云南邦棍尖山花岗岩的岩石学、地球化学和年代学特征对离子吸附型稀土成矿的制约
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1. 南方海洋科学与工程广东省实验室(广州),广东广州,511458;2. 广州海洋地质调查局,自然资源部海底矿产资源重点实验室,广东广州,510075;3. 自然资源部成矿作用与资源评价重点实验室,中国地质科学院矿产资源研究所,北京,100037

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陆蕾,女,1987年生。博士,主要从事稀土等战略矿产的调查研究工作。E-mail:lulei0830@qq.com。

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Constrains on metallogenic mechanism of ion-adsorption type REE deposit from mineralogy, geochemistry and chronology of Banggunjianshan granite, Yunnan Province
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1. Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou), Guangzhou, Guangdong 511458, China;2. Ministry of Natural Resources Key Laboratory of Marine Mineral Resources, Guangzhou Marine Geological Survey, Guangzhou, Guangdong 510075, China;3. Ministry of Natural Resources Key Laboratory of Metallogeny and Mineral Resource Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China

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    摘要:

    云南陇川龙安稀土矿是云南境内唯一开采的离子吸附型稀土(iREE)矿床,其成矿母岩为邦棍尖山花岗岩。近年来该花岗岩风化壳中相继发现了一系列iREE矿化点甚至矿床,其中不乏重稀土(HREE)矿。本文选取邦棍尖山南段的花岗岩进行岩石学、矿物学、地球化学和年代学等研究工作,并探讨其对iREE(甚至离子吸附型重稀土(iHREE))成矿的制约。邦棍尖山岩体的主要岩性为黑云母二长花岗岩,本研究测得花岗岩锆石U-Pb年龄为50.33 Ma(50.33±0.30 Ma,MSWD=0.15),形成于喜山期(古近纪),是目前发现的成矿母岩最年轻的iREE矿床。花岗岩具有以下地球化学特征:高硅高碱、低铁低镁,A/CNK>1.1,高钾-强过铝质,S型。岩体轻稀土(LREE)相对富集,轻重稀土分异较强烈(LREE/HREE为2.54~8.98),Eu负异常(δEu=0.06~0.17);微量元素显示出高Rb、Th,低Ba、Nb、Sr、Zr、Hf、Ti的特征,岩浆岩高度分异。邦棍尖山花岗岩中的(含)稀土矿物主要是榍石(∑REE=14506.24×10-6,LREE/HREE=1.14, n =6)、褐帘石(∑REE=232860.82×10-6, n =2)、褐钇铌矿和锆石,其次为少量独居石、磷钇矿、钍石、含稀土萤石和氟碳酸盐矿物等。此外,黑云母(∑REE=168.60×10-6,LREE/HREE=1.41, n =10)和斜长石(∑REE=123.60×10-6,LREE/HREE=2.77, n =8)中少量的REE对原岩也有贡献。(含)稀土矿物是基岩中REE含量的主要贡献者,这些矿物在自然风化作用下风化-解离后吸附于黏土矿物之上即有可能形成iREE矿床。通过本次研究得出以下认识:① 花岗岩的演化主要影响REE的迁移、分馏和再富集,与REE含量变化关系不大;② 花岗岩演化过程中产生的热液使REE从原矿物中迁出并形成新的(含)稀土矿物,是iREE(甚至iHREE)成矿的关键;③ 龙安iREE矿床基岩中,榍石、褐帘石、钍石、含稀土萤石和氟碳酸盐矿物是iREE成矿的主要来源,其次为斜长石和黑云母,这些矿物总体显示出LREE含量相对较高,从而使矿床LREE相对富集。

    Abstract:

    The Long'an deposit is the only mining ion-adsorption type REE (iREE) deposit in Yunnan Province, the parent rock of which is the Banggunjianshan (BGJ) granite. Recently, comparable systems have been recognized in the south-middle part of weathering BGJ granite. What's more, some of these deposits are relatively heavy REE (HREE) enrichment. In order to investigate the controlling factors of iREE deposit, the south part of BGJ granite has been chosen to study the petrology, mineralogy, geochemistry and chronology. The host rock of BGJ granite is biotite monzogranite, zircon U-Pb date of which is 50.33 Ma (50.33±0.30 Ma, MSWD=0.15), indicating that it was formed in Paleogene. It's the youngest age of parent rock of discovered iREE deposits. BGJ granite with high A/CNK ratios (>1.1), are strongly potassium rich and display peraluminous characteristics similar to S-type granite. BGJ granite is relatively LREE enriched, has strongly fractionated REE patterns (LREE/HREE=2.54~8.98), moderately negative Eu anomalies (Eu/Eu*=0.06~0.17), is high in Rb, Th, and depleted in Ba, Nb, Sr, Zr, Hf, Ti. REE bearing minerals (REE minerals) are the key factor for REE concentration in the rock. The REE minerals in BGJ granite are sphene (∑REE=14506.24×10-6, LREE/HREE=1.14, n =6), allanite (∑REE=232860.82×10-6, n =2), fergusonite, zircon, thorite, fluorite, REE-fluocarbonate; however, apatite, monazite and xenotime are not uncommon. In addition, biotite (∑REE=168.60×10-6, LREE/HREE=1.41, n =10) and feldspar (∑REE=123.60×10-6, LREE/HREE=2.77, n =8) also contribute to REE concentration in the BGJ granite. The REE bearing minerals dissolve in the weathering crust and release REE that could be the source of iREE deposits. Through this study, the following conclusions are obtained: ① REE migrate, fractionate and re-enrich because of the evolution of granite with little change in REE content; ② During granite evolution, REE moved out from the original minerals, subsequently forming secondary REE minerals that are the key to forming iREE (even iHREE) deposits; ③ In bedrock rocks (BGJ granite) of the Long'an iREE deposit, sphene, allanite, thorite, fluorite and REE-fluocarbonate minerals are the main sources of iREE mineralization, followed by feldspar and biotite. These minerals show that relative LREE enrichment led to the formation of iLREE deposit.

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陆蕾,王成辉,王登红,何高文,孙艳.2023.云南邦棍尖山花岗岩的岩石学、地球化学和年代学特征对离子吸附型稀土成矿的制约[J].地质学报,97(5):1494-1507.
LU Lei, WANG Chenghui, WANG Denghong, HE Gaowen, SUN Yan.2023. Constrains on metallogenic mechanism of ion-adsorption type REE deposit from mineralogy, geochemistry and chronology of Banggunjianshan granite, Yunnan Province[J]. Acta Geologica Sinica,97(5):1494-1507.

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  • 收稿日期:2021-10-30
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  • 在线发布日期: 2023-07-13
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