The Lujiang Zongyang ore concentrated area is one of the most important ore concentrated areas in the middle and lower region of the Yangtze River metallogenic belt of China. Five magnetotelluric (MT) sounding profiles have been conducted to understand the relationship between the metallogeny and petrogensis, and the deep conductivity structure. The underground conductivity structures extending from the shallow surface down to 10 kilometers clearly show the boundaries of the buried faults. It also shows the duple structures of the Lujiang Zongyang volcanic basins as well as the characteristics of the Dabie orogeny, the foreland depressed basin and the exposed basements. The electrical resistivity anomalies show that the diorite porphyry hosted copper deposits in Shaxi area is the Dabei orogenic affinity which is different from the volcanic basin in magma evolutionary. The two dimensional inversion results on the three NW SE and the two NE SW directed profiles shows that the NE SW directed conductivity structures are dominant in this area. Inferred from the characteristics of tectonic units which controlled by NE SW trending faults, we find that the Yanshanian structures was inherited from the Indosinian structures.