矿的地球化学特征的对比结果,认为海德乌拉铀矿床中成矿期和成矿后期的两期萤石形成于不同来源的流体,成矿期萤石反映了其形成于富含F-、Cl-的酸性流体,可能是大气降水与岩浆水的混合,且在相对还原的环境下沉淀成矿;成矿后期紫色萤石主要继承了赋矿火山岩围岩的Eu负异常特征,但Ce明显正异常,暗示成矿后期萤石形成于更为氧化的环境,具有更高比例大气降水的加入,且成矿后期流体的氧逸度和pH值与成矿期的流体相比更高。

    Abstract:

    The Haidewula uranium deposit is the first typical volcanic-related hydrothermal uranium deposit to be discovered in northwest China currently. Revealing the nature of the ore-forming fluids and the mineralized mechanism is favorable to understand the genesis of the deposit and to guide the prospecting in this area. Detailed studies on mineralogy, petrography and trace elements of fluorites from the deposit have been conducted in this paper. The results show that two stages of hydrothermal fluorite including metallogenic stage dark purple fluorite and post metallogenic stage purple fluorite have been identified, with the metallogenic stage dark purple fluorite closely associated with the uranium mineralization. The characteristics of trace elements and the REEs pattern are significantly different in two stage fluorites. The dark purple fluorite in the metallogenic stage is relatively enriched in Sr and Ba, while the purple fluorite in the post metallogenic stage is relatively enriched in REE and trace elements such as Co, Ni, Cu, Zn, Ga, Rb, Y, Zr, Nb, Mo, Cs, Pb, Th and U. The ΣREE of dark purple fluorite in the metallogenic stage ranges from 59.98×10-6 to 118.31×10-6, with a median value of 75.02×10-6, and the REE pattern is characterized by enriched LREE (LREE/HREE ratios median 5.06) and a strong fractionation between LREE and HREE ((La/Yb) N value median 12.24)), with moderate negative Eu anomaly (with median of 0.56), week Ce anomaly (with median of 0.99) and positive Y anomaly (with median of 2.21). The ΣREE of purple fluorite in the post metallogenic stage ranges from 194.12×10-6 to 207.67×10-6, with a median value of 195.55×10-6. The REE patterns of purple ?uorite is characterized by enriched LREE (LREE/HREE ratios median 4.76) and a relatively strong fractionation between LREE and HREE ((La/Yb) N value median 6.37)), with a well-pronounced negative Eu anomaly (with median of 0.09), positive Ce anomaly (with median of 1.33) and positive Y anomaly (with median of 1.90). Based on the comparison with the geochemical characteristics of the surrounding rocks and the pitchblende, two stages of fluorite (metallogenic stage dark purple fluorite and post metallogenic stage purple fluorite) in Haidewula uranium deposit were formed in the fluids with different sources. The metallogenic stage dark purple fluorite was formed in the acidic ore-forming ?uid rich in F- and Cl-, and maybe precipitated by the mixing mechanism of meteoric water with magmatic water in a reducing environment. The trace element geochemical characteristics of post metallogenic stage purple fluorite, such as with Ce positive anomaly and inheriting the Eu negative anomaly of the ore-bearing volcanic host rocks, indicated that the fluorite was formed in the oxidizing environment with higher proportion of meteoric water and higher oxygen fugacity and pH value in the fluid.

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  • 收稿日期:2023-07-03
  • 最后修改日期:2023-12-06
  • 录用日期:2023-12-27
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