云南兰坪盆地云龙组上段稀土、微量元素地球化学特征及其环境意义
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Geochemical Characteristics of Rare Earths and Trace Elements, of the Upper Yunlong Formation in Lanping Basin, Yunnan and Its Environments Significance
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    摘要:

    沉积岩的地球化学特征蕴含了大量的地质信息,对于沉积环境的重塑及物源研究具有重要意义。云南兰坪盆地云龙组上段由一层碳酸盐岩及其上覆的碎屑岩组成。通过对碳酸盐岩和碎屑岩的主、微量及稀土元素含量等地球化学特征的研究表明:碳酸盐岩和碎屑岩∑REE总量分别为14265×10-6~18685×10-6和2172×10-6~4837×10-6,均值分别为16744×10-6和3587×10-6,(La/Yb)N值分别介于822~1096和907~1501之间,标准化曲线右倾,表明轻稀土相对重稀土富集。负Eu异常程度中等,3个泥岩样品负Ce异常强烈,其他样品无明显负异常。利用对氧化还原环境最敏感的Ce/ Ce*判断,云龙组上段沉积时期主要为氧化环境,碳酸盐岩沉积时期呈弱氧化性,部分层位为还原环境,氧化性:泥岩>粉砂岩>碳酸盐岩。Sr/Ba比值<075,表明当时为淡水沉积。根据∑REE和(La/Yb)n,结合Fe2O3/MnO、EFMn、CaCO3(%)和Al(%)等其他特征值判断,碎屑岩沉积时期以温暖湿润为主、碳酸盐岩沉积时期以干旱炎热为主的古气候条件,并且存在干湿交替的气候变化。沉积物源来自于上地壳,原始物质主要为长英质岩石,还有部分的中基性岩。

    Abstract:

    Because the characteristics of geochemistry in sedimentary rocks contain lots of geological information, it has a great significance for restoring the sedimentary environment and discussing the provenance. The upper Yunlong Formation in Yunnan Lanping Basin consists of a set of carbonate rocks and its overlying clastic rocks. Through the study of major, trace elements and REE for carbonates and clastic rocks respectively, the results and geochemical characteristics can be concluded as followed: the total ∑REE of carbonate and clastic rocks range from 14265×10-6~18685×10-6 and 2172×10-6~4837×10-6, 16744×10-6 and 3587×10-6 in average respectively. The (La/Yb)N values range from 8.22~10.96 and 9.07~15.01 respectively, the standard curve inclined right which indicate the light rare earth elements enriched compared with heavy rare earth elements. Negative Eu anomalies were in a medium level, negative Ce anomalies of three mudstones were very strong, and other samples show no significant negative Ce anomalies. According to the eigenvalue Ce/Ce* which is the most sensitive about redox environment, the upper Yunlong Formation sedimentary period was mainly in an oxidizing milieu, the sedimentary period of carbonate rocks was in a weak oxidizing milieu and some stages was in relatively reducing milieu, and the mudstone was in the most oxidizing milieu, the siltstone took second place and carbonate rock took the last. Based on ∑REE and (La/Yb)n, Fe2O3/MnO, EF Mn, CaCO3(%) and Al(%), it can indicate that the stage of clastic rocks deposited was in a paleo climate of warm and wet environment, and the stage of carbonate rocks deposited was in a paleo climate of arid and hot environment, and had an alternate changes between drying and wetting at the same time. Sedimentary material source was from the upper continental crust, and consisted of mainly original felsic materials, and intermediate and intermediate mafic matetials.

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沈立建,刘成林,王立成.2015.云南兰坪盆地云龙组上段稀土、微量元素地球化学特征及其环境意义[J].地质学报,89(11):2036-2045.
SHEN Lijian, LIU Chenglin, WANG Licheng.2015. Geochemical Characteristics of Rare Earths and Trace Elements, of the Upper Yunlong Formation in Lanping Basin, Yunnan and Its Environments Significance[J]. Acta Geologica Sinica,89(11):2036-2045.

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  • 在线发布日期: 2015-11-02
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